R EV I E W T E ST- 2

C
H E
M I
STRY
Class : XIII (XYZ)
Time : 2 hour PAPER CODE : A Max. Marks : 160
INSTRUCTIONS
1. The question paper contain 12 pages and 3-parts. Part-A contains 32 objective question, Part-B contains
3 questions of "Match the Column" type and Part-C contains 4 subjective type questions. All questions are
compulsory. Please ensure that the Question Paper you have received contains all the QUESTIONS
and Pages. If you found some mistake like missing questions or pages then contact immediately to
the Invigilator.
PART-A
(i) Q.1 to Q.16 have only one correct alternative and carry 3 marks each.
There is NEGATIVE marking. 1 mark will be deducted for each wrong answer.
(ii) Q.17 to Q.25 have only one correct alternative and carry 4 marks each.
There is NEGATIVE marking. 1 mark will be deducted for each wrong answer.
(ii) Q.26 to Q.32 have One or more than one is / are correct alternative and carry 4 marks each.
There is NO NEGATIVE marking. Marks will be awarded only if all the correct alternatives are selected.
PART-B
(iii) Q.1 to Q.3 are "Match the Column" type which may have one or more than one match and carry 2 marks
for each correct match. There is NEGATIVE marking. 0.5 Marks will be deducted for each wrong
match. Marks will be awarded only if all the correct alternatives are selected.
PART-C
(iv) Q.1 to Q.4 are "Subjective" questions. There is NO NEGATIVE marking. Marks will be awarded only if
all the correct bubble are filled in you answer sheet.
2. Indicate the correct answer for each question by filling appropriate bubble in your answer sheet.
3. Use only HB pencil for darkening the bubble.
4. Use of Calculator, Log Table, Slide Rule and Mobile is not allowed.
5. The answer(s) of the questions must be marked by shading the circles against the question by dark HB pencil only.
PART-A PART-B PART-C
For example if only 'B' choice is For example if Correct match for Ensure that all columns (3 before
correct then, the correct method for (A) is P, Q; for (B) is P, R; decimal and 2 after decimal) are filled.
filling the bubble is for (C) is P and for (D) is S then the Answer having blank column will be
A B C D correct method for filling the bubble treated as incorrect. Insert leading
is zero(s) if required after rounding the
For example if only 'B & D' choices P Q R S result to 2 decimal places.
are correct then, the correct method (A) e.g. 86 should be filled as 0086.00
for filling the bubble is (B) .
A B C D .
(C)
.
the wrong method for filling the (D) .
bubble are .
.
The answer of the questions in wrong .
or any other manner will be treated .
as wrong. .
.
 P ART-A
Select the correct alternative. (Only one is correct) [16 × 3 = 48]

Q.1 For the hypothetical reaction

A2(g) + B2(g) l 2AB(g)
rG° and rS° are 20 kJ/mol & –20 JK–1 mol–1 respectively at 200 K.
If rCp is 20 JK–1 mol–1 then rH° at 400 K is
(A*) 20 kJ / mol (B) 7.98 kJ/mol (C) 28 kJ / mol (D) None

Q.2 Which of the following compounds can exist in optically active form
(A) 1-butanol (B*) 2-butanol (C) 3-pentanol (D) 4-heptanol

Q.3 "Solubility of Alkali metal fluorides increases down the group" Select correct explanation for given
statement.
(A) Hydration energy increases and lattice energy decreases down the group
(B) Both energy decrease down the group but decrease in hydration energy is rapid
(C*) Both energy decrease down the group but decrease in lattice energy is rapid
(D) Both energy increase down the group but increase in hydration energy is rapid

Q.4 For the reaction

N2H4 (g)  N2H2 (g) + H2(g) rH° = 109 kJ / mol
Calculate the bond enthalpy of N = N.
Given : B.E. (N–N) = 163 kJ/mol, B.E. (N–H) = 391 kJ/mol, B.E. (H–H) = 436 kJ/mol
(A) 182 kJ/mol (B) 218 kJ/mol (C*) 400 kJ/mol (D) None

Q.5 What can be said about the magnitude of the equilibrium constant K for the following process?

(A) K = 1 (B) K > 1

(C*) K < 1 (D) No estimate of K can be made

Q.6 Inorganic benzene reacts with HCl to form a compound B3N3H9Cl3. The protonation occurs at
(A) B-atom
(B*) N-atom
(C) First at B-atom then rearranges into N–atom
(D) First at N-atom then rearranges into B-atom

Q.7 Calculate the enthalpy change for the given reaction from data provided (kJ/mole)
HA (g) + B(g)  AHB(s)
(weak acid) (weak acid) (Salt)
Hneutralization {HA(aq) [at infinite dilution] / B(aq)[at infinite dilution]}= – 40 kJ/mole
Hsolution [HA(g)] = –10 kJ/mole {at infinite dilution}
Hsolution [B(g)] = –5 kJ/mole {at infinite dilution}
Hsolution [HAB(s)] = +8 kJ/mole {at infinite dilution}
(A) –36 (B*) –63 (C) –45 (D) –37
 Questions No. 8 to 10 (3 questions)
Isomers which are nonsuper-imposable mirror images of each other are called enantiomers. All optically
active compounds exhibit enantiomerism. The stereoisomers which are not mirror images of each other
are called diastereomers. Enantiomers are always chiral molecules whereas diastereomers may or may
not be chiral, configuration of the compound having no element of symmetry is always chiral. Chiral
molecule may or may not contain chiral carbon.
Q.8 Which of the following compounds are chiral?

(A) (B)

(C) (D*) All of these

Q.9 Which of the following pairs are diastereomers ?

(A) and (B) and

(C*) and (D) All of these

Q.10 Which one of the following pairs is correctly matched?

(A) enantiomers: (B*) Diastereomers:

and and

(C) meso form (D) Enantiomer

and

Q.11 Which of the following have X–O–X linkage (where X is central atom)
(i) Cr2O 72 (ii) S2O 32 (iii) Pyrosilicate (iv) Hyponitrus acid
(A*) (i) (iii) (B) (iii) (iv) (C) (i) (iii) (iv) (D) (i) (ii)
Q.12 The work done (calories) in adiabatic compression of 2 moles of ideal monoatomic gas against constant
external pressure of 2 atm starting from initial pressure of 1 atm and initial temperature of 300 K.
(R = 2cal / mole degree)
(A) 360 (B*) 720 (C) 800 (D) 1000

Q.13 If CdI2 is pink in colour, the CdCl2 will be '_______' coloured

(A) Yellow (B) Red (C) Blue (D*) Can not be predicted

Q.14 The enthalpy of gas phase trimerization of one mole of gaseous fermaldehyde in (kJ/mole)
Bond energies (kJ/mole)
C O C O C  H
3H2CO (g)  (g)
700 360 410

(A*) –20 (B) –60 (C) –10 (D) –50

Q.15 The correct increasing order of extent of hydrolysis is

(A*) CCl4 < MgCl2 < AlCl3 < SiCl4 < PCl5
(B) CCl4 < AlCl3 < MgCl2< PCl5 < SiCl4
(C) CCl4 < SiCl4 < PCl5 < AlCl3 < MgCl2
(D) CCl4 < PCl5 < SiCl4 < AlCl3 < MgCl2

Q.16 Which of the following is correct skeleton for Ge–N–C–O in H3GeNCO molecule

(A) (B) (C) (D*)

Select the correct alternative. (Only one is correct) [9 × 4 = 36]

Q.17 If enthalpy of hydrogenation of C6H6(l) into C6H12(l) is –205 kJ & resonance energy of C6H6(l)
–152 kJ/mol then enthalpy of hydrogenation of 1,4-cyclohexadiene (l) is
Assume Hvap of C6H6(l), C6H8(l), C6H12(l) all are equal
(A) –535.5 kJ/mol (B*) –238 kJ/mol (C) –357 kJ/mol (D) None

Q.18 Four Newman projection formula of compound CH2OH–CHOH–CHOH–CHO are shown below:

(I) (II) (III) (IV)

Which of the above represents erythro isomer?

(A*) I and IV (B) I and II (C) II and IV (D) I and III

Q.19 Give the correct order of initials T or F for following statements. Use T if statement is true and F if it is
false.
I. (CH3)2P(CF3)3 is non polar & (CH3)3P(CF3)2 is polar molecule
^
II. CH 3 P CH 3 bond angles are equal in (CH3)3P(CF3)2 molecule
III. PF3 will be more soluble in polar solvent than SiF4
(A) TTF (B) FFT (C) FFF (D*) FTT
Q.20 The enthalpy of combustion of methane gas in terms of given data is
Bond energy (kJ/mole)
C H OO C O O H Re sonance Energy CO 2  R (kJ / mol)
 X1  X 2  X 3  X 4 H vaporizati on [H 2 O(l )]  Y (kJ / mol)

(A*) 4X1 + 2X2 – 2X3– 4X4 – R – Y (B) 4X1 + 2X2 – 2X3 – 4X4 + R–Y
(C) 4X1 + 2X2 – 2X3– 4X4 + R+Y (D) 4X1 + 4X2 – 2X3 – 4X4 + R – Y
Q.21 An optically pure compound X gave an [ ]25
D = + 20.0°. A mixture of X and its enantiomer Y gave

[]25
D = +10°. The ratio of X to Y in the mixture is
(A) 2 : 1 (B) 1 : 3 (C*) 3 : 1 (D) 1 : 2

Q.22 The total number of -bonds in fullerene are

(A) 60 (B) 120 (C*) 90 (D) 150

Q.23 (a) Et3N (b) (c)

Compare basic strength of following:
(A) a > b > c (B) b > a > c (C*) b > c > a (D) c > b > a

Q.24 Nodal planes of  bond(s) in CH2=C=C=CH2 are located in

(A) All are in molecular plane
(B*) Two in molecular plane and one in a plane perpendicular to molecular plane which contains C–C
-bond
(C) One in molecular plane and two in plane perpendicular to molecular plane which contains C–C
-bond
(D) Two in molecular plane and one in a plane perpendicular to molecular plane which bisects C–C
-bond at right angle

Q.25 Stereoisomers possible for following compound is

(A*) 8 (B) 16 (C) 32 (D) 64

Select the correct alternative. (More than one are correct) [7 × 4 = 28]

Q.26 The normal boiling point of a liquid 'A' is 300 K. Which of the following statement is true about the
process A(l)  A(g)
(A*) at 300 K and 1 atm pressure G = 0 (B*) at 300 K and 2 atm pressure G = +ve
(C*) at 300 K and 0.1 atm pressure G = –ve (D) at 310 K and 1 atm pressure G = +ve
Q.27 Which of the following statement are correct?
(A*) & are chain isomer

(B*) & are position isomer

(C*) & are tautomers

(D*) & (enantiomer)

Q.28 Which of the following statements is/are incorrect for following species:
BO33 , CO 32 , NO3
(A) They are isoelectronic and isostructural.
(B*) They have same bond order for E–O bond, where E is the central atom.
(C*) The extent of -bonding is in the order of CO32  NO3  BO33 .
(D) Bond angles are same in every cases.

Q.29 Which of the following compounds is optically active?

(A) (B*)

(C*) (D)

Q.30 Silane is more reactive than CH4 due to

(A*) larger size of Si compared to C which facililates the attack by nucleophile.
(B*) Polarity of Si–H bond is opposite to that of C–H bond.
(C*) Availability of vacant 3d orbitals in case of Si to form the reaction intermediate easily.
(D*) Si–H bond energy is lower than that of C–H bond.

Q.31 Which of the following double bond will not exhibit geometrical isomerism.

(A*) (B*) (C) (D) Me–N=N–Me

Q.32 If NB is the number of bonding electrons and NA is the number of antibonding electrons of a molecule.
Then choose the incorrect statement(s) for the given relationship,
NB > NA
(A) Molecule may be stable or unstable
(B*) Molecule may have any integral, fractional or zero value of bond order
(C*) Molecule is only paramagnetic species
(D*) Molecule does not exist

P A RT-B
MATCH THE COLUMN [3 × 8 = 24]

INSTRUCTIONS:
Column-I and column-II contains four entries each. Entries of column-I are to be matched with some
entries of column-II. One or more than one entries of column-I may have the matching with the some
entries of column-II.

Q.1 Column I Column II

(A) Sheet silicate (P) (SiO 3 ) 2n n 

(B) Pyroxene chain (Q) (Si 4O11 )6nn 

(C) Pyro silicate (R) 3-Corner oxygen atoms are shared
(D) Amphibole chain (S) Non-planar
[Ans. (A) R,S; (B) P, S; (C) S; (D) Q,S ]

Q.2 Carefully observe the given diagrams which indicates standard heat of formation of different states of
one mole Mg and 2 mole Cl atom and match the entries in column A and B provided.

Column I Column II
(A) Hf [Mg2+ (aq)] (P) – 1900 kJ/mole
(B) Hf [Cl– (aq)] (Q) + 460 kJ/mole
(C) Hhydration [Mg2+ (g)] (R) – 625 kJ/mole
(D) L.E.MgCl (S) + 2510 kJ/mole
2 (s )

L.E. = Lattice energy

[Ans. (A) Q, (B) R, (C) P, (D) S]
Q.3 Column I Column II

(A) (P) Chiral

(B) (Q) Plane of symmetry

(C) (R) S

(D) (S) E (Entegen)

[Ans. (A) P,R,S (B) P, R, (C) P, S, (D) P]

P ART-C
SUBJECTIVE:

Q.1 At 500 kilobar pressure density of diamond and graphite are 3 g/cc and 2 g/cc respectively, at certain
temperature 'T'. Find the value of |H – U| for the conversion of 1 mole of graphite to 1 mole of
diamond at temperature 'T'. [5]
[Sol. C (graphite)  C (diamond)
H = U + P2V2 – P1V1
 12 12  48 48
H – U = (500 × 103 × 105 N/m2)    × 10–6 = × 500 × 102 J = × 104 J
 3 2 35 7
= 500 × 2×103 ×105 × 10–6
= 100 kJ /mole ]

Q.2 0.1 mole of a gaseous compound B is mixed with 0.5 mole of solid A in a constant volume adiabatic
bomb calorimeter in which A and B react according to reaction
3A (s) + 2B (g)  3C (g) + 4D (l) : H = ?
The temperature inside the calorimeter rose to 310 K from 300 K as a result of complete reaction.
The mixture of products now cooled back to original temperature at 300 K. Now a current of strength
100 mA flowing across a potential gradient of 10 Volt is passed for 1974 seconds through the calorimeter
system which restores the temperature of product mixture to 310 K. Find H of given reaction
(calories). [Use R = 2 calories/degree mole, 1 calorie = 4.2 Joule] [5]
[Ans. – 8800 (calorie)]
 10  0.1 1974
[Sol. qv =
4. 2
qv
U = ×2
0.1

3 5
Q.3 0.5 mole each of two ideal gases A (Cv = R) and B (Cv = R) are taken in a container and expanded
2 2
reversibly and adiabatically from V = 1 L to V = 4 L starting from initial temperature T = 300 K. Find
|H| for the process in (Cal/mol). [7]
dV
[Sol. n1Cv1dT + n2Cv2dT = –(n1RT + n2RT)
V
dT R dV
 =–
T Cv V

T2 1 V2
ln T = – ln V
1 2 1

1/ 2
T2  V1 
 =  
T1 V 
 2
T1 T1
T2 – T1 = – T1 = –
2 2
1 3  1 5 
H =  R  R  +  R  R  (T)
2 2  2 2 
1
= (6R)T = 3RT = –3(2)(150) = – 900 calories ]
2

1
Q.4 mol of an ideal monatomic gas undergoes a reversible process for which PV2 = C. The gas is
22.4
expanded from initial volume of 1 L to final volume of 2 L starting from initial temperature of 273 K. Find
the heat exchanged q during the process. Express your answer in litre atm. [7]
22.4
R= litre atm mole–1 degree–1. [Ans. –0.25 (litre atm)]
273
[Sol. P2 V22 = P1 V12
2
P2  V1 
 =  
P1 V 
 2
T2 P2 V2 V 1 273
Now = = 1 =  T2 = K
T1 P1V1 V2 2 2
 dV
dW = – PdV = –C
V2
Upon integration
 1 1  P2 V2  nRT1 R 1
W = + C  V  V  = [P2V2 – P1V1] = nRT
T1  P V 1 = – = – × 273 ×
 2 1
  1 1  2 2 22.4

1
=– (litre atm)
2
dU = q + W
q = nCv T – W
1 3  273  1  3 1  1
=– · R·   + =  –   lit atm = – litre atm = – 0.25 litre atm. ]
22.4 2  2  2  2 2 4