R EV I E W T E ST- 5

Class : XIII
Time : 3 hour Max. Marks : 243
INSTRUCTIONS
1. The question paper contain 26 pages and 4-parts. Part-A contains 9 objective question, Part-B contains
6 questions of "Match the Column" type and Part-C contains 15 and Part-D contains 2 subjective type questions. All
questions are compulsory. Please ensure that the Question Paper you have received contains all the QUESTIONS and
Pages. If you found some mistake like missing questions or pages then contact immediately to the Invigilator.
PART-A
(i) Q.1 to Q.9 have One or More than one is / are correct alternative(s) and carry 5 marks each.
There is NEGATIVE marking. 1 mark will be deducted for each wrong answer.
PART-B
(iii) Q.1 to Q.6 are "Match the Column" type which may have one or more than one matching options and carry 8 marks
for each question. 2 marks will be awarded for each correct match within a question.
There is NEGATIVE marking. 0.5 Marks will be deducted for each wrong match. Marks will be awarded only if all the
correct alternatives are selected.
PART-C
(iv) Q.1 to Q.15 are "Subjective" questions. There is NO NEGATIVE marking. Marks will be awarded only if all the correct
bubbles are filled in your OMR sheet.
PART-D
(iv) Q.1 to Q.2 are "Subjective" questions. There is NO NEGATIVE marking. Marks will be awarded only if all the correct
bubbles are filled in your OMR sheet.
2. Indicate the correct answer for each question by filling appropriate bubble(s) in your answer sheet.
3. Use only HB pencil for darkening the bubble(s).
4. Use of Calculator, Log Table, Slide Rule and Mobile is not allowed.
5. The answer(s) of the questions must be marked by shading the circles against the question by dark HB pencil only.

PART-A PART-B PART-C PART-D

For example if only 'B' choice
is correct then, the correct
method for filling the bubble
is
A B C D
For example if only 'B & D'
choices are correct then, the
correct method for filling the
bubbles is
A B C D
The answer of the question
in any other manner (such as
putting , cross , or
partial shading etc.) will
be treated as wrong.
For example if Correct match Ensure that all columns Ensure that all columns
for (A) is P, Q; for (B) is P, R; (4 before decimal and 2 after {1 before decimal and 2 after
for (C) is P and for (D) is S decimal) are filled. Answer decimal with proper sign (+)
then the correct method for having blank column will be or (–)} are filled and columns
filling the bubble is treated as incorrect. Insert after 'E' used for filling power
P Q R S leading zero(s) if required after of 10 with proper sign (+) or
(A) rounding the result to 2 (–). Answer having blank
decimal places. column will be treated as
(B) e.g. 86 should be filled as incorrect.
0086.00 e.g. – 4.19 × 1027 should be
(C) . filled as – 4.19 E + 27
.
(D) .
.
.
.
.
.
.
.
 P ART-A
Select the correct alternative. (One or more than one are correct) [9 × 5 = 45]
[Take g = 10 m/s2]
Q.1 Which of the following is/are correct?
(A) If centre of mass of three particles is at rest and it is known that two of them are moving along
different lines then the third particle must also be moving.
(B) If centre of mass remains at rest, then net work done by the forces acting on the system must be zero.
(C) If centre of mass remains at rest then the net external force must be zero.
(D) If speed of centre of mass is changing then there must be some net work being done on the system

Q.2 A thin uniform rod of mass m and length l is free to rotate about its upper end. When it is at rest, it
recieves an impulse J as its lowest point, normal to its length. Immediately, after impact
(A) the angular momentum of rod about its centre of mass is Jl.
3J
(B) the angular velocity of rod is
ml
3J 2
(C) the kinetic energy of rod is
2m
3J
(D) the linear velocity of mid point of rod is .
2m

Q.3 Which of the following statements is/are true

(A) work done by kinetic friction on a rigid body may be positive
(B) a uniform sphere rolls up an inclined plane without sliding. The friction force on it will be up the
incline. (only contact force and gravitational force is acting)
(C) a uniform sphere rolls down an inclined plane without sliding. The friction force on it will be up the
incline. (only contact force and gravitational force is acting)
(D) a uniform sphere is left from rest from the top of a rough inclined plane. It moves down the plane with
slipping. The friction force on it will be up the incline always.
Q.4 Which of the following is(are) wrong
(A) A molecular orbitals of benzene has two non bonding molecular orbitals
(B) Carbene is sp2 hybridised only
(C) On adding solute in volatile solvent reduced the entropy
(D) MeCONH2 gives bad smelling substance with CHCl3 + KOH

Q.5 Which is/are correct statement(s)?

(A) Yellow ammonium sulphide is suitable reagent for the sepration of CdS and As2S3.
(B) When borax is added in water the pH is remains constant (almost) on adding small amount of HCl
and NaOH seprately.
(C) Na2B4O7.4H2O is known as borax.
(D) The pH and structure of B(OH)3 is different at different concentrations.

Q.6 Which of the following will decolourise bromine water

(A) CH2 = CH2 (B) HC  CH (C) (D)

Q.7 Let a1, a2, a3 ....... and b1, b2, b3 ...... be arithmetic progressions such that a1 = 25, b1 = 75 and
a100 + b100 = 100. Then
(A) the difference between successive terms in progression 'a' is opposite of the difference in progression 'b'.
(B) an + bn = 100 for any n.
(C) (a1 + b1), (a2 + b2), (a3 + b3), ....... are in A.P.
100
(D)  (a r  b r ) = 10000
r 1

1
x    x[ x ] if x  0
Q.8 Let f (x) =   x  where [x] denotes the greatest integer function, then the correct

0 if x  0
statements are
(A) Limit exists for x = – 1.
(B) f (x) has a removable discontinuity at x = 1.
(C) f (x) has a non removable discontinuity at x = 2.
(D) f (x) is discontinuous at all positive integers.

Q.9 f ''(x) > 0 for all x  [–3, 4], then which of the following are always true?
(A) f (x) has a relative minimum on (–3, 4)
(B) f (x) has a minimum on [–3, 4]
(C) f (x) is concave upwards on [–3, 4]
(D) if f (3) = f (4) then f (x) has a critical point on [–3, 4]
 P A RT-B
MATCH THE COLUMN [2 × 8 = 16]
INSTRUCTIONS:
Column-I and column-II contains four entries each. Entries of column-I are to be matched with some
entries of column-II. One or more than one entries of column-I may have the matching with the same entries
of column-II and one entry of column-I may have one or more than one matching with entries of column-I

Q1. A particle P strikes the uniform rod R normally at a distance x from hinge
as shown. The rod of length l is suspended vertically with upper end hinged.
Arrangement For the collision
l
(A) If x = , elastic collision (P) Linear momentum of (P+R) system increases
2
(B) If x = l, elastic collision (Q) Linear momentum of (P+R) system decreases
l
(C) If x = , P sticks to R (R) KE of the particle P decreases
2
(D) If x = l, P sticks to R (S) Angular momentum of the (P+R) system is
conserved about hinge.
Q.2 A uniform yo-yo is resting on a perfectly rough horizontal table. Forces F1, F2, F3 and F4 are applied
separately as shown.
Column I Column II

(A) (P) centre of mass of yo-yo accelerates towards left

(B) (Q) center of mass of yo-yo accelerates towards right

(C) (R) friction on yo-yo acts towards left

(D) (S) friction of yo-yo acts towards right

Q.3 Column I Column II
(Pair of complexes) (Property which is similar in given pair)

(A) (P) Cis

(B) (Q) trans

(C) (R) CH3 (diaxial)

(D) (S) CH3 (diequitorial)

Q.4 Column-I (Carbanions) Column -II (Half lives)

(a) (P) 4.3 × 10–8 s

(b) (Q) 2.5 × 10–5 s

(c) (R) 8.7 × 10–7 s

(d) (S) 1.4 × 10–4 s

Q.52 Column–I Column–II
(A) Let Z = (cos 12° + i sin 12° + cos 48° + i sin 48°)6 (P) –1
then Im(z) is equal to

(B)
x 0
 
Lim ln sin 3 x  ln (x 4  ex 3 ) equals (Q) 0

(C) If twice the square on the diameter of a circle is equal to the (R) 1
sum of the squares on the sides of the inscribed triangle ABC
then sin2A + sin2B + sin2C equals
(D) Let g (x) be a function such that g(a + b) = g(a) · g(b) (S) 2
for all real numbers a and b. If 0 is not an element of the
range of g then g (x) · g(–x) equals

Q.62 Column I Column II

(A) ABC is a triangle. If P is a point inside the ABC such that (P) centroid
areas of the triangles PBC, PCA and PAB are equal, then
w.r.t the ABC, P is its (Q) orthocentre
  
(B) If a , b, c are the position vectors of the three non collinear
points A, B and C respectively such that the vector (R) Incentre

V  P A  P B  P C is a null vector then w.r.t.
the ABC, P is its
(C) If P is a point inside the ABC such that the vector (S) circumcentre

R  (BC)(P A)  (CA )(P B)  (AB)(P C) is a null vector then
w.r.t. the ABC, P is its
(D) If P is a point in the plane of the triangle ABC such that the
scalar product P A ·C B and P B ·A C , vanishes then w.r.t.
the ABC, P is its
 P ART-C
SUBJECTIVE:
Q.1 We would like to increase the length of a 15 cm long copper rod of cross-section 4 mm2 by 1mm. The
energy absorbed by the rod if it is heated is E1. The energy absorbed by the rod if it is stretched slowly
is E2. Then find E1/E2.
[Various parameters of Copper are: Density = 9 × 103 kg/m3, Thermal coefficient of linear expansion
= 16 × 10–6 K–1, Young's modulus = 135 × 109 Pa, Specific heat = 400 J/kg-K] [10]
Q.2 One side of a spring of initial, unstretched length l0 = 1 m, lying on a frictionless table, is fixed, the other
one is fastened to a small puck of mass m = 0.1 kg. The puck is given velocity in a direction perpendicular
to the spring, at an initial speed v0 = 11 m/s. In the course of the motion, the maximum elongation of the
spring is l=l0/10. What is the force constant of the spring (in SI units)? [10]
Q.3 A direct-vision prism is made out of three prisms, each with a refracting angle of 60o, attached to each
other as shown in the figure. Light of a certain wavelength is incident on the first prism. The angle of
incidence is 30o and the ray leaves the third prism parallel to the direction of incidence. The refractive
index of the glass of the first and third prisms is 1.5. Find the refractive index of the material of the middle
prism. ( 6 = 2.45) [10]
Q.4 A uniform rod of cross-section area A = 0.20 cm2 is bent to form a ring.
The length of rod L = 60 cm. Three points on this ring P1, P2 & P3 are
maintained at temperature 800C, 800C & 1100C. Here P1P2 = P2P3 =
P3P1. The thermal conductivity of material of rod K = 385 W/m0C.
Neglect the heat loss through lateral side. Find the rate of heat flow
(in watt) in branch P3 to P1. [10]
Q.5 A solid uniform cylinder of mass m = 6 kg and radius r = 0.1 m is kept in balance on a slope of inclination
= 37° with the help of a thread fastened to its jacket. The cylinder does not slip on the slope. What is
the minimum required coefficient of friction to keep the cylinder in balance when the thread is held
vertically? [10]
Q.6 Calculate the number of moles of gas present in the container of
volume 10 lit at 300 K. If the manometer containing glycerin
shows 5m difference in level as shown in diagram.
Given: dglycerin = 2.72 gm/ml, dmercury = 13.6 gm/ml. [6]
Q.7 A gaseous mixture containing N2 & H2 in mole ratio 1 : 3 is used to carry out the reaction in a sealed
container.
N2 (g) + 3H2(g)  2NH3 (g)
The total pressure was 0.8 atm at 25°C before the reaction. Determine final pressure at 323°C assuming
60% dissociation of reaction. [6]
Q.8 Equimolar mixture of two gases A2 and B2 is taken in a container of volume 'V' at temperature 300 K.
At constant temperature the gases reacts according to given equations:
A2 (g) 2A (g) Kp = ?
B2 (g) 2B (g) Kp = ?
A2 (g) + B2 (g) 2AB Kp = 2 atm
If the initial pressure in the container was 2 atm and final pressure developed at equilibrium is 2.75 atm
in which equilibrium partial pressure of gas AB was 0.5 atm, find equilibrium constant Kp for the reaction.
AB (g) A (g) + B (g)
(Temperature & Volume of container remain constant throughout the experiment). [8]
Q.9 Fluorocarbon polymers can be made by fluorinating polyethylene according to the reaction
(CH2)n + 4nCoF3  (CF2)n + 2nHF + 4nCoF2, where n is a large integer. The CoF3 can be
regenerated by the reaction 2 CoF2 + F2  2CoF3. If HF can be recovered and electrolyzed to
hydrogen and fluorine, and if this fluorine is used for regenerating CoF3, what is the net consumption of
fluorine per kg of fluorocarbon ? (F = 19, Co = 58) [8]
Q.10 For the reaction,
Cl2O (g) + H2O (g) 2HOCl (g) : Kp = 0.1 at 300 K
º
The value of equilibrium constant is 0.1. From the given data, find H f [ HOCl ( g )] (in kJ/mol). (All data
given at 300 K)
H of [Cl2O(g)] = + 77 kJ/mol

H of [H2O(g)] = –242 kJ/mol

 rSo = 15.91 J/K mole

ln X
Take [R = 8.3 JK–1 mol–1 ; log X = 2.3] [8]
Q.11 ABCD is a tetrahedron with pv's of its angular points as A(–5, 22, 5); B(1, 2, 3); C(4, 3, 2) and
D(–1, 2, – 3). If the area of the triangle AEF where the quadrilaterals ABDE and ABCF are parallelograms
is S then find the value of S. [10]
 1
tan 1 x  ln 2
Q.12 If the value of the definite integral  1  x dx is equal to k then find the value of k. [10]
0
Q.13 Suppose f : R  R+ be a differentiable function and satisfies 3 f (x + y) = f (x) · f (y) for all x, y  R with
3
  1 
f (1) = 6. If U = Lim n f
n 
1    f (1)  and V =
 n
 f ( x) dx . Find the value of (U·V). [10]
 0
Q.14 The sides of a triangle are consecutive integers n, n + 1 and n + 2 and the largest angle is twice the
smallest angle. Find n. [10]
 3x 2  mx  n
Q.15 f : R  R, f (x) = . If the range of this function is [– 4, 3) then find the value of (m2 + n2).
x2 1
[10]
 P ART-D

Q.1 How many gm of solid NaOH must be added to 100 ml of a buffer solution which is 0.1 M each w.r.t.
acid HA and salt Na + A – to make the pH of so lutio n 5.5. Given pK a (HA) = 5.
(antilog (0.5) = 3.16) [6]
 k
Q.2 The kinetic data for the given reaction A (aq) + 2B (aq) 
 C is provided in the following table for
three experiments at 300 K

Ex. No. [A / M ] [B / M ] Initial rate (M sec 1 )

1 0.01 0.01 6.930  10 6
2 0.02 0.01 1.386 10 5
3 0.02 0.02 1.386 10 5
In another experiment starting with initial concentration of 0.5 and 1 mole respectively for A & B at
300K, find the rate of reaction after 16.667 minutes from start of experiment in (M/sec). [8]