PA RT T E ST- 1

Class : XIII
Time : 3 hour Max. Marks : 60
INSTRUCTIONS
1. The question paper contain pages and 3-parts. Part-A contains 6 objective question , Part-B contains 2
questions of "Match the Column" type and Part-C contains 4 subjective type questions. All questions are
compulsory. Please ensure that the Question Paper you have received contains all the QUESTIONS
and Pages. If you found some mistake like missing questions or pages then contact immediately to
the Invigilator.
PART-A
(i) Q.1 to Q.6 have One or More than one is / are correct alternative(s) and carry 4 marks each.
There is NEGATIVE marking. 1 mark will be deducted for each wrong answer.
PART-B
(iii) Q.1 to Q.2 are "Match the Column" type which may have one or more than one matching options and
carry 8 marks for each question. 2 marks will be awarded for each correct match within a question.
There is NO NEGATIVE marking. Marks will be awarded only if all the correct alternatives are selected.
PART-C
(iv) Q.1 to Q.4 are "Subjective" questions. There is NO NEGATIVE marking. Marks will be awarded
only if all the correct bubbles are filled in your OMR sheet.
2. Indicate the correct answer for each question by filling appropriate bubble(s) in your answer sheet.
3. Use only HB pencil for darkening the bubble(s).
4. Use of Calculator, Log Table, Slide Rule and Mobile is not allowed.
5. The answer(s) of the questions must be marked by shading the circles against the question by dark HB pencil
only.
PART-A PART-B PART-C
For example if only 'B' For example if Correct Ensure that all columns
choice is correct then, match for (A) is P, Q; for (4 before decimal and 2
the correct method for (B) is P, R; for (C) is P after decimal) are filled.
filling the bubble is and for (D) is S then the Answer having blank
A B C D correct method for filling column will be treated as
the bubble is incorrect. Insert leading
P Q R S zero(s) if required after
For example if only 'B & (A) rounding the result to 2
D' choices are correct decimal places.
then, the correct method (B) e.g. 86 should be filled as
for filling the bubbles is 0086.00
A B C D (C) .
.
(D) .
The answer of t he .
question in any other .
manner (such as putting .
, cross , or partial .
shading etc.) will be .
treated as wrong. .
.
Class - XIII Chemistry Part Test - 1
PART A
Q.1 Calculate total maximum mass (kg) which can be lifted by 10 identical balloon (each having volume 82.1
lit. and mass of balloon & gas = 3 kg) at a height 83.14 m at Mars where g = 5 m/s2 & atmosphere
contains only Ar (At. wt.40). At Mars temperature is 10 K and density of atmosphere at ground level is
2
k gm/lit. [Given : e–0.1 = 0.9] (Assume dH = d0 eMgh RT to be applicable).
0.821
(A*) 2000 × 0.81–30 (B) 1970 (C) 2000 × 0.9 –30 (D) 2000 × 0.81 – 3
Mgh

RT
[Sol: (A) d = d0 e
40103 5  83.14
2 
e 8.31410
d = 0.821
2 2
= 0.821 e–0.2 =  ( 0.9) 2
0.821
Now at height h = 83.14 m
V × d = mass of balloons  mass of gas filled  mass of load


82.1 10
  (0.9) 2 = (3 × 10) + m
0.821
 m = (2000 × 0.81) – 30 Kg ]
Q.2 How many mg of quick lime is required to remove hardness of 1 kg of hard water having 366 ppm of
HCO3– and contains Ca2+ as the only cation
(A) 72 mg (B) 84 mg (C*) 168 mg (D) 170 mg
[Sol: In 1 Kg water
w HCO– = 366 × 10–3 gm
3

n HCO – = 6 × 10–3
3

CaO + Ca(HCO3–)2  2CaCO3 + H2O

n HCO –
 moles of CaO required = 3
= 3 × 10–3
2
 wt. of CaO required = 3 × 10–3 × 56
= 168 × 10–3 gm
= 168 mg [C] ]

Q.3 A 10 litre box contains O3 and O2 at equilibrium at 2000K. Kp = 4.17 × 1014 for 2O3 3O2.
Assume that PO 2  PO3 and if total pressure is 7.33 atm, then partial pressure of O3 will be
(A) 9.71 × 10–5 atm (B*) 9.71 × 10–7 atm
(C) 9.71 × 10–6 atm (D) 9.71 × 10–2 atm
[Sol: 2O3 3O2
PO3
2
Kp = P 2
O 3

Here PO 2  PO3 so the total pressure  PO 2

 7.333
 4.17 × 1014 = PO 2
3

PO3 = 9.71 × 10–7 atm ]

Q.4 2 KOH
Br 

If the reactant is (d) (dextrorotatory) then in final product 

(A) inversion of configuration takes place
(B) racemisation takes place
(C*) retention of configuration takes place
(D) none of the above
[Sol: r.d.s. is 1, 2 shift, shifting takes place with retention of configuration ]
Q.5 Select the correct statement(s)
If S = f (E, V, n1, n2) & A = f (T, V, n1, n2)
(A*) S is equal to f (E, V, n1, n2) (B) S is equal to f (E, V, n1, n2)
(C*) A is equal to f (T, V, n1, n2) (D) A is equal to f (E, V, n1, n2)
[Sol: S = f (E, V, n1, n2)
& E, V, n1, n2 all are extensive vairable
 S = f (E, V, n1, n2)
A = f (T, V, n1, n2)
here T is intensive variable
 A = f (T, V, n1, n2) [A, C] ]

Q.6

Compound B has a neutralisation equivalent 112. G is a dichloro alkane.

(A*) A = ,B= ,C= ,E= ;F=

& G = ClCH2CH2CH2CH2Cl

(B) A = ,B= ,C= ,E=

& G = ClCH2CH2CH2CH2CH2Cl

(C) A = ,B= ,C= ,E= ,F=

& G = ClCH2CH2CH2CH2CH2Cl
 (D) A = ,B= ,C= ;

E= ;F= & G = ClCH2CH2CH2CH2CH2Cl

[Sol:

PART B

Q.1 Match the following

Column I Column II
(A) Canary yellow precipitate with (NH4)2MoO4 (P) NO3–
(B) Brown ring test (Q) NO2–
(C) Acid radical which evolves gas with conc. HCl (R) AsO43–
(D) Acid radical which gives gas with dil. H2SO4 (S) PO43–
[Ans: (A)  R, S; (B)  P, Q; (C)  P; (D)  Q]
[Sol: (A) (NH4)2MoO4 + AsO43– + H+  (NH4)3Mo12AsO40
Canary yellow ppt.
(NH4)2MoO4 + PO43– + H+  (NH4)3M12PO40 
Canary yellow ppt.
(B) NO3 + Fe + H2SO4  Fe + NO + SO42– + H2O
– 2+ 3+

Fe2+ + NO [Fe(NO)]2+

Brown ring
 NO2– + CH3COOH  HNO2 + CH3COO–
HNO2  NO + HNO3 + H2O
Fe2+ + SO42– + NO [Fe(NO)]2+ Brown ring
(C) NO3– + H+ NO2 + H2O
(D) NO2– + H+  HNO2  NO + HNO3 + H2O ]

Q.2 Match the following

List I List II

(A) CuCl
 (P) Free radical mechanism

(B) CH3–CH=CH2 (Q) Non Classical Carbocation

 Cl2/
CH 2  CH  CH 2
|
Cl
(C) CH3–CH=CH2 CH
2I 2 / Zn / Cu
  (R) Carbenoid

(i ) Hg ( OAc ) 2 / H 2O
(D) CH3–CH=CH2     
( ii ) NaBH / OH 
(S) Through carbocation
4

[Ans: (A)  P; (B)  P; (C)  R; (D)  Q]


[Sol: (A) Ph N 2  CuCl  PhCl
 
Mechanism Ph N 2 Cl CuCl  Ph o  N 2  CuCl2

Ph o  CuCl2  PhCl  CuCl


(B) Cl2  2Clo

(C)
 (D)

PART C

Q.1 1.0 g of a mixture containing Sb2O3 and Sb2O5 and some inert impurities required 100ml 0.01 N iodine
for titration. The resulting solution is then acidified and excess of KI was added. The liberated I2 required
100 ml 0.02 M Na2S2O3·5H2O for complete reaction. Calculate the % of Sb2O5 in the mixture. The
reactions are [at. wt. Sb = 122]
Sb2O3 + 2I2 + 2H2O  Sb2O5 + 4H+ + 4I–
Sb2O5 + 4H+ + 4I–  Sb2O3 + 2I2 + 2H2O
[Sol: Meq of I2 used = 100 × 0.01 = 1 meq
Let meq of Sb2O3 and Sb2O5 are a and b, on addition of I2 to mixture Sb+3 converts into Sb+5
Meq. of Sb+5 formed = meq of I2 = 1 meq = meq of Sb2O3
a = 1 meq
After reaction,. mixture contains all the Sb in +5 oxidation state.
Meq of Sb+5 = meq of liberated I2 = meq of hypo solution used
a + b = 100 × 0.02 × 1 = 2 meq
1 324 0.324
b = 1 meq =   g = 0.081 g
1000 4 4
 Sb2O5 = 8.1 % ]

Q.2 A balloon containing 1 mole air at 1 atm initially is filled further with air till pressure increases to 3 atm.
The initial diameter of the balloon is 1 m and the pressure at each state is proportion to diameter of the
balloon. If balloon will burst when pressure increases to 7 atm. Calculate the number of moles of air that
must be added after initial condition to burst the balloon.
[Sol: P  diameter
d = Kp
Initially 1 = K × 1
m
K=1
atm
For Pf = 7 atm
 d = 7m
3
4 7
V =    m3
3 2
3
4 7
7 ×    = nf RT
T ..................(3)
3 2
nf
Dividing (3) by (1) = 7×7×7×7
ni
nf = 2401
 moles added = 2400 ]

Q.3 The key reaction in the manufacture of synthetic cryolight for aluminium electrolysis is
HF(g) + Al(OH)3 (s) + NaOH (aq)  Na3AlF6(aq) + H2O(l)
Assuming a 96 % yield of dried, crystallized product, what mass (in kg) of cryolite can be obtained from
the reaction of 351 kg of Al(OH)3, 1.10 m3 of 50.0% by mass aqueous NaOH (d = 1.50 g/mL), and
225 m3 of gaseous HF at 312.08 kPa and 87oC? (assume that the ideal gas law holds)
[Given: Al = 27, O = 16, H = 1, Na = 23, F = 19, R = 8.3 JK–1 mol–1]
[Sol: 6HF + Al(OH)3 + 3NaOH  Na3AlF6 + 6 H2O(l)
351 103
moles of Al(OH)3 = = 4500
78

moles of NaOH =
1.110 1.5  0.5 = 20625
6

40
PV 312080  225
moles of HF = = = 23500
RT 8.3  360
Here HF is limiting reagent
23500 96
so moles of Na3AlF6 formed =  = 3760
6 100
3760  210
wt. of Na3AlF6 formed = = 789.6 kg ]
1000

Q.4 The vapour pressure of water at 300 K is 25 torr. If the standard state pressure is defined as 1 bar (750
torr) estimate the G° [in kJ/mol] for the process.
H2O (l)  H2O (g) at 300 K
(Neglect variation of H and S with pressure for liquid)
ln X
Use [R = 8.314 JK–1 mol–1 ; log X = 2.3, log 3 = 0.48] [Ans. 8.49 ]

[Sol: G 0 = –2.3RT log Kp

= – 2.3 × 8.314 × 300 log PH 2O (bar)

 25 
= – 2.3 × 8.314 × 300 log  
 750 
1
= – 2.3 × 8.314 × 300 log = 8490J/mol = 8.49 kJ/mol ]
30