R EV I E W T E ST- 3

PAPER-
2
Class : XIII
Time : 3 hour Max. Marks : 276
INSTRUCTIONS
1. The question paper contain 28 pages and 3-parts. Part-A contains 9 objective question, Part-B contains
9 questions of "Match the Column" type and Part-C contains 15 subjective type questions. All questions are compulsory.
Please ensure that the Question Paper you have received contains all the QUESTIONS and Pages. If you find some
mistake like missing questions or pages then contact immediately to the Invigilator.
PART-A
(i) Q.1 to Q.9 have More than one are correct alternative and carry 6 marks each.
There is NEGATIVE marking. 1 mark will be deducted for each wrong answer.
PART-B
(iii) Q.1 to Q.9 are "Match the Column" type which may have one or more than one matching options and carry 8 marks
for each question. 2 marks will be awarded for each correct match within a question.
There is NEGATIVE marking. 0.5 Marks will be deducted for each wrong match. Marks will be awarded only if all the
correct alternatives are selected.
PART-C
(iv) Q.1 to Q.15 are "Subjective" questions and carry 10 marks for each. There is NO NEGATIVE marking. Marks will be
awarded only if all the correct bubble are filled in you answer sheet.
2. Indicate the correct answer for each question by filling appropriate bubble in your answer sheet.
3. Use only HB pencil for darkening the bubble.
4. Use of Calculator, Log Table, Slide Rule and Mobile is not allowed.
5. The answer(s) of the questions must be marked by shading the circles against the question by dark HB pencil only.
USEFUL DATA
Atomic weights: Al = 27, Mg = 24, Cu = 63.5, Mn = 55, Cl = 35.5, O = 16, H = 1, P = 31, Ag = 108, N = 14, Li = 7, I = 127, Cr = 52, K=39,
S = 32, Na = 23, C = 12, Br = 80, Fe = 56, Ca = 40, Zn = 65.4,
Radius of nucleus =10–14 m; h = 6.626 ×10–34 Js; me = 9.1 ×10–31 kg, R = 109637 cm–1
PART-A PART-B PART-C
For example if only 'B' choice For example if Correct match Ensure that all columns
is correct then, the correct for (A) is P, Q; for (B) is P, R; (3 before decimal and 2 after
method for filling the bubble for (C) is P and for (D) is S decimal) are filled. Answer
is then the correct method for having blank column will be
A B C D filling the bubble is treated as incorrect. Insert
P Q R S leading zero(s) if required after
(A) rounding the result to 2
For example if only 'B & D' decimal places.
choices are correct then, the (B) e.g. 86 should be filled as
correct method for filling the 0086.00
bubble is (C) .
A B C D .
(D) .
the wrong method for filling
the bubble are .
.
The answer of the questions .
in wrong or any other manner .
will be treated as wrong. .
.
.
 Take g = 10 m/s2 where ever required in this paper.
P ART-A
Select the correct alternative. (More than one is/are correct) [9 × 6 = 54]
There is NEGATIVE marking. 1 mark will be deducted for each wrong answer.

Q.1 The function f (x) is defined for x  0 and has its inverse g (x) which is differentiable. If f (x) satisfies
g(x )

 f ( t) dt = x2 and g (0) = 0 then

0
(A) f (x) is an odd linear polynomial (B) f (x) is some quadratic polynomial
(C) f (2) = 1 (D) g (2) = 4

Q.2 Consider a triangle ABC in xy plane with D, E and F as the middle points of the sides BC, CA and AB
respectively. If the coordinates of the points D, E and F are (3/2, 3/2); (7/2, 0) and (0, – 1/2) then which
of the following are correct?
(A) circumcentre of the triangle ABC does not lie inside the triangle.
(B) orthocentre, centroid, circumcentre and incentre of triangle DEF are collinear but of triangle ABC
are non collinear.
(C) Equation of a line passes through the orthocentre of triangle ABC and perpendicular to its plane is

r  2( î  ˆj)   k̂
5 2
(D) distance between centroid and orthocentre of the triangle ABC is .
3
x x
Q.3 If a continuous function f (x) satisfies the relation,  t f ( x  t ) dt =  f (t) dt + sin x + cos x – x – 1, for
0 0
all real numbers x, then which of the following does not hold good?

(A) f (0) = 1 (B) f ' (0) = 0 (C) f '' (0) = 2 (D)  f ( x ) dx = e
0
ROUGH WORK

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Q.4 Which of the reactions can be predicted by the colour of the product
(A ) M n2+ + NaBiO3 + HNO3  HMnO4 + Bi(NO3)3 + NaNO3 + H2O
(B) Fe3+ + [Fe(CN)6]3–  Fe[Fe(CN)6]
(C) PO43– + (NH4)2MoO4 + HNO3  (NH4)3PMo12O40 + NH4NO3
(D) (NH4)2S2  (NH4)2S + (NH4)2S3

Q.5 Select the correct statement

(A) on treatment with NaCN retains its configuration

(B) on reaction with NaN3 changes its configuration

(C) reacts faster than on treatment with H2O according to first

order rate kinetics

(D) CH2 = CH–CH2–CH2–Br on treament with water undergoes solvolysis with very high rate and
yields CH2=CH–CH2–CH2–OH

ROUGH WORK

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Q.6 Select the correct statement(s)
(A) 30 butyl alcohol on treament with brosyl chloride followed by mixture (equimolar) of NH4Cl, NH4Br,
NH4I, results more iodide product than chloride
(B) on treament with Tosyl chloride followed by equimolar mixture of NH4Cl, NH4Br,,

NH4I results more Iodide product than Bromide.

(C) Organic compound on reaction with aq. KOH gives EtOH by

second order rate kinetics.

(D) None of these

Q.7 Interference fringes are obtained in YDSE (performed in air) on a screen. Which of the following
statements will be correct about the effect of introducing a thin transparent plate in the path of one of
interfering wave
(A) The separation between fringes remain unaffected.
(B) The entire fringe pattern shifts towards the side on which plate is placed.

(C) The condition for maxima and minima must reversed i.e. maxima for odd multiple of and minima
2

for even multiple of .
2
(D) shape of the fringe remains unaffected.

ROUGH WORK

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Q.8 You wish to lift a heavy block through a height h by attaching a string of negligible mass to it and
pulling so that it moves at a constant velocity. You have the choice of lifting it either by pulling the
string (i) vertically upward or (ii) along a frictionless inclined plane (see diagram).Which one of the
following statements is true?

(A) The magnitude of the tension force in the string is smaller in case (i) than in case (ii).
(B) The work done on the block by the tension force is the same in both cases.
(C) The work done on the block by the tension force is smaller in case (ii) than in case (i).
(D) The work done on the block by the gravitational force is smaller in case (ii) than in case (i).

Q.9 A real object is placed infront of a convex mirror (focal length f) . It moves towards the mirror, the image
also moves. If Vi = speed of image and V0 = speed of the object and u is the distance of object from
mirror along principal axis, then
(A) Vi < V0 if |u| < |F| (B) Vi > V0 if |u| > |F|
(C) Vi < V0 if |u| > |F| (D) Vi = V0 if |u| = |F|

ROUGH WORK

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 P A RT-B
MATCH THE COLUMN [9 × 8 = 72]
There is NEGATIVE marking. 0.5 mark will be deducted for each wrong match within a question.
INSTRUCTIONS:
Column-I and column-II contains four entries each. Entries of column-I are to be matched with some
entries of column-II. One or more than one entries of column-I may have the matching with the same entries
of column-II and one entry of column-I may have one or more than one matching with entries of column-II.
Q.1 Column I Column II
x
ln x dt
(A) Lim is (P) 0
x  x 3 ln t
e

 x 4 1 2
1  1
(B) Lim  e  ex  is (Q)
x    2
( n  1) 
(C) Lim ( 1) n sin   n 2  0.5n  1  sin is where n  N (R) 1
n   4n
 x 
tan 1 
1 
 x 1
(D) The value of the integral  2
dx is (S) non existent
0 1  1  2 x  2 x
tan  

 2 

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 3  4 a b
Q.2 APT
Consider the matrices A = 1  1  and B = 0 1 and let P be any orthogonal matrix and Q = PAP
   
and R = PTQKP also S = PBPT and T = PTSKP
Column I Column II
(A) If we vary K from 1 to n then the first row (P) G.P. with common ratio a
first column elements at R will form
(B) If we vary K from 1 to n then the 2nd row 2nd (Q) A.P. with common difference 2
column elements at R will form
(C) If we vary K from 1 to n then the first row first (R) G.P. with common ratio b
column elements of T will form
(D) If we vary K from 3 to n then the first row 2nd column (S) A.P. with common difference – 2.
elements of T will represent the sum of

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Q.3 Column I Column II
     
(A) Given two vectors a and b such that | a |  | b | = | a  b | = 1 (P) 30°
  
The angle between the vectors 2a  b and a is
(B) In a scalene triangle ABC, if a cos A = b cos B (Q) 45°
then  C equals
(C) In a triangle ABC, BC = 1 and AC = 2. The maximum possible (R) 60°
value which the  A can have is
(D) In a  ABC  B = 75° and BC = 2AD where AD is the (S) 90°
altitude from A, then  C equals

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Q.4 Match the column:
Column I Column II

(A) (P) Conformation of maximum torsional strain

(B) (Q) Conformation with strong intramolecular hydrogen bond

(C) (R) Highest boiling point

(D) (S) Conformation of minimum Vander Waal strain

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Q.5 Reaction Type
(A) Substitution nucleophilic bi molecular (P) 10 > 20 > 30 halides
(B) Elimination unimolecular (Q) 30 > 20 > 10 halides
(C) Substitution nucleophilic unimolecular (R) Racemization of configuration
(D) Elimination bi molecular (S) Inversion of configuration

Q.6 Reaction Intermediate Name of the Reaction

(A) Carbocation (P) –elimination
(B) Cl2 (Q) E1 & S N 1

(C) (R) Reimmer Tiemann reaction

(D) (S) Hoffmann Bromoamide degradation

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Q.7 A glass disk whose plane surfaces are parallel is cut in two parts as shown in figure then
the lenses so obtained are moved apart. What will happen to a beam of parallel rays
falling on to the system. ( f is the focal length of converging lens).
COLUMN I COLUMN II (EFFECT)

(A) (P) Emerging rays are converging & image distance from L2 < f

(B) (Q) Emerging rays are diverging & image distance from L2 < f

(C) (R) Emerging rays are converging & image distance from L2 > f

(D) (S) Emerging rays are diverging & image distance from L2 > f

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Q.8 A body initially moving towards right explodes into two pieces 1 and 2 having masses m1 and m2.
Direction of motion of the pieces is shown in column I and possible mass ratio are shown in column II
Column I Column II

(A) (P) m1 > m2

(B) (Q) m1 = m2

(C) , v1 > v2 (R) m1 < m2

(D) (S) Impossible for any masses

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Q.9 A projectile is launched at angle  to the horizontal from point L and it hits the target T on level ground.
Column I Column II
(A) Magnitude of radial acceleration (P) Increases
(B) Magnitude of tangential acceleration (Q) Decreases
(C) Power delivered by gravity (R) First increases, then decreases
(D) Torque of gravity about T (S) First decreases, then increases

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 P ART-C
SUBJECTIVE: [15 × 10 =150]
2
1 96V
Q.1 Suppose V =  x sin 2 x  dx , find the value of .
2 
0

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 m n
Q.2 One of the roots of the equation 2000x6 + 100x5 + 10x3 + x – 2 = 0 is of the form , where m
r
is non zero integer and n and r are relatively prime natural numbers. Find the value of m + n + r.

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Q.3 A circle C is tangent to the x and y axis in the first quadrant at the points P and Q respectively. BC and
AD are parallel tangents to the circle with slope – 1. If the points A and B are on the y-axis while C and
D are on the x-axis and the area of the figure ABCD is 900 2 sq. units then find the radius of the circle.

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Q.4 Let f (x) = ax2 – 4ax + b (a > 0) be defined in 1  x  5. Suppose the average of the maximum value and
the minimum value of the function is 14, and the difference between the maximum value and minimum
value is 18. Find the value of a2 + b2.

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 1  1 1  ax  1 2 3
Q.5 If the Lim 3
   exists and has the value equal to l, then find the value of   .
x 0 x  1  x 1  bx  a l b

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Q.6 The specific rotation for a pure enantiomer is known to be –390g–1ml–1dm–1. A sample containing both
enantiomers is found to have a an observed rotation of –0.620 in a one dm tube at a concentration of 3.5
g/100ml. What is the optical purity of the sample.

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   A  
Q.7 EtO
 K
  Reaction intermedia te 
Ph C C  Ph
 B EtO
 K

HBr
 C  D

Write the formula weight of D.

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Q.8 When 1 mole of A(g) is introduced in a closed rigid 1 litre vessel maintained at constant temperature the
following equilibria are established.
A (g) B(g) + C(g) : KC
1

C (g) D(g) + B(g) : KC

2

KC [C]eq 1
2
The pressure at equilibrium is twice the initial pressure. Calculate the value of if =
KC [ B]eq 5
1

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Q.9 500 ml of 0.2 M aqueous solution of acetic acid is mixed with 500 ml of 0.2 M HCl at 250C
(i) Calculate the pH of the resulting solution. (not to be reported)
(ii) If 6 gm of NaOH is added to the above solution, determine the final pH. (not to be reported)
[Assume there is no change in volume on mixing, Given pKa of CH3COOH = 4.74]
Report your answer as a sum of pH in 1st case and pH in 2nd cases.

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Q.10 The equilibrium constant Kp for the reaction
N2O4 (g) 2NO2(g) is 4.5 at temperature T..
What would be the average molar mass (in gm/mol) of an equilibrium mixture of N2O4 & NO2 formed
by the dissociation of pure N2O4 at a total pressure of 2 atm at temperature T.

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Q.11 A boy sitting at the rear end of a railway comparment of a train, running at a constant acceleration on
horizontal rails, throws a ball towards the fore end of the compartment with velocity 20m/s (relative to
train) at an angle 370 above the horizontal, when the train is running at speed of 10m/s. If same boy
catches the ball without moving from seat & at the same height of projection. Then find the speed of train
at the instant of his catching the ball. (Here g = 10m/s2, sin370 = 3 / 5 )

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Q.12 Board A is placed on board B as shown. Both boards slide, without moving with respect to each other,
along a frictionless horizontal surface at a speed 6 m/s. Board B hits a resulting board C "head-on". After
the collision, boards B and C stick together and board A slides on top of board C and stops its motion
relative to C in the position shown on the diagram. What is the length (in m) of each board? All three
boards have the same mass, size and shape. The coefficient of kinetic friction between boards A and C
and between boards A & B is . (here g = 10 m/s2)

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Q.13 A side view of a simplified form of vertical latch B is as shown. The lower
member A can be pushed forward in its horizontal channel. The sides of
the channels are smooth, but at the interfaces of A and B, which are at
45° with the horizontal, there exists a static coefficient of friction = 0.4.
What is the minimum force F (in N) that must be applied horizontally to A
to start motion of the latch B if it has a mass m = 0.6 kg ?

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Q.14 The essential elements of one form of simple speed governor are as shown:
to a vertical shaft a horizontal rod is mounted symmetrically and on the
horizontal rod there are freely sliding (no friction) brake shoes. When the
shaft turns at a frequency of rotation f = 10 Hz, the brake shoes press
against the inner surface of a stationary cylindrical brake drum. If the brake
shoes are each of mass m = 1kg, and their thickness dimension is negligible
compared to the inner radius of the brake drum r =0.1 m, and the coefficient
of sliding friction between the shoes and the drum is = 0.5, find the
power required in watt to turn the governor shaft.
[Take:  2 = 10]

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Q.15 In a Young's double slit experiment a light of wavelength  = 5000 Å is used. When a thin film of
transparent material is put behind one of the slits the central bright fringe moves to the position previously
occupied by the 4th order bright fringe. The refractive index of film is n = 1.2 . Then calculate the
thickness of film in micrometer (m)

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