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CHEMISTRY
Class : XI (P,Q,R,S & J) PAPER CODE : A
Time : 2 hour Max. Marks : 130
INSTRUCTIONS
1. The question paper contains 12 pages and 3-parts. Part-A contains 20 objective questions, Part-B contains
3 "Match the Column" questions and Part-C contains 4 "Subjective" questions. All questions are compulsory.
Please ensure that the Question Paper you have received contains all the QUESTIONS and Pages. If
you found some mistake like missing questions or pages then contact immediately to the Invigilator.
PART-A
(i) Q.1 to Q.15 have only one correct alternative and carry 3 marks each.
There is NEGATIVE marking and 1 mark will be deducted for each wrong answer.
(ii) Q.16 to Q.20 have one or more than one correct alternative(s) and carry 5 marks each.
There is NO NEGATIVE marking. Marks will be awarded only if all the correct alternatives are selected.
PART-B
(iii) Q.1 to Q.3 are "Match the Column" type which may have one or more than one matching options and
carry 8 marks for each question. 2 marks will be awarded for each correct match within a question.
There is NEGATIVE marking. 0.5 Marks will be deducted for each wrong match. Marks will be awarded
only if all the correct alternative(s) is/are selected.
PART-C
(iv) Q.1 to Q.4 are "Subjective" questions and carry 9 marks each. There is NO NEGATIVE marking.
Marks will be awarded only if all the correct bubbles are filled in your OMR answer sheet.
2. Indicate the correct answer for each question by filling appropriate bubble in your OMR answer sheet.
3. Use only HB pencil for darkening the bubble.
4. Use of Calculator, Log Table, Slide Rule and Mobile is not allowed.
5. The answer(s) of the questions must be marked by shading the circles against the question by dark HB pencil only.
Q.2 Statement 1: If the number of -particles observed in Rutterford experiment are 150 at 90° then the
number of particles scattered under similar experimental conditions at 120° are approx 67.
Statement 2 : Ionisation energy of deuterium atom is slightly lesser than that of hydrogen atom.
Statement 3 : The difference in total energy always remain same between any two electronic shell in
hydrogen atom irrespective of any reference value of potential energy assigned to n = .
Select the correct statement.
(A) Statements 1, 2 and 3 (B) Statements 1 and 2
(C) Statements 1 and 3 (D) Statements 2 and 3
ROUGH WORK
Q.3 30 ml of CH 3OH (d = 0.8 gm/cm3) is mixed with 60 ml of C2H5OH (d = 0.92 gm/ cm3) at 25°C to form
a solution of density 0.88 gm/cm3.Select the correct option.
(A) Molarity & molality of resulting solution are 6.33 & 13.59 respectively.
(B) The mol fraction of solute and molality are 0.385 and 13.59 respectively.
(C) % change in volume and molarity are zero and 13.59 respectively.
(D) Molarity & mol fraction of solute are 13.59 & 0.485 respectively.
Q.4 Al2(SO4)3 solution of 1 molal concentration is present in 1 litre solution of 2.684 gm/cc. How many
moles of BaSO4 would be precipitated on adding BaCl2 in excess.
(A) 3 moles (B) 2.684 × 3 moles (C) 6 moles (D) 2 moles
Q.6 The question below consists of an Assertion and the Reason. Mark appropriate option using the given
directions.
(A) If both assertion and reason are CORRECT, and reason is the CORRECT explanation of the
assertion.
(B) If both assertion and reason are CORRECT, but reason is not the CORRECT explanation of the
assertion.
(C) If assertion is CORRECT but reason is INCORRECT.
(D) If assertion is INCORRECT but reason is CORRECT.
Assertion: Bond energy of F2 is higher than that of Cl2.
Reason: According to VBT, 2p-2p overlap is stronger than 3p-3p.
ROUGH WORK
Q.7 The magnitude of resonance energy of benzene is 39 kcal/mole. It means that
(I) the magnitude of experimental heat of hydrogenation is 39 kcal/mol more than that of hypothetical
model.
(II) 39 kcal/mol would be required to convert 1 mole of benzene into hypothetical 1, 3, 5 cyclohexatriene.
(III) the magnitude experimental heat of formation of benzene is 39 kcal/mole less than that of a
hypothetical model.
(IV) this much amount of energy is involved in the conversion of cyclohexadiene to benzene and hydrogen
(A) only (II) is correct (B) (I), (III) & (IV) are correct
(C) (I) & (II) are correct (D) none of these
Q.8 Which of the following options are written with correct order of polar nature of bonds.
(i) NH3 > PH3 > SbH3 > AsH3 (ii) NH3 > AsH3 > SbH3 > PH3
(iii) NH3 > SbH3 > AsH3 > PH3 (iv) H2O > H2S > H2Se > H2Te
(v) H2O > H2Te > H2Se > H2S
(A) (i) & (iv) (B) (iii) & (iv) (C) (iii) & (v) (D) (ii) & (iv)
Q.9 44 gm of a sample on complete combustion gives 88 gm CO2 & 36 gm of H2O. The molecular formula
of the compound may be
(A) C4H6 (B) C2H6O (C) C2H4O (D) C2H4
ROUGH WORK
Q.12 The correct order of bond angles is
(A) H2S < NH3 < BF3 < SiH4 (B) H2S < NH3 < SiH4 < BF3
(C) NH3 < H2S < SiH4 < BF3 (D) H2S < SiH4 < NH3 < BF3
Q.13 The maximum number of 90° angles between bond pair – bond pair is observed in
(A) sp3d hybridisation (B) sp3d2 hybridisation
(C) sp3d3 hybridisation (D) dsp2 hybridisation
Q.14 Which molecular geometry is least likely to result from a trigonal bipyramidal geometry?
(A) Trigonal planar (B) See-Saw (C) Linear (D) T-shape
Q.15 Ionic conductance (I.C.) is a measure of electrical conductivity of ions in their aqueous solution. Select
the option in which the values of ionic conductance given, are correctly matched with ions. Data:
(A) Na+ 50.1 mho cm2 mol–1, Cl– 65.5 mho cm2 mol–1 & K+ 64.5 mho cm2 mol–1
(B) Na+ 64.5 mho cm2 mol–1, Cl– 65.5 mho cm2 mol–1 & K+ 50.1 mho cm2 mol–1
(C) Na+ 50.1 mho cm2 mol–1, Cl– 64.5 mho cm2 mol–1 & K+ 65.5 mho cm2 mol–1
(D) Na+ 64.5 mho cm2 mol–1, Cl– 50.1 mho cm2 mol–1 & K+ 65.5 mho cm2 mol–1
Select the correct alternatives. (One or more than one is/are correct) [5 × 5 = 25]
There is NO NEGATIVE marking.
Q.16 Select the incorrect statement(s):
(A) In PO 34 ion, the P–O bond order is 1.33.
(B) Covalent bond can be formed by overlapping of py and pz orbitals
(C) Bond angle in H2O is lesser than bond angle in OCl2 molecule.
(D) SeF4 and CH4 have same shape.
ROUGH WORK
Q.17 Species having maximum number of lone pairs on the central atom is/are:
(A) ClO– (B) XeF5— (C) SF4 (D) I3—
Q.19 Which of the following represent the equation relating density(d) and pressure(P) for a real / ideal gas at
a particular temperature.
(A) d = 4P + 0.02P2 (B) d = 4 + 0.02 P2 (C) d = 4P + 0.02 P4/3 (D) d = 4P
Q.20 Assuming the bond direction to be z-axis, which of the overlapping of atomic orbitals of two atom (A)
and (B) will result in bonding?
(A) s-orbital of A and px orbital of B (B) s-orbital of A and pz orbital of B
(C) py-orbital of A and pz orbital of B (D) s-orbitals of both (A) and (B)
ROUGH WORK
P A RT-B
MATCH THE COLUMN [3 × 8 = 24]
There is NEGATIVE marking. 0.5 Marks will be deducted for each wrong match.
INSTRUCTIONS:
Column-I and column-II contains four entries each. Entries of column-I are to be matched with some
entries of column-II. One or more than one entries of column-I may have the matching with the same entries
of column-II and one entry of column-I may have one or more than one matching with entries of column-II.
(D) Solid N2O5 (Resonating structures) (S) Non Polar Covalent bond
ROUGH WORK
Q.3 Column - I Column -II
(A) Energy of a photon having (P) 3.2 × 10–19 J
wavelength 2480 Å is