R E VI E W T E S T- 6

Class : XIII
Time : 3 hour PAPER CODE : B Max. Marks : 225
INSTRUCTIONS

1. The question paper contains 45 questions and 15 pages. Each question carry 5 marks and all of them are
compulsory. There is NEGATIVE marking. 1 mark will be deducted for each wrong answer.
Please ensure that the Question Paper you have received contains all the QUESTIONS and
Pages. If you found some mistake like missing questions or pages then contact immediately to the
Invigilator.

2. Indicate the correct answer(s) for each question by filling appropriate bubble(s) in your OMR sheet.

3. Use only HB pencil for darkening the bubble(s).

4. Use of Calculator, Log Table, Slide Rule and Mobile is not allowed.

5. For example if only 'B' choice is correct then, the correct method for filling the bubble is
A B C D

For example if only 'B & D' choices are correct then, the correct method for filling the bubbles is
A B C D

The answer of the question in any other manner (such as putting , cross , or partial shading etc.)
will be treated as wrong.

USEFUL DATA
Atomic Mass: Al = 27, Mg = 24, Cu = 63.5, Mn = 55, Cl = 35.5, O = 16, H = 1, P = 31, Ag = 108, N = 14,
Li = 7, I = 127, Cr = 52, K=39, S = 32, Na = 23, C = 12, Br = 80, Fe = 56, Ca = 40, Zn = 65.4, Ba = 137,
Co = 59, Hg = 200, Pb = 207, He = 4, F=19.
Radius of nucleus =10–14 m; h = 6.626 ×10–34 Js; me = 9.1 ×10–31 kg, R = 109637 cm–1.
 Select the correct alternative(s). (One or More than one is/are correct) [45 × 5 = 225]
There is NEGATIVE marking. 1 mark will be deducted for each wrong answer.

Q.1 The right hand derivative of f (x – 1) = 2x2 – 3x + 1 at x = k where k  I, is

(A) 4k + 1 (B) 2k + 1 (C) 2k – 1 (D) 4k – 3
5 sin 3 x cos x
Q.2 Which of the following numbers is the maximum value of the function f (x) = ,  x  R?
tan 2 x  1
(A) 5/8 (B) 3/4 (C) 1 (D) 5/2

3 3
Q.3 The equation x3 – x=– is satisfied by
4 8
 5   7   17    23 
(A) x = cos   (B) x = cos   (C) x = cos   (D) x = cos  
 18   18   18   18 

Q.4 The number 916238457 is an example of nine digit number which contains each of the digit 1 to 9
exactly once. It also has the property that the digit 1 to 5 occur in their natural order, while the digit 1 to 6
do not. Number of such numbers are
(A) 2268 (B) 2520 (C) 2975 (D) 1560
v( u  z)
Q.5 Let u, v, w, z be complex numbers such that | u | < 1, | v | = 1 and w = u z  1 , then
(A) | w |  1  |z|1 (B) | w |  1  |z|1
(C) | w |  1  |z|1 (D) | w |  1  |z|1
x
Q.6 A function f (x) satisfies f (x) = sin x +  f ' (t) (2 sin t – sin2t) dt then f (x) is
0
x sin x 1 cos x tan x
(A) (B) (C) (D)
1  sin x 1  sin x cos x 1  sin x

ROUGH WORK
Q.7 If A and B are different matrices satisfying A3 = B3 and A2B = B2A, then
(A) det (A2 + B2) must be zero.
(B) det (A – B) must be zero.
(C) det (A2 + B2) as well as det (A – B) must be zero.
(D) At least one of det (A2 + B2) or det (A – B) must be zero.

Q.8 Suppose we are given a point P on the Argand plane represented by the complex number Z, moving
anticlockwise along the circle with | z | = 2 from the point of complex number 2 + 0i to 0 + 2i.
Z 1
If  = then the path described by Q which represents the complex number  is
Z2
(A) a line with gradient 1/3 passing through the origin.
(B) a circle
(C) a segment of line 4x – 3 =0 with y varying from [0, 1/4]
(D) a line 4x – 3 = 0 with y varying from [0, )

Q.9 If the line passing through (–2, 1, b) and (4, 1, 2) is perpendicular to the vector î  3ˆj  2k̂ and is parallel
to the plane containing the vectors î  c k̂ and c ˆj  b k̂ then the ordered pair (b, c) is

 1  1
(A)   1,   (B) (1, – 6) (C) (– 1, 0) (D)   1, 
 2  2

Q.10 A committee of three persons is to be randomly selected from a group of three men and two women and
the chair person will be randomly selected from the committee. The probability that the committee will
have exactly two women and one man, and that the chair person will be a woman, is
1 8 2 3
(A) (B) (C) (D)
5 15 3 10

ROUGH WORK
Q.11 A circle having centre (0, k) with k > 6 is tangent to the lines pair x2 – y2 = 0 and y = 6. The radius of
the circle is
(A) 6( 2 – 1) (B) 12 (C) 6 2 (D) 6 2 + 6

cos 2n x if x  0

Q.12 The function defined as f (x) = Lim  n
1 xn if 0  x  1 . Which of the following does not
n 
 1
if x  1
1 xn
hold good?
(A) continuous at x = 0 but discontinuous at x = 1.
(B) continuous at x = 1 but discontinuous at x = 0.
(C) continuous both at x = 1 and x = 0.
(D) discontinuous both at x = 1 and x = 0.
Q.13 The ends A and B of a rod of length 5 are sliding along the curve y = 2x2. Let xA and xB be the
dx
x-coordinate of the ends. At the moment when A is at (0, 0) and B is at (1, 2) the derivative B has the
dx A
value equal to
(A) 1/3 (B) 1/5 (C) 1/8 (D) 1/9

Q.14 Which of the following function(s) satisfy the hypothesis of Rolle's theorem in the stated interval?
(A) f (x) = 1 – x2/3 in [–1, 1] (B) f (x) = x x  6 in [–6, 0]
(C) f (x) = (x – 1)–2 in [0, 2] (D) f (x) = x3 – 3x2 + 2x + 5 in [0, 2]

Q.15 The line which contains all points (x, y, z) which are of the form (x, y, z) = (2, –2, 5) + (1, –3, 2)
intersects the plane 2x – 3y + 4z = 163 at P and intersects the YZ plane at Q. If the distance PQ is a b
where a, b are relatively prime and a > 3 then (a + b) equals
(A) 23 (B) 95 (C) 27 (D) none

ROUGH WORK
Take g = 10 m/s2 where ever required.
Q.16 In the diagram shown, in steady state
(A) Charge on 1 f capacitor is 1 C
(B) Charge on 2 f capacitor is 2 C
(C) Charge on 3 f is zero
(D) Potential difference across 2f capacitor is 2 volt

Q.17 A particle of mass 'm' is projected with velocity u at an angle '' with the horizontal. The coefficient of
restitution for any of its impact with the smooth ground is e.

2u sin 
(A) Total time taken by the particle before it stops moving vertically is
g1  e 
u 2 sin 2
(B) Total horizontal distance moved in the time before it stops moving vertically is
2g (1  e)
(C) Average force on the particle over the time interval in which it makes first 'n' impacts with ground
mg
equals (1 – e) directed upwards.
2
(D) Average force on the particle over the time interval in which it makes first 'n' impact equals
mg
(1 – e) directed downwards
2
Q.18 The time period of a particle executing SHM is T. There is a point P, at a distance x from the mean
position O. When the particle passes P towards OP (moving away from mean position O), it has
speed V then find the time in which it return to P again
T  VT   VT  T  VT 
(A) T (B) tan 1   (C) Tsin–1   (D) cot 1  
  2x   x  2  2x 
ROUGH WORK
Q.19 Which of the following is sufficient condition for finding the electric flux E through a closed surface?

(A) If the magnitude of E is known everywhere on the surface
(B) If the total charge inside the surface is specified
(C) If the total charge outside the surface is specified
(D) Only if the location of each point charge inside the surface is specified

Q.20 The spring is compressed by a distance a and released. The block again comes to rest when the spring
is elongated by a distance b. During this process
1
(A) work done by the spring on the block = k(a2 + b2)
2
1
(B) work done by the spring on the block = k(a2 – b2)
2
k (a  b )
(C) coefficient of friction =
2mg
k (a  b )
(D) coefficient of friction =
2mg

Q.21 The electric potential due to an infinite thin non conducting sheet of positive charge density  at a point
located at a perpendicular distance Z from the sheet is (Assume V0 to be the potential at the surface of
sheet) :
Z Z Z
(A) V0 (B) V0   (C) V0 + 2 (D) V0 – 2
0 0 0

ROUGH WORK
Q.22 The figure shows, two point charges q1 = 2Q (>0) and q2 = –Q. The charges divide the line joining them
in three parts I, II and III

(A) Region III has a local maxima of electric field

(B) Region I has a local minima of electric field
(C) Equilibrium position for a test charge lies in region II
(D) The equilibrium for constrained motion along the line joining the charges is stable for a negative test
charge

Q.23 In displacement method, the distance between object and screen is 96 cm. The ratio of length of two
images formed by a convex lens placed between them is 4.84.
(A) Ratio of the length of object to the length of shorter image is 11/5
(B) Distance between the two positions of the lens is 36 cm
(C) Focal length of the lens is 22.5 cm
(D) Distance of the lens from the shorter image is 30 cm

Q.34 The net rate of heat loss by a hot body depends upon.
(A) temperature of body (B) temperature of surroundings
(C) material of the body (D) nature of the surface

Q.25 A man of mass M is carrying a ball of the mass M/2. The man is initially
in the state of rest at a distance D from fixed vertical wall. He throws the
ball along the floor towards the wall with a velocity V with respect to
earth at t = 0. As a result of throwing, the man also starts moving
backwards. The ball rebounds elastically from the wall. The man finally
collects the ball. Assuming friction to be absent.
2V
(A) The velocity of the man + ball system after the man has collected the ball is
3
MV
(B) Linear impulse by ball on man is
3
ROUGH WORK
 MV
(C) Linear impulse by ball on man is
6
4D
(D) He catches the ball again at t =
V

Q.26 Two identical blocks each of mass 2M are joined by means of

a light spring of spring constant k. A man of mass M is standing
on one of the block as shown in the diagram. If man jumps
horizontally with a velocity V relative to block and horizontal
surface is smooth, then
2M V
(A) the maximum compression in the spring is  
k 3

2h
(B) man lands at horizontal distance V from initial position of the block
g
(C) right block loses contact with wall when the elongation in spring is maximum
V
(D) velocity of centre of mass of two blocks after 2M loses contact with wall is
6

ROUGH WORK
Q.27 A capacitor of capacitance C is charged to a potential difference V0. The charging battery is disconnected
and the capacitor is connected to a uncharged capacitor of unknown capacitance Cx. The final potential
difference across the combination is V, after the switch S is closed, then:

CV0  V  1
(A) Cx = (B) Final energy stored is CV0V
V 2
CV0 V0  V 
(C) Heat generated in the circuit is
2
CV0 V
(D) Heat generated in the circuit is
2

Q.28 An ideal gas has molar heat capacity at constant pressure Cp = 5R/2. The gas is kept in a cylindrical
vessel fitted with a piston which is free to move. Side walls of the container and the piston are non
conducting. Mass of the frictionless piston is 9 kg. Initial volume of the gas is 0.0027 m3 and cross-
section area of the piston is 0.09 m2. The initial temperature of the gas is 300 K. Atmospheric pressure
P0 = 1.05 × 105 N/m2. An amount of 2.5 × 104 J of heat energy is supplied to the gas by a heating coil,
then
(A) Initial pressure of the gas is 1.06 × 105 N/m2
(B) Final temperature of the gas is 1000 K
(C) Final pressure of the gas is 1.06 × 105 N/m2
(D) Work done by gas is 9.94 × 103 J

ROUGH WORK
Q.29 The accompanying figure shows two concentric conducting thin spherical shells
isolated from each other. The smaller shell has radius b and net charge +Q. The
larger shell has radius 2b and net charge –Q. If R is the distance from the
common center,
(A) the highest electric field magnitude E occurs immediately outside the smaller shell (R ~ b)
(B) the highest electric field magnitude E occurs immediately outside the larger shell (R ~ 2b)
(C) At R = b potential is maximum
(D) At R = 0 potential is maximum

Q.30 A uniform bar of length 6a and mass 8m lies on a smooth horizontal table. Two point masses m and 2m
moving in the same horizontal plane with speeds 2v, and v, respectively, strike the bar (as shown in
figure) and stick to the bar after collision. Denoting angular velocity, total energy and velocity of centre of
mass by , E and Vc respectively, we have after collision

3v
(A) Vc = 0 (B)  =
5a
v 3mv 2
(C)  = (D) E =
5a 5

ROUGH WORK
Q.31 Which of following reaction product is Diastereomer.

Br
(
i ) NaCN
(A) 2
 (B) 
CCl 4 (ii ) H 

(C) HBr
 (D) CH 3  CH  CH  CH  Ph HCl

CCl4 peroxide
|
Et
Q.32 Select the correct statement
(A) Resonance energy is temperature dependent
(B) 4d & 5d series metals forms low spin complex
(C) Cisplatin express geometrical isomerism
(D) Benzene reacts with CrCl3 and forms organometallic compound

Q.33 Which among the following are correctly matched

2C O HCl ZnCl2

(A) NaNH
2 / NH3
 (B) H   

HNO
     O 
(C) Ac O
3 2
(D)
||
CH 3  C  NO 3

ROUGH WORK
Q.34 The correct order of energies of d-orbitals of metal ion in a square planar complex is
(A) dxy = dyz = dzx > d = d (B) d = d 2 > dxy = dyz = dzx
x 2 y 2 z2 x 2 y 2 z

(C) d > d > dxy > dyz = dzx (D) d > dxy > d > dzx = dyz
x 2 y 2 z2 x 2 y 2 z2

Q.35 In the given reaction:

[X]

[X] is:

(A) 2 moles (B)

(C) one mole (D) All of these

Q.36 Select the correct statement

(A) [Fe(NO)(H2O)5]SO4 is coloured because of d–d transition
(B) [Fe(NO)(H2O)5]SO4 is coloured because of charge transfer
(C) [Fe(NO)(H2O)5]SO4 is brown ring
(D) [Fe(NO)(H2O)5]SO4 is high spin complex

Q.37 Select the correct statement(s):

(A)G > 0 for oxidation-reduction reaction (Redox) performed in electrolytic cell
(B) The rate constants of the forward & reverse reactions are equal at chemical equilibrium.
(C) Molar conductivity for a strong electrolyte increases as the electrolyte concentration increases.
228
(D) 89 Ac is a member of 4n + 3 series.

ROUGH WORK
 NaOH
Q.38 (A) 


Reactant (A) is
O O O O
|| || || ||
(A) CH 3  C  (CH 2 )5  C  CH 3 (B) CH 3  C  (CH 2 ) 4  C  H

O O O
|| || ||
(C) H  C  (CH 2 )5  C  H (D) CH 3  C  (CH 2 ) 4  CH 2  OH

Q.39 Saturated solution of SO2 is heated at 150°C in a closed container. The product obtained is treated with
BaCl2 solution. What is/are the most suitable observation(s)
(A) No ppt. (B) white turbidity
(C) evolution of SO2 (D) The turbidity becomes white ppt
O
|| CH N 2 CH CO 3H
Q.40 CH 3  C  CH 2  CH 3 2 A (Major) 3   B (Major)
Product B is:
O O
|| ||
(A) CH 3  O  C  CH 2  CH 2  CH 3 (B) CH 3  C  O  CH 2  CH 2  CH 3

O O
|| ||
(C) CH 3  CH 2  C  O  CH 2  CH 3 (D) CH 3  C  O  CH 2  CH 3

Q.41 Which reaction is(are) possible

(A) MgCl2 + NaNO3  (B) BaSO4 + HCl 
(C) ZnSO4 + BaS  (D) BaCO3 + CH3COOH 
ROUGH WORK
 PCl
Q.42 5  (A)


Identify product (A). Name of the reaction.

O
||
(A) NH  C Cl, Beckmann rearrangement

O
||
(B) C  NH Cl, Hoffmann bromamide reaction

O
||
(C) NH  C Cl, Hoffmann bromamide reaction

O
||
(D) C  NH Cl, Beckmann rearrangement

Q.43 Which of the following complex are coloured

(A ) M nO4– (B) CrO42– (C) Cr2O72– (D) MnO42–
Q.44 Compound (X) C4H8O, which gives 2,4-Dinitrophenyl hydrazine derivative and negative haloform test.
O
||
(A) CH 3  C  CH 2  CH 3 (B) CH 3  CH  CHO
|
CH 3
(C) (D) CH3 – CH2 – CH2 – CHO

ROUGH WORK
Q.45 Which of the following statements is/are true
(A) In Ferrocyanide ion, the effective atomic number is 36
(B) Chelating ligands are atleast bidentate ligands
(C) [CrCl 2 (CN ) 2 ( NH 3 ) 2 ]– and [CrCl3(NH3)3] both have d2sp3 hybridisation
(D) As the number of rings in complex increases, stability of complex (chelate) also increases

ROUGH WORK