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Desalination 407 (2017) 61–74

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Desalination

journal homepage: www.elsevier.com/locate/desal

Heat transfer coefficients and yield analysis of a double-slope solar still


hybrid with rubber scrapers: An experimental and theoretical study
Ali Omran Al-Sulttani a, Amimul Ahsan a,b,⁎, Ataur Rahman c, N.N. Nik Daud a, S. Idrus a
a
Department of Civil Engineering, and Institute of Advanced Technology, University Putra Malaysia, 43400, UPM Serdang, Selangor, Malaysia
b
Housing Research Centre, Faculty of Engineering, University Putra Malaysia, 43400, UPM Serdang, Selangor, Malaysia
c
School of Computing, Engineering and Mathematics, University of Western Sydney, Penrith, NSW 2751, Australia

H I G H L I G H T S

• A new double-slope solar still hybrid with rubber scrapers is designed.


• It has a small slope of the condensing cover of the solar still.
• It allows more solar radiation to enter the still.
• It avoids falling down of the condensation drops back to basin water.
• The productivity of this new model is increased by 63%.

a r t i c l e i n f o a b s t r a c t

Article history: In this study, a new double-slope solar still hybrid with rubber scrapers (DSSSHS) and a double-slope solar still
Received 20 September 2016 (DSSS) were designed, manufactured and tested. The proposed design of DSSSHS makes use of the advantages
Received in revised form 22 December 2016 of using a small slope of the condensing cover of the still that allows higher solar radiation to enter into the
Accepted 23 December 2016
still. Disadvantages resulting from using the small slope are overcome by using the rubber scrapers. No researcher
Available online 3 January 2017
has yet used the scrapers in solar still. Experimental measurements and results were used to calculate the theo-
Keywords:
retical values of convective and evaporative heat transfer coefficients, in addition to the theoretical values of the
Double-slope yields. Results of the two models were compared to evaluate the advantages of using rubber scrapers in the new
Rubber scrapers model. Using rubber scrapers in DSSSHS model enhanced the total internal heat transfer coefficient (h1) as well
Hybrid solar still as the productivity. The maximum recorded value of the total internal heat transfer coefficient for the DSSSHS is
Heat transfer coefficient found as 38.754 W/m2 °C and the daily yield as 4.24 L/m2 day with productivity improvement of 63%, for the case
Yields when the inclination angle of the glass cover is quite small (about 3.0°).
© 2016 Elsevier B.V. All rights reserved.

1. Introduction rise in population and higher living standard, as well the expansion of
industrial and agricultural activities [2].
In the last four decades, solving fresh water shortage problem has Therefore, finding sustainable, safe, cheap, and environment-friend-
become a great challenge to many nations around the globe. Potable ly techniques to produce potable water from salty water is necessary.
water is vital for our existence; however, non-potable water is also im- The best solution to this problem is solar distillation; this process is
portant to meet agricultural and industrial demands. Despite that more safer for the environment and uses only sustainable energy [3]. Solar
than three quarters of the earth is covered with water, only 0.014% is distillation is a desalination method with many advantages, including
potable. Conversely, sea water constitutes 97.5% of global water; this the ability to reduce or solve the problem of potable water shortage in
water can be purified by distillation to be suitable for human use [1]. the future, especially in arid, coastal, remote, and rugged areas. Thus,
Many countries suffer from shortage of natural fresh water. Increasing in the last three decades, many researchers and scientists have conduct-
amounts of fresh water will be required in the future as a result of the ed studies to improve fresh water production and/or efficiency of a con-
ventional solar still, which simply works based on the principles of
evaporation and condensation. These improvements increase the effec-
⁎ Corresponding author at: Department of Civil Engineering, and Institute of Advanced
tiveness of solar distillation technique in solving potable water shortage.
Technology, University Putra Malaysia, 43400, UPM Serdang, Selangor, Malaysia. Many researchers have investigated various types of solar stills, such
E-mail addresses: amimul@upm.edu.my, ashikcivil@yahoo.com (A. Ahsan). as weir type [4], simple single basin [5], active double slope [6], tubular

http://dx.doi.org/10.1016/j.desal.2016.12.017
0011-9164/© 2016 Elsevier B.V. All rights reserved.
62 A.O. Al-Sulttani et al. / Desalination 407 (2017) 61–74

solar still [7] and portable thermoelectric solar still [8]. Tests were also are installed in a fixed east–west orientation. The movements of rubber
conducted to increase the productivity of solar stills by using the follow- scrapers of DSSSHS are achieved by using two 12 V DC motors, which
ing designs: double-glass glaze where brine flows between them [9], are operated using DC current supplied from two 12 V, 150 Ah DC bat-
utilizing water and air flow [10,11], sponge cubes of different sizes in teries. The DC batteries are powered by a charger, which obtains its
the still basin [12], a built-in sandy heat reservoir [13], increasing con- power from a 12 V, 200 W/h DC solar photovoltaic panel. The system
densation area [14,15], parabolic concentrator with focal pipe and also consists of a feeding tank of saline water. All six faces of this tank
heat exchanger [16], solar collector with water sprinkling system and are made of aluminum which is non-transparent. All external faces of
thermoelectric cooling device [17], tubular and triangular still [18–22], this tank, except the one facing the sun, are insulated from the ambient
fin at the basin of the still [23–25], parabolic concentrator tubular air using 19 mm-thick nitrite foam (insulation sheet). Its thermal con-
solar stills [26–28], internal and external reflectors [29–31], vinyl chlo- ductivity equals to 0.038 W/m K and density equals to 70 kg/m3. The
ride sheet and polythene film transparent tubular covers [32], thermo- external face opposite to the sun is blackened with paint to increase
electric cooler [33], low cost technique [34–36], forced convection its solar radiation absorptivity, which in turn increasing the water tem-
inside the solar still [37,38], optimized position and size partition inside perature inside this tank because of conductive heat transfer from the
a single slope solar still [39] and nanomaterials with and without a vac- tank to the water.
uum fan [40]. The parameters affecting the performance of solar stills Two PVC water hoses are insulated from the ambient air with 10-
were studied to improve the yield [41–43]. Theoretical and numerical mm-thick nitrite foam (insulation pipes). Its thermal conductivity
studies were also reported for estimating the productivity and the con- equals to 0.038 W/m K and density equals to 70 kg/m3. Then, they are
vective heat transfer coefficient in solar stills [44–47]. connected to the main feeding tank to supply the two solar stills with
The best inclination of the condensing cover to give the highest yield saline water via floating valves. Two colored rulers are fixed on the op-
through receiving maximum solar radiation varies from season-to-sea- posite sides of each basin base of the stills to ensure depth adjustment of
son. However, it should be optimized from the annual yield perspective. saline water in both solar stills. Thermocouples (K-type model, Omega
Many researchers reported that the best cover inclination angle is near Engineering, USA) are fixed in different locations, inside and outside
[48–50] or nearly equivalent [5,51–57] to the latitude angle. Some other the solar stills, to measure the basin, saline water, air inside the solar
researchers concluded that this angle should be far from the latitude stills, and glass temperatures. The thermocouples are linked with a
angle [58–62]. Data and results from previous studies were obtained data logger (model GL 800, Graphtec Corporation, Yokohama Japan)
[57] for different locations, climate conditions, and solar still shapes; a to record temperatures every 5 min. Fig. 1 illustrates the experimental
trend for the variation between the latitude and optimum inclination setup.
angles for the cover was established. That is, when the latitude angle Fig. 2 shows the schematic diagram of DSSSHS. This still consists of
for the experiment location is increased, the inclination angle of the an aluminum rectangular base. The still dimensions are as follows:
condensing cover should also increase. In addition, the trend showed each of the basin length and width is 1000 mm; basin height is
that the best inclination angle for the condensing cover is close to the 30 mm; glass sides are 1000 mm in length; two opposite ones are of
latitude angle of the experiment's location. The minimum inclination fixed height, which is 100 mm; while the other two opposite ones are
of the glass cover should be at least 10° to avoid falling and/or slowing of height that starts from 100 mm at the edges, reaching 126.2 mm in
down the condensate [63]. the middle of their lengths; and basin area is 1 m2. The inner faces of
Most of previous studies have shown that the best productivity is the basin are painted with food grade, black paint to increase its solar
achieved when the condensing cover slope is the same as the latitude absorptivity. The thickness, thermal conductivity and density of the
angle of the experiment location. However, problems that result from basin are 3 mm, 222 W/m K and 2710 kg/m3, respectively. The base
the reduction in productivity when the condensate water stays on the and all sides of the basin are insulated from the outside by using 19-
inner surface of a small inclination condensing cover for a relatively mm-thick nitrite foam (insulation sheets). Its thermal conductivity
long time before collection were not resolved. Productivity reduction equals to 0.038 W/m K and density equals to 70 kg/m3.
occurs when the condensate film decreases the total amount of solar ra- Four inclined collecting channels are used to collect the condensed
diation that enters the solar still or when this condensate fall toward the water into two 3-L-capacity containers. The condensing still cover is a
basin because of gravitational force or re-evaporate when exposure to 2.6-mm-thick clear glass. Its thermal conductivity equals to 0.96 W/m
solar radiation. K and density equals to 2500 kg/m3. The cover is fixed on the edges of
In this study, a double-slope solar still hybrid with rubber scrapers the still sides with a 3.0° angle with horizontal plane, which is the lati-
(DSSSHS) is designed for the first time with a 3.0° slope condensing tude of the experiment location, maximizing the solar radiation intensi-
cover, which is equal to the latitude angle of the experiment location ty that enters the still. Two rubber scrapers are used to scrape the
(latitude N 3° 0′ 27.71″, longitude E 101° 43′ 15.24″ and 45 m height condensed water on the inner side of the condensing surface toward
from sea level). The main aim is to obtain maximum fresh water yield the PVC collecting channels, which lead the collected condensed water
during daytime using the DSSSHS. The proposed design makes use of toward the collecting containers.
the advantages of using the small slope of the condensing cover of the The movements of the rubber scrapers are achieved by using two
still. This allows higher solar radiation to enter into the still. Disadvan- 12 V DC motors, which are operated using DC current supplied from
tages resulting from using the small slope are solved by using the rubber two 12 V, 150 Ah DC batteries. The batteries are powered by a charger,
scrapers. No researcher has used the scrapers in solar still till to-date. which obtains its power from a 12 V, 200 W/h DC solar photovoltaic
These rubber scrapers have water guides (made of aluminum) with a panel. This model is mounted on a hollow iron post with 100 mm diam-
suitable slope and are fixed to collect scraped water during movement eter and 1100 mm length, which can be rotated 360° in a horizontal
of the rubber scrapers without allowing the fall of water drops toward plane. Speed, direction, and time interval of movements of the rubber
the basin of the still. scrapers are controlled by electrical control boards. In this study the
rubber scrapers are moving in 15 min intervals at 0.2 m/s speed. The
2. Methodology control boards consist mainly of DC 12 V delay relay timers, general pur-
pose relays, micro basic switch of rotary roller hinge lever, resistances,
2.1. Experimental setup and wiring system. These boards are operated using DC current, sup-
plied by two 12 V, 150 Ah DC batteries. To prevent any losses of collect-
In the current study, two solar stills are designed, manufactured, and ed water while scraping the condensed water, aluminum water guides
tested to study and compare their effectiveness. The first one is a dou- are fixed under each scraper. These guides have a suitable slope that di-
ble-slope solar still (DSSS) and the second one is DSSSHS. Both stills rects any amount of collected water through their open sides toward
A.O. Al-Sulttani et al. / Desalination 407 (2017) 61–74 63

Fig. 1. Photograph of the experimental setup.

the surrounding inclined collecting channels. All gaps are filled with The uncertainty percentage error of the experimental solar intensity
food grade silicon to prevent any leakage of saline and fresh water, values measured by the pyranometer is between ± 0.101% and
and water vapor from the solar still. DSSS has the same shape, dimen- ±0.108%, for solar intensities of 955.73 and 120.7 W/m2, respectively.
sions, and specifications with DSSSHS, except that the rubber scrapers The uncertainty percentage error of the experimental temperature
with all their related parts, such as motors and electrical control boards, values measured by thermocouples is between ± 0.729% and ±
do not exist in the DSSS, as shown in Fig. 3. 2.386%, for temperatures of 81.78 °C and 24.1 °C, respectively. The un-
Experiments are conducted at the Faculty of Engineering, UPM, certainty percentage error of the experimental yield values measured
43,400, Serdang, Selangor, Malaysia (latitude N 3° 0′ 27.71″, longitude by the electronic balance is between ±0.096% and ±0.1000% for hourly
E 101° 43′ 15.24″ and 45 m height from sea level) and carried out yields of 0.824 and 0.006 L/m2 h, respectively.
from 8:00 a.m. to 7:00 p.m. for five selected days (March 30, 2016 and
April 1, 8, 9, and 11, 2016). Glass, air inside the solar still, saline water, 2.2. Thermal model
basin and ambient air temperatures, and solar radiation are measured
and saved in the data logger every 5 min. The hourly values of these re- Heat transfer mechanisms inside the solar still depend mainly on the
cords are calculated. Specifically, the amount of distilled water is mea- amount of solar radiation entering the still and other climate parame-
sured every hour. Accumulated productivity during daytime is also ters. As solar radiation penetrates the atmosphere, some of the radiation
measured. These measurements assess DSSSHS performance under is scattered, reflected, or absorbed by the atmosphere, gases, clouds, and
field condition. All experiments are performed for a constant saline dust. Solar or global radiation is the amount of radiation reaching a hor-
water depth (19 mm). Hourly and accumulated total solar intensity, izontal plane [64,65]. Heat transfer in solar still is classified as external
yield, and temperatures are recorded. and internal heat transfer. External heat transfer is mainly governed
Temperatures inside and outside the solar still are measured by ther- by radiation, conduction, and convection, which are independent of
mocouples fixed at different positions inside and outside the solar stills, one another. Internal heat transfer is due to radiation, convection, and
as shown in Figs. 2 and 3. One thermocouple is used to measure temper- evaporation, wherein convection and evaporation are coupled together.
ature of the inner basin surface (Tb), and the other one is used to identify Saline water inside the still's basin is heated, and then, it evaporates be-
saline water temperature (Tw). Another thermocouple is placed inside cause of solar energy. The vapor is then transmitted freely from water
the still to measure the temperature of humid air inside the solar still surface toward the upper condensing cover of the still by the buoyancy
(Tv); and two thermocouples measure the temperature of transparent force caused by density reduction. Temperature difference between sa-
glass (Tg1 and Tg2). Glass temperature (Tg) which is used in this study line water and glass condensing cover will circulate the humid air inside
is the average value of Tg1 and Tg2. Ambient temperature of the surround- the still, causing heat and mass transfer that is instigated by natural con-
ing environment (Ta) is measured by using a thermocouple, which is vection. In other words, heat transfer from saline water to the condens-
placed in a shaded area outside the still. Adhesive tape is used to attach ing cover inside the solar still is due to convection, evaporation, and
these thermocouples properly. To obtain the actual readings for Tg1 and radiation [66].
Tg2, the thermocouples are covered from the outside with small pieces Dunkle's model, which is widely used by many researchers, is an
of aluminum foil to reflect direct solar radiation. A pyranometer (model empirical expression for the coefficient of convective heat transfer
8-48, Eppley Laboratory, Inc., Rhode Island USA) is placed outside the [67]. In Dunkle's model, the values of constants n and C are 1/3 and
still to measure solar radiation intensity. An electronic balance (model 0.075, respectively. This model has been used not only in conditions
EK6100i, A&D Company, Limited, California, USA) is used to measure that matches the limitations of this model but also in other conditions.
the hourly fresh water production during daytime. Therefore, examining the validity of Dunkle's model is considerably
64 A.O. Al-Sulttani et al. / Desalination 407 (2017) 61–74

Fig. 2. Schematic diagram of DSSSHS.


A.O. Al-Sulttani et al. / Desalination 407 (2017) 61–74 65

Fig. 3. Schematic diagram of DSSS.

important at least under the conditions that are out of the limitations of humid air (W/m K). The coefficient of convective heat transfer from
this model. Operating temperature ranges and shapes of the condensing water to glass cover is expressed as follows:
cover affect the values of n and C. Thus, using any values of those con-
stants that are calculated under simulated conditions will garner incor- CK
hcw ¼ ðGr  PrÞn
rect results. Thus, for theoretical prediction of still performance, d
performing experiments for a certain model under known climate con- ð3Þ
ditions to find the corresponding values of n and C is necessary. After
evaluating n and C experimentally, hcw and hew can be calculated with- Grashof and Prandtl numbers can be expressed by the following
out any limitation [68]. Furthermore, to predict the performance of any equations:
type of solar still in field conditions, convective mass transfer need to be  
3
estimated [69]. Bouyancy force g  β  d  ρ2v  ΔT
Gr ¼ ¼ ð4Þ
Viscous force μ2
2.2.1. Convective heat transfer from water to glass cover
Free convection, which results from buoyancy force and density var- where g is gravitational acceleration (9.807 m/s2); β is volumetric ther-
iation of humid air inside the solar still, will cause convective heat trans- mal expansion coefficient (K−1); ρv is the density of humid air (kg/m3);
fer inside the still. Regression analysis can develop the relationship for ΔT is the temperature difference between water surface and cover (°C);
convective heat and mass transfer coefficients. The general equation and μ is the viscosity of humid air (N s/m2).
for convective heat transfer can be expressed as follows:
μ  Cv
  Pr ¼
Q cw ¼ hcw  A  T w −T g ¼ hcw  A K
 ΔT ð1Þ ð5Þ

where Cv is the specific heat of humid air (J/kg °C).


where hcw is the coefficient of convective heat transfer from water to
Temperature-dependent physical properties of humid air given by
glass cover (W/m2 °C); A is the area of basin (m2); and ΔT is the temper-
[71] are as follows:
ature difference between saline water and glass condensing cover (°C).
The hcw is a function of flow characteristics, fluid properties, operating
K ¼ 0:0244  0:7673  10−4  T v ð6Þ
temperatures, and still geometry. The relation between Nusselt number
and heat transfer coefficient can be expressed as follows [70]:
β ¼ 1=ðT v þ 273:15Þ

Nu ¼ ðhcw  dÞ=K ð7Þ


¼ CðGr  Pr Þn ð2Þ
ρv ¼ 353:44=ðT v þ 273:15Þ
where d is the characteristic length of the still (m); Gr and Pr are Grashof ð8Þ
and Prandtl numbers, respectively (dimensionless); and C and n are
constant parameters (dimensionless). These constants can be calculated μ ¼ 1:718  10−5 þ 4:620  10−8
using linear regression analysis [70], and K is the thermal conductivity of  Tv ð9Þ
66 A.O. Al-Sulttani et al. / Desalination 407 (2017) 61–74

Cv ¼ 999:2 þ 0:1434  Tv þ 1:101  10−4  T2v −6:7581  10−8 In the same manner, evaporative heat transfer coefficient from
 T 3v ð10Þ water to glass cover for Dunkle's model (hewD (W/m2 °C)) can be
given as:

h  i P w −P g
hfg ¼ 3:1615  106  1− 7:616  10−4  T v ð11aÞ hewD ¼ 16:23  10−3  hcwD  ð18bÞ
T w −T g

for Tv N 70 ° C The Pw and Pg are expressed as follows [67]:


6
hfg ¼ 2:4935  10
  P w ¼ eð25:317−5144=ðT w þ273:15ÞÞ ð19Þ
 1−9:4779  10−4  T v þ 1:3132  10−7  T 2v −4:7974  10−9 T 3v

ð11bÞ P g ¼ eð25:317−5144=ðT g þ273:15ÞÞ ð20Þ

for Tv b 70° C By substituting Eq. (3) into Eq. (18a), hew will be:
The coefficient of convective heat transfer from water to glass cover
" #
for Dunkle's model is expressed by [67], which is as follows: K P w −P g
hew ¼ 16:23  10−3   C  ðGr  PrÞn    ð21Þ
d T w −T g
hcwD ¼ 0:884
   1 =3
  Pw −Pg
 Tw −Tg þ 3
 ðTw þ 273:15Þ ð12Þ When Eqs. (17) and (21) are substituted into Eq. (16), mew can be
268:9  10 −Pw expressed as:

16:23  10−3 K  
2.2.2. Radiative heat transfer from water to glass cover mew ¼   Aw  t  C  P w −P g  ðGr  Pr Þn ð22Þ
hfg d
For small cover inclination and large width of the still, water surface
and cover are considered as parallel surfaces. The rate of radiative heat
transfer from water to glass cover is given by [67], as follows: Assuming that:
 
qrw ¼ hrw  T w −T g ð13Þ 16:23  10−3 K  
  Aw  t  P w −P g ¼ S ð23Þ
hfg d
The coefficient of radiative heat transfer from water to glass cover is
given by [72], as follows: Eq. (22) can be rewritten as follows:
hm i
  2  ew
¼ C  ðGr  Pr Þn ð24Þ
hrw ¼ εeff  σ  ðT w þ 273:15Þ2 þ T g þ 273:15 S
 
 T w þ T g þ 546:3 ð14Þ
Using the logarithm for both sides of Eq. (24) gives the following:
hm i
ew
The εeff can be calculated as follows: ln ¼ lnC þ n  ln ðGr  Pr Þ ð25Þ
S

 −1 Eq. (16) represents a linear equation form that can be written as fol-
1 1
εeff ¼ þ −1 ð15Þ lows:
εw εg
Y ¼ Co þ m  X ð26Þ
where εg and εw are glass and water emissivity with values of 0.90 and
0.96, respectively (dimensionless); Tg and Tw are the temperatures of Where
glass and water, respectively (°C); and σ is Stefan–Boltzmann constant,
m¼n h
which is (5.6697 × 10−8 W/m2 K4). mew i
Y ¼ ln
S ð26Þ
2.2.3. Evaporative heat transfer from water to glass cover X ¼ ln ðGr  Pr Þ
C o ¼ ln C
The amount of distilled water is calculated using the following ex-
pressions [67,73]:
Values of n and C constants can be calculated using the method of
q  Aw  t linear regression analysis [70].
mew ¼ ew ð16Þ
hfg
2.2.4. Total internal heat transfer coefficient
where Combination of convective, radiative, and evaporative heat transfer
  coefficients obtained by Eqs. 3, 14 and 18a respectively forms the total
qew ¼ hew  T w −T g ð17Þ internal heat transfer coefficient (h1 (W/m2 °C)) as:

and h1 ¼ hcw þ hrw þ hew ð27aÞ

P w −P g
hew ¼ 16:23  10−3  hcw  ð18aÞ In the same manner, total internal coefficient of heat transfer for
T w −T g
Dunkle's model (h1D (W/m2 °C)) can be given as:
where hfg is the latent heat of water vaporization (J/kg); t is time inter-
val (s); and Aw is basin area (m2). h1D ¼ hcwD þ hrwD þ hewD ð27bÞ
A.O. Al-Sulttani et al. / Desalination 407 (2017) 61–74 67

2.2.5. External heat transfer 2.3. Energy balance equations


Heat transfer from solar still to the ambient is known as external
heat transfer. This heat transfer can be classified into two types. First 2.3.1. Energy balance equation for glass cover
one is the heat transfer from the condensing cover to the ambient The energy balance equation for unit area of glass cover which ex-
which is called top heat loss, the second is from the basin to the ambient changes heat with water and surroundings can be written as follows
which is known as bottom and sides heat loss coefficient. [78]:

2.2.5.1. Top heat loss coefficient ∂T g


mg C g ¼ Hg ðt Þ þ qcw þ qew þ qrw −qr;g−sky −qc;g−a ð37Þ
2.2.5.1.1. Radiative heat transfer. Radiative heat transfer rate from ∂t
glass cover to the sky (qr,g-sky (W/m2)) can be calculated as [63]:
where mg is the mass of glass cover (kg); Cg is the specific heat of glass
  cover (J/kg° C); and Hg(t) is the fraction of absorbed solar radiation by
qr;g−sky ¼ hr;g−sky T g þ 273:15−T sky ð28Þ
the glass cover (W/m2).
 2  2  
hr;g−sky ¼ εg σ T g þ 273:15 þ T sky T g þ T sky þ 273:15 ð29Þ 2.3.2. Energy balance equation for water
The energy balance equation for unit area of water which exchanges
Tsky can be calculated as [74]: heat with basin liner, glass cover and surroundings can be written as fol-
lows [78]:
T sky ¼ 0:0552ðT a þ 273:15Þ1:5 ð30Þ
∂T w
mw C w ¼ H w ðt Þ þ qc;b−w −qcw −qew −qrw ð38Þ
∂t
where hr.,g-sky is the radiative heat transfer coefficient from glass cover to
the sky (W/m2 °C) and Tsky is the sky temperature (K). where mw is the mass of water (kg); Cw is the specific heat of water (J/
2.2.5.1.2. Convective heat transfer. Convective heat transfer rate from kg ° C); Hw(t) is the fraction of absorbed solar radiation by the water
glass cover to the ambient (qc,g-a (W/m2)) can be calculated as [75]: (W/m2); and qc,b-w is the convective heat transfer rate from basin liner
  to water (W/m2). qc,b-w is expressed as [76]:
qc;g−a ¼ hc;g−a T g −T a ð31Þ
qc;b−w ¼ hc;b−w ðT b −T w Þ ð39Þ
hc,g-a can be calculated as [63,75]
where hc,b-w is the convective heat transfer coefficient from basin
hc;g−a ¼ 2:8 þ 3:0V ð32Þ liner to water (W/m2°C) which can obtained from the following
equations [56]:
where hc,g-a is the convective heat transfer coefficient from glass cover
to the ambient (W/m2 °C); and V is the wind speed (m/s).
1
=
kw  Raw 4
The total external heat transfer coefficient from glass cover to the hc;b−w ¼ 0:54  for Ra ¼ 104 to 107 ð40aÞ
Lw
ambient (h1g (W/m2 °C)), is the combination of radiative and convective
heat transfer coefficients which are obtained from Eqs. (29) and (32), 1
=
kw  Raw 3
respectively. hc;b−w ¼ 0:15  for Ra ¼ 107 to 1011 ð40bÞ
Lw
h1g ¼ hr;g−sky þ hc;g−a ð33Þ
where kw is the thermal conductivity of water (W/m K); Raw is the
Rayleigh number of water (dimensionless); and Lw is the character-
The top heat loss coefficient from water surface to the ambient istic length of water in the basin (m).
through glass cover (Ut (W/m2 °C)) can be expressed as [63] :

 −1 2.3.3. Energy balance equation for basin


1 lg 1 The energy balance equation for unit area of basin can be expressed
Ut ¼ þ þ ð34Þ
h1 kg h1g as follows [78]:

where kg is the thermal conductivity of glass (W/m K); and lg is the ∂T b


mb C b ¼ Hb ðt Þ−qc;b−w −qb−a ð41Þ
thickness of glass cover (m). ∂t

where mb is the mass of basin (kg); Cb is the specific heat of basin (J/
2.2.5.2. Basin heat loss coefficient. Heat loss coefficient from basin liner to
kg ° C); and Hb(t) is the fraction of absorbed solar radiation by the
the ambient (Ub-a (W/m2 °C)) can be written as [76]:
basin (W/m2).
 −1
lb l 1
U b−a ¼ þ i þ ð35Þ 3. Results and discussion
kb ki hi
Performance of each solar still was mainly affected by weather con-
where kb is the thermal conductivity of basin liner (W/m K); lb. is the
ditions, especially solar radiation, so the experimental work was done
thickness of basin liner (m); ki is the thermal conductivity of insulation
during sunny days of the year (March 30, 2016 and April 1, 8, 9, and
(W/m K); li is the thickness of insulation and hi is the convective heat
11, 2016). Figs. 4 and 5 show that peak value of solar radiation was
transfer coefficient from insulation to the ambient (W/m2 °C).
955.73 W/m2 at 3:00 p.m.
Heat loss from basin liner to the insulation by conduction and heat
loss from insulation to the ambient air by convection form the heat
3.1. Performances of solar stills
loss from basin liner to the ambient (qb-a (W/m2)), which can be written
as [77]:
Figs. 4 and 5 represent the variation of glass, air inside the solar still,
saline water, basin, and ambient air temperatures for DSSSHS and DSSS
qb−a ¼ U b−a ðTb −Ta Þ ð36Þ with daytime, respectively. Fig. 4 shows that still basin, saline water, air
68 A.O. Al-Sulttani et al. / Desalination 407 (2017) 61–74

Fig. 4. Variations of hourly basin, water, air inside the still, glass and ambient temperatures, and solar intensity during daytime for DSSSHS.

inside the solar still, and glass temperatures for DSSSHS reach the max- cover, increasing the amount of collected fresh water. Generally, this dif-
imum values of 81.78 °C, 76.67 °C, 69.84 °C, and 56.67 °C, respectively. ference is higher in DSSSHS than in DSSS because of the advantages of
Clearly, the basin receives and absorbs most of the energy from solar ra- using rubber scrapers. Increasing the temperature difference between
diation. The increase of basin temperature and of saline water tempera- evaporating and condensing areas will lead to productivity enhancement.
ture in effect starts the evaporation from the water surface. The Variances of the cumulative distilled fresh water during daytime for
condensed water on the inner surface of the glass cover is scraped DSSSHS and DSSS with cumulative solar intensity are shown in Fig. 6.
with two rubber scrapers toward PVC-collecting channels. Then, the The experiment is implemented at a constant height of saline water,
produced distilled water in the collecting containers is measured which is equal to 19 mm. Controlling the fixed height of saline water
using the electronic balance. DSSS exhibits the same performance is done by adding hot water from the main feeding tank of saline
with DSSSHS, but its glass, air inside the solar still, saline water, and water, which is controlled by a floating valve installed on a 1/2” inlet
basin temperatures are lower than those of DSSSHS. The maximum pipe fixed to the still's basin. Figs. 6 shows that DSSSHS gives higher
values for basin, saline water, air inside solar still, and glass tempera- yield compared with DSSS. The daily productions of fresh water for
tures for DSSS are 72.87, 70.95, 69.01, and 59.56 °C, respectively, as illus- DSSSHS and DSSS are 4.24 and 2.6 L/m2.day, respectively.
trated in Fig. 5. Ambient air and glass temperatures increase from the Use of rubber scrapers enhances the productivity of the still by 63%
early morning until they reach their peak values at about 4:00 p.m. due to increasing the solar intensity that enters the solar still and pre-
Then, they begin to decrease to the end of daytime. vents re-evaporation of condensate film, and avoids falling down of con-
For both DSSSHS and DSSS, Figs. 4 and 5 show that along daytime, sa- densed water drops. Usually, the condensed water drops accumulate
line water and glass cover have a significant temperature difference. This and stick on the inner surface of the glass cover for relatively longer
assists water vapor to condense on the inner side of the glass condensing time of an ordinary still.

Fig. 5. Variations of hourly basin, water, air inside the still, glass and ambient temperatures, and solar intensity during daytime for DSSS.
A.O. Al-Sulttani et al. / Desalination 407 (2017) 61–74 69

Fig. 6. Comparison between the cumulative hourly experimental productivities for DSSS and DSSSHS with cumulative solar intensity.

3.2. Heat transfer coefficients As mentioned previously, Dunkle's model is widely used by many
researchers, in which the values of constants n and C are 1/3 and
To evaluate the performances of DSSSHS precisely, accurate relations 0.075, respectively. This model has been used not only in conditions
for the calculation of heat and mass transfer coefficients in this solar still that matches the limitations of this model but also in other conditions.
should be used. The suggested empirical relation required for the de- Therefore, examining the validity of Dunkle's model is considerably im-
scription of analogy for heat transfer of these stills is represented by portant at least under the conditions that are out of the limitations of
Eq. (2), which is: Nu = C(Gr .Pr)n. this model [68,79].
The method of linear regression analysis is used to calculate the Fig. 9 shows the experimental results of the hourly yields according
values of n and C constants from Eq. (25). The calculated values of to this study for both DSSS and DSSSHS models with the theoretical
constants n and C for DSSSHS are 0.166 and 0.486, respectively, and hourly yields according to this study and Dunkle's model for DSSSHS.
coefficient of determination R2 for this regression analysis is 0.951. The DSSSHS model gives an excellent output, reaching the value of
R2 for regression analyses shows that dependent variable and inde- 0.824 L/m2 h, while DSSS model gives a maximum flow that is equal
pendent variables have a strong relationship. Then, the values of to 0.453 L/m2 h. Theoretical and experimental results are compared
heat transfer coefficients, hcw, hrw, and hew, are calculated directly for DSSSHS model. Statistical analysis shows that the error for DSSSHS
using Eqs. (3), (14), and (21), respectively; while hcwD is calculated model is 2.91%.
using Eq. (12) for comparison purposes. Convective heat and mass It is observed from Fig. 9 that the deviations of Dunkle's model yields
transfer coefficients are significant parameters in measuring heat (which are based on n and C values equal to 1/3 and 0.075, respectively)
and mass transfer resistance between water surface and air over are far from the experimental yields for DSSSHS. The theoretical yields
that surface. of this study which are based on the proposed values of n and C
Table 1 shows the values of convective, radiative, and evaporative (0.166 and 0.486, respectively) are very close to the experimental
heat transfer coefficients from water to glass cover for DSSSHS using yields.
this study and Dunkle's model. The highest values of convective, evapo-
rative, and radiative heat transfer coefficients from water to glass cover Table 1
in the daytime for DSSSHS according to this study are 1.479, 29.503, and Comparison of convective, evaporative and radiative heat transfer coefficients from water
to glass cover of this study with Dunkle's model for DSSSHS.
7.776, respectively and according Dunkle's model are 3.349, 66.613, and
7.776, respectively. Maximum values of radiative and evaporative heat DSSSHS (this study) DSSSHS (Dunkle)
transfer coefficients depend on solar radiation intensity and tempera- hcw hew hrw hcwD hewD hrwD
tures of the saline water and basin. Radiative and evaporative heat Time (W/m2°C) (W/m2°C) (W/m2°C) (W/m2°C) (W/m2°C) (W/m2°C)
transfer coefficients reach their peak values at 4:00 p.m. and then 09:00 0.851 2.654 5.257 1.139 3.554 5.257
trend downward to lower values at the end of daytime. 10:00 0.941 4.485 5.723 1.383 6.594 5.723
Fig. 7 shows the variation of coefficient of convective heat transfer 11:00 1.137 8.164 6.225 2.007 14.405 6.225
from water to glass cover during daytime according to this study and 12:00 1.306 14.741 6.850 2.625 29.635 6.850
13:00 1.416 21.933 7.337 3.080 47.692 7.337
Dunkle's model for DSSSHS. The results of present work have a consid-
14:00 1.470 26.361 7.579 3.315 59.436 7.579
erable difference of hcw values for DSSSHS model from its corresponding 15:00 1.479 27.854 7.665 3.349 63.072 7.665
hcwD for Dunkle's model, which agree with [68]. 16:00 1.475 29.503 7.776 3.330 66.613 7.776
Fig. 8 shows the variation of total coefficient of heat transfer for 17:00 1.345 17.928 7.104 2.780 37.061 7.104
DSSSHS during daytime according to this study (hcw) and Dunkle's 18:00 1.253 12.720 6.698 2.426 24.624 6.698
19:00 1.162 8.894 6.309 2.097 16.058 6.309
model (hcwD). The maximum values of total coefficient of heat transfer
for DSSSHS according to this study (h1) is 38.754 W/m2°C which oc- Note: DSSSHS: Double-slope solar still hybrid with rubber scrapers; hcw, hrw, and hew:
Convective, radiative and evaporative heat transfer coefficients from water to glass
curred at 4:00 p.m. High deviation between total coefficient of heat
cover for this study using Eqs. (3), (14) and (21), respectively; hcwD, hrwD, and hewD: Con-
transfer according to this study (h1) and Dunkle's model (h1D) for vective, radiative and evaporative heat transfer coefficients from water to glass cover for
DSSSHS during daytime can be noticed clearly in this figure. Dunkle's model using Eqs. (12), (14) and (18b), respectively; hrw = hrwD.
70 A.O. Al-Sulttani et al. / Desalination 407 (2017) 61–74

Fig. 7. Variation of coefficient of convective heat transfer from water to glass cover hcw during daytime according to this study and Dunkle's model for DSSSHS.

As noted from Figs. 7, 8, and 9, there is a high deviation of hcw, h1, 3.3. Cost analysis
and yield (this study) values from their corresponding values of
h cwD , h1D , and yield (Dunkle's model), respectively. Therefore An economic analysis of the DSSSHS is performed where the annual
the Dunkle's model cannot be used for the performance study of fixed cost, annual salvage cost and annual maintenance cost are used for
DSSSHS. estimating the annual total cost [80].
Fig. 10 shows the relation between daily solar radiation and their The annual fixed cost (AFC) can be obtained as:
corresponding values of experimental and theoretical daily water pro-
duction of DSSSHS for five selected days (March 30, 2016 and April 1,
i  ð1 þ iÞul
8, 9, and 11, 2016). It is clear from this figure that the experimental AFC ¼  TFC ð31Þ
and theoretical values of the daily yield are directly proportional to ð1 þ iÞul −1
the solar intensity that entering into the still.
It can also note that there is a convergence between the experimen- where ul is the useful life of the still, which is taken as 20 years; TFC is
tal yields and the theoretical ones according to this study. However, the- the total fixed cost of the still; i is the rate of interest, taken as 12% of TFC.
oretical yields calculated based on Dunkle's model are far from The annual maintenance cost (AMC) is taken as 10% of AFC which
experimental values of daily water production. includes saline water filling, distilled water collection, glass cover

Fig. 8. Variation of total coefficient of heat transfer h1 according to this study and Dunkle's model for DSSSHS during daytime.
A.O. Al-Sulttani et al. / Desalination 407 (2017) 61–74 71

Fig. 9. Hourly variation of experimental and theoretical productivities for DSSSHS and experimental productivities for DSSS.

cleaning, rubber scrapers replacement, maintenance of electrical boards water for the DSSSHS is 0.03 $/kg, so the payback period of this still is
and removal of salt deposited. 376 days.
The annual salvage cost (ASC) of the still is calculated as:
4. Conclusions
i
ASC ¼  Sa ð32Þ
ð1 þ iÞul −1 In the current study, a new DSSSHS model was designed,
manufactured, tested, and operated during daytime under the climate
where Sa is the salvage value of the still taken as 20% of TFC. conditions of Serdang, Selangor, Malaysia. The following conclusions
Then, the still annual total cost (SATC) can be determined by: can be drawn from this study:

SATC ¼ AFC þ AMC−ASC ð33Þ 1. The DSSSHS model, in which rubber scrapers are used to scrape the
condensation drops that accumulate on the inner surface of the
The average daily productivity of the still is determined as glass (condensing cover), is better than the DSSS from productivity
4.24 kg/m2. The still is expected to operate 335 days in a year as per point of view. The validity of this result is achieved by combining
the sunshine duration characterizing the region of Serdang, Malaysia. the use of rubber scrapers and small slope for glass condensing
As a result, the cost of a liter of distilled water can be calculated from di- cover, which is equal to the latitude angle of the experiment's loca-
viding the SATC by annual yield of the still. Table 2 shows the cost esti- tion (3.0°). Low inclination of the glass condensing cover in low-lat-
mation of the DSSSHS components. The economic analysis of DSSSHS is itude location allows more solar radiation to reach the basin of the
illustrated in Table 3. This analysis clearly shows that the cost of distilled still. This increases the temperature of the saline water inside the

y = 0.5061x - 3.1537
R2 = 0.9269

y = 0.1442x + 0.6918
R² = 0.9117

y = 0.1723x + 0 .1087
R² = 0.9738

Fig. 10. Relation between daily production and daily solar radiation for DSSSHS.
72 A.O. Al-Sulttani et al. / Desalination 407 (2017) 61–74

Table 2
Cost estimation of the DSSSHS components.

Unit components Quantity Cost/unit (RM) Cost

Glass cover 1.46 m2 46.3/m2 RM 67.6 (16.15 US$)


Aluminum trough 1.124 m2 210/m2 RM 236 (56.39 US$)
Electrical boards including sensors and wiring system 2 pieces 100/piece RM 200 (47.79 US$)
DC 12 V motor 2 pieces 90/piece RM 180 (43.01 US$)
Rubber scrapers 2 pieces 8/piece RM 16 (3.82 US$)
Aluminum frame for glass 2 pieces 30/piece RM 60 (14.34 US$)
Insulation materials 1.124 m2 27.5/m2 RM 30.91 (7.39 US$)
Steel stand 1 piece 210/piece RM 210 (50.18 US$)
PVC water hose with insulation, valves and fittings Lump sum RM 80 (19.12 US$)
Silicon for sealing, black paint for trough and water collecting system Lump sum RM 65 (15.53 US$)
Pulleys, shafts, rollers and other accessories Lump sum RM 40 (9.56 US$)
Labor cost Lump sum RM 250 (59.74 US$)
Total fixed cost (TFC) RM 1435.51 (343.01 US$)

Note: 1 US$ = RM 4.185

still, thereby increasing the temperature difference between water Cw Specific heat of water (J/kg° C)
surface and glass condensing cover and further increasing the yield d Characteristic length of solar still (m)
of the still significantly. Similar phenomenon will happen when rub- g Gravitational acceleration (9.807 m/s2)
ber scrapers scrape and collect the water condensate accumulated on Gr Grashof number (5.45 × 105 b Gr b 3.39 × 106)
the inner side of the glass condensing cover. This makes the cover Hb(t) Fraction of absorbed solar radiation by the basin (W/m2).
more transparent, allowing more solar intensity to penetrate hc,b-w Convective heat transfer coefficient from basin liner to water
through it and reach the basin. The advantage of using rubber (W/m2°C)
scrapers to increase the productivity of the still is not limited to the hc,g-a Convective heat transfer coefficient from glass cover to the
increase in the solar intensity entering into the still. The use of rubber ambient (W/m2 °C)
scrapers also prevents re-evaporation and dropping down toward hcw Convective heat transfer coefficient from water to glass cover
the basin of the still of the condensate accumulated and left for rela- (W/m2 °C)
tively longer time on the inner side of the glass condensing cover. hcwD Convective heat transfer coefficient from water to glass cover
2. For DSSSHS the theoretical yields were found to be in good agree- for Dunkle's model (W/m2 °C)
ment with their experimental values. The coefficient of determina- hew Evaporative heat transfer coefficient from water to glass
tion (R2) between the theoretical and experimental yields was cover (W/m2 °C)
0.997 indicating a strong correlation. hewD Evaporative heat transfer coefficient from water to glass
3. The maximum values of hcw, hew, and mexp that obtained for the cover for Dunkle's model (W/m2 °C)
DSSSHS model were found to be 1.479 W/m2 °C, 29.503 W/m2 °C, hfg Latent heat of vaporization (J/kg)
and 0.824 L/m2 h, respectively. Hg(t) Fraction of absorbed solar radiation by the glass cover (W/
4. Using DSSSHS model enhanced the productivity by 63%, compared m2)
with the use of DSSS under the same climate conditions. hi Convective heat transfer coefficient from insulation to the
ambient (W/m2 °C)
Nomenclature hr,g-sky Radiative heat transfer coefficient from glass cover to the sky
A Surface area of the basin (m2) (W/m2 °C)
AFC Annual fixed cost of the still (US$/year) hrw Radiative heat transfer coefficient from water to glass cover
AMC Annual maintenance cost of the still (US$/year) (W/m2 °C)
ASC Annual salvage cost of the still (US$/year) hrwD Radiative heat transfer coefficient from water to glass cover
Aw Area of water (m2) for Dunkle's model (W/m2 °C)
AWP Annual water productivity (kg/year) Hw(t) Fraction of absorbed solar radiation by the water (W/m2)
C Experimental constant for Nusselt number expression h1 Total internal heat transfer coefficient (W/m2 °C)
Cb Specific heat of basin (J/kg ° C) h1D Total internal heat transfer coefficient for Dunkle's model (W/
CDWP Cost of daily water produced (US$/kg) m2 °C)
Cg Specific heat of glass cover (J/kg ° C) h1g Total external heat transfer coefficient from glass cover to the
Cv Specific heat of humid air (J/kg °C) ambient (W/m2 °C)
i Rate of interest taken as 12% of the total fixed cost of the still
Table 3 (%)
Economic analysis of the DSSSHS. K Thermal conductivity of humid air (W/m K)
Cost types Value
kb Thermal conductivity of basin liner (W/m K)
ki Thermal conductivity of insulation (W/m K)
Total fixed cost (TFC) 343.01 US$
kg Thermal conductivity of glass cover (W/m K)
Annual salvage cost (ASC) 0.95 US$/year
Annual fixed cost (AFC) 45.92 US$/year kw Thermal conductivity of water (W/m K)
Annual maintenance cost (AMC) 4.59 US$/year lb Thickness of basin liner (0.003 m)
Annual water productivity (AWP) 1420.40 kg/year lg Thickness of glass cover (0.0026 m)
Still annual total cost (SATC) 49.56 US$/year
li Thickness of insulation (0.019 m)
Cost of daily water produced (CDWP) 0.03 US$/kg
Net profit (NF) 305.54 US$/year Lw Characteristic length of water in the basin (m)
Payback period (PP) 376 days m Constant in Eq. (26)
Note: The basin area is 1 m2. The market price of distilled water (MPDW) is considered as
mb Mass of basin (kg)
0.25 US$/kg. CDWP = SATC/AWP; NF = AWP × (MPDW − CDWP); PP = (TFC / NF) × still mew Hourly theoretical distillate yields (kg)
operation days per year. mg Mass of glass cover (kg)
A.O. Al-Sulttani et al. / Desalination 407 (2017) 61–74 73

MPDW Market price of distilled water (US$/kg) Acknowledgment


mw Mass of water (kg)
n Exponent for Nusselt number expression The authors would like to express their gratitude to the support pro-
NF Net profit (US$/year) vided by Universiti Putra Malaysia (UPM) (9460700; GP-IPS/2015/
Nu Nusselt number (dimensionless) 9460700). The first author also acknowledges the scholarship program
Pg Saturation vapor pressure of water at cover temperature (N/ from Iraq's Ministry of Higher Education and Scientific Research for
m2) their scientific assistance and financial support.
PP Payback period (day)
Pr Prandtl number (dimensionless)
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