R EV I E W T E ST- 3

PA P E R -
1
Class : XII
Time : 3 hour
PAPER CODE : B Max. Marks : 216
INSTRUCTIONS

1. The question paper contains 72 questions and 20 pages. Each question carry 3 marks and all of them are
compulsory. There is NEGATIVE marking. 1 mark will be deducted for each wrong answer.
Please ensure that the Question Paper you have received contains all the QUESTIONS and
Pages. If you find some mistake like missing questions or pages then contact immediately to the
Invigilator.

2. Indicate the correct answer for each question by filling appropriate bubble in your OMR sheet.

3. Use only HB pencil for darkening the bubble.

4. Use of Calculator, Log Table, Slide Rule and Mobile is not allowed.

5. The answer of the questions must be marked by shading the circles against the question by dark HB pencil only.

6. The answer(s) of the questions must be marked by shading the circles against the question by dark HB
pencil only.
For example if only 'B' choice is correct then, the correct method for filling the bubble is
A B C D

the wrong method for filling the bubble are

(i) A B C D

(ii) A B C D

(iii) A B C D

The answer of the questions in wrong or any other manner will be treated as wrong.

USEFUL DATA
Atomic weights: Al = 27, Mg = 24, Cu = 63.5, Mn = 55, Cl = 35.5, O = 16, H = 1, P = 31, Ag = 108, N = 14,
Li = 7, I = 127, Cr = 52, K=39, S = 32, Na = 23, C = 12, Br = 80, Fe = 56, Ca = 40, Zn = 65.4,
Radius of nucleus =10–14 m; h = 6.626 ×10–34 Js; me = 9.1 ×10–31 kg, R = 109637 cm–1
 Select the correct alternative. (Only one is correct) [72×3 = 216]
There is NEGATIVE marking. 1 mark will be deducted for each wrong answer.
Q.1 I alternatively toss a fair coin and throw a fair die until I, either toss a head or throw a 2. If I toss the coin
first, the probability that I throw a 2 before I toss a head, is
(A) 1/7 (B) 7/12 (C) 5/12 (D) 5/7

Q.2 Let A, B, C, D be (not necessarily square) real matrices such that

AT = BCD; BT = CDA; CT = DAB and DT = ABC
for the matrix S = ABCD, consider the two statements.
I S3 = S
II S2 = S4
(A) II is true but not I (B) I is true but not II
(C) both I and II are true (D) both I and II are false.

Q.3 The area of the region of the plane bounded above by the graph of x2 + y2 + 6x + 8 = 0 and below by
the graph of y = | x + 3 |, is
 2 
(A) (B) (C) (D) 
4 4 2

Q.4 Consider straight line ax + by = c where a, b, c  R+ and a, b, c are distinct. This line meets the
coordinate axes at P and Q respectively. If area of OPQ, 'O' being origin does not depend upon a, b
and c, then
(A) a, b, c are in G.P. (B) a, c, b are in G.P. (C) a, b, c are in A.P. (D) a, c, b are in A.P.

Q.5 If x and y are real numbers and x2 + y2 = 1, then the maximum value of (x + y)2 is
(A) 3 (B) 2 (C) 3/2 (D) 5

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 
dx
Q.6 The value of the definite integral  (1  x a )(1  x 2 ) (a > 0) is
0

 
(A) (B) (C)  (D) some function of a.
4 2
a b c
cos  cos cos
Q.7 Let a, b, c are non zero constant number then Lim r r r equals
r b c
sin sin
r r

a 2  b2  c2 c2  a 2  b2 b2  c 2  a 2
(A) (B) (C) (D) independent of a, b and c
2bc 2bc 2bc

Q.8 A curve y = f (x) such that f ''(x) = 4x at each point (x, y) on it and crosses the x-axis at (–2, 0) at an
angle of 45°. The value of f (1), is
55 35
(A) – 5 (B) – 15 (C) – (D) –
3 3
sin x cos x tan x cot x
Q.9 The minimum value of the function f (x) = + + +
1  cos2 x 1  sin 2 x sec 2 x  1 cosec2 x  1
as x varies over all numbers in the largest possible domain of f (x) is
(A) 4 (B) – 2 (C) 0 (D) 2

Q.10 A non zero polynomial with real coefficients has the property that f (x) = f ' (x) · f ''(x). The leading
coefficient of f (x) is
1 1 1 1
(A) (B) (C) (D)
6 9 12 18
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 1
n
tan 1 (nx) n 2 ·C n equals
Q.11 Let Cn =  1
dx then Lim
n
1 sin (nx )
n 1

1
(A) 1 (B) 0 (C) – 1 (D)
2

Q.12 Let z1, z2, z3 be complex numbers such that z1 + z2 + z3 = 0 and | z1 | = | z2 | = | z3 | = 1 then
z12  z 22  z 32 , is
(A) greater than zero (B) equal to 3 (C) equal to zero (D) equal to 1

Q.13 Number of rectangles with sides parallel to the coordinate axes whose vertices are all of the form (a, b)
with a and b integers such that 0  a, b  n, is (n  N)
n 2 (n  1) 2 (n  1) 2 n 2 (n  1) 2
(A) (B) (C) (D) n2
4 4 4
1
Q.14 Number of roots of the function f (x) = – 3x + sin x is
( x  1) 3
(A) 0 (B) 1 (C) 2 (D) more than 2
Q.15 If p (x) = ax2 + bx + c leaves a remainder of 4 when divided by x, a remainder of 3 when divided by
x + 1, and a remainder of 1 when divided by x – 1 then p(2) is
(A) 3 (B) 6 (C) – 3 (D) – 6
Q.16 Let f (x) be a function that has a continuous derivative on [a, b], f (a) and f (b) have opposite signs, and
f ' (x)  0 for all numbers x between a and b, (a < x < b). Number of solutions does the equation
f (x) = 0 have (a < x < b).
(A) 1 (B) 0 (C) 2 (D) cannot be determined
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Q.17 Which of the following definite integral has a positive value?
2 3
3 0 0
2
(A)  sin( 3x  )dx (B)  sin( 3x  )dx (C)  sin( 3x  )dx
 3
(D)  sin(3x  )dx
0 2 0
3 2
Q.18 Let set A consists of 5 elements and set B consists of 3 elements. Number of functions that can be
defined from A to B which are neither injective nor surjective, is
(A) 99 (B) 93 (C) 123 (D) none

Q.19 A circle with center A and radius 7 is tangent to the sides of an angle of
60°. A larger circle with center B is tangent to the sides of the angle and
to the first circle. The radius of the larger circle is
(A) 30 3 (B) 21
(C) 20 3 (D) 30

   
Q.20 The value of the scalar p  q · r  s  can be expressed in the determinant form as
               
q · r q ·s p · r p ·s p · r q ·s p ·r p ·s
(A)     (B)     (C)     (D) q · r q ·s
p · r p ·s q ·s q · r q · r p ·s

 x 1 
Q.21 If Lim x ·ln 0 1 x  = – 5, where , ,  are finite real numbers then
x 
1 0 1x
(A)  = 2,  = 1,   R (B)  = 2,  = 2,  = 5
(C)   R,  = 1,   R (D)   R,  = 1,  = 5

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Q.22 If f (x, y) = sin–1( | x | + | y | ), then the area of the domain of f, is
(A) 2 (B) 2 2 (C) 4 (D) 1

Q.23 A, B and C are distinct positive integers, less than or equal to 10. The arithmetic mean of A and B is 9.
The geometric mean of A and C is 6 2 . The harmonic mean of B and C is
9 8 7 8
(A) 9 (B) 8 (C) 2 (D) 2
19 9 19 17

Q.24 If x is real and 4y2 + 4xy + x + 6 = 0, then the complete set of values of x for which y is real, is
(A) x  2 or x  3 (B) x  – 2 or x  3
(C) – 3  x  2 (D) x  – 3 or x  2

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Q.25 Which of the following compound has pyramidal geometry?
(A) B(CH 3)3 (B) (CH3)3C (C) (CH3)3N (D) BF3

Q.26 20 ml of 0.2 M – NaOH and 40 ml 0.1 M – H2SO4 are mixed together in a flask & volume made up to
250 ml. The pH of the resultant solution is
(A) 5 (B) 6 (C) 8 (D) none of these

Q.27 Which of the following is incorrect statement

(A) I3– is linear in shape and consist 22 valence electrons
(B) HNCO and N3– is linear in shape
(C) hydroxyl amine is more nucleophilic than NH3
(D) AlN is more ionic than MgO

Q.28 For the following reaction

CH3–CH2 – Cl + NaOH  CH3–CH2–OH+NaCl
If the reagent is NaOH the best solvent is
(A) water (B) C2H5OH + H2O (C) C2H5OH (D) only NaOH

Q.29 Select the correct statement

(A) bond energy of N  N << P  P
(B) bond energy of P – P < N – N
(C) Ti(H2O)3+3 is a coloured compound in pure state
(D) AgI2– is unstable while AgF2– is stable compound

Q.30 Organic compound (A) reacts with alc. KOH and gives (B), which on treatment with NaOEt isomerizes
to (C). Compound (C), on treatment with OsO4 followed by HIO4 results CH3CH=O only. Select the
incorrect statement. If (A) is a monohalogen hydrocarbon with molecular weight is 92.5.
(A) (A) gives yellow ppt. with AgNO3
(B) (A) do not give any ppt. with AgNO3 in NH3
(C) (C) gives brown ppt. with AgNO3/NH3
(D) (A) reacts with NaI/acetone according to first order rate kinetics.
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Q.31 If R–isomer have –ve rotation and S-isomer have +ve rotation, select the correct statement about the
mixture of R and S 2–bromobutane, specific rotation of mixture is +18.40 and specific rotation of R–2–
bromobutane is –230 then select the incorrect statement
(A) S–isomer has 23% specific rotation (B) 80% excess of S over R isomer
(C) R-isomer has composition 10% only (D) None of these

Q.32 When 2–chlorobutane reacts with NaOH in presence of ethyl alcohol and water, rate kinetics of reaction
follows

(A) (B)

(C) (D)

Q.33 H
 major product is

(A) (B) (C) (D)

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Q.34 Chirapos was developed by professor Kagan & has found useful applications in asymmetric synthesis.
Using fischer projection shown below, which is correct statement about configuration of the chirapose in
terms of R/S notation.

(A) It is 2R, 3R molecule (B) It is 2S, 3R, molecule

(C) It is 2S, 3S molecule (D) It is 2R, 3S molecule

Q.35 In the following reaction

Product is

(A) (B) (C) (D)

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Q.36 Select the incorrect statement
(A) Al3+ on treatment with aq. Na2S gives Al(OH)3
(B) Cr3+ on treatment with aq. Na2S gives Cr(OH)3
(C) Cr(OH)3 dissolved in basic solution of bromine water
(D) When mixture of AgCl, Hg2Cl2 is treated with NH3 and resultant is filtered, black residue consist
HgNH2Cl, Hg, only

Q.37 For the reactions

I NaOAc
 
AcOH

II NaOAc
 
AcOH

Select the correct statement

(A) rate of Ist reaction is 1011 times faster than trans IInd
(B) rate of IInd reaction is 1011 times faster than trans Ist
(C) rate of Ist reaction and IInd reaction are equal
(D) reaction not possible

Q.38 The equilibrium constant for the ionization of R–NH2(aq) in water as

R–NH2(g) + H2O(l)  R–NH2(aq) R–NH3+(aq) + OH–(aq)
is 8 × 10–6 at 25°C. Find the pH of a solution at equilibrium with pressure of R–NH2(g) is 0.5 atm.
Assume Henry's Law, at equilibrium PA = K[A]; where K =1.[Take log 2.82 = 0.45]
(A)  12.3 (B)  11.3 (C)  11.45 (D) None

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Q.39 Which statement(s) is/are true about the relation between the following compounds?

(a) (b) (c)

(I) a and b are tautomers (II) b and c are resonating structures

(III) a and c are resonating structures (IV) a and c are tautomers
(A) I & III (B) II & IV (C) I, II & III (D) I & IV

Q.40 Arrange the following carbocations in the increasing order of their stability.

(I) (II) (III)

(A) I > II > III (B) I > II = III (C) I > III > II (D) III > I > II

Q.41 Which statement about the following equilibrium is/are true?

 
Ph3C–H + MeO K

Ph3C K  + MeOH
(I) The reaction favours the product formation.
(II) Ph3CK is the dominant anionic species in this reaction.
(III) Methanol is the weaker acid in this reaction.
(IV) The reaction favours the reactant formation.
(A) I & II (B) I, II & III (C) IV only (D) III & IV

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Q.42 Which one of following carbonyl compound when treated with dilute acid forms the most stable
carbocation?
O O
|| ||
(A) CH 3  C  CH 3 (B) (C) (D) C 6 H 5  C  C6 H 5

Q.43 Correct order of heat of combustion is:

(p) 1,3-Pentadiene (q) 1,3-Butadiene
(r) 2,3-Dimethyl-1, 3-butadiene (s) Propadiene
(A) s > q > p > r (B) s > r > q > p (C) r > p > q > s (D) s > r > p > q

Q.44 Write correct order of reactivity of following halogen derivatives.

(I) (II) CH2=CH–Cl (III) Et3C–Cl (IV) PhCH2Cl (V) Ph3C–Cl

(A) I > V > IV > III > II (B) V > IV > I > III > II
(C) V > I > IV > III> II (D) I > V > III > IV > II

Q.45 Correct order of nucleophilicity of following anions in polar protic solvent is:
   
(A) CH3 >

NH 2- > OH > F (B) CH3 <

NH 2- < OH < F
   
(C) CH3 =

NH 2- = OH = F  -
(D) CH3 > F > OH > NH 2

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Q.46 NO2 is involved in the formation of smog and acid rain. A reaction that is important in the formation of
NO2 is
O3(g) + NO(g) O2(g) + NO2(g) K = 6 × 1034
If the air over a section of Pooja Towers contained 1.0 × 10–6M O3, 1.0 × 10–5M NO, 2.5 × 10–4M
NO2 and 8.2 × 10–3M O2, what can we conclude
(A) there will be a tendency to form more NO and O3
(B) there will be a tendency to form more NO2 and O2
(C) There will be a tendency to form more NO2 and O3
(D) There will be no tendency for change because the reaction is at equilibrium

Q.47 The equilibrium SO2Cl2(g) SO2(g) + Cl2(g) is attained at 250C in a closed container and Helium
is introduced. Which of the following statement is correct
(1) The concentrations of SO2, Cl2 and SO2Cl2 change
(2) More chlorine is formed
(3) Concentration of SO2 is reduced
(4) More SO2Cl2 is formed
(A) 1, 2, 3 (B) 2, 3, 4 (C) 3, 4 (D) none of these

Q.48 In the system LaCl3(s) + H2O(g) + heat LaClO(s) + 2HCl (g) equilibrium is established. More
water vapour is added to re-establish the equilibrium. The pressure of water vapour is doubled. The
factor by which pressure of HCl is changed is
(A) 2 (B) 2 (C) 3 (D) none of these

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Q.49 A small object placed on a rotating horizontal turn table just slips when it is placed at a distance of 4 cm
from the axis of rotation. If the angular velocity of the turn table is doubled, the object slips when its
distance from the axis of rotation is
(A) 8 cm (B) 4 cm (C) 2 cm (D) 1 cm

Q.50 A small block of mass m is released from A inside the frictionless circular groove of radius 2 m on an
inclined plane as shown in figure. The contact force between the block and inclined plane at point B is

(A) 28 mg (B) 2.5 mg

28
(C) mg (D) 18.5 mg
2

Q.51 Two isochoric cooling process AB and CD are shown in P-V diagram for the same gas. In which case
heat lost will be more.

(A) AB (B) same in both cases (C) CD (D) can't say

Q.52 PV versus T graph of equal masses of H2, He and CO2 is shown in figure. Choose the correct alternative
(A) 3 corresponds to H2, 2 to He and 1 to CO2
(B) 1 corresponds to He, 2 to H2 and 3 to CO2
(C) 1 corresponds to He, 3 to H2 and 2 to CO2
(D) 1 corresponds to CO2, 2 to H2 and 3 to He

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Q.53 Two smooth cylindrical bars weighing W each lie next to each other in contact. A similar third bar is
placed over the two bars as shown in figure. Neglecting friction, the minimum horizontal force on each
lower bar necessary to keep them together is

(A) W/2 (B) W (C) W/ 3 (D) W/(2 3 )

Q.54 A possible means for making an aeroplane invisible to radar is to coat the plane with an anti reflective
polymer. If the radar waves have a wavelength of 3.0 cm and refractive index of polymer is n = 1.50.
Then what will be the minimum thickness of coating (here refractive index of aeroplane material is higher
than polymer)
(A) 0.5 cm (B) 1.0 cm (C) 0.25 cm (D) 1.25 cm

Q.55 A river is flowing with velocity 2 m/s. A boat is moving downstream. Velocity of boat in still water is
3 m/s. A person standing on boat throws a ball vertically upwards w.r.t himself with a velocity of
10 m/s. At the top most point, the velocity of ball w.r.t man standing on boat, w.r.t river and w.r.t ground
respectively is
(A) 5, 3, 0 m/s (B) 0, 3, 5 m/s (C) 0, 5, 3 m/s (D) none of these

Q.56 An object starts moving at an angle of 45° with the principal axis as shown in the figure in front of a
biconvex lens of focal length +10 cm. If  denotes the angle at which image starts to move with principal
axis then
3 
(A)  = (B)  =
4 2
 
(C)  = (D)  = –
4 4
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For Problems 57 to 58
Parallel light beam of wavelength 500 nm falls on two narrow slit in YDSE
at angle  = 300 as shown in figure. The distance between slit d=25×10–4
cm. On lower slit a transparent material of thickness t = 15 × 10–3 cm is
placed. The refractive index of transparent material  = 7/6. The
interference pattern appears on screen at distance D (D >> d), then
Q.57 The central maxima will occur on screen
(A) below point O (B) above point O
(C) at point O (D) data's are insufficient to decide

Q.58 How many number of fringes will pass through from point  = 0 (point 0). If we remove transparent
material from the lower slit?
(A) 50 (B) 25 (C) 12 (D) none of these

Q.59 A concave mirror of radius of curvature 40 cm forms an image of an object placed on the principal axis
at a distance 45 cm in front of it. Now if the system is completely immersed in water ( = 1.33) then
(A) the image will shift towards the mirror
(B) the magnification will reduce
(C) the image will shift away from the mirror and magnification will increase.
(D) the position of the image and magnification will not change.

Q.60 Imagine a hypothetical material whose average temperature coefficient of linear expansion is 0.1 /°C.
Find the fractional increase in the area of a thin square plate of above material when temperature increase
by 10°C.
(A) 1 (B) 2 (C) 3 (D) None

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Q.61 A particle of mass m is projected at an angle of 60° with a velocity of
20 m/s relative to the ground from a plank of same mass m which is
placed on smooth surface. Initially plank was at rest. The minimum length
of the plank for which the ball will fall on the plank itself is (g = 10 m/s2)
(A) 40 3 m (B) 20 3 m (C) 10 3 m (D) 60 3 m

Q.62 A man slowly pulls a bucket of water from a well of depth h. If the mass of the uniform rope and bucket
full of water are m and M respectively. The value of work done by the man is
m  mM
(A) (m+M) gh (B)   M  gh (C)   gh (D) None of the above
2   2 

Q.63 If the mass of block is 1 kg and a horizontal force of 10 3 N is applied

horizontally on the block as shown in the figure. The frictional force
acting on the block is
10 20
(A) zero (B) N (C) N (D) 5 N
3 3

Q.64 A beaker contains 200 g of water. The water equivalent of beaker is 20 gm. The initial temperature of
water in the beaker is 20°C. If 440 g of hot water at 92°C is poured in, then the final temperature, will
be nearest to: (neglect heat loss)
(A) 58°C (B) 68°C (C) 73°C (D) none

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Q.65 The friction force acting between surfaces in contact in the adjoining figure is best represented by

(A) (B)

(C) (D)

 
Q.66 Two particles having position vectors r1  (3î  5 ĵ) m and r2  (5î  3 ĵ) m are moving with velocities
 
v1  (4î  3ˆj) m/s and v 2  (a î  7 ĵ) m/s. If they collide after 2 sec, the value of 'a' is
(A) 2 (B) 4 (C) 6 (D) 8

Q.67 In the balance machine shown in the figure, which arm will move downward
after the system is released (assuming string, arm of balance machine and
the pulley to be light)
(A) left (B) right
(C) remains stationary (D) none of these

Q.68 A point moves on a circle of radius 2 meter and its speed depends on the distance covered as v =  S .
Then the time taken by the particle in making the full circle is
(A) 2 sec. (B) 3 sec. (C) 4 sec. (D) none

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Q.69 A plane mirror of length 2 m is kept along the line y = –x as shown in the
figure. An insect having velocity of 4î cm/s is moving along the x-axis
from far away. The time span for which the insect can see its image will
be
(A) 50 sec (B) 25 sec
(C) 25 2 sec (D) 50 2 sec

Q.70 The Potential Energy U vs x curve for a particle is shown in figure.

Then the conservative force (F) vs x curve will be:

(A) (B) (C) (D)

Q.71 A converging beam of rays is incident on a diverging thin lens. Having passed through the lens the rays
intersect at a point 15 cm from the lens. If lens is removed the point where the rays meet will move 5 cm
closer to the mounting that holds the lens. The focal length of lens is
(A) f = 10 cm (B) f = 15 cm (C) f = 30 cm (D) f = 40 cm

Q.72 Two particles tied to different light strings are whirled in a horizontal circle as shown in figure. The ratio
of length of the strings (L2/L1) so that they complete their circular path with equal time period is
3 2
(A) (B)
2 3
(C) 1 (D) none of these

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