KAPILLIVE

KAPIL RANA (IIT KGP)

Use Code
KAPILLIVE
FOR DISCOUNT ON UNACADEMY
PLUS SUBSCRIPTION
 Hypovalent

Not
Valid
For
Odd
Hypervalent Electron
Species
 Species can’t act as lewis
acid:

1. SF6 ( Kinetically Inert)

2.(BCl3 + Cl-) and Similar is BBr3/BI3 ,
3. (SiCl4 , 2Cl- ) and Similar is SiBr4, SiI4.
4. (PBr5, Br- ) , (PI5 , I-)
5.(XeF2, F-)
✓ C-C > Si-Si
✓ P-P > N-N
✓ S-S > O-O
✓ Cl2 > Br2 > F2 > I2
✓ C-C > N-N > F-F>O-O
 EXCEPTIONAL STRUCTURE

➢ Structure of H4P2O5 : ժ

➢ Structure of H2S2O3 :

➢ Steric Repulsion in Bond Angle : When C.A is O/C

and bulky group are 2Cl /2 Br / 2I / 2Me / 2 SiR3
 PH5
IH7 SH4
Species
Species that doesn’t exist : PH5, SH4 , SH6 ,that
XeH2 , XeH4 , IH7 ,
doesn’t
exist
XeH4 SH6
XeH2
 NOBLE GAS
PSEUDO NOBLE GAS CONFIGURATION
CONFIGURATION CATION WITH 8e-S (φ)
CATION (φ)
AND NON-INERT GAS
>
Species that doesn’t exist : PH5, SH4 , SH6 , XeH2 , XeH4 , IH7 ,
(IRRESPECTIVE OF
CHARGE AND SIZE
CONFIGURATION (φ) EXCEPT Al3+, Be2+, Li+,
Mg2+)
Species that doesn’t exist : PH5, SH4 , SH6 , XeH2 , XeH4 , IH7 ,
1.(Fe(NH3)6)2+ | (Mn(NH3)6)2+ : sp3d2
2.(NiF6)2- : d2sp3
3.CO3+ → Irrespective of Nature of Ligand
(Before Fluoride in Spectrochemical
Series) : d2sp3
4.5d T.S | 4d T.S → Inner Orbital Complex
5.( Ni(NH3)2Cl2) – Sp3
1.Chelation > Strength of Ligand (Except
Carbon Donor)
2.Geometry > Strength of Ligand
3.Geometry > Charge on Central Metal
ion
4.(5d > 4d > 3d) > Strength of Ligand
 Down The Across The
Group Period

• Tl > In > Al > Ga > B

• 5d = 4d > 3d ( Gp No 4 to 11)
• Eu > Size decreases across (Ce) to (Lu)
• Sc > Ti > V > Cr < Mn > Fe = Co = Ni <Cu<Zn
 Down The Across The
Group Period

✓ B > Tl > Ga > Al > In

✓ C > Si > Ge > Sn < Pb
✓ 5d > 3d > 4d ( Gp no 7 to 9 & 11)
✓ 5d > 4d > 3d( Gp no 5, 6 and 10)
 • 3rd Period > 2nd Period
P-Block • Li>B

Heg = +ve • N|Be|Mg|

• Gp | 18
i.e. E.A =0
 Down The Across The
Group Period

▪ B > Tl>In>Ga>Al
▪ C > Pb >Si=Ge=Sn
▪ N > P > As > Sb = Bi
 Reactions With Oxygen

Species that doesn’t exist : PH5, SH4 , SH6 , XeH2 , XeH4 , IH7 ,
 Reactions With HNO3:

Species that doesn’t exist : PH5, SH4 , SH6 , XeH2 , XeH4 , IH7 ,
 Reactions With H2O

Species that doesn’t exist : PH5, SH4 , SH6 , XeH2 , XeH4 , IH7 ,
 Preparation of BeCl2 and BeF2

Species that doesn’t exist : PH5, SH4 , SH6 , XeH2 , XeH4 , IH7 ,
 Diamond and Graphite

Species that doesn’t exist : PH5, SH4 , SH6 , XeH2 , XeH4 , IH7 ,
 Carbides , Hydride and Hydride Gap

Species that doesn’t exist : PH5, SH4 , SH6 , XeH2 , XeH4 , IH7 ,
 Alum

Species that doesn’t exist : PH5, SH4 , SH6 , XeH2 , XeH4 , IH7 ,
 Alum

Species that doesn’t exist : PH5, SH4 , SH6 , XeH2 , XeH4 , IH7 ,