UV-

VIS
1.Pembuat
anLar
utanSt
ok
50mgpar
aset
amolp.
adi
lar
utkandal
am100mLet
anol96%
50mg x
=
100mL 1000

50.
000
x =
100

x =500ppm
2.Per
hit
unganPengenc
eran
Konsentr
asi
Abs
orbans
i a.Kons
ent
ras
i3,
5ppm
Standar(
ppm)
3,
5 0,
34 V1.
N1 =V2.
N2
4 0,
41
V1.
500ppm =10mL.
3,5ppm
4,
5 0,
48
35
0,
56 V1 =
5 500

5,
5 0,
68 =0,
07mL=70µL

6 0,
75 b.Kons
ent
ras
i4ppm

6,
5 0,
83 V1.
N1 =V2.
N2
V1.
500ppm =10mL.
4ppm
40
V1 =
500

=0,
08mL=80µL

c
.Kons
ent
ras
i4,
5ppm
V1.
N1 =V2.
N2
V1.
500ppm =10mL.
4,5ppm
45
V1 =
500
g.Kons
ent
ras
i6,
5ppm
=0,
09mL=90µL
V1.
N1 =V2.
N2
d.Kons
ent
ras
i5ppm
V1.
500ppm =10mL.
6,5ppm
V1.
N1 =V2.
N2
65
V1 =
V1.
500ppm =10mL.
5ppm 500

50 =1,
3mL=130µL
V1 =
500

=0,
10mL=100µL
3.Per
hit
unganKadarSampel
e.Kons
ent
ras
i5,
5ppm
Di
ket
ahui
:
V1.
N1 =V2.
N2
a=0,
2607
V1.
500ppm =10mL.
5,5ppm
b=0,
1679
55
V1 = Abs
orbans
isampel=0,
4125
500
Per
hit
unganPer
samaanRegr
esi
Linear:
=1,
1mL=110µL
y =bx+a
f
. Kons
ent
ras
i6ppm
0,
4125 =0,
01679x+0,
2607
V1.
N1 =V2.
N2
0,
4125-0,
2607=0,
01679x
V1.
500ppm =10mL.
6ppm
x =4,
0095
60
V1 =
500 Kons
ent
ras
i=4,
0095xf
act
orpengenc
eran
=1,
2mL=120µL Kons
ent
ras
i=4,
0095x10

Kons
ent
ras
i=40,
095ppm
 Rat
a-r
ata 0,
049N

Per
hit
ungan:
1)MgekNa2S2O3=MgekK2Cr
2O7

mgK2Cr2O7
VNa2S2O3.
NNa2S2O3 =
BEK2Cr
2O7

mgK2Cr2O7
NNa2S2O3 =
BEK2Cr
2O7.VNa2S2O3

50mg
=
49.20,
6ml

NNa2S2O3 =0,
0495N
mgK2Cr2O7
2)NNa2S2O3 =
BEK2Cr
2O7.VNa2S2O3
50mg
=
49.20,
5ml

NNa2S2O3 =0,
0497N

I
ODI
METRI mgK2Cr2O7
3)NNa2S2O3 =
BEK2Cr
2O7.VNa2S2O3
50mg
 PembakuanVi
tami
nCdenganK2Cr
2O7
=
49.20,
6ml
Di
k:K2Cr
2O7=50mg,
BMK2Cr
2O7=249 NNa2S2O3 =0,
0495N
Per
cobaanKe VNa2S2O3 NNa2S2O3
-
 PembakuanLar
utanI
odi
um(
I2)denganl
arut
anNa2S2O3(
0,049N)
1 20,
6ml 0,
049N
Pec
obaanKe- VI VNa2S2O3 NI
2 20,
5ml 0,
049N
1 10ml 9,
6ml 0,
047N
3 20,
6ml 0,
049N
2 10ml 9,
8ml 0,
048N
 3 10ml 9,
7ml 0,
047N 2 10ml 11,
7ml 0,
055N

Rat
a-r
ata 0,
047N 3 10ml 11,
5ml 0,
054N

Per
hit
ungan: Rat
a-r
ata 0,
054N

1) VI.
NI=VNa2S2O3.
NNa2S2O3 Per
hit
ungan:
VNa2S2O3.NNa2S2O3 1)VVitC.
NVitC=VI.
NI
NI =
VI
VI .NI
NVitC =
9,
6ml.0,
049N VVit
C
=
10ml
11,
5ml.0,
047N
=
NI =0,
047N 10ml
VNa2S2O3.NNa2S2O3 NVitC =0,
054N
2)NI =
VI
VI .NI
9,
8ml.0,
049N 2)NVitC =
= VVit
C
10ml
11,
7ml.0,
047N
=
NI =0,
048N 10ml
VNa2S2O3.NNa2S2O3 NVitC =0,
055N
3)NI =
VI
VI .NI
9,
7ml.0,
049N 3)NVitC =
= VVit
C
10ml
11,
5ml.0,
047N
=
NI =0,
047N 10ml
0,
047N+0,
048N+0,
047N NVitC =0,
054N
NIr
ata-
rat
a= =0,
047N
3
0,
054N+0,
055N+0,
054N
Rat
a-r
ata= =0,
054N
 Penet
apanKadarAnal
it(
Vit
ami
nC) 3
Pec
obaanKe VVitC VI NVitC  gVi
tC=NVitCxBEVi
tCxVVitC
-
=0,
054Nx88,
065x0,
05L
1 10ml 11,
5ml 0,
054N
=0,
237gr
am/
50ml
 gVi
tC mgZnSO4
 % Vi
tC = x100% VEDTA.
MEDTA =
VVi
tC MrZnSO4
0,237g mgZnSO4
= x100% MEDTA =
50ml MrZnSO4.VEDTA
% Vi
tC =0,
474% 100mg
=
161.12,
8ml

MEDTA =0,
048M
mgZnSO4
2.MEDTA =
MrZnSO4.VEDTA
100mg
=
161.12,
6ml

MEDTA =0,
049M
mgZnSO4
3.MEDTA =
MrZnSO4.VEDTA
100mg
=
161.12,
8ml

MEDTA =0,
048M
KOMPLEKSOMETRI
0,
048N+0,
049N+0,
048N
MEDTAr
ata-
rat
a= =0,
048N
 PembakuanEDTAmenggunakanZnSO40,
05M 3
Per
cobaan VNa2EDTA MNa2EDTA  Ti
tras
iBl
anko
Ke-
1 12,8ml 0,
048M Perc
obaanKe- VPelarut VEDTA MPelarut
2 12,6ml 0,
049M 1 10ml 0,4ml 0,002M
3 12,8ml 0,
048M 2 10ml 0,6ml 0,003M
Rata-rat
a 0,
048M 3 10ml 0,4ml 0,002M
Per
hitungan: Rata-r
ata 0,0023M

1.mmolEDTA=mmolZnSO4
Per
hit
ungan:
 1.VPelarut.
MPelarut =VEDTA.
MEDTA 2 10ml 10ml 0,
6ml 8,
7ml 8,35 1,
05ml
ml
VEDTA.MEDTA
MPelarut1 = 3 10ml 10ml 0,
4ml 8,
7ml 8,5ml 1,
25ml
VPel
arut

0,
4ml.0,
048M
=
10ml

MPelarut1 =0,
002M
Per
hit
ungan:
VEDTA.MEDTA
2.MPelarut2 =
VPel
arut - Menghi
tungVZnSO4ber
lebi
h
0,
6ml.0,
048M 1.VZnSO4.
MZnSO4=VEDTA.
MEDTA
=
10ml VEDTA.MEDTA
VZnSO4berlebih =
MPelarut2 =0,
003M MZnSO4

VEDTA.MEDTA 8,
8ml.0,
048M
3.MPelarut3 = =
VPel
arut 0,
05M

0,
4ml.0,
048M VZnSO4berlebih =8,
45ml
=
10ml
VEDTA.MEDTA
2.VZnSO4berlebih =
MPelaurt3 =0,
002M MZnSO4

0,
002M+0,
003M+0,
002M 8,
7ml.0,
048M
MPelarutr
ata-
rat
a= =0,
0023M =
3 0,
05M

 PenetapanKadarAnal
it(
AsamMef
enamat
)denganTi
tras
iKompl
esomet
ri VZnSO4berlebih =8,
35ml
Refr
es hment
Perc
obaa VAsam VZnSO4yang VTitrasi VEDTA VZnSO4 VZnSO4
nKe- ditambahk Blanko (
VEDTA yang VEDTA.MEDTA
Mef
enamat ber
lebi
h 3.VZnSO4berlebih =
an yang bereaks
i MZnSO4
bereaks i dengan 8,
7ml.0,
048M
dengan anali
t =
0,
05M
ZnSO4)
1 10ml 10ml 0,
4ml 8, 8ml 8,45 1,
15ml VZnSO4berlebih =8,
35ml
ml
- Menghi
tungVZnSO4yangber
eaks
idengananal
it VZnSO4.
MZnSO4
2.MAsamMefenamat=
VAsamMefenamat
1.VZnSO4anal i
t =VZnSO4 yangdi
tambahkan–VtitrasiBlanko –
VZnSO4berlebih 1,
05ml.0,
05M
=
=10ml–0,
4ml–8,
45ml 10ml

VZnSO4anal
it =1,
15ml MAsamMefenamat=0,
005M

2.VZnSO4anal
it =10ml–0,
6ml–8,
35ml
=1,
05ml VZnSO4.
MZnSO4
3.MAsamMefenamat=
VAsamMefenamat
1,
25ml.0,
05M
3.VZnSO4anal
it =10ml–0,
4ml–8,
5ml =
10ml
VZnSO4anal
it =1,
25 MAsamMefenamat=0,
006M
0,
006M+0,
005M+0,
006M
MAsam Mef
enamat r
ata-
rat
a= =
3
0,
006M
 gAs amMef enamat=MAsam enamatxB
Mef M As
am Mef
enamatx
VAsamMefenamat

 Penet
apan KadarAsam Mefenamatmenggunakan Ti
tras
i =0,
006Mx241,
29x0,
05L
Kompleks
ometriRef
rres
hment
gAs
amMef
enamat=0,
07g
1.VAsamMefenamat.
MAsamMefenamat=VZnSO4.
MZnSO4
gAsamMef
enamat
VZnSO4.
MZnSO4  % As
amMef
enamat
= x100%
MAsamMefenamat= VAs
amMefenamat
VAsamMefenamat
0,
07g
= x100%
1,
15ml.0,
05M 50ml
=
10ml
% As
amMef
enamat
=0,
14% b/
v
MAsamMefenamat=0,
006M
 63mg
=
63.10,
6ml

NNaOH3 =0,
094N
ASAMBASATI
DAKLANGSUNG
0,
092N+0,
095N+0,
094N
Sampel:18 NNaOHr
ata-
rat
a= =0,
094N
3
 PembakuanNaOHmenggunakanAs
amOks
alat0,
1N  PembakuanHClmenggunakanNaOHhas
ilpembakuan(
0,094N)
PercobaanKe- VAsamOksalat VNaOH NNaOH Perc
obaanKe- VNaOH VHCl NHCl
1 10ml 10,8ml 0,
092N 1 10ml 10,
4ml 0,
090N
2 10ml 10,5ml 0,
095N 2 10ml 10,
6ml 0,
090N
3 10ml 10,6ml 0,
094N 3 10ml 10,
4ml 0,
090N
Rata-rat
a 0,
094N Rata-r
ata 0,
090N
Perhi
tungan:
MgekNaOH=MgekAs
amOks
alat Per
hit
ungan:
mgAsamOks
alat 1.VHCl.
NHCl =VNaOH.
NNaOH
1.VNaOH.
NNaOH =
BEAs
amOksalat
VNaOH.NNaOH
mgAsamOksalat NHCl1 =
NNaOH = VHCl
1
BEAsamOksal
at.VNaOH
10ml.0,
094N
63mg =
NNaOH = 10,4ml
63.10,
8ml
NHCl1 =0,
090N
NNaOH1=0,
092N
VNaOH.NNaOH
mgAsamOksalat 2.NHCl2 =
2.NNaOH2 = VHCl
2
BEAsamOksal
at.VNaOH
10ml.0,
094N
63mg =
= 10,6ml
63.10,
5ml
NHCl2 =0,
090N
NNaOH2 =0,
095N
VNaOH.NNaOH
mgAsamOksalat 3.NHCl3 =
3.NNaOH3 = VHCl
3
BEAsamOksal
at.VNaOH
 10ml.0,
094N 0,
1ml.0,
090N
= =
10,4ml 10ml

NHCl3 =0,
090N NPelarut3 =0,
0009N
0,
090N+0,
090N+0,
090N 0,
0018N+0,
0018N+0,
0009N
NHClr
ata–r
ata= =0,
090N NPelarutr
ata-
rat
a= =0,
0015N
3 3

 Ti
tras
iBl
anko(
Pel
arutyangdi
gunakanet
anol96%)
PercobaanKe- VPelarut VHCl NPelarut  Penet
apanKadarAnal
it(
Aset
osal
)denganTi
tras
iAs
am Bas
a
1 10ml 0,
2ml 0,
0018N Ti
dakLangs
ung
2 10ml 0,
2ml 0,
0018N
3 10ml 0,
1ml 0,
0009N Perc
obaa VAsetosal VNaOHyang VTitrasi VHCl(VNaOH VNaOH VNaOH
Rata-rat
a 0,
0015N nKe- di
tambahkan Bl
anko y ang ber
lebi
h yang
bereaks i bereaksi
Perhi
tungan:
dengan dengan
1.VPelarut.
NPelarut =VHCl.
NHCl HCl) anali
t
1 10ml 25ml 0,2ml 20, 8ml 19,91 4,89ml
VHCl.NHCl ml
NPelarut1 =
VPel
arut
1 2 10ml 25ml 0, 2ml 20, 5ml 19, 63 5,
17ml
ml
0,
2ml.0,
090N
= 3 10ml 25ml 0, 1ml 20, 6ml 19, 72 5,
18ml
10ml ml
NPelarut1 =0,
0018N Ket erangan :VNaOH y angber eaks idengan anal
it=VNaOH yang
di
tambahkan-VTi
tras
i anko–V
Bl NaOHber
lebi
h
VHCl.NHCl
2.NPelarut2 = NNaOH=0,
094N
VPel
arut
2
0,
2ml.0,
090N
=
10ml Per
hit
ungan:
NPelarut2 =0,
0018N 1.VNaOHberlebih.
NNaOH =VHCl.
NHCl
VHCl.NHCl
VNaOHberlebih =
NNaOH

20,
8ml.0,
090N
VHCl.NHCl =
3.NPelarut3 = 0,
094N
VPel
arut
3
 VNaOHberlebih =19,
91ml
VNaOH.NNaOHber
lebi
h
3.NAsetosal =
VAs
etos
al
1.VAsetosal.
NAsetosal =VNaOH.
NNaOH
5,
18ml.0,
094ml
VNaOH.NNaOHber
lebi
h =
NAsetosal = 10ml
VAs
etos
al
NAsetosal =0,
049N
4,
89ml.0,
094N
=
10ml 0,
046N+0,
049N+0,
049N
NAsetosalr
ata-
rat
a= =0,
048N
3
NAsetosal =0,
046N
 gAs
etos
al =NAsetosalxBEAs
etos
alxVAsetosal
=0,
048Nx180,
16x0,
05L
VHCl.NHCl
2.VNaOHberlebih = gAs
etos
al =0,
43g
NNaOH
20,
5ml.0,
090N gAset
osal
=  % As
etos
al = x100%
0,
094N VAs
etosal

VNaOHberlebih =19,
63ml 0,
43g
= x100%
50ml
VNaOH.NNaOHber
lebi
h
2.NAsetosal = % As
etos
al =0,
86% b/
v
VAs
etos
al
5,
17ml.
0,094N
=
10ml

NAsetosal =0,
049ml

VHCl.NHCl
3.VNaOHberlebih =
NNaOH
20,
6ml.0,
090N
=
0,
094N

VNaOHberlebih =19,
72ml