R EV I E W T E ST- 1

CHEMISTRY
PAPER CODE : A
Class : XIII (XYZ)
Time : 2 hour Max. Marks : 150
INSTRUCTIONS
1. The question paper contain 16 pages and 3-parts. Part-A contains 34 objective questions, Part-B contains
4 Match the Column type questions and Part-C contains 3 subjective questions. All questions are compulsory.
Please ensure that the Question Paper you have received contains all the QUESTIONS and
PAGES. If you find any mistake like missing question(s) or page(s) then contact immediately to
the Invigilator.
PART-A
(i) Q.1 to Q.26 have only one correct alternative and carry 3 marks each.
There is NEGATIVE marking and 1 mark will be deducted for each wrong answer.
(ii) Q.27 to Q.34 have One or more than one is/are correct alternative and carry 4 marks each.
There is NO NEGATIVE marking. Marks will be awarded only if all the correct alternatives are selected.
PART-B
(iii) Q.1 to Q.4 are "Match the Column" type which may have one or more than one matching options.
There is NO NEGATIVE marking. Marks will be awarded only if all the correct alternatives are selected.
PART-C
(iv) Q.1 to Q.3 are "Subjective" questions. There is NO NEGATIVE marking. Marks will be awarded only if
all the correct bubble are filled in you answer sheet.
2. Indicate the correct answer for each question by filling appropriate bubble in your answer sheet.
3. Use only HB pencil for darkening the bubble.
4. Use of Calculator, Log Table, Slide Rule and Mobile is not allowed.

PART-A PART-B PART-C

For example if only 'B' choice is For example if Correct match for Ensure that all columns (3 before
correct then, the correct method for (A) is P, Q; for (B) is P, R; decimal and 2 after decimal) are filled.
filling the bubble is for (C) is P and for (D) is S then the Answer having blank column will be
A B C D correct method for filling the bubble treated as incorrect. Insert leading
is zero(s) if required after rounding the
For example if only 'B & D' choices P Q R S result to 2 decimal places.
are correct then, the correct method (A) e.g. 86 should be filled as 086.00
for filling the bubble is (B) .
A B C D .
(C)
.
the wrong method for filling the (D) .
bubble are .
.
The answer of the questions in wrong .
or any other manner will be treated .
as wrong. .
.
 USEFUL DATA
Atomic weights: Al = 27, Mg = 24, Cu = 63.5, Mn = 55, Cl = 35.5, O = 16, H = 1, P = 31, Ag = 108, N = 14,
Li = 7, I = 127, Cr = 52, K=39, S = 32, Na = 23, C = 12, Br = 80, Fe = 56, Ca = 40, Zn = 65.4,
Radius of nucleus =10–14 m; h = 6.626 ×10–34 Js; me = 9.1 ×10–31 kg

PART-A
Select the correct alternative. (Only one is correct) [26 × 3 = 78]
Q.1 Find f H° for HCl(g) from the following data:
NH3(g) + HCl(g)  NH4Cl(s); rH° = –176 kJ/mole
N2(g) + 3H2(g)  2NH3(g); rH° = –92 kJ/mole
N2(g) + 4H2(g) + Cl2(g)  2NH4Cl(g); rH° = –629 kJ/mole
(A) 536.5 kJ/mol (B) –361 kJ/mol (C) –92.5 kJ/mol (D) None

Q.2 This compound shows:

(A) geometrical isomerism (B) optical isomerism

(C) both (D) none

Q.3 A compound contains three elements A, B and C, if the oxidation number of A = +2, B = +5 and
C = –2, the possible formula of the compound is
(A) A3(B4C)2 (B) A3(BC4)2 (C) A2(BC3)2 (D) ABC2

Q.4 With what minimum pressure (in kPa) must a given volume of nitrogen, originally at 400 K and 100 kPa
pressure, be adiabatically co mpressed in order to raise its temperature to 700 K.
7
Given : Cp,m(N2) = R.
2
(A) 362.5 kPa (B) 12.5 kPa (C) 437.5 kPa (D) None

ROUGH WORK
Q.5 Give the correct order of initials T or F for following statements. Use T if statement is true and F if it is
false.
I. Me–CH=C=C=CH–Br is optically active.
II. All optically active compound are chiral.
III. All chiral pyramidal molecules are optically inactive.
IV CH3–CH2–CH2–COOH and CH 3  CH  CH 3 are positional isomers.
|
COOH
(A) TTTF (B) FTFT (C) FTFF (D) TFTT

Q.6 SbF5 reacts with XeF4 to form an adduct. The shapes of cation and anion in the adduct are respectively.
(A) Square planar, trigonal bipyramidal (B) T-shaped, octahedral
(C) Square pyramidal, octahedral (D) Square planar, octahedral
5
Q.7 A gas (Cv,m = R) behaving ideally was allowed to expand reversibly and adiabatically from 1 litre to
2
32 litre. It's initial temperature was 527°C
M olar Enthalpy Change ( Hm) for the process is
(A) –1500 R Joule (B) –2100 R Joule (C) 2100 Joule (D) None

Q.8 Which pairs of the salts should have identical solubilities in methanol?

(I) (II)

(III) (IV)

(A) I & IV (B) I & III (C) I & II (D) II & IV

ROUGH WORK
 Question No. 9 to 12 (4 questions)
Bond length is the average distance between the nuclei of the two atoms held by a bond. This represents
the internuclear distance corresponding to minimum potential energy for the system. Main factors which
affect the bond length are given below:
(i) Multiple bonds are shorter than corresponding single bonds.
(ii) Some times single bond distances are some what shorter than double of their respective covalent radii
because bonds acquire some partial double bond character. This normally happens when one atom
having vacant orbital and another atom containing lone pair. It is also possible that it becomes shorter
due to high ionic character in the covalent bond.

Q.9 Which is correct about two C–N bond lengths (marked as 'a' and 'b')?

(A) a = b (B) a > b (C) b > a (D) can't be predicted

Q.10 Which is not true about the N–N bond length among the following species?
 
(I) H2N – NH2 (II) N2 (III) H 3 N – N H 3 (IV) N2O
(A) N – N bond length is shortest in II
(B) N–N bond length in I is shorter than that of in III
(C) N–N bond length in III is shorter than that of in I
(D) N–N bond length IV is intermediate between I and II

Q.11 In which of the following case central atom-F bond has partial double bond character?
(A) NF3 (B) CF4 (C) PF3 (D) OF2

Q.12 The C–Cl bond in vinyl chloride is _______ and _______ compared to C–Cl bond in ethyl chloride.
(A) longer, weaker (B) shorter, weaker (C) longer, stronger (D) shorter, stronger

ROUGH WORK
Q.13 For a perfectly crystalline solid Cp,m = aT3 + bT, where a & b are constant. If Cp,m is 0.40 J/K-mol at
10 K and 0.92 J/K-mol at 20 K, then molar entropy at 20 K is
(A) 0.92 J/K-mol (B) 8.66 J/K-mol (C) 0.813 J/K-mol (D) None

Q.14 Ph  CH  CHO
|
OH
( A)
(A) & (B) are isomer and isomerization is effectively carried out by trace of base. Identify isomer (B).
O
||
(A) Ph–CH2–CO2H (B) Ph  C  O  CH 3

O O
|| ||
(C) Ph  C  CH 2  OH (D) H  C  CH 2  O  Ph

Q.15 The molar heat capacities at constant pressure (assumed constant with respect to temperature) of A, B
and C are in ratio of 1.5 : 3.0 : 2.5 . If enthalpy change for the exothermic reaction A + 2B  3C at
300 K and 310 K is H1 and H2 respectively then
(A) H1 > H2 (B) H1 < H2 (C) H1 = H2
(D) If T2 > T1 then H2 > H1 & if T2 < T1 then H2 < H1

Q.16 Choose the correct statement from the following :

(A) Bonds associated in a bridge are of identical length in case of B2H6 and Al(BH4)3.
(B) Bonds associated in a bridge are of different length in case of B2H6 and Al(BH4)3.
(C) Bonds associated in a bridge are of identical length in case of B2H6 but different in case of Al(BH4)3.
(D) Bonds associated in a bridge are of identical length in Al(BH4)3 but different in case of B2H6.

ROUGH WORK
Q.17 Sentene ozonolysis
 

Which is the correct structure of Sentene

(A) (B) (C) (D)

Q.18 The enthalpy changes of the following reactions at 27°C are

1
Na(s) + Cl (g)  NaCl (s) rH = –411 kJ/mol
2 2
H2(g) + S (s) + 2O2 (g)  H2SO4 (l) rH = –811 kJ/mol
2Na(s) + S(s) + 2O2 (g)  Na2SO4 (s) rH = –1382 kJ/mol
1 1
H2(g) + Cl2(g)  HCl (g) rH = –92 kJ/mol; R = 8.3 J/K-mol
2 2
from these data, the heat change of reaction at constant volume ( in kJ/mol) at 27°C for the process
2NaCl (s) + H2SO4 (l)  Na2SO4 (s) + 2HCl (g) is
(A) 67 (B) 62.02 (C) 71.98 (D) None

ROUGH WORK
 Question No. 19 to 23 (5 questions)
Alkanes are halogenated in presence of sunlight. The reaction follows free radical mechanism which
completes in three steps.
h
R  H  X 2  RXHX
(i) Chain initiation (fast)
h
X–X  X° + X°
(ii) Chain propogation (slow)
R–H+X° RDS  H–X + R°
R°+X–X  R–X + X°
(iii) Chain termination (fast)
R° + X°  R – X
R°+ R°  R – R
X° + X°  X – X
Rate of this reaction increasing with stability of free radical formed and ease of its formation.
Rate 1° < 2°<3° (for same halogen)
Rate F2 > Cl2 > Br2 > I2 (for same alkane)
If excess of halogen is used one by one all H are replaced by X.
Q.19 Correct order of rate of photochlorination for following compounds is:
CH 3
|
CH3–CH3 CD3–CD3 CH 3  C  CH 3
|
CH 3
(I) (II) (III)
(A) II < I < III (B) I < II < III (C) III < I < II (D) II < III < I
Q.20 If rate determining step of this reaction is chain initiation not chain propogation what will be the order of
rate of reaction for same alkane?
(A) F2 >Cl2 < Br2 < I2 (B) F2 > Cl2 > Br2 > I2
(C) F2 < Cl2 < Br2 < I2 (D) F2 = Cl2 = Br2 = I2
ROUGH WORK
Q.21 How many possible monochloro products are formed when 2-methoxy propane is treated with Cl2 in
presence of sunlight?
(A) 4 (B) 3 (C) 2 (D) 1

Q.22 Total number of chloro derivative possible for ethane is:

(A) 6 (B) 7 (C) 8 (D) 9
Q.23 Pick the correct statement for monochlorination of R-secbutyl chloride.

Cl
2

300C

(A) There are four possible products ; three are optically active one is optically inactive
(B) There are five possible products ; three are optically inactive & two are optically active
(C) There are five possible products ; two are optically inactive & three are optically active
(D) There are four possible products ; two are optically active & two are optically inactive

Q.24 In which of compounds octet is complete and incomplete for all atoms.
Al2Cl6 Al2(CH3)6 AlF3 Dimer of BeCl2 Dimer of BeH2
(A) IC IC IC C C
(B) C IC IC C IC
(C) C IC C IC IC
(D) IC C IC IC IC
Note: C for complete octet and IC for incomplete octet.

Q.25 Least stable hybride is

(A) stannane (B) Silane (C) Plumbane (D) Germane

Q.26 The ratio of -bond and -bond in tetracyano ethylene is

(A) 2 : 1 (B) 1 : 1 (C) 1 : 2 (D) None

ROUGH WORK
 One or more than one is/are correct [8 × 4 = 32]

Q.27 Which of the following is/are a bicyclo compound(s):

(A) (B) (C) (D)

Q.28 Which of the following statement(s) is/are false?

(A) All adiabatic processes are isoentropic (or isentropic) processes
(B) E = 0 for combustion of C2H6(g) in a sealed rigid adiabatic container
(C) dG = VdP – SdT is applicable for closed system, both PV and non-PV work
(D) The heat of vaporisation of water at 100°C is 40.6 kJ/mol. When 9 gm of water vapour condenses
to liquid at 100°C of 1 atm, then Ssystem = 54.42 J/K

Q.29 Select the incorrect statements:

(A) Hydrogen peroxy phosphate ion contains one P–O–H bond.
(B) PH5 exists but NH5 does not.
(C)  Cl PCl and  Br PBr bond angles are equal in PCl3F2 and PF3Br2 molecule.
(D) According to MOT, in C2 molecule there are two covalent bonds between two C atoms in which
both are bonds.

Q.30 Configuration of is

(A) R (B) S (C) D (D) L

ROUGH WORK
Q.31 Which of the following statement(s) is/are true?
(A) When (Gsystem)T,P < 0; the reaction must be exothermic
(B) f H° (S, monoclinic)  0
(C) If dissociation energy of CH4(g) is 1656 kJ/mole and C2H6 (g) is 2812 kJ/mole, then value of
C–C bond energy will be 328 kJ/mole
(D) If H+(aq) + OH–(aq)  H2O(l) rH° = –56 kJ/mol
f H°(H2O, g) = –242 kJ/mole; Enthalpy of vaporization of liquid water = 44 kJ/mol
–
then, f H°(OH , aq) will be –142 kJ/mole

Q.32 Which of following process is/are associated with change of hybridisation of the underlined compound.
(A) Al(OH)3 ppt. dissolved in NaOH.
(B) B2H6 is dissolved in THF
(C) SiF4 vapour is passed through liq. HF.
(D) Solidification PCl5 vapour.

Q.33 Which of the following is primary amine

(A) t-butyl amine (B) aniline (C) sec. butylamine (D) N-methyl methanamine

Q.34 For H3PO3 and H3PO4, the correct choice is

(A) H3PO3 is dibasic and reducing agent. (B) H3PO3 is dibasic and non reducing agent.
(C) H3PO4 is tribasic and reducing agent (D) H3PO4 is tribasic and non reducing agent.

ROUGH WORK
 P A RT-B
MATCH THE COLUMN [4 × 4 = 16]
Q.1 Match the column-I with column-II, where column I indicates a pair compound and column II indicates
their relationship. Note that column-I may have more than one matching options in column-II.
Column-I Column-II

(A) & (P) Identical

(B) & (Q) Geometrical isomers

(C) & (R) Diastereoisomers

(D) & (S) Enantiomers

ROUGH WORK
Q.2 Match the column-I with column-II, where column I indicates a compound and column II indicates its
configuration. Note that column-I may have more than one matching options in column-II.
Column-I Column-II

(A) (P) 2R 3S

(B) (Q) S

(C) (R) R

(D) (S) 2S 3R

ROUGH WORK
 INSTRUCTIONS:
Column-I and column-II contains four entries each. Entries of column-I are to be matched with some
entries of column-II. One or more than one entries of column-I may have the matching with the same
entries of column-II and one entry of column-I may have one or more than one matching with entries of
column-II.
Q.3 Column - I Column -II
(A) NH4Cl (P) Hydrogen bond
(B) CuSO4.5H2 O (Q) Co-ordinate bond
(C) HNC (R) Ionic bond
(D) Liquid. H2O2 (S) Covalent bond

Q.4 Column - I Column -II

(A) B3N3H6 (P) Planar geometry
(B) S2Cl2 (Q) Non-planar geometry
(C) B2H6 (R) No lone pair
(D) I2Cl6 (S) Non-polar molecule

ROUGH WORK
 PART-C
SUBJECTIVE: [3 × 8 = 24]

Q.1 Calculate f G°| for (NH4Cl, s) at 350 K.

Given: f H°(NH4Cl, s) = –314.5 kJ/mol

SN 2 (g ) = 192 JK–1mol–1; SH 2 (g ) = 130.5 JK–1mol–1

SCl2 ( g ) = 223 JK–1mol–1; SNH 4 Cl(s ) = 94.5 JK–1mol–1; All given data at 300K.

 350 
rCP = –20 J/mol-K ; ln   = 0.15
 300 
Q.2 Fixed amount of an ideal gas contained in a sealed rigid vessel (V = 24.6 litre) at 1.0 bar is heated
reversibly from 27°C to 127°C. Determine change in Gibb's energy (G | in Joule) if entropy of gas
S = 10 + 10–2 T (J/K)
Q.3 One mole of a monoatomic gas behaving ideally is used as
working substance in an engine working in the cycle as shown
in the figure. The process AB, BC, CD and DA are respectively
reversible isobaric, adiabatic, isochoric and isothermal. The ratio
of maximum to minimum volume and temperature during the
cycle is 8 2 and 4 respectively. If the maximum T is 800 K
and  = 5/3. Calculate E ( in kJ) for the process BC.
Given R = 8.3 J/K-mol.