R EV I E W T E ST- 3

Class : XIII (XYZ)

Time : 3 hour Max. Marks : 276
INSTRUCTIONS
1. The question paper contain 28 pages and 3-parts. Part-A contains 9 objective question, Part-B contains
9 questions of "Match the Column" type and Part-C contains 15 subjective type questions. All questions are compulsory.
Please ensure that the Question Paper you have received contains all the QUESTIONS and Pages. If you found some
mistake like missing questions or pages then contact immediately to the Invigilator.
PART-A
(i) Q.1 to Q.9 have More than one are correct alternative and carry 6 marks each.
There is NEGATIVE marking. 1 mark will be deducted for each wrong answer.
PART-B
(iii) Q.1 to Q.9 are "Match the Column" type which may have one or more than one matching options and carry 8 marks
for each question. 2 marks will be awarded for each correct match within a question.
There is NEGATIVE marking. 0.5 Marks will be deducted for each wrong match. Marks will be awarded only if all the
correct alternatives are selected.
PART-C
(iv) Q.1 to Q.15 are "Subjective" questions and carry 10 marks for each. There is NO NEGATIVE marking. Marks will be
awarded only if all the correct bubble are filled in you answer sheet.
2. Indicate the correct answer for each question by filling appropriate bubble in your answer sheet.
3. Use only HB pencil for darkening the bubble.
4. Use of Calculator, Log Table, Slide Rule and Mobile is not allowed.
5. The answer(s) of the questions must be marked by shading the circles against the question by dark HB pencil only.
USEFUL DATA
Atomic weights: Al = 27, Mg = 24, Cu = 63.5, Mn = 55, Cl = 35.5, O = 16, H = 1, P = 31, Ag = 108, N = 14, Li = 7, I = 127, Cr = 52, K=39,
S = 32, Na = 23, C = 12, Br = 80, Fe = 56, Ca = 40, Zn = 65.4,
Radius of nucleus =10–14 m; h = 6.626 ×10–34 Js; me = 9.1 ×10–31 kg, R = 109637 cm–1
PART-A PART-B PART-C
For example if only 'B' choice For example if Correct match Ensure that all columns
is correct then, the correct for (A) is P, Q; for (B) is P, R; (3 before decimal and 2 after
method for filling the bubble for (C) is P and for (D) is S decimal) are filled. Answer
is then the correct method for having blank column will be
A B C D filling the bubble is treated as incorrect. Insert
P Q R S leading zero(s) if required after
(A) rounding the result to 2
For example if only 'B & D' decimal places.
choices are correct then, the (B) e.g. 86 should be filled as
correct method for filling the 0086.00
bubble is (C) .
A B C D .
(D) .
the wrong method for filling
the bubble are .
.
The answer of the questions .
in wrong or any other manner .
will be treated as wrong. .
.
.
 Take g = 10 m/s2 where ever required in this paper.
P ART-A
Select the correct alternative. (More than one is/are correct) [9 × 6 = 54]
There is NEGATIVE marking. 1 mark will be deducted for each wrong answer.

Q.1 The function f (x) is defined for x  0 and has its inverse g (x) which is differentiable. If f (x) satisfies
g(x )

 f ( t) dt = x2 and g (0) = 0 then

0
(A) f (x) is an odd linear polynomial (B) f (x) is some quadratic polynomial
(C) f (2) = 1 (D) g (2) = 4

Q.2 Consider a triangle ABC in xy plane with D, E and F as the middle points of the sides BC, CA and AB
respectively. If the coordinates of the points D, E and F are (3/2, 3/2); (7/2, 0) and (0, – 1/2) then which
of the following are correct?
(A) circumcentre of the triangle ABC does not lie inside the triangle.
(B) orthocentre, centroid, circumcentre and incentre of triangle DEF are collinear but of triangle ABC
are non collinear.
(C) Equation of a line passes through the orthocentre of triangle ABC and perpendicular to its plane is

r  2( î  ˆj)   k̂
5 2
(D) distance between centroid and orthocentre of the triangle ABC is .
3
x x
Q.3 If a continuous function f (x) satisfies the relation,  t f ( x  t ) dt =  f (t) dt + sin x + cos x – x – 1, for
0 0
all real numbers x, then which of the following does not hold good?

(A) f (0) = 1 (B) f ' (0) = 0 (C) f '' (0) = 2 (D)  f ( x ) dx = e
0
ROUGH WORK
Q.4 Stepwise hydrolysis of P4O10 takes place via formation of
(A) Tetrametaphosphoric acid
(B) Tetrapolyphosphoric acid
(C) Pyrophosphoric acid
(D) Orthophosphoric acid

Q.5 Monochlorination of (S)-2-chlorobutane can give

(A) (S)-1,2-dichlorobutane (B) (R)-1,2- dichlorobutane
(C) (2R, 3S)-2,3-dichlorobutane (D) (2R,3R)-2,3-dichlorobutane

Q.6 Select the correct statement about the compound NO[BF4]

(A) It has 5  and 2  bond
(B) Nitrogen-oxygen bond length is higher than nitric oxide (NO)
(C) It is a diamagnetic specie
(D) B–F bond length in this compound is lower than in BF3.

ROUGH WORK
Q.7 A blast breaks a body initially at rest of mass 0.5 kg into three pieces, two smaller pieces of equal mass
and the third double the mass of either of small piece. After the blast the two smaller masses move at right
angles to one another with equal speed. Find the statements that is/are true for this case assuming that the
energy of blast is totally transferred to masses.
(A) All the three pieces share the energy of blast equally
(B) The speed of bigger mass is 2 times the speed of either of the smaller mass
(C) The direction of motion of bigger mass makes an angle of 135° with the direction of smaller pieces
(D) The bigger piece carries double the energy of either piece.

Q.8 You wish to lift a heavy block through a height h by attaching a string of negligible mass to it and
pulling so that it moves at a constant velocity. You have the choice of lifting it either by pulling the
string (i) vertically upward or (ii) along a frictionless inclined plane (see diagram).Which one of the
following statements is true?

(A) The magnitude of the tension force in the string is smaller in case (i) than in case (ii).
(B) The work done on the block by the tension force is the same in both cases.
(C) The work done on the block by the tension force is smaller in case (ii) than in case (i).
(D) The work done on the block by the gravitational force is smaller in case (ii) than in case (i).

Q.9 The wires A and B shown in the figure are made of the same material and have radii
rA and rB respectively. The block between them has a mass m. When the force F is
mg/3, one of the wires breaks.
(A) A breaks if rA = rB
(B) A breaks if r A < 2rB
(C) Either A or B may break if r A = 2rB
(D) The lengths of A and B must be known to predict which wire will break
ROUGH WORK
 P A RT-B
MATCH THE COLUMN [9 × 8 = 72]
There is NEGATIVE marking. 0.5 mark will be deducted for each wrong match within a question.
INSTRUCTIONS:
Column-I and column-II contains four entries each. Entries of column-I are to be matched with some
entries of column-II. One or more than one entries of column-I may have the matching with the same entries
of column-II and one entry of column-I may have one or more than one matching with entries of column-II.
Q.1 Column I Column II
x
ln x dt
(A) Lim is (P) 0
x  x 3 ln t
e

 x 4 1 2
1  1
(B) Lim  e  ex  is (Q)
x    2
( n  1) 
(C) Lim ( 1) n sin   n 2  0.5n  1  sin is where n  N (R) 1
n   4n
 x 
tan 1 
1 
 x 1
(D) The value of the integral  2
dx is (S) non existent
0 1  1  2 x  2 x
tan  

 2 
 3  4 a b
Q.2 APT
Consider the matrices A = 1  1  and B = 0 1 and let P be any orthogonal matrix and Q = PAP
   
and R = PTQKP also S = PBPT and T = PTSKP
Column I Column II
(A) If we vary K from 1 to n then the first row (P) G.P. with common ratio a
first column elements at R will form
(B) If we vary K from 1 to n then the 2nd row 2nd (Q) A.P. with common difference 2
column elements at R will form
(C) If we vary K from 1 to n then the first row first (R) G.P. with common ratio b
column elements of T will form
(D) If we vary K from 3 to n then the first row 2nd column (S) A.P. with common difference – 2.
elements of T will represent the sum of
Q.3 Column I Column II
     
(A) Given two vectors a and b such that | a |  | b | = | a  b | = 1 (P) 30°
  
The angle between the vectors 2a  b and a is
(B) In a scalene triangle ABC, if a cos A = b cos B (Q) 45°
then  C equals
(C) In a triangle ABC, BC = 1 and AC = 2. The maximum possible (R) 60°
value which the  A can have is
(D) In a  ABC  B = 75° and BC = 2AD where AD is the (S) 90°
altitude from A, then  C equals
Q.4 Match the column:
Column I Column II

(A) (P) Conformation of maximum torsional strain

(B) (Q) Conformation with strong intramolecular hydrogen bond

(C) (R) Highest boiling point

(D) (S) Conformation of minimum Vander Waal strain

Q.5 Column I Column II
(Co-ordination compound) (Type of isomerism shown)
(A) Na2[Pt(SCN)2(Ox)2] (P) Ionization isomerism
(B) [CrCl2(NH3)4]NO3 (Q) Linkage isomerism
(C) [Pt(NO2)(Gly)(NH3)] (R) Geometrical isomerism
(D) K3[Fe(OH)2(C2O4)2 ] (S) Optical isomerism

Q.6 Match the names of carboxylic acids in column I with pka value in column II.
Column I Column II
(A) Benzoic acid (P) 4.17
(B) Ethanoic acid (Q) 4.14
(C) o-methyl benzoic acid (R) 4.74
(D) p-flourobenzoic acid (S) 3.91
Q.7 A glass disk whose plane surfaces are parallel is cut as shown in figure then the lenses so
obtained are moved apart. What will happen to a beam of parallel rays falling on to the
system. ( f is the focal length of converging lens).
EFFECT

(A) (P) Emerging rays are converging & image distance from L2 < f

(B) (Q) Emerging rays are diverging & image distance from L2 < f

(C) (R) Emerging rays are converging & image distance from L2 > f

(D) (S) Emerging rays are diverging & image distance from L2 > f
Q.8 A body initially moving towards right explodes into two pieces 1 and 2. Direction of motion of the pieces
is shown in column I and possible mass ratio are shown in column II
Column I Column II

(A) (P) m1 > m2

(B) (Q) m1 = m2

(C) , v1 > v2 (R) m1 < m2

(D) (S) Impossible for any masses

Q.9 A projectile is launched at angle  to horizontal from L and it hits the target T on level ground.
Column I Column II
(A) Magnitude of radial acceleration (P) Increases
(B) Magnitude of tangential acceleration (Q) Decreases
(C) Power delivered by gravity (R) First increases, then decreases
(D) Torque of gravity about T (S) First decreases, then increases
 P ART-C
SUBJECTIVE: [15 × 10 =150]
2
1 96V
Q.1 Suppose V =  x sin 2 x  dx , find the value of .
2 
0
 m n
Q.2 One of the roots of the equation 2000x6 + 100x5 + 10x3 + x – 2 = 0 is of the form , where m
r
is non zero integer and n and r are relatively prime natural numbers. Find the value of m + n + r.
Q.3 A circle C is tangent to the x and y axis in the first quadrant at the points P and Q respectively. BC and
AD are parallel tangents to the circle with slope – 1. If the points A and B are on the y-axis while C and
D are on the x-axis and the area of the figure ABCD is 900 2 sq. units then find the radius of the circle.
Q.4 Let f (x) = ax2 – 4ax + b (a > 0) be defined in 1  x  5. Suppose the average of the maximum value and
the minimum value of the function is 14, and the difference between the maximum value and minimum
value is 18. Find the value of a2 + b2.
 1  1 1  ax  1 2 3
Q.5 If the Lim 3
   exists and has the value equal to l, then find the value of   .
x 0 x  1  x 1  bx  a l b
Q.6 Calculate the Hvaporization [CH3COOH( l )] in kJ/mol
Given data
Hsolution [KF. CH3COOH(s)] in glacial acetic acid = –3 kJ/mole
Hsolution [KF(s)] in glacial acetic acid = +35 kJ/mole
The strength of H-bond between F–(g) and CH3COOH (g) = +46 kJ/mole
Lattice enthalpy of KF.CH3COOH(s) = +734 kJ/mole
Lattice Enthalpy of KF(s) = +797 kJ/mole
Q.7 The gaseous decomposition reaction
A(g)  2B(g) + C(g)
is observed to first order over the excess of liquid water at 25°C, it is found that at the end of 10 min, the
total pressure of system is 188 torr and after very long time it is 388 torr.
Calculate rate constant of the reaction (in hr–1)
Given : vapour pressure of H2O at 25° is 28 torr (ln2 = 0.7, ln3 = 1.1, ln10 = 2.3)
Q.8 When 1 mole of A(g) is introduced in a closed rigid 1 litre vessel maintained at constant temperature the
following equilibria are established.
A (g) l B(g) + C(g) : KC
1

C (g) l D(g) + B(g) : KC

2

KC [C]eq 1
2
The pressure at equilibrium is twice the initial pressure. Calculate the value of if =
KC [ B]eq 5
1
Q.9 Total entropy change (system + surrounding) for the process H2O (l ,–8°C) H2O (s, –8°C) at 1 atm
and – 8°C is 1 J/K mol.
Find Cp,m (H2O, l) in J/K mol.
Given : Hmelting(at –8°C) = + 5784.95 J/mol, Hmelting(at 0°C) =6006 J/mol
 273 
Cp,m(H2O, s) = 36 J/K mol ln   = 0.03
 265 
Q.10 The equilibrium constant Kp for the reaction
N2O4 (g) l 2NO2(g) is 4.5 at temperature T.
What would be the average molar mass (in gm/mol) of an equilibrium mixture of N2O4 & NO2 formed
by the dissociation of pure N2O4 at a total pressure of 2 atm at temperature T.
Q.11 A rocket is projected straight up and explodes into three equally massive fragments just as it reaches the
top of its flight (refer figure). One of the fragments is observed to come straight down in 2 sec, while the
other two take 4 sec to come to ground, after the burst. Find the height h (in m) at which the fragmentation
occurred.
Q.12 Board A is placed on board B as shown. Both boards slide, without moving with respect to each other,
along a frictionless horizontal surface at a speed 6 m/s. Board B hits a resulting board C "head-on". After
the collision, boards B and C stick together and board A slides on top of board C and stops its motion
relative to C in the position shown on the diagram. What is the length (in m) of each board? All three
boards have the same mass, size and shape. The coefficient of kinetic friction between boards A and C
and between boards A & B is .
Q.13 A side view of a simplified form of vertical latch B is as shown. The lower
member A can be pushed forward in its horizontal channel. The sides of
the channels are smooth, but at the interfaces of A and B, which are at
45° with the horizontal, there exists a static coefficient of friction = 0.4.
What is the minimum force F (in N) that must be applied horizontally to A
to start motion of the latch B if it has a mass m = 0.6 kg ?
Q.14 The essential elements of one form of simple speed governor are as shown:
to a vertical shaft a horizontal rod is mounted symmetrically and on the
horizontal rod are freely sliding brake shoes. When the shaft turns at a
frequency of rotation f = 10 Hz, the brake shoes press against the inner
surface of a stationary cylindrical brake drum. If the brake shoes are each
of mass m = 1kg, and their thickness dimension is negligible compared to
the inner radius of the brake drum r =0.1 m, and the coefficient of sliding
friction between the shoes and the drum is = 0.5, find the power
required in watt to turn the governor shaft.
[Take: 2 = 10]
Q.15 A ring of mass m = 1 kg can slide over a smooth vertical rod. A light string attached
to the ring passing over a smooth fixed pulley at a distance of L = 0.7 m from the
rod as shown in the figure. At the other end of the string mass M = 5 kg is attached,
lying over a smooth fixed inclined plane of inclination angle 37°. The ring is held in
level with the pulley and released. Determine the velocity of ring (in m/s) when the
string makes an angle (  37°) with the horizontal. [sin37°=0.6]