Competitive Equi I

Exatns.

Example 4 :
I'Vritethe unit of
equi/lb/i(itn constant (K) [or the given reaction.
Baco BOO(s) O) R c-
Solution :

Example 5 : VI/ntethe relation between K, and K for the following reactions.

(i) + 3H ,(g) 2NHJg)

(li) 2H.O(g) 2H2(g) + 02(g)
Solution .

EXERCISE
In a closed system: A(s) 2B(g) + 3C(g) if the partialpressureof C is doubledthen partialpressure of
B will be
(1) Twice the orignal pressure (2) Half of its orignal pressure

times, the original pressure (4) 2N/ä times its original pressure

2. Sulphide ion reacts with solid sulphur

(aq)

(aq) •K = 130
The equilibrium constant for the formation of S32-(aq) from S22-(aq) and sulphur is
(2 13
(3) 130 (4) 1300
3. For the reaction,Caco ——y caqs) + CO K is equalto
( ) KcRT

4. The active mass of 7.0 g of nitrogenin a 2.0 L containerwouldbe

(1) 0.25 (2) .125
(3) 0.5 (4) 14.0
5. For the system 3A + 2B C, the expressionfor equilibriumconstantK is

[AJ3 x [B]

(4)

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 184 Equilibrium
Board & Competitive Exams.
6. A state of equilibrium
is reached when
(1) The rate of
forward reaction is •greater
(2) The concentration than the rate of the reverse reaction
of the products and reactants are equal
(3) More product is
present than reactant
(4) ) The concentration
of the products and reactants have reached constant value
In which of the following
cases, the reaction goes farthest to completion?

(4) X + Y XY2 (K = 10-1)

8. The ratio of Kp/Kc for reaction

CO(g) + 2 02(g) C02(g) is

9. For the reactionA + 3B 2C + D, initialmole of A is twicethat of B. If at equilibriummoles of B and C

are equal, then percent of B reacted is
(2) 20%
(3) 40% 4) 60%
O. The equilibriumA(g) + 4B(g) AB4(g) is attainedby mixingequal moles of A and B in a one litre vessel.
Then at equilibriumu

Try Yourself
3. The value of the equilibrium constant for the reaction
H2(g) + 12(g) 2HI(g)
at 720 K is 48. What is the value of the equilibrium constant for the reaction.

H2(g) + —12(g)

4. For the reaction,A(g) + B(s) C(g) + D(g). KG= 49 mol L-1 at 1270C. Calculate K

APPLICATIONS OF EQUILIBRIUM CONSTANT

 Exams,
Board P, Com otitive

spontaneous in
• or tho

the the ret;tlion spontane'tycah be interpretedin ferrns the vn ue

- NC,URI ts positive and > 1 making K > which implies a spontaneous

the teact:on which proceeds In the forwarddirection to such an extent that the products are
predom;nant'y
O. then is negative and e < 1, i.e., K < 1, which implies a non-spontaneous
reaction a which proceeds in the forward direction to such a small degree that only a very
m;nwtequantity ot product is formed.

Try Yourse!f
7 The value of AG Ofor the phosphorylationof glucose in glycolysis is 13.8'kJ/rnol. Find the value
of at 298 K.
8 Hydro*ysisof sucrose gives
Sucrose+ H O Glucose+ Fructose
Equilibriumconstant Kc for the reaction is 2 x 1013at 300 K. Calculate AGOat 300 K.

EXERCISE
11 The numencal value of equiåibnumconstant depends on
(1) Temperature (2) Pressure
(3) Concentration of reactants (4) All of these
12. The favourable conditions for mefting of ice is
(1) Low pressure (2 High pressure
(3) Low temperature (4) Absence of catalyst
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 —Eüoard &
Competitive
Exatns.
13. The
oxidation of
so and 02 Equilibrium
(l) to SO; is
an e
and pressure
(3) Temperature both are
increased decreased, pressure increased
increased, pressure
constant (4) Temperatureand pressure both decreased
C + D, K for
In a container this reaction is 10.
at 25 0C, the If 1, 2, 3, 4 mole/litreof A, B, C and
direction of reaction D respectively are present
From left to right will be
(3) Reaction is at (2) From right to left
equilibrium
15. For the reaction (4) Unpredictable
CÖ(g) + 2H2(g)
H2 is tripled, the
rate of forward reactionCH30H(g). If active mass of CO is kept constant and active mass of
will become
(i) Three times
• (2) Six times
(3) Eight times
(4) Nine times
16. The equilibrium
constant for the reaction, H +1
2(g) 2Hl(g)
is 32 a-t a given temperature.
8 x 10 -3 M respectively. The equilibrium concentration of 12and HI are 0.5 x 10-3 and
The equilibriumconce trationof 1--12
is
(1) 1 x 10-3 M
(2) 0.5 x 10-3 M
(3) 2 x 10-3 M (4) 4 x 10-3 M
17. For the reaction equilibrium, 2NOBr(g)
2NO(g) +

If P = — at equilibrium and P is total pressure, the

ratio of is equal to

81

(3)

18. When 20 g of CaC03 were put into 10 litre flask and heated to 8000C, 30% of CaC03 remained unreaågciåt
equilibrium. K for decomposition of CaC03 willbe

(1) 1.145 atm (2 1.231 atm

(3) 2.146 atm (4) 3.145 atm
19. At temperature T K, PC15 is 50% dissociated at an equilibriumpressure of 4 atm. At what pressure it would
dissociate to the extent of 80% at the same temperature?
(1) 0.05 atm (2) 0.60 atm
(3) 0.75 atm (4) 2.50 atm

s— CHrCH-CH
20. For the equilibrium,CH3CH2CÅ2CH3(g)
CH3
iso-butane

If the value of Kc is 3.0, the percentageby mass of iso-butane in th equilibriummi ture would be
(2) 90%
(4) 60%
(3) 30%
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Board & CompetitiveExams. Equilibrium 193

EXERCISE
21, 2H2(g)
+ CO(g) CH IOH(g), AH = —92.2kJ. Which of the following condition will shift the equilibrium in
the forward direction?
1) CO is removed .c N e {2) CH30H is added
(3 The pressure of the system is increased (4) Temperatureof the system is increased
[Feo k 2NH3(g);
22. In the manufacture of NH3 by Haber's process involving the reaction. N2(g) + 3H2(g)
AH = —22.08kcal. The favourableconditionsare
(1 High pressure and low temperature (2) Low pressure and low temperature
(3) High pressure and high temperature (4) Low pressure and high temperature
23. Ice and water are placed in a closed containerat a pressure of 1 atm and 273.15 K temperature.If pressure
of the system is increased by 2 atm keeping temperatureconstant the correct observation would be
(1) The liquid phase disappears completely
(2) The amount of ice increases
(3 The solid phase (ice) disappears completely
(4) Volume of the system increases
1
ions times will cause the
24. In the system ; Fe(OH) (aq), decreasing the conc. of OH 3
equilibrium conc. of Fe 3+ to increase . times

(4 27
(3) 18
water in equilibriumwith water vapour at 250C. Which
25. A cylinder filled with a movable piston contains liquid
equilibriumvapour pressure?
one of the following operations results in a decrease in the
(1) Moving piston downward a short distance
(2) Removing a small amountof vapour
(3) Removing a small amount of the liquid water
(4) Dissolving salt in the water
equilibriumconstant?
26. Which of the following will change the value of
(I) Change in concentration of reactant (2) Change in amount of catalyst

(3) Change in pressure (4) Change in temperature

27. Choose the correct statement

(1) Catalyst increases the rate of reaction
(2) Catalyst decreases the time of attainmentof equilibrium
(3) Catalyst decreases the activationenergy
(4 All are correct
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194 Equilibrium Board & CompetitiveExams.
28. In which of the following equilibrium,
change in pressure will not affect the equilibrium?
2NH3(g)
(2) H2(g) + 12(g)
21-11(g)

(3) PCI (g) PC13(g) +

5 C12(g)

29. If Kl is the equilibriumconstant at temperatureT I and K2 is the equilibriumconstant at temperatureT2, and

if T > Tl and reactionis endothermicthen

Ives
4) All of these
30. If Ar is added to the equilibrium N2(g) + 3H2(g) 2NH., at constant volume, then equilibrium will
(1) Shift in forward direction
(2) Shift in reverse direction
(3 Not shift in any direction
(4) All are incorrect

Try Yourself

9, The followingsystem is in equilibrium. + Heat SO + Cl 2

What will happen to the temperatureof the system initially if some C12is added into it at
constant volume?
10. Mentionat least three ways by which the concentrationof S03 can be increased in the
following reaction in a state of equilibrium
2S02(g) + 02(g) 2S03(g) + Heat