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Arjuna JEE (2024)

Thermodynamics DPP-04

1. Correct expression of 1st law of 7. If w1, w2, w3 and w4 for an ideal gas are
thermodynamics. magnitude of work done in isothermal, adiabatic,
(1) ΔU = q2 + w isobaric and isochoric reversible expansion
(2) ΔU = q – w processes, the correct order will be
(3) ΔU = q + w2 (1) w1 > w2 > w3 > w4
(4) ΔU = q + w (2) w3 > w2 > w1 > w4
(3) w3 > w2 > w4 > w1
2. For an adiabatic process
(4) w3 > w1 > w2 > w4
(1) dq = 0 (2) dU = 0
(3) dV = 0 (4) none of these
8. Consider the following cyclic process
3. A system absorb 10kJ of heat at constant
volume and its temperature rises from 270°C
to 370°C. The value of U is
(1) 100 kJ (2) 1 kJ
(3) 0 kJ (4) 10 kJ

4. In thermodynamics, a process is called

reversible when I. Isothermal
(1) Surroundings and system change into each II. Adiabatic
other III. Constant-pressure process
(2) There is no boundary between system and Sum of the work and heat in the above is
surroundings (1) Zero
(3) The surroundings are always in equilibrium (2) PV
with the system (3) R
(4) The system changes into the surroundings (4) – pV
spontaneously
9. A sample of an ideal gas undergoes an expansion
5. For an isothermal expansion correct relationship
against a constant external pressure of 1 bar from
between Wirr and Wrev (magnitude only)
1.0 m3, 1 bar and 273 K to 10.0 m3, 1 bar and 273
(1) Wirr > Wrev K. What was the work done by the system on the
(2) Wirr = Wrev surroundings?
(3) Wirr < Wrev
(4) None of these 10. Calculate the work done (in Kcal) when 56 g of
iron reacts with hydrochloric acid in
6. In an adiabatic expansion of an ideal gas
(A) A closed vessel of fixed volume,
(1) T = 0 (2) w = 0
(B) An open beaker at 27°C.
(3) q = 0 (4) U = 0
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11. Assign the sign of work done (based on SI 14. I and II are two isotherms, between p and V
convention) in following chemical changes
taking place against external atmospheric
pressure.
(A) 3H2(g) + N2(g)  2NH3(g)
(B) CH4(g) + 2O2(g)  CO2(g) + 2H2O(g)
(C) CaCO3(s)  CaO(s) + CO2(g)
(D) NH4HS(s)  NH3(g) + H2S(g) Select correct alternate
(E) PCl5(g)  PCl3(g) + Cl2(g) (1) I is a reversible process while II is
(F) C(s) + CO2(g)  2CO(g) irreversible process
(G) C2H6(g) + 3.5O2(g)  2CO2(g)+3H2O(l) (2) I is irreversible process while II is
reversible process
12. One mole of an ideal monoatomic gas initially (3) Both are reversible process
at 27°C occupying volume of 10 L undergoes (4) Both are irreversible process
adiabatic expansion to 20 L against a constant
external pressure of 1 atm. Thus, final 15. The work by the gas in reversible adiabatic
temperature is expansion process is
(1) 218.8 K (2) 150.0 K P2V2  PV
1 1 P V  PV
(1) (2) 2 2 1 1
(3) 175.2 K (4) 0 K  1  1
P2V2  PV
1 1
13. An engine takes up 80.0 kJ of heat to complete (3) (4) None of these

the cycle as shown. Thus, efficiency is

(1) 40.1% (2) 20.6%

(3) 70.2% (4) 50.6%
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Note: Kindly find the Video Solution of DPPs Questions in the DPPs Section.
Answer Key
1. (4) 10. (A) W = 0 (B) –0.6 kcal
2. (1) 11. (A) +ve (B) 0
3. (4) (C) –ve (D) –ve
4. (3) (E) –ve (F) –ve
5. (3) (G) +ve
6. (3) 12. (1)
7. (4) 13. (4)
8. (1) 14. (2)
9. –900 kJ 15. (1)

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