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Environ Geol (2009) 58:1797–1810

DOI 10.1007/s00254-008-1678-1

ORIGINAL ARTICLE

Structural control of groundwater flow regimes and groundwater


chemistry along the lower reaches of the Zerka River, West
Jordan, using remote sensing, GIS, and field methods
Taleb Odeh Æ Elias Salameh Æ Mario Schirmer Æ
Gerhard Strauch

Received: 19 October 2006 / Accepted: 26 November 2008 / Published online: 7 January 2009
Ó Springer-Verlag 2008

Abstract A hydrogeological study was completed within a of discharge wherein large spring discharges are located in
sub-catchment of the Zerka River drainage basin, in western zones of converging groundwater flow lines. In areas where
Jordan. The system is characterized by anticlinal bending faults are not abundant, the groundwater retention time in the
with an axis trending SSW–NNE and plunging a few degrees aquifers is long and a zonation of the electrical conductivity
in the SSW direction. The anticlinal structure diverts was detected due to mineral dissolution. By controlling
groundwater flow towards the SSW while the strike-slipe groundwater flow, the anticlinal setting produces three
faults cause the groundwater to diverge where the fault is genetic groups of groundwater flow systems: (1) alkaline–
perpendicular to the groundwater flow lines, and to converge earth alkaline water which is predominately a bicarbonate-
where the fault is parallel to the groundwater flow lines. A type composition, (2) alkaline–earth alkaline water which is
direct relationship was found between the location of springs predominately bicarbonate–sulfate, and (3) alkaline–earth
and the type of groundwater flow with regard to the amount alkaline water with a high alkaline component.

Keywords Geographic information system 


Groundwater flow regime  Hydrochemistry 
Electronic supplementary material The online version of this Remote sensing  Structural setting  Zerka River
article (doi:10.1007/s00254-008-1678-1) contains supplementary
material, which is available to authorized users.

T. Odeh (&) Introduction


Department of Hydrogeology,
Helmholtz Centre for Environmental Research - UFZ, The Zerka River is the second largest River in Jordan with a
Halle, Germany
e-mail: taleb.odeh@ufz.de
4,025 km2 drainage basin area which extends from the
foothills of the Jordan Valley to Jabel Druz in southern
E. Salameh Syria. The current study area focusses on a sub-catchment
Department of Geology, University of Jordan, of the Zerka River drainage basin with an area of about
Amman, Jordan
e-mail: salameli@ju.edu.jo
146 km2 which lies about 13 km downstream of the King
Talal Dam (KTD) to the west (Fig. 1). Aquifers and aqui-
M. Schirmer cludes which outcrop in the area range in age from Triassic
Department of Water Resources and Drinking Water, to Upper Cretaceous. The site is also characterized by recent
Eawag, Swiss Federal Institute of Aquatic Science
sediments and various geologic structures, including strike
and Technology, Dübendorf, Switzerland
e-mail: mario.schirmer@eawag.ch slip faults and anticlines that play major roles in the
groundwater flow regimes and chemistry. Based on geo-
G. Strauch graphic information system (GIS) and remote sensing (RS)
Department of Hydrogeology,
methods, the roles of geologic structures in controlling the
Helmholtz Centre for Environmental Research - UFZ,
Leipzig, Germany groundwater flow regime and chemistry were evaluated. To
e-mail: gerhard.strauch@ufz.de achieve these objectives, we determined the structural

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Fig. 1 Location map of the


study area

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Environ Geol (2009) 58:1797–1810 1799

Table 1 Methods of chemical


Lab. parameter Instrument used
analyses
Calcium (Ca) Titration with 0.02 N Na2–EDTA using murexide-indicator
Calcium and magnesium (Ca, Mg) Titration with 0.02 N Na2–EDTA using eriochrome-black indicator
Chloride (Cl) Titration with 0.01 N AgNO3 using potassium chromate indicator
Bicarbonate (HCO3) Titration with 0.02 N H2SO4 and bromocresol indicator
Carbonate (CO3) Titration with 0.02 N H2SO4 and phenolphthalein indicator
COD chemical oxygen demand Potassium dichromate solution
BOD biological oxygen demand BOD5 test
Nitrate (NO3) Spectrophotometer (UV–visible) wave length 206 nm
Phosphate (PO4) Spectrophotometer (UV–visible) wave length 699 nm
Sulphate (SO4) Spectrophotometer (UV–visible) wave length 492 nm
Sodium, Potassium (Na, K) Flamephotometer

setting, the groundwater flow regime and chemistry geologic features are represented similarly. For example,
including the distribution of contaminants. Furthermore, the on the geological map the formations are represented
effects of the structures on the groundwater flow regime and as polygons and faults are represented as lines. When
chemistry were evaluated using GIS and RS methods. thematic layers are geo-referenced, they have a real world
location and overlay one another. Figure 2 shows the
flowchart that was used to produce digitized, thematic and
Methodology land use maps according to the geo-referenced maps, the
GIS data base, and the supervised classification method in
Field work included a survey of springs and well sites RS. The overlaying method in GIS was used to ease the
which were correlated with the geologic units and struc- correlation between the different layers of geology,
tures. Additional work was performed to correlate spring hydrogeology, and hydrochemistry. Since delineation of
discharge sites and faults. Water samples were collected groundwater resource zones is based on the combined role
at the end of the summer in 2004 (13/09/04, 20/10/04). being played by various factors, the use of GIS improves
Twenty samples were collected from the springs and the assessment of the investigated region (Jaiswal et al.
wells distributed on both sides of the Zerka River for both 2003).
chemical and biological analyses. In situ measurements of
hydrological parameters such as pH, electrical conduc-
Geographic and geological background
tivity (EC), and temperature were carried out during
sampling. In addition to the depth of water in wells and
Topography
springs, site elevations were also measured. Chemical and
biological analyses of the water samples were carried out
A digital elevation model (DEM) was created from the
at the University of Jordan laboratories. The American
triangle irregular network (TIN) of the digitized contour
Standard Methods for the analyses of water (Eaton et al.
lines (Fig. 3), which shows a high relief topography with
2005) were used for the different chemical parameters as
elevations ranging from -240 to 1,040 m above sea level
listed in Table 1. GIS software provided appropriate
(a.s.l.). Accordingly, three distinct topographic zones were
methods for efficient storage, retrieval, manipulation
classified as follows:
analysis, and display of large volumes of the spatial ref-
erenced data. Accordingly, the GIS processing consisted 1. Highland zone: this zone appears on both sides of the
of four basic components: (1) data input and editing, (2) sub-catchment area with elevations ranging from 720
storage of geographic databases, (3) data analysis and to 1,040 m a.s.l.
spatial modelling, and (4) visualization and presentation. 2. Escarpment zone: this zone is clearly visible on the
RS and its associated image processing technology pro- right-hand side of the Zerka River with elevations
vided an ideal tool for determining the land use in the ranging from 400 to 720 m a.s.l. while it appears on
watershed (Schultz and Engman 2000). The GIS tools both sides of the River at elevations ranging from 80 to
transformed the geographic features into a series of 400 m a.s.l.
thematic layers and attribute tables which represented 3. Foothill zone: the foothill zone is located at the foot of
the characteristics of those features. The geographic the mountains of the escarpment leading into the Jordan
features are represented as points, lines and polygons. The Valley. The elevation of this zone is about 400 m a.s.l.

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Fig. 2 Flow charts of work 1) Raster Data.


mechanism
Data input
(ARCGIS 2 sheets of scanned geologic maps (1:50000) scale, one sheet of topographic map (1:10000) scale and satellite image
8.1)

Georeferencing to Palestine Grid

Storage as Rectified geological map, Rectified topographic map and rectified Satellite Image
raster

Digitizing Digitizing Supervised classification


(ENVI4.1 SOFTWARE)
Storage as
vector (with
Faults, Strikes and Zerka River, village location,
GIS data geological Formations KTD, counter lines Landuse map
base)

GIS analysis Geological period map TIN


(Triangle irregular net)

2) Tabulate Data.

Data input to
ArcGIS 8.1 Tabulate data DBF4 format

Hydrogeology (wells and springs): Hydrochemistry (wells and


GIS data Hydrostatic water level and springs springs):Major anion and cation,
base elevations (Coordinates from GPS).
EC.
Hydrology: Rainfall, evaporation,
runoff and ifiltration

Interpolation Thematic maps:


(kringging method) Hydrostatic water level, Major anion and cations, EC,
Using ArcGIS 8.1 Rainfall, evaporation, runoff and ifiltration.
SOFTWAR

GIS
manipulation Contour lines for groundwater
level thematic map

Geologic framework Structural framework

The Nubian-Arabian Pre-Cambrian Shield composed of The study area is located on the eastern side of the Dead
crystalline basement rocks underlies Jordan and outcrops in Sea–Jordan Valley transform fault. The Dead Sea trans-
the south western areas of the country. This shield has form fault forms a part of the boundary between the
undergone both uplift and subduction during various Pre- African and Arabian plates. According to Quennell (1958),
Cambrian epirogenic events which resulted in marine this fault shows major strike slip movement in two stages
transgressions and regressions. During two major trans- with a total sinistral displacement of 107 km and large
gressions, marine sediments of considerable thickness were vertical downthrows of more than 1,500 m. Due to its
deposited. Sediment thickness reaches up to 4,000 m in the proximity to the Dead Sea transform fault, the study area
Jafer Basin and even thicker sediments likely accumulated in has—since the beginning of the movements—been
the Sirhan depression. In the central part of Jordan— strongly affected, especially in its relief topography and
including the study area—marine sediments were deposited drainage pattern. The distribution of faults and rose dia-
during the Middle Cambrian, Jurassic, and Cretaceous gram representation given in Fig. 4 shows that the major
through to the Oligocene ages. Transgressions came from fault system strikes WNW–ESE and the minor ones strike
north-west (Bender 1974). The formation outcrops in the (NNW to N)–(SSE to S). The WNW–ESE fault system is
study area are of the Mesozoic era (Table 2). one of the oldest systems in the region. Its strike is parallel

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Environ Geol (2009) 58:1797–1810 1801

Fig. 3 Topographical features in the study area. a Topograpic map. b TIN Traingle irregular network. c DEM vertical exaggeration 9 5) for the
study area

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Table 2 The main rock types of the formation in the study area
Group Formation Main rock type Age Period Era

Belqa G. Wadi Um Gudran F. Chalk and marl Santonian Cretaceous Mesozoic


Ajlun G. Wai Sir F. Limestone Touronian
Shueib F. Limestone Cenomanian to early Touranian
Hummar F. Dolomite Upper Cenomainian
Fuheis F. Marly limestone Cenomanian
Naur F. Dolomitic limestone Albian to early Cenomanian
Kurnub G. Kurnub F. Sandstone Neocmian to Albanian Jurassic
Azap G. Mugahanniyya F. Limestone and some clay Kimmeridgian
Hamam F. Carbonate, siliclastic Bajocion
Ramla F. Sandstone, clay and limestone Bajocion
Dahab F. Carbonate rock Bajocion
Silal F. Siliclastic rock Aalenian
Nimr F. Dolomitic limestone Liassic
Hihi F. Mudstone Lower Jurassic
Zerka G. Abu Ruweis F. Gypsum Carnian Triassic

Fig. 4 Faults distribution system in Jordan and in the study area. a Deed Sea transform fault and study area. b Faults distributions in the study
area. c Rose diagrams of faults in the study area

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Fig. 5 Geological setting of the study area. a Geological map of the study area. b Cross sections. c Stereographic projection for the two main dip
angles of the system

to the trend of the Red Sea and Wadi Sirhan faults, namely (1965) and El-Naser (1991). The lithostratigraphic
NW–SE (Quennell 1958). The system was later rejuve- sequence of the study area, according to the classification
nated, with a clockwise rotation of the stress field. Most of by MacDonald et al. (1965), can be divided into three
the faults in the study area show strike-slipe components as hydrogeological units as follows (Table 3):
a result of the rejuvenated stress system with acting forces
1. The upper aquifer complex
rotating clockwise from a NE–SW oriented to SSE–NNW.
The cross-sections show that the area has anticlinal bend- This complex consists mainly of limestone, dolomite,
ing, while the stereographic projection indicates that the and silicified limestone of Upper Cretaceous/Tertiary age
anticlinal axis is generally trending NNE–SSW and plun- with a total thickness ranging from 600 to 700 m.
ges by a few degrees in a SSW direction. The anticlinal
2. The upper aquiclude
bending was caused by the various stages of the rotating
stress field (Fig. 5). This unit consists of marly Limestone of Middle
Cretaceous age with a total thickness about 60 m.
3. The lower aquifer complex
Classification and analyses
This complex consists mainly of sandstone of the Lower
Cretaceous age underlain by Jurassic rocks with interbed-
Hydrogeological system
dings of limestone and sandstone and a total thickness
ranging from 200 to 500 m.
Many studies have been performed on the hydrogeologic
framework of northern Jordan such as MacDonald et al. 4. The lower aquiclude

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Table 3 The hydrogeological


Geological Main rock type Hydrogeological Thickens Permeability (m/d)
units in the study area
formation classification (m) according JICA (1995)

Wadi Umm Gudran Chalk The upper aquifer 600–700 7.58 9 10-4
Wai Sir Limestone complex (unconfined
aquifer)
Shueib Limestone
Hummar Dolomite
Fuheis Marly Limestone Aquiclude 60 0
Naur Dolomitic The lower aquifer 200–500 4.48 9 10-5
limestone complex (semi
Kurnub Sandstone confined aquifer)
Mugahanniyya Limestone
Hamam Carbonate,
siliclastic
Ramla Sandstone
Dahab Carbonate rock
Nimr Siliclastic rock
Silal Dolomitic
limestone
Hihi Mudstone
Abu Ruweis Gypsum The lower aquiclude 40–80 0
complex

This unit consists of clays of the Lower Jurassic and geochemistry of percolated rock units, retention time of
gypsum of the Upper Triassic with a total thickness ranging groundwater in the different aquifers, weathering and
from 40 to 80 m. erosion of rocks in addition to human activities such as
urbanization, irrigation, and industrialization (Drever
Groundwater flow 1986; Gray 1994). To specify the origin of the dissolved
substances, 32 groundwater samples were collected from
Groundwater recharge through infiltration takes place over wells and springs in addition to rainfall and analyzed for
the highlands in the southern and northern parts of the study their chemical constituents (Supplementary Fig. 2; Sup-
area, as determined from thematic infiltration maps produced plementary Table 1). Plotting the samples on a modified
by applying the general formula of the water balance equa- Piper diagram (Piper 1944; Furtak and Langguth 1967)
tion (Fig. 6). Infiltration water forms in the upper aquifer shows three genetic groups of groundwater generated
perched water bodies, which discharge through springs and within the groundwater flow that is affected by the
seeps along the higher lands. Part of the infiltration water structures (Fig. 7):
percolates into the lower aquifer complex which also
1. Normal earth-alkaline water is predominantly bicar-
receives water from other recharge areas lying further east,
bonate-type
north, and south of the study area. The groundwater flow was
determined by the measured groundwater levels. A contour The groundwater in the upper aquifer originates from
map for the groundwater level was drawn by interpolating precipitation. Precipitation water in Jordan is normally
the values of the hydrostatic water level in 49 wells and from alkaline because of atmospheric dust, and is composed to
the elevations of 22 springs located within and around the a great extent of carbonate (Salameh et al. 1991).
study area (Supplememtary Fig. 1). The maps show that The groundwater in the upper aquifer is of an earth-alkaline
groundwater flows from the northern and southern recharge type with prevailing bicarbonate. The saturation indi-
areas towards the wadi Zerka, south and the north of the ces indicate under-saturated water with respect to
recharge areas respectively, and from here, along the wadi dolomite and calcite in the upper aquifer (Supplementary
sediments towards the west. Fig. 3).
2. Normal earth-alkaline water is predominately bicarbo-
Groundwater chemistry
natic–sulfatic
Groundwater chemistry is influenced by different factors Groundwater percolates from the upper to the lower
such as dissolved substances in precipitation water, aquifer where additional dissolution of minerals takes

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Fig. 6 Recharge water in the study area from the infiltration. a Wundt equation (1937). c Themtaic map for runoff distribution by
Thematic map for rainfall distribution (mm/year) in the study area estimating the amount of runoff (overland flow) in each rainfall
(Ministry of Water and Irrigation of Jordan). According to the polygon according to the runnoff coefficient estimated by GTZ 1978
thematic map the study area is divided into eight polygons from A–H. (equal to 1.8%). d Thematic map for infiltration distribution (mm/
b Thematic map for evaporation distribution (mm/year) by estimating year) in the study area by using the general water balance equation
the amount of evaporation in each rainfall polygon according to the (Infiltration = Precipitation - (Runoff ? Evaporation)

place. There are two main lithological units: the Sandstone Sandstone Unit The groundwater reaching this unit is
Unit (Lower Cretaceous rocks), and the Carbonate Unit over-saturated with respect to calcite and dolomite (SI [ 1)
(Upper Jurassic rocks). The changes in the groundwater and both minerals start to precipitate in the rock matrix.
chemistry during percolation in the two rock types can be However, the water remains under-saturated with respect to
interpreted as follows: halite and gypsum, although the saturation indices for both

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Fig. 7 Groundwater genises in the study area. a Plotting of the samples on a Piper Diagram. The samples symbols in Table 4 have been
converted to numbers. b Hydrochemical classification and groundwater genetic groups. c Groundwater genetic group flow directions

slightly decrease. In addition, as mentioned above, the dolomite indicate dissolution of calcite and dolomite which
water remains earth-alkaline type with prevailing bicar- starts again after precipitation within the Sandstone Unit.
bonate and sulphates. The saturation indices with respect to other minerals like
gypsum and halite fluctuate significantly due to ionic
Carbonate Unit The groundwater reaches this unit from
exchange.
the Sandstone Unit. The saturation indices for calcite and

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Fig. 8 Landuse and groundwater contaminations. a Rectified space image with overlapping of the catchment area. b Rectified classified space
image. c Distribution of nitrate concentration and COD. d Distribution of microbiological contamination

3. Earth alkaline-water with a high alkaline component urbanisation, is more polluted with bacteria and fecal col-
iforms than in the southern part. Waste water collection in
When the groundwater reaches the foothills of the
this area is managed by use of cesspools for all kinds of
escarpment and the Jordan Valley area, it mixes with a
liquid wastes. The degree of microbial pollution of the
groundwater body of high chloride and sodium concen-
groundwater is, therefore, a consequence of the settlement
trations leading to groundwater with alkaline components.
in the northern part of the Zerka River.
The water is under-saturated with respect to calcite and
dolomite and slightly over-saturated with respect to anhy-
drite and chlorides (Salameh 2001). Figure 8 shows the Results and discussion
locations of groundwater sampling locations superimposed
on the land use map and the distributions of some variables Groundwater flow regimes and geological structures
related to land use (Supplementary Table 2). The nitrate
concentrations and the chemical oxygen demand (COD) in The structures in the study area have major effects on the
the groundwater of the southern part are higher and have a groundwater flow regime. The anticlinal axis with its
wider distribution than those of the northern part. This associated jointing allows the general direction of the
behaviour is due to the intensive agricultural land use groundwater flow to follow the approximate direction of
where fertilizers and pesticides are applied. The biological the anticline axis, plunging SSW. This indicates that a
analysis shows that the groundwater in the northern part of folded structure creates a ‘river-like’ flow pattern within
the study area, characterized by a higher degree of the aquifers (Ben-Itzhak and Gvirtzman 2005). The water

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Fig. 9 Groundwater flow


regimes in the study area

Table 4 The amount of discharge from spring originating along the highlands flows towards the centre of
Springe name No. on the map 3
Discharge (m /year) the wadi which almost coincides with the anticlinal axis.
Faults in the study area make the groundwater flow lines
El Bassah 53 31,233.34 diverge if the fault is perpendicular to the groundwater flow
El Balad (Burma) 54 78,145.25 direction and converge if the fault is parallel to ground-
Hamed 55 72,268.38 water flow (Fig. 9). This is attributed to the fact that
Um Jurn 56 45,922.34 faulting increases the permeability and the porosity of the
El Balad (Sahen) 57 18,563.90 rocks along their trend lines. On the other hand, there is a
Dafal 58 27,224.83 relationship between the location of springs, the ground-
Eshshati 59 11,198.20 water flow lines, and the amount of discharge (Table 4):
El Azab 60 40,650.89 the greater amount of discharge is from springs located on
Subeihi 61 6,670.23 the zone of converging groundwater flow lines which
El Heisha 62 0 indicates that the strike slip faults in the study area are
El Huna 63 59,876.60 high-permeability faults. High-permeability faults act as
El Beid 64 6,876.60 preferential pathways for fluid migration and solute trans-
El Arqetain 65 16,114.02 port (López and Smith 1995).
El Kursi 66 9,460.80
Subeihi 67 0 Groundwater chemistry and geological structures
Hafayer 68 5,518.80
Hajjaj 69 17,373.25 The anticlinal setting of the study area diverts the
Jamman 70 20,654.83
groundwater towards the SW, carrying dissolved cations
and anions and causing their concentrations to increase in

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Fig. 10 Increasing of EC with


long groundwater retention time

that direction. From Fig. 10, it appears that there is a The faults in the study area are strike slip faults while
zonation for the EC values. This is especially the case the major fault system strikes WNW–ESE. These faults are
where faults are less abundant and where the retention time highly permeable, thus causing groundwater flow lines to
for the groundwater in the aquifers is long, hence the diverge when the faults are perpendicular to groundwater
increase in EC values which is related to mineral dissolu- flow, and to converge when they are parallel.
tion. Furthermore, the faults which are common in the The strike slip faults are weakness zones which cause
northern part are structurally weak zones and allow for faster exchange of surface and subsurface water including
faster percolation of surface pollutants, especially those pollutants from anthropogenic activities.
coming from cesspools widely used in the northern part. Where strike slip faults are less abundant, groundwater
retention times in the aquifers are longer, which causes
increasing groundwater EC values.
Conclusions
Acknowledgment We would like to thank the University of Jordan
The investigated area of the Zerka River, Jordan, shows for technical support, and John Molson (Laval University, Canada) is
anticlinal bending with an anticlinal axis trending SSW– thanked for reviewing the manuscript.
NNE and an axis that plunges a few degrees in a SSW
direction. As result of jointing, the anticlinal setting allows
the groundwater to flow in the same direction as the plunge
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