CHEMISTRY CHEMICAL BONDING

EE
ChemicalTJ
:
Bonding
A
d e
C o
Ashwani Tyagi Sir (Code: ATJEE)
Chemistry

ASHWANI TYAGI SIR 1 CODE: ATJEE

CHEMISTRY CHEMICAL BONDING
PRACTICE DPP # 1
Questions Q.6 The electtonegativity of cesium is 0.7 and
based on Cause of Chemical Combination fluorine is 4.0. The bond formed between the
two is:
Q.1 W hen two atoms combine to f orm a (A) Covalent
molecules: (B) Electrovalent/ionic
(A) Energy is released
(C) Coordinate
(B) Energy is absorbed (D) Metallic
(C) Energy is neither released nor absorbed
(D) Energy may either released or aborbed Q.7 Electrovalent bond or ionic bond is formed
by:
Q.2 The combination of atoms occur because (A) Sharing of electons
they want : (B) Donaton of electrons
(A) To decrease number of electrons in the (C) Transfer of electrons
outer most orbit (D) None of these
(B) To attain an inert gas configuration
(C) To increase number of electrons in the Q.8 Element X is strongly electropositive and is
outer most orbit strongly electronegative. Both are univalent.
The compound formed would be:
(D) To attain 18 electrons in the outermost
orbit (A) X+ Y– (B) X – Y
(C) X– Y+

E
(D) X Y

E
Q.3 Which condition favours the bond formation:
Q.9 Element a has 3 electrons in the outermost

J
(A) Maximum attraction and maximum
orbit and element B has 6 eletrons in the

T
potential energy
outermost orbit. The formula of the compound
(B) Minimum attraction and minimum

A
formed between A and B would be:
potential energy (A) High melting points and non-directional

:
(C) Minimum potential energy and maximum bonds
attraction (B) High melting points and low boiling points

e
(D) None of the above (C) Directional bonds and low boiling points

d
(D) High solubilities in polar and non-polar
Questions
Electrovalent or Ionic Bond point

o
based on

C
Q.4 an electrovalent bond or ionic bond is formed Q.10 Ionic compounds in general possess both:
between: (A) High melting points and non-directional
(A) Two electronegative atoms bonds
(B) Two metals (B) High melting points and low boiling points
(C) Electropositive and electronegative atoms (C) Directional bonds and low boiling points
(D) Two electropositive atoms (D) High solubilities in polar and non-polar
solvents
Q.5 Most favourable conditions for electrovalent
Q.11 Conditions for ionic bond formation is/are:
bonding are:
(1) Small cation, large anion
(A) Low ionisation potential of one atom and
(2) low IP of cation, high electron affinity of
high electron affinity of the other atom
anion
(B) High electron affinity and high ionisation
(3) Large cation, small anion and less charge
potential of both the atoms
(4) Less lattice energy
(C) low electron affinity and low ionisation
potential of both the atoms Correct answer is:
(D) High ionisation potential of one atom and (A) 1, 4 (B) 2, 3 and 4
low electrons afinity of the other atom (C) 2 and 3 (D) 1, 2

ASHWANI TYAGI SIR 2 CODE: ATJEE

CHEMISTRY CHEMICAL BONDING
Q.12 An ionic compound A+ B– is most likely to Q.19 Solid NaCl is a bad conductor of electricity
be formed when: because:
(A) Ionization energy of A is low (A) In solid NaCl there are no ions
(B) Electron affinity of B is high (B) Solid NaCl is covalent
(C) Electron affinity of B is low (C) In solid NaCl there is no mobility of ions
(D) Both (A) and (B) (D) In solid NaCl there are no electrons

Q.13 Electrovalent compounds or ionic compounds Q.20 Molten sodium chloride conducts electricity
do not show stereoisomerism. The reason due to the presence of :
is:
(A) Free electrons
(A) Presence of ions
(B) Free molecules
(B) Strong electro static force of attraction
(C) Free sodium and chloride atoms
(C) Brittleness
(D) Free sodium and chloride ions
(D) Non-directional nature of ionic bond
Q.21 Ionic reactions occur in :
Q.14 Compound of a metal ‘M’ is M 2O 3. The
formula of its nitride will be: (A) Aqueous solution and organic solvents of
(A) M3N (B) MN high polarity
(C) M3N2 (D) M2N3 (B) Non-polar or solvents of low polarity
(C) Gaseous state
Q.15 Polarity between two atoms is depend on: (D) Solid state
(A) Ionization potential of element

EE Q.22 Which of the following statements about LiCl

J
(B) Electronegativity of element
and NaCl is wrong:

T
(C) Electronic configuration of element
(D) No. of unpaired electrons (A) LiCl has lower melting point that NaCl

Q.16 As compared to cov alent compounds

: A
electrovalent compounds generally possess:
(B) LiCl dissolves more in organic solvents
whereas NaCl does not
(C) LiCl would ionise in water more than

e
(A) High m.p. and high b.p. NaCl
(B) Low m.p. and low b.p.

d
(D) Fused LiCl would be less conducting than
(C) Low m.p. and high b.p. fused NaCl

Q.17
(D) high m.p. and low b.p.

formed when: C o
An ionic compound A+B– is most likely to be Questions
based on
Covalent Bond & Polarisation
(Fazans Rule)
(A) The ionization energy of A is high and
electron affinity of B is low Q.23 A covalent bond is possible between:
(B) The ionization energy of A is low and (A) Similar atoms
electron affinity of B is high (B) Dissimilar atoms
(C) Both, the ionization energy of A and (C) Similar and dissimilar atoms
electron affinity of B are high (D) Similar molecules
(D) Both, the ionization energy of A and
electron affinity of B are low Q.24 Which of the following statement is not true
about covalent compounds:
Q.18 In which of the following solvents, KI has
(A) They may exhibit space isomerism
highest solubility? The dielectric constant ()
of each liquid is given in parentheses: (B) They have low melting and boiling points
(A) C6H6 ( = 0) (B) (CH3)2CO (= 2) (C) They show ionic reactions
(C) CH3OH ( = 32) (D) CCl4 (= 0) (D) They show molecular reactions

ASHWANI TYAGI SIR 3 CODE: ATJEE

CHEMISTRY CHEMICAL BONDING
Q.25 In a triple bond there is sharing of: Q.33 Which of the following statements regarding
(A) 3 electrons (B) 4 electrons covalent bond is not true?
(C) Several electrons (D) 6 electrons (A) The electrons are shared between atoms
(B) The bond is non-directional
Q.26 Which of the following bonds will have (C) The strength of the bond depends upon
directional character: the extent of overlapping
(A) Ionic bond (D) The bond formed may or may not be polar
(B) Metalic bond
(C) Covalent bond Q.34 Which of the following has least polarity in
(D) Both covalent & metallic bond?
(A) H–F (B) H–Cl
Q.27 The boiling point of ICl is nearly 40°C higher (C) H–O (D) H–S
than that of Br2 although the two subtances
have the same relative molecular mass. This Q.35 Among LiCl, BeCl 2, BCl 3 and CCl 4, the
is bacause: covalent bond character follows the order:
(A) ICl is ionic compound (A) LiCl < BeCl2 > BCl3 > CCl 4
(B) I-Cl bond is stronger than Br-Br bond (B) LiCl > BeCl2 < BCl3 < CCl 4
(C) ICl is polar covalent molecular while Br2 (C) LiCl < BeCl2 < BCl3 < CCl 4
is non polar (D) LiCl > BeCl2 > BCl3 > CCl 4
(D) Ionization energy IP of Iodine is less than
that of Br Q.36 Elements have electronegativities 1.5 and 3.0,
Q.28 The type of bond formed between two

EE bond formed between them would be:

(A) Ionic (B) Covalent

J
electronegative atoms would be:
(C) Co-ordinate (D) Metallic

T
(A) Covalent (B) Ionic
(C) Coordinate (D) All the above

A
Q.37 The correct order of decreasing polarisable
ions is:
Q.29 Correct order of covalent character of alkaline
earth metal chloride in:

e :
(A) BeCl2 < MgCl2 < CaCl2 < SrCl2
(B) BeCl2 < CaCl2 < SrCl2 < MgCl2
(A) Cl– > Br– > I– > F –
(B) F– > I – > Br– > Cl–
(C) F– > Cl– > Br– > I –

od
(C) BeCl2 > MgCl2 > CaCl2 > SrCl2
(D) SrCl2 > BeCl2 > CaCl 2 > MgCl2
Q.38
(D) l– > Br– > Cl– > F –

According to Fajan’s rules necessary

Q.30
water:
(A) AgF
C
Which of the compound is least soluble in

(B) AgCl
condition to form covalent bond is:
(A) small cation and large anion
(B) small cation and small anion
(C) large cation and large anion
(C) AgBr (D) Agl
(D) large cation and small anion
Q.31 Which pair in the following has maximum
and minimum ionic character respectively: Q.39 Which is most ionic:
(A) LiCl, RbCl (B) RbCl, BeCl 2 (A) P2O 5 (B) MnO
(C) BeCl2, RbCl (D) AgCl, RbCl (C) CrO3 (D) Mn2O 7

Q.32 The M.P. of SnCl4 is less than of SnCl2, the
suitable reason for the observed fact is:
(A) There is more charge on Sn+4
(B) The size of Sn+4 is small
(C) Ionic potential () of Sn+4 is high
(D) The shape of SnCl4 is tetrahedral
Q.40 The correct order of increasing covalent
character of the following is:
(A) SiCl4 < AlCl3 < CaCl2 < KCl
(B) KCl < CaCl2 < AlCl3 < SiCl 4
(C) AlCl3 < CaCl2 < KCl < SiCl4
(D) None of these

ASHWANI TYAGI SIR 4 CODE: ATJEE

CHEMISTRY CHEMICAL BONDING
Q.41 Which of the following is not a characteristic Q.47 Correct statement regarding this reaction
of a covalent compound: BF3 + NH3  [F3B  NH3]
(A) It has low melting point and boiling point
(A) Hybridisation of N is changed
(B) It is formed between two atoms having
(B) Hybridisation of B is changed
not very small electronegativity difference
(C) They have no definite geometry (C) NH3 act as a lewis base
(D) They are generally insoluble in water (D) (B) & (C) both

Q.42 The order of decreasing polarity in the Q.48 The correct statement for the reaction
compounds:
NH 3  H   NH 4
CaO, CsF, KCl, MgO is-
(A) CaO > CsF > KCl > MgO (A) Hybridisation state is changed
(B) MgO > KCl > CaO > CsF (B) Bond angle increases
(C) KCl > CaO > CsF > MgO (C) NH3 act as a Lewis acid
(D) CsF > KCl > CaO > MgO (D) Regular geometry is changed

Q.43 Correct order of polarising power is: Q.49 The bonds present in N2O5 are:
(A) Cs+ < K+ < Mg2+ < Al3+
(A) Only ionic
(B) Al3+ < Mg2+ < K+ < Cs+
(B) Covalent & coordinate
(C) Mg+ < Al3+ < K+ < Cs+
(C) Only covalent
(D) K+ < Cs+ < Mg2+ < Al3+

Q.44

EE
Which of the following statements is correct :
(D) Covalent & ionic

J
(A) HCl is covalent both in auqeous solution Q.50 The pair of compounds which can form a

T
and in the gaseous state co-ordinate bond is:

A
(B) HCl is covalent in the gaseous state but (A) (C2H5)3 B and (CH3)3N
ionic in aqueous solution (B) HCl and HBr

and in aqueous solution

(D) None of the above
e :
(C) HCl is ionic both in the gaseous state (C) BF3 and NH3
(D) (A) and (C) both

Q.45

od
The cyanide ion, CN– and N2 are isoelectronic
But in constast to CN– , N2 is chemically
Q.51 In which compound coordinate bond is
present:

C
inert, because of: (A) NH3 (B) NH4OH
(A) Low bond energy (C) H2O (D) HCl
(B) Absence of bond polarity
Questions
(C) Unsymmetrical electron distribution based on Hydrogen Bond
(D) Presence of more number of electrons in
bonding orbitals Q.52 The hydrogen bond is strongest in:
(A) O – H - - - S
Questions
based on Co-ordinate Bond (B) S – H - - - O
(C) F – H - - - F
Q.46 In Co-ordinate bond, the acceptor atoms must
essentially contain in its valency shell an (D) O – H - - - O
orbital:
(A) With paired electron Q.53 H2O boils at higher temperature than H2S,
because it is capable of forming:
(B) With single electron
(C) With no electron (A) Ionic bonds (B) Covalent bonds
(D) With three electron (C) Hydrogen bonds (D) Metallic bonds

ASHWANI TYAGI SIR 5 CODE: ATJEE

CHEMISTRY CHEMICAL BONDING
Q.54 In which of the following molecule, the shown Q.58 Which of the following has strongest intra
hydrogen bond is not possible: molecular hydrogen bonding:

OH OCH3
H H COOH
COOH
(A) N H N H (A) (B)

H H
OH
OCH3
H
O (C) (D)
O

C COOH
(B) COOH
O
H Q.59 Acetic acid exists as dimer in benzene due
O to :
(A) Condensation reaction
O H (B) Hydrogen bonding

EE (C) Presence of carboxyl group

J
(C) (D) None of the above

ON O

AT Q.60 In which case hydrogen bond will not be

observed -
(A) H3O2– (B) H2O
Cl H
O

e : Q.61
(C) HF (D) H3O+

The high boiling point of water is due to the

(D) Cl Cl C

odO
H presence of:
(A) Dative bond

Q.55
Cl H

The correct order of volatility is :

(A) NH3 < H2 O
C (B) Covalant bond
(C) Hydrogen bond
(D) Vander waals bond

(B) p-nitro phenol < o-nitro phenol Q.62 Maximum no. of hydrogen bonds formed by
(C) CH3OH > CH3 – O – CH3 a water molecule in ice is:
(D) HF > HCl (A) 4 (B) 3
Q.56 Intramolecular H-bond: (C) 2 (D) 1
(A) Decreases Volatility
(B) Increases melting point Q.63 Hydrogen bonding is formed in compounds
(C) Increases viscosity containing hydrogen and:
(D) Increases vapour pressure (A) Highly electro-negative atoms
(B) Highly electro-positive atoms
Q.57 Weakest hydrogen bond is:
(A) O – H ......N (B) S – H .....S (C) Metal atoms with d-orbitals occupies
(C) F – H ......F (D) N – H .....N (D) Metalloids

ASHWANI TYAGI SIR 6 CODE: ATJEE

CHEMISTRY CHEMICAL BONDING
Q.64 The intermolecular force in hydrogen fluoride Q.70 The boiling point of a compound is raised by:
is due to : (A) intermolecular hydrogen bonding
(A) Dipole induced dipole interactions (B) high volatility
(B) Dipole-dipole interactions (C) intramolecular hydrogen bonding
(C) Hydrogen bond (D) non-polarity
(D) None of these
Q.71 The boiling point of methanol is greater than
Q.65 The boiling point of p-nitrophenol is higher of methyl thiol because:
than that of o-nitrophenol because: (A) There is intramolecular hydrogen bonding
(A) NO2 group at p-position behaves in a in methanol and intermolecular hydrogen
bonding in methyl thiol
different way from that at o-position
(B) there is intermolecular hydrogen hydrogen
(B) intramolecular hydrogen bonding exists
bonding in methanol and no hydrogen
in p-nitrophenol bonding in methythiol
(C) there is intermolecular hydrogen bonding (C) There is no hydrogen bonding in methanol
in p-nitrophenol and intermolecular hydrogen bonding in
(D) p-nitrophenol has a higher molecular methylthiol
weight than o-nitrophenol (D) There is intramolecular hydrogen bonding
in methanol and no hydrogen bonding in
Q.66 Density of ice is less than that of water methythiol
because of :
(A) presence hydrogen bonding
(B) crystal modification of ice

EE Q.72 Out of the two compounds shown below, the

vapour pressure of (2) at a particular

J
(C) open porous structure of ice due to temperature is expected to be:
hydrogen bonding

AT
(D) different physical states of these
OH

and
OH

:
Q.67 KF combines with HF to form KHF2. The NO2 NO2
compound contains the species: (1)

e
(2)
(A) K+, F– and H+ (B) K+, F– and HF

d
+
(C) K and [HF2] – (D) [KHF]+ and F 2 (A) Higher than that of (1)

o
(B) Lower than that of (1)
Q.68 Which of the following compounds show (C) Same as that of (1)

(1) o-nitrophenol
(3) phenol
(A) 1 & 2
C
intramolecular hydrogen bonding:
(2) p-nitrophenol
(4)salicylaldehyde
(B) 1 & 3
(D)

Questions
Can be higher or lower depending upon
the size of the vessel

based on V.B.T. for Covalent Bond

(C) 1 & 4 (D) 2 & 3
Q.73 A sigma bond is formed by the overlapping
Q.69 The pair of molecules forming strongest of :
hydrogen bonds are :
(A) s-s orbital alone
(A) SiH4 and SiF 6
(B) s and p orbitals alone
(B) CH3 — C — CH3 and CHCl3 (C) s-s, s-p or p-p orbitals along internuclear
|| axis
O
(D) p-p orbital along the sides
(C) H — C — OH and CH3 — C — OH
|| || Q.74 Which overlapping is involved in HCl molecule:
O O (A) s-s overlap (B) p-p overlap
(D) H2O and H2 (C) s-d overlap (D) s-p overlap

ASHWANI TYAGI SIR 7 CODE: ATJEE

CHEMISTRY CHEMICAL BONDING
Q.75 which of the following configuration shows Q.82 bond is formed:
second excitation state of Iodine: (A) By overlapping of hybridised orbital
(A) (B) Ovelapping of co-axial p–p orbitals
(C) Head on overlapping of s – s orbitals
(B)
(D) By p – p collateral overlapping
(C)
Q.83 Number of and bonds present in
(D)
CH3 — CH  CH — C  CH are:
Q.76 Which of the following compound is formed (A) 10, 3 (B) 102
in the second excitation state of sulphur atom:
(C) 9, 2 (D) 8, 3
(A) SF 4 (B) SF 6
(C) SF 2 (D) None Q.84 Which of the following fluorides does not
exists?
Q.77 The strength of bonds by 2s – 2s, 2p – 2p
(A) NF 5 (B) PF 5
and 2p – 2s overlapping has the order:
(A) s – s > p – p > s – p (C) AsF5 (D) SbF5
(B) s – s > p – s > p – p
(C) p – p > s – p > s – s Q.85 p-p overlapping will be observed in the
molecules of -

E
(D) p – p > s – s > p – s
(A) H2 (B) HBr
Q.78

J E
The triple bond in ethyne is made up of: (C) HCl (D) Cl 2

T
(A) Three sigma bonds
(B) Three - bonds Q.86 Nitrogen does not form NF5 because:
(C) One sigma and two  bonds
(D) Two sigma and one  bond

: A (A) Nitrogen is member of V group

(B) It contains no empty d-orbital
(C) The bond energy of N  N is very high
Q.79
ClF3 is formed:

d e
In which of the excitation state of chlorine
(D) Inert pair effect exists in the molecule

o
(A) In ground state
Q.87 The correct order of bond length is

C
(B) In third excitation state
(A) C – C  C  C  C  C
(C) In first excitation state
(D) In second excitation state (B) C  C  C  C  C – C
(C) C  C  C  C  C – C
Q.80 Variable covalency is exhibited by:
(D) C  C  C – C  C  C
(A) P and S (B) N and O
(C) N and P (D) F and Cl
Q.88 Which of the following statements is not
correct?
Q.81 Which is not characteristic of -bond:
(A) -bond is formed when a sigma bond (A) Double bonds is shorter than a single
already formed bond
(B) -bond are formed from hybrid orbitals (B) – bond is weaker than  bond
(C) - bond may be formed by the overlapping (C) Double bond is stronger than a single
of p-orbitals bond
(D) - bond results from lateral overlap of (D) Covalent bond is stronger than a hydrogen
atomic orbital bond

ASHWANI TYAGI SIR 8 CODE: ATJEE

CHEMISTRY CHEMICAL BONDING
Q.89 Fluorine molecule is formed by: Q.95 Which of the set of species have same
(A) the axial p–p orbital overlap hybridisation state but different shapes:
(B) the sideways p–p orbital overlap
(A) NO 2 , NO 2 , NO 2
(C) the s–s orbital overlap
(D) the s–p orbital overlap (B) CIO4 , SF4 , XeF4

Q.90 Consider the following statements: (C) NH 4 , H3 O  , OF2

I. A sigma () bond is formed when two
s–orbitals overlap (D) SO42 , PO43 , ClO4

II. A pi() bond is f ormed when two

p-orbitals overlap axially Q.96 Which of the following elements can not
III. A - bond is weaker than  -bond exhibit sp3d hybridisation state:

Which of the above statements is/are correct? (1) C (2) P

(A) I and II (B) II and III (3) Cl (4) B
(C) I alone (D) II alone Correct answer is:
(A) 1, 3 (B) 1, 4
Questions
based on Hybridization (C) 2, 3 (D) 2, 4

Q.91
E
In the protonation of H2O, change occurs in :

E
Q.97 In the protonation of NH3 molecule, following
statement is true:

J
(A) Hybridisation state of oxygen

T
(B) Shape of molecule (A) A covalent bond is formed

A
(C) Hybridisation and shape both (B) Hydrogen bond is formed
(D) None (C) Hybridisation state of N is changed

Q.92
is :

e :
The d-orbitals involved in sp3d hybridisation
Q.98
(D) Shape of NH3 molecule is changed

The shape of sulphate ion is:

(A) dx 2  y 2

od
(B) d z2 (A) Hexagonal (B) Square planar
(C) Trigonal bipyramidal(D) Tetrahedral

C
(C) d xy (D) d xz

Q.99 In which following set of compound/ion has

Q.93 A sp3 hybrid orbital contains:
linear geometry:
3 1
(A) s–character (B) p–character (A) CH 4 , NH 4 , BH 4
4 4

3 1 (B) CO23  , NO3 , BF3

(C) p–character (D) s – character
4 2
(C) NO 2 , CO 2 , N3
Q.94 In the compound
(D) BeCl 2 , BCl3 , CH 4
1 2 3 4 5 6
C H 2  C H — C H 2 — C H 2 — C  C H , the
C2 — C3 bond formed by the overlapping of : Q.100 Which of the molecule is trigonal bipyramidal :
(A) sp – sp2 (B) sp3 – sp3 (A) BF 3 (B) CH4
(C) sp – sp3 (D) sp2 – sp3 (C) PCl5 (D) SF 6

ASHWANI TYAGI SIR 9 CODE: ATJEE

CHEMISTRY CHEMICAL BONDING
Q.101 The type of hybrid orbitals used by chlorine Q.108 The bond-orders of the given species are
such that -
atom in CIO  , CIO2 , CIO3 and CIO 4 is/are:
(A) O2– > O 2+ > O 22– > O 2
(A) sp, sp2, sp3 and sp3d (B) O2+ > O2 > O2– > O22–
(B) sp and sp3 (C) O2+ > O 22– > O2– > O 2
(C) Only sp3 (D) O22– > O 2 > O 2+ > O2–
(D) Only sp
Q.109 The ion that is isoelectronic with CO and
Q.102 Which of the following having a square planner having same bond order is:
structure is: (A) CN  (B) O2
(A) NH 4 (B) BF4
(C) O2 (D) N 2
(C) XeF4 (D) CCl4
Q.110 Which of the following is paramagnetic:

Q.103 The shape of I 3 is : (A) O2 (B) CN
(A) Tetrahedral (B) Linear (C) CO (D) NO+
(C) T-shape (D) Trigonal
Q.111 In the f ollowing which of the two are
Q.104 Among the following compounds the one that paramagnetic:
is polar and has the central atom with sp3 (1) N2 (2) CO
hybridisation is:
(A) H2CO 3 (B) SiF4

EE (3) B2
correct answer is:
(4) NO 2

(C) BF 3 (D) HClO2

TJ (A) (1) & (3)

(C) (3) & (4)
(B) (2) & (3)
(D) (2) & (4)

A
Q.105 Which of the following will be octahedral:
Q.112 Increasing order of bond length in NO, NO+
BF4–

:
(A) SF 6 (B) and NO– is:
(A) NO > NO– > NO +
(C) PCl5 (D) XeF6

Questions
Molecular Orbital Theory
d e (B) NO+ < NO < NO –
(C) NO < NO+ < NO –

o
based on (D) NO < NO+ = NO–

C
Q.106 The number of antibonding electron pairs in
O22 molecular ion on the basis of molecular
orbital theory is (at no. O = 8):
Q.113 In which of the following set, the value of
bond order will be 2.5:
(A) O 2 , NO, NO 2 , CN

(A) 2 (B) 3 (B) CN, NO 2 , CN – , F2

(C) 4 (D) 5
(C) O 2 , NO 2 , O 2 2 , CN 
Q.107 Which of the following option w.r.t. increasing
bond order is correct? (D) O 22 , O2 , O 2 , O 2

(A) NO  C2  O2  He2 Q.114 The paramagnetic property of oxygen is well

explained by:
(B) C2  NO  He2  O2 (A) Molecular orbital theory
(B) Resonance theory
(C) He2  O2  NO  C2
(C) Valence bond theory
(D) He2  O2  C2  NO (D) VSEPR theory

ASHWANI TYAGI SIR 10 CODE: ATJEE

CHEMISTRY CHEMICAL BONDING
Q.115 Which of the following has fractional bond Questions
Dipole Moment
based on
order?

(A) O 22  (B) O22 Q.123 BeF2 has zero dipole moment whereas H2O
has dipole moment because:
(C) F22  (D) H 2
(A) Water is linear
Q.116 Higher is the bond order, greater is: (B) H2O is bent
(A) Bond dissociation energy
(C) F is more electronegative than O
(B) Covalent character
(D) Hydrogen bonding is present in H2O
(C) Bond length
(D) Paramagnetism
Q.124 Which of the following molecule have zero
Q.117 The bond order of CO molecule on the basis dipole moment:
of molecular orbital theory is:
(A) BF 3 (B) CH2Cl 2
(A) Zero (B) 2 (C) 3 (D) 1
(C) NF 3 (D) SO 2
Q.118 Which of the follwing group of molecules have
Q.125 The dipole moment of NH3 is:
1
2 bond order: (A) Less than dipole moment of NCl3
2
(B) Higher than dipole moment of NCl3
(A) N 22 , O 2,2 CO (B) N 2 , O 2, NO

(C) C 22 , BN, O 2

EE
(D) CN  , NO  , O 22
(C) Equal to the dipole moment of NCl3

J
(D) None of these

minimum bond energy:

AT
Q.119 Which of the following species will have the Q.126 Which of the following species are polar:
(1) C6H6 (2) XeF2

:
(A) N 2 (B) N 2 (C) N 2 (D) N 2 2
(3) SO 2 (4) SF 4

of 2.5 ?

d e
Q.120 Which of the following ion has not bond order (5) SF 6
correct answer is:

o
(A) O2 (B) O2 (C) N 2 (D) N 2
(A) (2) & (4) (B) (1), (2) & (5)

C
Q.121 N2 and O 2 are converted into monoanions,
N 2 and O2 respectively. Which of the
following statements is wrong?
(C) (1) & (5) (D) (3) & (4)

Q.127 Which set of molecules is polar:

(A) XeF4, IF7, SO 3
(A) In N 2 , N-N bond weakens
(B) PCl5, C6H6, SF 6
(B) In O 2 , O-O bond order increases (C) SnCl2, SO2, NO 2
(C) In O 2 , O-O bond order decreases (D) CO2, CS2, C2H6

(D) N 2 becomes paramegnetic Q.128 Dipole moment is shown by:

(A) 1, 4 - dichlorobenzene
Q.122 Which of the following has maximum bond
stength - (B) Cis 1, 2 - dichloro ethene
(A) O2 (B) O2 +
(C) Trans -1, 2 - dichloro ethene
(C) O2 – (D) O22– (D) benzene

ASHWANI TYAGI SIR 11 CODE: ATJEE

CHEMISTRY CHEMICAL BONDING
Q.129 The correct oreder of dipole moment is: Q.132 Species having zero dipole moment:
(A) CH4 < NF3 < NH3 < H2O (A) XeF4 (B) SO2
(C) SF 4 (D) CH2Cl2
(B) NF3 < CH4 < NH3 < H2O
(C) NH3 < NF3 < CH4 < H2O Q.133 The correct order of decreasing polarity is:
(D) H2O < NH3 < NF3 < CH4 (A) HF > SO2 > H2O > NH3
(B) HF > H2O> SO2 > NH3
Q.130 Which contains both polar and non-polar
(C) HF > NH3 > SO2 > H2O
bonds?
(D) H2O > NH3 > SO2 > HF
(A) NH4Cl (B) HCN
(C) H2O 2 (D) CH4 Q.134 The dipole moment of given molecules are
such that -
Q.131 What conclusion can be draw from the fact (A) BF 3 > NF 3 > NH3
that BF3 has no dipole moment but PF3 is
does: (B) NF 3 > BF 3 > NH3
(A) BF 3 is not symmetrical but PF 3 is (C) NH3 > NF 3 > BF 3
symmetrical (D) NH3 > BF 3 > NF 3
(B) BF 3 molecule must be linear
(C) Atomic radius of P is larger than that

E
of B
(D) BF3 molecule must be planar triangular

J E
AT
e :
od
C

ASHWANI TYAGI SIR 12 CODE: ATJEE

CHEMISTRY CHEMICAL BONDING
PRACTICE DPP # 2
Q.1 Which of the following statements is correct Q.8 The d-orbitals involved in dsp2 hybridization
about N2 molecule: is :
(A) It has a bond order of 3
(A) dxy (B) d z2 (C) dx 2  y 2 (D) d xz
(B) The number of unpaired electrons present
in is zero and hence it is diamagnetic
(C) The order of f illing of MO is Q.9 Which of the following has been arranged in
(2px) = (2py)],  (2pz) order of decreasing dipole moment:
(D) All the above three statements are (A) CH3Cl > CH3F > CH3Br > CH3I
correct (B) CH3F > CH3Cl > CH3Br > CH3I
(C) CH3Cl > CH3Br > CH3l > CH3F
Q.2 N atom in NH 4 ion involves the hybridization: (D) CH3F > CH3Cl > CH3I > CH3Br
(A) sp (B) sp2 (C) sp3 (D) sp3d
Q.10 The phosphate of a metal has the formula
Q.3 A hybrid orbital formed from s-and p-orbital MHPO4. The formula of its chloride would
can contribute to: be:
(A) A bond only (A) MCl (B) MCl2
(B) bond only (C) MCl3 (D) M2Cl3

E
(C) Either or bond
Q.11 Intramolecular H-bonding is preasent in:

E
(D) None of these

J
(A) o-Nitrophenol (B) Salicylaldhyde
Q.4 Which carbon is more electronegative:

T
(C) m-Nitrophenol (D) Both (A) and (B)
(A) sp3 hybridised carbon
(B) sp hybridised carbon
(C) sp2 hybridised carbon

: A
(D) The electron attracting power of C is
Q.12 Which of the following statement is not correct -
(A) CH3+ shows sp2-hybridisation whereas
CH3– shows sp3-hybridisation

state

d e
always same irrespective of its hybrid
(B) NH4+ has a regular tetrahedral geometry
(C) sp2-hybridised orbitals have equal s and
Q.5
of PCl5:
(A)
o
Which of the following statement is incorrect

C
Its all P-Cl bond lengths are equal
p character
(D) Hybridisation orbitals always f orm
-bonds
(B) It involves sp3d hybridization
(C) It has an irregular geometry Q.13 Which of the following compound does not
(D) Its shape is trigonal bipyramidal follow octet rule:
(A) CO 2 (B) PCl3
Q.6 In a change from PCl3 PCl5, The hybrid (C) ICl (D) CIF3
state of P change from:
(A) sp2 to sp3 (B) sp3 to sp2 Q.14 The magnitude of the lattice energy of a solid
(C) sp3 to sp3d (D) sp3 to dsp2 increases if:
(A) The ions are of large size
Q.7 The hybrid state of B in BF4 is : (B) The ions are of small size
(A) sp2 (B) sp (C) The ions are of equal size
(C) sp 3 (D) No specific (D) Charges on the ions are small

ASHWANI TYAGI SIR 13 CODE: ATJEE

CHEMISTRY CHEMICAL BONDING
Q.15 Out of CHCl3, CH4 and SF4 the molecules Q.21 Which of the following will be least polar:
having regular geometry are: (A) N–H (B) C–H (C) O–H (D) H–F
(A) CHCl3 only (B) CHCl3 and SF4
Q.22 Which of the following has zero value of dipole
(C) CH4 only (D) CH4 and SF4
moment:
Q.16 The bond angle in H2O molecule is less than (A) Benzene (B) Naphthalene
that of NH3 molecule because: (C) p-dichlorobenzene (D) All the three
(A) The hybridisation of O in H2O and N in
Q.23 Which one of the following molecules has
NH3 is different
highest dipole moment:
(B) The atomic radii of N and O are different
(A) H2S (B) CO2 (C) CCl4 (D) BF 3
(C) There is one lone pair of electrons on O
and two lone pairs of electrons on N Q.24 Number of valence electrons present in atoms
(D) There are two lone pairs of electrons on of HClO4, HClO 3, HClO 2 respectively are:
O and one lone pairs of electrons on N (A) 32, 26, 20 (B) 26, 20, 14
(C) 36, 30, 24 (D) 28, 22, 16
Q.17 In which of the following species the angle
arround the central atom is exactly equal to
Q.25 Which of the following does not apply to
109°28’ :
metallic bond:
(A) SF 4
(B) NH3

EE (A) Overlapping valence orbital

J
(B) Mobile valency electron
NH 4

T
(C) (C) Delocalized electrons

A
(D) None of the above (D) Highly directed bonds

Q.18
in the order:

e :
The bond angless of NH3, NH 4 and NH 2 are
Q.26 Acetic acid is a dimer in benzene due to
(A) Condensation reaction

d
(B) Hydrogen bonding
(A) NH 2  NH 3  NH 4
(C) Presence of carboxylic group
(B) NH 4  NH 3  NH 2

(C) NH 3  NH 2  NH 4 C o Q.27
(D) Presence of hydrogen atom at -carbon

The nature of intermolecular forces among

benzene (C6H6) molecules is:
(D) NH 3  NH 4  NH 2 (A) Dipole-dipole attraction
(B) London dispersion force
Q.19 The pair of molecules having identical (C) Ion-dipole attraction
geometry is: (D) Hydrogen bonding
(A) BCl3, PCl3 (B) BF3, NF 3
(C) CCl4, CH4 (D) CH4, SF 4 Q.28 The compound formed by which of the
following pair of ions will have lowest melting
Q.20 Which of the following compounds is non- point :
polar:
(A) Na+ and Cl – (B) Mg 2  and Cl–
(A) CH3Cl (B) CH2Cl2
(C) CHCl3 (D) CCl4 (C) Al3 and Cl– (D) Sn4+ and Cl –

ASHWANI TYAGI SIR 14 CODE: ATJEE

CHEMISTRY CHEMICAL BONDING
Q.29 In the electronic structure of acetic acid the Q.34 The value of bond order in NO+ according to
number of electrons present are: MOT is:
(A) 16 shared and 8 unshared (A) 3 (B) 2
(B) 8 shared and 16 unshared (C) 1 (D) 0
(C) 12 shared and 12 unshared
(D) 18 shared and 6 unshared Q.35 Which one of the following is most polar:
(A) CI–Cl (B) N–F
Q.30 Amongst NH3, BeCl2, CO2 and H2O, the non-
linear molecules are : (C) C–F (D) O–F

(A) BeCl2 and H2O (B) BeCl2 and CO2

Q.36 Which of the following halogens has the
(C) NH3 and H2O (D) NH3 and CO2
highest bond energy:

Q.31 Which is not correct: (A) F2 (B) Cl2

(A) Bond angle H–S–H < H–OH (C) Br2 (D) I2

(B) Bond angle F–O–F < Cl–O–Cl
Q.37 In the series, ethane, ethylene & acetylene,
(C) Bond angle H–P–H < H–N–H
the carbon-hydrogen bond length is:
(D) Bond angle Cl–Sn–Cl > Cl–Hg–Cl
(A) Equal in all the three
Q.32 Which of the following match is not correct: (B) Largest in ethane

(A) ICI 2 — Linear ion

EE (C) Smallest in ethylene

(D) Largest in acetylene
(B) ICI 4 — Square planar ion

TJ Q.38 Which of the following are isoelectronic and

A
(C) XeF2 — Linear molecule isostuctural:
(D) SO24 — Trigonal planar ion

Q.33 The number of unpaired electrons in

e : NO 3 , CO23  , ClO3– , SO 3

(A) NO3 , CO23– (B) SO 3 , NO 3

d
paramagnetic tetrachloromagnate (II) anion is:

o
(A) 5 (B) 2 (C) 3 (D) 6 (C) ClO3 , CO32 (D) CO23 ,ClO3

ASHWANI TYAGI SIR 15 CODE: ATJEE

CHEMISTRY CHEMICAL BONDING
PRACTICE DPP # 3
Q.1 In which of the following molecules S atom Q.7 Which one of the following postulates is
does not assume sp3 hybridisation: wrong about the electron gas theory of
metallic bonding:
(A) SO24 (B) SF 4
(A) A metal consists of positively charged
(C) SF 2 (D) S 8 spheres called kernels and the loosely
bond valence electrons.
Q.2 The hybridization of phosphorous in POCl3 is
(B) The kernels remain fixed but the valence
the same as in:
electrons are free to move throughout the
(A) P in PCl 3 (B) S in SF4 metallic crystal
(C) Cl in CIF3 (D) B in BCl 3 (C) The strength of the metallic bond
depends number of valence electrons
Q.3 The formation of which of the following ions
(D) Metallic bond is stronger than a covalent
is not possible -
bond
(A) [SiF6]2– (B) [AlF 6] 3–
(C) [BF 4] – (D) [BF 6] 3– Q.8 The ratio  bond  bond in tetracyano
ethylene:
Q.4 The geometrical arrangement and shape of
(A) 2 : 1 (B) 1 : 1
I 3 are respectively (C) 1 : 2 (D) None of these

shape E
(A) Trigonal bipyramidal geometry, linear

E Q.9 Which of the following statement concerning

(B) Hexagonal geometry, T-shape

TJ
(C) Triangular planar goemetry, triangular
a covalent bond is false:
(A) The electrons are shared between atoms
shape

: A
(D) Tetrahedral geometry, pyramidal shape
(B) The bond is non-directional
(C) The strength of the bond depends upon
the extent of overlapping

e
Q.5 Which of the following conditions is not (D) The bond formed may be polar or non-
correct for resonating structures:

d
polar
(A) The contributing structures must have the

o
same number of unpaired electrons

C
(B) The contributing structures should have
similar enegies
(C) The contributing structures should be so
written that unlike charges reside on
atoms that are far apart
(D) The positive charge should be present on
the electropositive element and the
negative charge on the electronegative
element
Q.6 What is not true about resonance:
(A) The resonating structures are hypothetical
(B) The unpaired electrons in v arious
resonating structures are same
(C) Hybrid structure is least stable
(D) Hybrid structure is least energetic
Q.10 The correct increasing order of extent of
hydrolysis is:
(A) CCl4 < MgCl2 < AlCl3 <SiCl 4 < PCl 5
(B) CCl4 < AlCl3 < MgCl2 < PCl5 < SiCl4
(C) CCl4 < SiCl4 < PCl5 < AlCl3 < MgCl2
(D) CCl4 < PCl5 < SiCl4 < AlCl3 < MgCl2
Q.11 The bond angle in H2O in nearly 105° whereas
bond angle in H2S in nearly 90°. This is
because:
(A) Electronegativity of oxygen is greater than
that of sulphur
(B) Oxygen is a gas whereas sulphur is solid
(C) Sulphur contains d-orbitals whereas
oxygen does not
(D) The number of lone pairs present on
oxygen and sulphur is not equal

ASHWANI TYAGI SIR 16 CODE: ATJEE

CHEMISTRY CHEMICAL BONDING
Q.12 Which of the following set contains species Q.18 The corect sequence of increasing covalent
having same angle arround the central atom: character is represented by:
(A) SF4, CH4, NH3 (B) NF3, BCl3, NH3 (A) BeCl2 < NaCl < LiCl
(C) BF3, NF 3, AlCl 3 (D) BF3 BCl3, BBr3 (B) NaCl < LiCl < BeCl 2
Q.13 Hydrogen bonding is different than the other (C) BeCl2 < LiCl < NaCl
three is shown by - (D) LiCl < NaCl < BeCl 2
(A) Aceto-acetic ester
Q.19 The Cl–C–Cl angle in 1, 1, 2, 2 - tetrachloro
(B) Acetic acid
ethene and tetrachloro methane respectively
(C) Ethyl alcohol will be about:
(D) Ethyl amine
(A) 120° and 109.5° (B) 90° and 109.5°
Q.14 Choose the molecules in which hybridisation (C) 109.5° and 90° (D) 109.5° and 120°
occurs in the ground state:
Q.20 Which of the following statements is wrong:
(1) BCl3 (2) NH3
(A) Hybridisation is the mixing of atomic
(3) PCl3 (4) BeF2
orbitals prior to their combining into
The correct answer is:
molecular orbitals
(A) 1, 2, 4 (B) 1, 2, 3
(B) sp2 hybrid orbital are formed from two p
(C) 2, 3 (D) 3, 4 atomic orbitals and one s atomic orbital

E
Q.15 Identify the corrent statement from the given (C) dsp2 hybrid orbitals are all at 90° to one

E
alternatives: another

TJ
(A) Intra molecular hydrogen bonding is not
found to occur in 2 hydroxy benzaldehyde
(D) sp 3 d 2 hybrid orbitals are directed
towards the corners of a regular

A
(B) The boiling poing of hydrogen iodide (HI)
is more than hydrogen fluoride (HF)

:
(C) The dipole moment of CH3Cl is not equal
to zero
Q.21
tetrahedron

In which of the following solvents KBr should

be soluble at 25° C- ( is the dielectric

CH3Cl
d e
(D) CH3F has a larger dipole moment that constant)
(A) C6H6 (=0)

Q.16

C o
Four elements A (with one valence electron),
B (with three valence electrons), C (with five
valence electrons) and D (with seven valence
(B) CH3 OH ( = 32)
(C) (CH3)2 CO ( = 2)
(D) CCl4 ( = 0)
electrons) are lying in the second period which
of periodic table which of the following is/are Q.22 A : Tetracyanomethane, B: Carbondioxide, C
diatomic at room temperature: : Benzne, D : 1, 3 butadiene ratio of  and
 bonds is in order:
(A) Only C2 (B) Only A2
(C) C2 and D2 (D) Only B2 (A) A = B < C < D (B) A = B < D < C
(C) A = B = C = D (D) C < D < A < B
Q.17 From the following sequence calculate the
lattice energy of AB(s) : Q.23 The order of increasing bond angle in the
A(s)  A+(g) + e; 610 KJ mol–1 molecules BeCl2, BCl 3, CCl4 and SF6 is:
B(g) + e  B– (g); –260 KJ mol–1 (A) SF6 < CCl 4 < BCl 3 < BeCl 2
A(s) + B(g)  AB(s); –569 KJ mol–1 (B) BeCl2 < BCl 3 < CCl 4 < SF 6
(A) –219 (B) –-919 (C) SF6 < CCl4 < BeCl2 < BCl 3
(C) +1539 (D) + 301 (D) BCl3 < BeCl2 < SF6 < CCl 4

ASHWANI TYAGI SIR 17 CODE: ATJEE

CHEMISTRY CHEMICAL BONDING
Q.24 The species which do not support octet rule Q.32 In terms of polar character, which of the
are: following order is correct:
(1) H2O (2) Cl2O (A) NH3 < H2O < HF < H2S
(3) NO (4) PCl5 (B) H2S < NH3 < H2O < HF
correct answer is (C) H2O < NH3 < H2S < HF
(A) (1) (2) & (3) (B) (3) & (4) (D) HF < H2O < NH3 < H2S
(C) (2), (3) & (4) (D) (2), (4) & (1)
Q.33 The lattice energies of KF, KCl, KBr and KI
Q.25 How many  and  bonds will be in follow the order:
allyl isocyanide: (A) KF > KCl > KBr > KI
(A) 9  and 3 (B) 9  and 9 (B) KI > KBr > KCl > KF
(C) 3  and 4 (D) 5  and 7 (C) KF > KCl > KI > KBr
(D) KI > KBr > KF > KCl
Q.26 In which of the following pair the boilling point of
first compound is not more than the second : Q.34 Select correct statement about hydrolysis of
(A) KCl, Cl2 (B) Ne, He BCI3 and NCl3 :
(C) PH3, AsH3 (D) HF, HCl (A) NCl3 is hydrolysed and gives HClO but
BCl3 is not hydrolysed
Q.27 The correct order of dipole moment is:
(B) Both NCl3 and BCl3 on hydrolysis gives
(A) CH4 < NF3 < NH3 < H2O
HCl
(B) NF3 < CH4 < NH3 < H2O
(C) NCl3 on hydrolysis gives HClO but BCl3

E
(C) NH3 < NF3 < CH4 < H2O gives HCl
(D) H2O < NH3 < NF3 < CH4

E
(D) Both NCl3 and BCl3 on hydrolysis gives

J
HOCl
Q.28 The order of increasing bond length in F2,
N2, Cl 2 and O2 is:
(A) N2 < O2 < Cl2 < F 2
(B) N2 < O 2 < F2 < Cl2
AT Q.35 The order of increasing lattice energy of the
following compound is:
(A) NaCl < CaO < NaBr < BaO
(C) O2 < N2 < Cl2 < F 2
(D) N2 < Cl2 < O 2 < F 2

e : (B) NaBr < NaCl < BaO < CaO

(C) NaCl < NaBr < BaO < CaO

d
(D) NaBr < NaCl < CaO < BaO
Q.29 Carbon atoms in the compound (CN)4C2 are:

o
(A) sp hybridized Q.36 The type of bonds presents in CuSO4. 5H2O
(B) sp2 hybridized

C
are:
(C) sp and sp2 hybridized (A) Co-ordinate
(D) sp, sp2 and sp3 hybridized (B) Covalent and Co-ordinate
(C) Covalent, co-ordinate, ionic and H-bonds
Q.30 Fluorine does not form any polyhalide as
other halogens because: (D) Only ionic
(A) It has maximum ionic character
Q.37 The lattice energies of the oxides of Mg, Ca
(B) It has low F-F bond energy
Sr and Ba follow the order:
(38.5 kcl mol–1)
(A) BaO > SrO > CaO > MgO
(C) Of the absence of d-orbitals in the valence
shell of fluorine (B) CaO > BaO > SrO > MgO
(D) It brings about maximum coordination (C) MgO > CaO > SrO > BaO
number in other elements (D) MgO > SrO > CaO > BaO

Q.31 Which of the following pair of molecules will Q.38 No, of  and  bonds in C 2 (CN) 4 are
have permanent dipole moment: respectively:
(A) NO2 and CO 2 (B) NO2 and O 3 (A) 9  , 9 (B) 8 , 7
(C) SiF4 and CO2 (D) SiF4 and NO2 (C) 1  , 1 (D) 9 , 8

ASHWANI TYAGI SIR 18 CODE: ATJEE

CHEMISTRY
STATEMENT TYPE QUESTIONS -
Each of the questions given below consist of
Statement – I and Statement – II. Use the follow
ing Key to choose the appropriate answer.
(A) If both Statement- I and Statement- II are
true, and Statement - II is the correct
explanation of Statement–I.
(B) If both Statement-I and Statement-II are
true but Statement - II is not the correct
explanation of Statement–I.
(C) If Statement-I is true but Statement-II is
false.
(D) If Statement-I is false but Statement-II is
true.
Q.39 Statement I : The bond angle of directed
bonds around S in H2S is 92º
Statement II: S atom in H 2 S is sp 3
Hybridised
Q.40 Statement I : Both PCl 5 ans BrF 5 have
CHEMICAL BONDING
Q.41 Statement I : The dipole moment of NH3 is
more than dipole moment of NF3
Statement II : The lone pair e– on N atom
contribute more towards bond moment in NH3
and less in NF3
Q.42 Statement I : p- hydroxy benzoic acid has a
lower B.P. than o - hydroxy benzoic acid
Statement II : o- hydroxy benzoic acid has
intramolecular H - bonding
Q.43 Statement I : Pressing of two ice cube over
each othe cause their unification.
Statement II : Intermolecular H-bonding
occurs between H2O molecules.
Q.44 Statement I : XeF2 is a linear molecule.
Statement II : Xe atom assumes sp hybrid
state in XeF2.
Q.45 Statement I : HCH bond angle in C2H4 is

E
identical shape.
Statement II : PCl5 has trigonal bipyramidal approximately 120°.

J E
shape whereas BrF 5 has square pyramidal
shape.
Statement II : Both the carbon atoms in C2H4
are sp2 hybridised.

AT
e :
od
C

ASHWANI TYAGI SIR 19 CODE: ATJEE

CHEMISTRY CHEMICAL BONDING
LEVEL # 4
(Questions asked in previous AIEEE & IITJEE)

AIEEE / JEE MAIN Q.7 The correct order of bond angles (smallest
Q.1 In which of the following species is the first) in H2S, NH3, BF3 and SiH4 is:
underlined carbon having sp3-hybridisation? (A) H2S < NH3 < SiH4 < BF 3
(A) CH3–COOH (B) CH3CH2OH (B) NH3 < H2S < SiH4 < BF 3
(C) CH3COCH3 (D) CH2=CH–CH3
(C) H2S < SiH4 < NH3 < BF3
(D) H2S < NH3 < BF3 < SiH4
Q.2 Which of the follwing statements is true?
(A) HF is less polar than HBr Q.8 The bond order in NO is 2.5 while that in
(B) Water does not contain any ions NO+ is 3. Which of the following statements
(C) Chemical bond formation takes place is true for these two species?
when forces of attraction overcome the
(A) Bond length in NO+ is equal to that in
forces of repulsion
NO
(D) In covalent cond, transfer of electrons
(B) Bond length in NO is greater than in NO+
takes place
(C) Bond length in NO+ is greater than in
Q.3 A square planar complex is formed by NO
hybridisation of which atomic orbital?

EE (D) Bond length is unpredictable

J
(A) s, px, py, dyz (B) s, px, py, dx 2  y 2
Q.9 The states of hybridization of boron and

Q.4
(C) s, px, py, d 2
z

AT
(D) s, px py, d xy

The reason for double helical structure of DNA

oxygen atoms in boric acid (H3BO 3) are
respectively:

:
is operation of: (A) sp3 and sp2 (B) sp2 and sp3
(A) dipole-dipole interaction (C) sp2 and sp2 (D) sp3 and sp3
(B) hydrogen bonding
(C) electrostatic attraction
d e Q.10 Which one of the following has the regular

Q.5
(D) vander Wall’s forces

C o
Which one of the following pairs of molecules
will have permanent dipole moments for both
tetrahedral structure?

(A) BF4

(C) XeF4
(B) SF 4

(D) [Ni(CN)4]2–
members:
(Atomic nos. : B = 5, S = 16, Ni = 28, Xe = 54)
(A) NO2 and CO 2 (B) NO2 and O 3
(C) SiF4 and CO2 (D) SiF4 and NO2 Q.11 The maximum number of 90° angles between
bond pair-bond pair of electrons is observed
Q.6 The pair of species having identical shapes
in:
for molecules of both species is:
(A) dsp2
(A) XeF2, CO 2 (B) BF3, PCl 3
(C) PF5, IF 5 (D) CF4, SF 4 (B) sp3d hybridization
(C) dsp3 hybridization
(D) sp3d2 hybridization

ASHWANI TYAGI SIR 20 CODE: ATJEE

CHEMISTRY CHEMICAL BONDING
Q.12 Beryllium and aluminium exhibit many Q.17 The number and type of bond between two
properties which are similar. But, the two carbon atom in calcium carbide are:
elements differ in: (A) One sigma, one pi bond
(A) Forming covalent halides (B) One sigma, two pi bond
(B) Forming polymeric hydrides (C) Two sigma, one pi bond
(C) Exhibiting maximum cov alency in (D) Two sigma, two pi bond
compound
Q.18 Which of the following molecules\ions does
(D) Exhibiting amphoteric nature in their not contain unpaired electrons?
oxides
(A) N2 (B) O 2 (C) O 22  (D) B 2
Q.13 W hich one of the following species is
diamagnetic in nature? Q.19 Among the following mixtures, dipole-dipole
as the major interaction, is present in:
(A) He2 (B) H2 (C) H 2  (D) H 2
(A) KCI and water
(B) benzene and carbon tetrachloride
Q.14 Lattice energy of an ionic compound depends
(C) benzene and ethanol
upon:
(D) acetonitrile and acetone
(A) charge on the ion only
(B) size of the ion only Q.20 A metal, M foms chlorides in its +2 and +4
(C) packing of the ion only oxidation states. Which of the following
(D) charge and size of the ion

EE statements about these chlorides is correct?

(A) MCl2 is more ionic than MCl4
Q.15 The molecular shapes of SF4, CF4 and XeF4
are:

TJ (B) MCl 2 is more easily hydrolysed than

electrons on the central atom,

respectively

: A
(A) the same with 2, 0 and 1 lone pair of MCl4
(C) MCl2 is more volatile than MCl4

e
(B) the same with 1, 1 and 1 lone pair of (D) MCl 2 is more soluble in anhydrous
electrons on the central atoms, ethanol than MCl 4
respectively

od
(C) different with 0, 1 and 2 lone pair of Q.21 In which of the following molecules/ions are

C
electrons on the central atoms, all the bonds not equal?
respectively
(A) XeF4 (B) BF4 (C)SF4 (D) SiF 4
(D) different with 1, 0 and 2 lone pair of
electrons on the central atoms,
Q.22 The decreasing value of bond angles from
respectively
NH3 (106)° to SbH3 (101)° down group-15 of
the periodic table is due to:
Q.16 Of the following sets which one does not
(A) decreasing lp – bp repulsion
contain isoelectronic species?
(B) increasing electronegativity
(A) PO34 , SO24 , CIO 4 (C) increasing bp – bp repulsion
(D) increasing p–orbital character in sp3
(B) CN – , N2 , C 22

(C) SO32 , CO32 , NO3 Q.23 In which of the following ionizion processes,
the bond order has increased and the
(D) BO33  , CO23  , NO3 magnetic behaviour has changed
(A) NO  NO + (B) O2  O2

(C) N2  N2 (D) C2  C 2

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CHEMISTRY CHEMICAL BONDING
Q.5 The geometry and the type of hybrid orbital
Q.24 Which of the following hydrogen bonds is the
present about the central atom in BF3 is:
strongest
(A) Linear, sp
(A) F – H .... F (B) O – H ..... O
(C) O – H .... F (D) O – H .... N (B) Trigonal planar sp2
(C) Tetrahdedral, sp3
Q.25 Which of the following species exhibits the (D) Pyramidal, sp3
diamagnetic behaviou:
Q.6 NH3 and BF3 form adduct readily through:
(A) O2 (B) O2 (C) NO (D) O 22 
(A) Ionic bond between BF3 and NH3
Q.26 The charge/size ratio of a cation determines (B) Co-ordinate bond between B and N
its polarzing power. W hich one of the (C) Covalent bond between B and N
f ollowing sequences represents the (D) H-bonds between F atoms of BF3 and
increasing order of the polarizing power of H-atoms of NH3
the cationic species, K+, Ca+2 Mg+2, Be+2
(A) Be+2 < K+ < Ca+2 < Mg+2 Q.7 The hybridization of atomic orbitals of
(B) K+ < Ca+2 < Mg+2 < Be+2 nitrogen in NO 2 , NO 3 and NH 4 are:
(C) Ca+2 < Mg+2 < Be+2 < K+
(A) sp2, sp3 and sp2 respectively
(D) Mg+2 < Be+2 < K+ < Ca+2
(B) sp, sp2 and sp3 respectively
(C) sp2, sp and sp3 respectively
IIT JEE / JEE ADVANCED
(D) sp2, sp3 and sp respectively
Q.1 Homolytic fission of C–C bond in ethane

EE Q.8 The correct order of hybridization of the

J
(CH3–CH3) gives an inermediat in which
carbon atom is: central atom in the following species NH3,
(A) sp3 hybridised
(C) sp hybridised
(B) sp2 hybridised

AT
(D) sp3d hybridised
[PtCl4]2– , PCl5 and BCl3 is :
(A) dsp2, sp3d, sp2 and sp3
(B) sp3, dsp2, sp3d, sp2
Q.2 How many  and  bonds will be in
allyisoyanide:
(A) 9and 3 (B) 9and 9
e : (C) dsp2, sp2, sp3, sp3d
(D) dsp2, sp3, sp2, sp3d

Q.3
(C) 3and 4 (D) 5and 7

od
Among the following species, identify the
Q.9 The common features among the species
CN–, CO and NO+ are
isostructural pairs:

C
NF3 , NO 3 , BF3 , H3 O  , NH 3
(A) [NF3 , NO 3 ] and [BF3 , H3 O  ]
(A)
(B)
(C)
(D)
bond order three and isoelectronic
bond order three and weak field ligands
bond order two and - acceptors
isoelectronic and weak field ligands

(B) [NF3 , NH 3 ] and [NO 3, BF3 ] Q.10 Which of the following molecular species has
 unpaired elecron(s) ?
(C) [NF3 , H3 O] and [NO3 , BF3 ]

(A) N2 (B) F 2 (C) O 2 (D) O 22
(D) [NF3 , H3 O] and [NH 3 , BF3 ]
Q.11 Which of the following hydrocarbons has the
Q.4 Which of the following contains both polar lowest dipole momet ?
and non-polar bonds:
H3C Cl
(A) NH4Cl (B) HCN
(A) C (B) CH3C  CCH3
(C) H2O 2 (D) CH4
H H

(C) CH3CH2C  CH

(D) CH2  CH — C  CH

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CHEMISTRY CHEMICAL BONDING
Q.15 According to molecular orbital theory which
Q.12 Which of the following represent the given of the following statement about the megnetic
mode of hybridisation sp2, sp2, sp and sp character and bond order is correct regarding
from left to right:
O2 ?
(A) H2C  CH — C  CH
(A) paramagnetic and bond order < O2
(B) HC  C — C  CH (B) paramagnetic and bond order > O2
(C) H2C  C  C  CH2 (C) diamagnetic and bond order < O2
(D) diamagnetic and bond order > O2
CH2
(D) Q.16 Maximum number of lone pair of electrons
H 2C
are present in:

Q.13 Which of the following are iosoelectronic and (A) CIO 3 (B) XeF4

isostructural NO3 , CO32 , ClO3 , SO 3 (C) SF 4 (D) I 3

(A) NO3 , CO32 (B) SO3 ,NO3

Q.17 The species having bond order different from
(C) CIO3 ,CO32 (D) CO 32 , SO 3 that in CO is:
(A) NO – (B) NO +
Q.14 Total number of lone pair of electrons in
(C) CN– (D) N2
XeOF4 is
(A) 0 (B) 1

EE
J
(C) 2 (D) 3

AT
e :
od
C

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CHEMISTRY CHEMICAL BONDING
ANSWER KEY
PRACTICE DPP # 1
Ques. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20
Ans. A B C C A B C A A A C D D B B A B C C D
Ques. 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40
Ans. A C C C D C C A C D B C B D C B D A B B
Ques. 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60
Ans. C D A B B C D B B D B C C C B D B A B D
Ques. 61 62 63 64 65 66 67 68 69 70 71 72 73 74 75 76 77 78 79 80
Ans. C A A C C C C C C A B A C D C B C C C A
Ques. 81 82 83 84 85 86 87 88 89 90 91 92 93 94 95 96 97 98 99 100
Ans. B D A A D B B B A C B B C D C B D D C C
Ques. 101 102 103 104 105 106 107 108 109 110 111 112 113 114 115 116 117 118 119 120
Ans. C C B D A C D B A A C B A A D A C B D A
Ques. 121 122 123 124 125 126 127 128 129 130 131 132 133 134
Ans. B B B A B D C B A C D A B C

E
PRACTICE DPP # 2
E
Ques.
Ans.
1
D
2
C
3
A
4
B
5
A
6
C
7

T
C
J 8
C
9
A
10
B
11
D
12
C
13
D
14
B
15
C
16
D
17
C
18
B
19
C
20
D

A
Ques. 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38
Ans. B D A A D B B D A C D D A A C B B A

Ques. 1 2 3 4 5
e
6
:
PRACTICE DPP # 3
7

d
8 9 10 11 12 13 14 15 16 17 18 19 20
Ans. B A D A C C D B B A A D A C C C B B A D
Ques. 21
Ans. B
Ques. 41
Ans. A
22
A
42
D
23
A
43
A
24
B
44
C
25

C
A
45
A
o 26
C
27
A
28
B
29
C
30
C
31
B
32
B
33
A
34
C
35
B
36
C
37
C
38
A
39
B
40
D

PRACTICE DPP # 4
AIEEE / JEE MAIN
Ques. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20
Ans. B C B B B A A B B A D C B D D C B C D A
Ques. 21 22 23 24 25 26
Ans. C D A A D B

IIT JEE / JEE ADVANCED

Ques. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17
Ans. B A C C B B B B A C B A A B B D A

ASHWANI TYAGI SIR 24 CODE: ATJEE