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Composites: Part A 34 (2003) 151–161

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The assessment of novel materials and processes for the impact


tolerant design of stiffened composite aerospace structures
Emile Greenhalgh*, Matthew Hiley
Future Systems Technology, QinetiQ, Farnborough, UK
Received 18 June 2002; revised 16 September 2002; accepted 24 October 2002

Abstract
This paper reviews the most promising material concepts (tougher matrix systems, 2D and 3D woven materials, stitching and Z-pinning,
selective interlayers, protective surface layers and hybrid laminates) for improving the damage tolerance of aerospace stringer-stiffened
structures. Although all of these concepts can impart improvements, all also have disadvantages including reduced undamaged performance,
weight penalties and the need for requalification. Recommendations have been made as to which show the most promise for improving the
impact tolerance of current and future structures. For current structures, Z-pinning shows the most promise, although the cost associated with
this concept is currently high. For future structures, 3D woven materials show significant promise for impact tolerant design.
q 2003 Elsevier Science Ltd. All rights reserved.
Keywords: A. Polymer-matrix composites (PMCs); B. Damage tolerance; D. Mechanical testing; E. Prepreg

1. Introduction and background prepreg tape form. This review considers both the technical
and economic implications of each concept for improving
Although polymer matrix composites (PMCs) are being the impact tolerance with respect to this baseline fabrication
used in a wide range of applications, one of the critical route. To conduct this assessment, the failure processes in
parameters is their tolerance to impact; the damage generated impact damaged stiffened structures are described and the
is often hidden but can considerably reduce mechanical key parameters which control impact tolerance are outlined.
performance. The wide spectrum of constituents and Material concepts from the literature are then considered
architectures that can be utilised, has led to a large number and recommendations are made as to which show promise
of new materials and processing concepts being developed to for significantly improving the impact tolerance of PMC
reduce sensitivity to impact. These concepts have demon- structures.
strated improved properties at the material level, but need to There is some confusion over the term impact tolerance
be proved in a structural environment. Also, certification with respect to PMC structures [2]. There are two major
requirements require expensive and time-consuming testing issues, which may be addressed separately. The first, impact
to be conducted on new materials before they can be used in- resistance deals with the ability to sustain a given impact
service [1]. Informed decisions need to be taken as to whether threat with the minimum amount of damage. The second,
the improvements demonstrated at a material level will impact damage tolerance, deals with the ability to sustain a
translate into cost-effective benefits at a component level. given level of damage with minimum effect on the structural
The main aim of this review is to identify the most performance. If a structure is impact resistant it does not
promising material concepts for improving the impact follow that it will be impact damage tolerant; each of these
tolerance of PMC structures. It focuses on a common aspects is controlled by different parameters. Therefore, the
structural element in aerospace components; stringer- term ‘impact tolerance’ deals with the overall ability to
stiffened panels (Fig. 1). These structures are conventionally sustain a given impact with a minimum effect on the
made from carbon-fibre/epoxy composite in unidirectional structure and thus combines both impact resistance and
impact damage tolerance.
* Corresponding author. Fax: þ 44-1252-395077. Understanding the processes by which the damage initiates
E-mail address: esgreenhalgh@qinetiq.com (E. Greenhalgh). and forms during the impact process is key to assessing
1359-835X/03/$ - see front matter q 2003 Elsevier Science Ltd. All rights reserved.
PII: S 1 3 5 9 - 8 3 5 X ( 0 2 ) 0 0 1 8 8 - 4
152 E. Greenhalgh, M. Hiley / Composites: Part A 34 (2003) 151–161

Fig. 1. Typical example of a stringer-stiffened panel.

impact resistant concepts. On impact, the incident energy is important when assessing impact tolerance concepts [7 –9].
absorbed by a variety of mechanisms, [2–5] but to produce an The general failure process, which can be extended to larger
impact resistant component, the amount of energy absorbed structures [10] is shown in Fig. 2 and is described in the
through damage should be minimised. Generally, the first following paragraphs.
fracture event during an impact is the formation of matrix Firstly, upon loading, there is local buckling of the
cracks within the plies, caused by through-thickness shear damaged region (Fig. 2a) and as the load is increased (Fig.
stresses generated by the out-of-plane impact forces. The 2b), there is also local bending of the delaminated plies and
dominant failure mode during low velocity impact, that of the sub-laminate beneath these plies [2,5]. Initially this
delamination, can be split into two aspects; initiation and deflects away from the delaminated interface, but as the load
propagation. Delaminations are usually initiated by opening increases this generally snaps-through towards the delami-
forces at matrix cracks [5]. Delamination growth is mainly nated plies. This deformation induces mixed-mode delami-
driven by interlaminar shear stresses (mode II) induced by the nation forces at the boundary of the damage region and if
bending of the laminate during the impact event [5]. Finally, these exceed the local toughness, the delamination will
fibre fracture can be a significant energy absorbing mechan- grow (Fig. 2c). For impact damage, which consists of
ism, particularly at high velocities, and is generated by the delaminations at many ply interfaces, significant delamina-
high through-thickness forces generated during impact [6]. tion growth will occur at only a few interfaces; those in
Fibres can either fail in tension due to the membrane forces which the one ply direction and the driving force are
generated during impact, or by shear-out during penetration coincident [5]. Initially, this delamination growth will be
of the impactor. The relative proportions of the different stable and eventually, the delamination may reach structural
damage modes are controlled by a variety of material features, such as stringers (Fig. 2d). Upon reaching these
parameters such as impactor conditions (shape, energy, features, the added out-of-plane constraint imposed by the
mass and velocity), material properties (matrix toughness, substructure will inhibit further delamination growth.
fibre surface treatment, moisture content, fibre stiffness and However, if there is delamination close to the free surface
strength), stacking sequence and laminate geometry. In (i.e. under little influence of the structural detail), the
addition, there are structural aspects (overall geometry, delamination will continue to extend laterally (Fig. 2e), at
local structural detail and dynamic response) which can preferential ply interfaces (usually 908) from the impact site
have a significant effect on the impact damage [5]. With [7,10]. This narrow band of delamination will shed load
regard to stiffened structures, impacting in an inter-stiffener onto the material beneath, reducing the out-of-plane support
bay will generate very different damage to impacts over a on these plies. Ultimately, this process will become
stiffener. In the former, the compliance of the impact site will unstable; massive growth and subsequent local bending of
promote large deflections leading to delamination. Impact the delaminated plies and load-bearing layers beneath will
over the stiffener will lead to higher contact forces (fibre occur. When this situation develops, the excessive bending
damage), but more energy absorbed elastically through (and compressive) stress on the load-bearing layers leads to
displacing a larger volume of material. Impacting over the in-plane failure of these layers, and catastrophic structural
edge of a stiffener will introduce local twisting and failure (Fig. 2e).
preferential damage formation towards the bay [7]. If the damage growth is arrested by the substructure prior
Understanding the process by which damage grows (and to unstable delamination growth, the failure sequence can be
leads to ultimate failure) in stringer-stiffened panels is different. The presence of opening forces at the delamination
E. Greenhalgh, M. Hiley / Composites: Part A 34 (2003) 151–161 153

Fig. 2. General failure process for a damaged skin-stringer panel.

boundary will promote damage development beneath the the delaminated plies and sub-laminate. This damage
stringer. Eventually, global panel buckling will occur leading mode is particularly important during global buckling of
to large out-of-plane deflections in the bays. The global the bays of skin-stringer panels [12].
buckling will induce massive opening forces at the boundary Mode II toughness (GIIC). Shear (GII) is the dominant
of the delamination, and beneath the substructure. This will fracture mechanism during an impact event and skin/strin-
promote detachment of the stringers from the skin (Fig. 2f), ger detachment and is induced by the out-of-plane bending
as described in detail elsewhere [11]. This will lead to larger during impact. Similarly, impacting near or over a stringer
deflections of the skin, promoting larger opening forces, etc. induces high interlaminar shear forces parallel to the
until finally failure will occur by excessive loading of the skin stringer, generating mode II dominated growth parallel to
(Fig. 2g), induced by the loss of support from the stringers. the stringer. Finally, global panel buckling can induce
twisting at the stringer/skin interface, which also induces
mode II condition.
2. Key material parameters Bending (D11) and shear (G12) moduli. During the
impact event, the bending modulus of the laminate
Through improvements in the critical material par- influences the energy absorption process and area of the
ameters, significant increase in the impact tolerance of material which responds to the impact event. Also, the
skin-stringer panels can be achieved. bending and shear moduli influence delamination initiation,
Mode I toughness (GIC). The key driving force for growth and failure in buckling. This includes both local
delamination growth (damage tolerance) is mode I (peel) buckling of the delaminated plies, which induces damage
loading which is induced by the local buckling of growth, and global panel buckling, which promotes
154 E. Greenhalgh, M. Hiley / Composites: Part A 34 (2003) 151–161

skin/stringer detachment and drives unstable delamination exploit the potential of composites, treating their properties
growth. Increasing these moduli will increase the buckling as ‘black aluminium’. There is considerable scope for
loads, thus inhibiting damage growth [5]. improving impact tolerance by tailoring the lay-up to a
Compressive and flexural strength (sc and sf). Both the particular component. For example, putting angle plies (i.e.
ultimate failure of the panel and the formation of the impact not load-bearing) on the outer surface [17], using a stepped
damage (fibre cracking) are controlled by a combination of stacking sequence [4] and eliminating blocked plies can
the compressive and flexural strength. These properties are give improvements in performance. In addition to the
mainly controlled by the fibre micro-buckling, which is stacking sequence, the relative proportion of different
influenced by a number of factors, such as fibre/matrix orientations of plies will have an effect on the impact
interface strength, fibre waviness, matrix stiffness, fibre tolerance. In general, matrix-dominated stacking sequences
stiffness and matrix toughness [13]. (‘soft’ laminates) [18,19] or high in-plane shear concepts
[20], which contain a high proportion of off-axis plies, are
more damage tolerant than fibre dominated stacking
3. Impact tolerance through design sequences (‘hard’ laminates), which contain a high
proportion of load-bearing plies. Finally, delaminations
There is scope for improving the structural impact migrate through the layers until they reach preferential ply
tolerance purely through improved design and optimisation. interfaces; in which the driving force and upper ply
This is a preferable option since this does not incur the costs direction are coincident [7]. Clearly, by eliminating the
and increased timescales associated with requalifying a new preferential interfaces (generally 908 plies), the damage
material. In the context of skin-stringer panels, there are a growth can be inhibited.
number of options that can be considered.
Panel geometry. Studies [5,14] have shown that impact
response, and the subsequent damage formation, is 4. Novel material and processing concepts
dependent on the proportion of energy absorbed through
structural response (elastic) and damage. By changing the The advantages and disadvantages of the different
geometry, the relative proportions of these parameters can concepts for improving the impact tolerance of composite
be changed. If the deflections and forces can be kept below structures are summarised in Table 1. The following
limiting values, the incident energy will be mainly absorbed paragraphs discuss these concepts in more detail.
through structural response. Such an approach has already Tougher matrix systems. The established approach to
been employed in the design of impact resistant skin- improving impact tolerance has been to employ a tougher
stringer panels [14]. The stiffened panel geometry will also resin system than those in use, although it has been
have an effect on the impact damage tolerance; for a given suggested that this route has been exhausted [21]. The
buckling design strain, having a large bay width is materials used in current aerospace applications have a
preferable to a thin skin for impact damage tolerance [7]. range of delamination toughnesses; up to 250 J m22 (GIC)
Stringer geometry. The stringer geometry can signifi- and 650 J m22 (GIIC) [2,5]. An example of the fracture
cantly affect the performance since its detachment from morphology of these materials is shown in Fig. 4a. They are
the skin is a key mechanism in the failure process [11]. It characterised by fairly brittle fracture with little plasticity.
is preferable to use stringers with tapered feet or stiffener Newer materials have significantly improved toughnesses,
doublers [15] (Fig. 3a and b, respectively) which reduce often achieved through the incorporation of a second
the opening forces and inhibit damage growth. Another toughened phase within the matrix or ply interface. This
approach (Fig. 3c) is embedded stringers [15] which second phase acts to absorb significant amount of energy
eliminates skin/stringer detachment by incorporating the during fracture through mechanisms such as plastic flow,
foot as an integral part of the skin. Although this concept crack blunting and void coalescence (Fig. 4b). Increasing
is difficult and time-consuming to manufacture, there is the resin toughness also increases the size of the process
scope to use it in conjunction with other toughening zone at the crack tip, promoting toughening mechanisms
methods [12,16]. such as fibre bridging. Further improvements in toughness
Stacking sequence. The option to change the stacking can be achieved using thermoplastic rather than thermoset
sequence has often been ignored. Many components are matrices which absorb fracture energy through massive
designed using ‘quasi-isotropic’ lay-ups which do not fully plastic flow (Fig. 4c) [5]. Changing to a tougher resin system

Fig. 3. Different stiffener designs.


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Table 1
Advantages and disadvantages of different concepts compared to baseline of unidirectional tape structures

Concept Advantages Disadvantages

Panel design Low costs and timescales Limited improvements imparted


No need for material requalification
Tougher matrix Same architecture as baseline Reduced fatigue and compression properties
Usually similar costs and timescales Increased sensitivity to processing
No need for redesign Can require different processing routes
Usually same processing route Can be higher cost
Plain woven Improved drape and manufacturability Some redesign and requalification needed
More elastic response during impact Poor undamaged properties
Usually same processing route Weave needs to be balanced
NCF Low cost and timescales Redesign and requalification needed
Environmental benefits Reduced undamaged properties
Improved manufacturability Performance sensitive to processing

Mixed-woven Undamaged properties as baseline Some redesign and requalification needed


Similar processing route Weave needs to be balanced
Tape/fabric interface prone to delamination
Selective interlayers and hybrids Undamaged properties as baseline May reduce compressive performance
Similar processing route Increased thickness may lead to redesign required
Adds parasitic weight and extra cost
3D composites Reduced cost Relatively immature concept
Lends itself to design of substructure Can reduce undamaged properties
Requires redesign and requalification

Stitching Same processing route Can reduce undamaged properties


Offers fail-safe design Difficult to fabricate with stiffeners
Z-pinning Same processing route High cost
Optimisation can limit drop in undamaged properties Relatively immature concept
Offers fail-safe design
Protective layers Similar processing route Increased thickness may lead to redesign required
Generally no need for requalification Adds parasitic weight and extra cost

has a number of advantages, most notably an increase in have a reduced fatigue performance [22]. Some of the newer
delamination resistance. The composite architecture is the tougher materials have exhibited an increased susceptibility
same as that used in the original component and, in many to processing variables [23], which can introduce scatter in
instances the fibre type can be kept the same, eliminating the the material properties. Finally, the materials, which exhibit
need for redesign. However, there are a number of the best improvements in toughness (thermoplastics) have a
disadvantages with changing to a tougher resin system. different processing route to conventional materials. This
Firstly, other mechanical properties of tougher materials can lead to problems when manufacturing stiffened
tend to be reduced, particularly compression dominated structures, where the methods for fabricating the substruc-
properties, which may suffer due to increased matrix ture, and attaching it to the skin will need to be different to
compliance. There is also evidence that tougher materials that used in conventional materials.

Fig. 4. Delamination fracture of different matrix systems.


156 E. Greenhalgh, M. Hiley / Composites: Part A 34 (2003) 151–161

Planar woven laminates. The fibrous nature of CFRP of these materials are more sensitive to processing variables
composites has led to the exploitation of fabrication than conventional prepregs.
methods originally developed for the textile industry; e.g. Mixed-woven fabric laminates. Another route by which
the weaving of the tows of fibres together rather than using the poor undamaged performance of woven laminates can
unidirectional tape. A wide range of woven architectures be improved is by using hybrid laminates; a combination of
have been developed [17,21,24] and the construction and woven and unidirectional tape plies [17]. The woven layers
percentage of fibres in each direction can control the impart improvements in the impact tolerance whilst the
mechanical properties of the laminates. During impact, the unidirectional layers improve the stiffness and undamaged
weave acts to contain the shear and delamination cracks strength. This approach uses the same processing route as
[24], significantly inhibiting the damage extent. In addition, the conventional materials, which will ensure that high
the compliant nature of woven laminates compared to certification costs are not incurred. This material concept
unidirectional tape means that much of the energy is does have a number of disadvantages though. The tape and
absorbed through structural response rather than damage fabric layers need to be laid-up in such a manner to ensure
formation. Finally, the processing route (autoclaving) for that the stacking sequence is balanced which could lead to
woven laminates can be the same as that used for the need to redesign to recover the required performance.
unidirectional tape. However, there are some disadvantages; The interfaces between the woven and tape lamina are also
the most significant problem is that they have poorer prone to delamination.
undamaged properties, such as compression stiffness and Selective interlayers and hybrids. One alternative
strength. This is attributed to a high proportion of the fibres method for improving the impact tolerance is to insert
not being aligned with the main loading direction. The layers of a secondary material at critical locations in the
reduction in stiffness is an important drawback for skin- stacking sequence. This can take the form of toughened
stringer panels since it will reduce the buckling perform- particles on the ply surface, discrete toughened layers [27],
ance. Compression strength is also reduced by the local or as a hybrid with glass or Kevlar plies at critical locations.
crimping of the fibres (due to the weave), which promotes Commercially available prepreg materials with toughened
micro-buckling. These reduced undamaged properties will interlayers include Hexcel’s M21 [12] and Toray’s F3900
lead to a need to redesign the structure, which of course will [23] which contain particulates (usually thermoplastic) on
incur significantly increased costs and timescales. Finally, the surface of the plies. Although these have demonstrated
in thin laminates, the direction of the woven plies needs to improved damage tolerance in materials, they have
be balanced to ensure that there are no residual stresses increased scatter [12] and, in structures, poor local
inducing warping, etc. [17]. distribution of the particulates can lead to only limited
Unidirectional or non-crimp fabrics (NCF). The improvements in strength [23]. Discrete toughened layers
reduction in undamaged mechanical properties incurred by can be inserted at orthogonal ply interfaces for impact
using woven laminates is dependent on the proportion of resistance, or at interfaces containing 908 plies for impact
fibres running in the loading direction. If this approaches damage tolerance. Alternatively, they can be bonded to the
100%, the properties will be partially recovered. The fibres surfaces after cure. A recent development has been to place
of such fabrics are usually held together by a binding stitch, shape-memory alloy wires within the laminate [28]; these
often a different material (polyester or glass) to the main absorb energy through super elastic deformation of the
fibre type. These types of material are usually described as wires. They have demonstrated very good impact resistance
unidirectional or NCF [25]. The processing route for these although there are still issues, which need to be resolved
materials is different to the conventional autoclave route; such as long-term degradation of properties.
using resin infusion or resin transfer instead [26]. To speed Selective layers and hybrids have demonstrated improve-
up the manufacturing process and improve impact damage ments in both impact resistance and impact damage
tolerance, the individual layers are often held together in tolerance [27 – 29], although it is difficult to isolate the
bundles by stitches; this is discussed later in this paper. improvements due to toughening from those due to
NCFs promise both reduced material and through-life costs, the increase in thickness through the use of interlayers.
and improved damage tolerance. In addition, they offer The processing route is the same as that in conventional
considerable economic and environmental benefits (lower materials but the introduction of softened layers may reduce
storage costs, reduced exposure to resins, lower material the out-of-plane support on the load-bearing plies, promot-
costs) over conventional prepreg materials [26]. However, ing micro-buckling and compression failure. The need to
there are disadvantages in using these materials. There is increase thickness to achieve the same membrane stiffness
still a tendency for fibre crimping and waviness to be as the original component is also a problem, possibly
introduced during manufacture, which leads to reductions in requiring redesign. Finally, introduction of toughened layers
compression performance. The change in the fabrication will need to be balanced within the stacking sequence.
route makes the cost of certification as a replacement for Three dimensional architecture. The development of
conventional materials expensive and time-consuming. woven concepts from the textile industry has led to the
Also, recent studies [26] have shown that the performance development of three-dimensional materials. Clearly, having
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reinforcement in three directions will improve the resistance the stitching fibres induces ‘quilting’ in the parent fibres
to delamination, but may promote other failure modes. The which promotes micro-buckling during compressive load-
improvements in properties achieved using 3D architecture ing. Stitching does not reduce the threat level at which
are very dependent on factors such as weave pitch and tow impact damage starts to form, since the stitches can act as
sizes [21,30]. As with NCF laminates, these fabrics are initiation sites for cracking. The stitches also introduce fibre
produced as fibre preforms and the matrix is introduced later waviness to the load-bearing plies, promoting micro-
by resin infusion. These types of architecture lend them- buckling and compressive failure. The current preferred
selves well to substructure such as stringers, although the fabrication route [23] is to manufacture the stiffeners
mechanical properties are quite dependent on the detailed separately and then secondary bond them to the skin.
architecture [21]. The relatively homogeneous nature of Stitching would require the stringers to be co-cured to the
these materials and the greater thicknesses generally used skin which leads to difficulties particularly for I-section
also mean that balancing the layers is not so important. stiffeners [7]. Finally, there are concerns about the durability
However, as with the planar woven constructions, the of stitched laminates.
improvements in impact damage tolerance also lead to a Z-pinning. An alternative process to stitching is Z-
reduction in the undamaged performance. The through- pinning, where reinforcing pins are inserted using an
thickness fibres can also act as initiation sites for cracking, ultrasonic gun, which drives the pins into the laminate.
and thus the threat level at which damage starts to develop is Small diameter composite pins (less than 0.5 mm in
not improved. Also, it is more difficult to infuse the resin into diameter with an a real density of typically 2%) are
3D composites than conventional 2D laminates, which can introduced into the laminate prior to cure [28]. Unlike
lead to defect formation in large components. More stitching, where the fibres are mechanically driven into the
experimental work needs to be conducted on these materials, parent laminate, the Z-pinning process locally softens the
in particular development and modification of the standard resin, allowing the parent fibres to displace to accommodate
test methods to allow their full characterisation. It is through the pins. It is also preferable to use composite pins (precured
development of these standard test methods that these CFRP) rather than metal pins since the latter are heavier,
materials will reach a level of maturity, where they can be induce local thermal cracking and are difficult to adhere to
used in-service. the parent laminate. The literature describing the use of Z-
Stitching. A technique which has been used to good pins is sparse; most of the work has been conducted on flat
effect is stitching in composite laminates [30 – 36]. The plates, although there has been some work to evaluate them
stitching material is usually Kevlarq or glass fibres since in stiffened elements [12,16] and fuselage structures [28].
these have the flexibility required for the high curvatures The following only covers using Z-pins in conventional
although, recently, stitching with partly pyrolised carbon- unidirectional tape materials. There is certainly scope for
fibres has also been developed [25]. The stitches are using them in woven laminates, but there has been only
introduced prior to curing by mechanically driving the fibres limited research in this area.
into the laminates. Stitching greatly improves both the Z-pins impart massive improvements in mode I and II
impact resistance and impact damage tolerance of laminates toughnesses; increase of an order of magnitude have been
manufactured from tape [32,37] with the through-thickness reported [28,39]. The loading mechanisms around the pins
reinforcement reducing delamination forces and defor- are complicated (Fig. 5); processes such as deformation,
mations at the damage boundaries. The detailed mechan- splitting and fracture of the pins, pin pullout and ploughing
isms by which the stitches improve interfacial strength are all add to the work of fracture required to extend a
complicated [38] but involve processes such as deformation delamination. The pins also delocalise the loading at the
and failure of the stitching fibres, ploughing through the crack tip, by transferring the forces into adjacent plies [12,
laminate, and delocalisation of the crack-tip forces. 28]. Z-pins have demonstrated improvements in impact
Consequently, the stitches inhibit delamination formation resistance and damage tolerance, principally by inhibiting
during the impact event and inhibit delamination growth delamination growth [28], although there is some evidence
during compressive loading. In structures, stitching can be that they do not increase the threat level at which damage
used to good effect to improve critical sites such as the starts to form [7]. These improvements in toughness have
interface between the stringer foot and skin. Generally, mainly been demonstrated on coupons, but limited work on
stitching does not require a change in the fabrication structural elements [12,16] has demonstrated that Z-pins can
process, just an additional step, so it should be able to greatly improve the stringer pull-off and debonding
transfer to current components fairly easily. Finally, an strength; Z-pins gave considerably greater improvements
important advantage is the ‘fail-safe’ aspect stitching in mechanical properties than was observed through using a
imparts; inhibiting, or even arresting the delamination tougher resin system. Also, unlike tougher resins, using Z-
growth. However, stitching can lead to a reduction in pins in structures does not increase the scatter in the results,
undamaged performance, particularly in-plane [38]; the which has clear benefits with regards qualification [12].
introduction of the stitches damages the load-bearing fibres, Although the Z-pins confer improved interlaminar
reducing tensile strength. Furthermore, the tension in properties, the effect on Z-pins on in plane properties is
158 E. Greenhalgh, M. Hiley / Composites: Part A 34 (2003) 151–161

Fig. 5. Electron micrograph of Z-pins on the fracture surface from a stiffened element [12].

far from clear. Work done on unidirectional coupons [40] Protective layers. A completely different approach to
has demonstrated reductions in the undamaged properties. improve impact tolerance has been used for protective
However, more recent studies conducted on quasi- layers on the surface of the laminates. This can take many
isotropic laminates have shown that the properties of forms such as compliant (high strain resistant) layers of
laminates can be both improved or degraded depending glass fibre, polyethylene [41,42] or Kevlar [20] plies.
on the loading condition and Z-pinning arrangement [28]. Alternatively, softened or toughened layers such as
In plain compression, tests have shown some reduction in adhesives or resin filled with toughening particles [43] can
strength whilst notched and impacted laminates have be used. A more recent development has been hollow glass
demonstrated an improvement, particularly when small fibres [6,28] that can be tailored to fracture at critical levels
diameter pins are used. Fractographic studies [28] of impact threat. The principle is to give an alternative route
showed there are two competing failure mechanisms; for energy absorption. Although significant improvements
fibre micro-buckling promoted by distortion of the have been observed, it is often difficult to isolate these from
reinforcing fibres during pin insertion (Fig. 5b), and geometric effects; the protective layers lead to thicker
improved delamination resistance. The size and distri- laminates, which consequently have a higher bending
bution of the pins appears to be critical in controlling stiffness. The protective layers do not directly affect the
which of these mechanisms dominates. Z-pinning signifi- other mechanical properties of the laminate, so redesign of
cantly reduces the tensile strength of plain laminates, due the laminates for requalification may not be required.
to fibre fracture caused by pin insertion [12], although Protective layers do not generally require a change in the
the effect is less pronounced in notched laminates, where processing route, just an extra step, so again this should not
delamination growth is involved in the failure process. greatly effect requalification. Although protective layers do
Current understanding of the relationship between Z-pin not reduce the absolute properties of the laminates, they are
distribution/diameter and mechanical properties is limited parasitic and will reduce the specific stiffness and strengths;
and models to predict their effect on the in-plane this may be critical in aerospace structures, where reducing
properties are still in their infancy. This could make weight is vital. In addition, if they are attached to the
certification of such Z-pinned structures more expensive laminate after manufacture, the interface may act as a
due to a reliance on ‘make and test’. preferential site for damage and consequently moisture
For skin-stringer panels, introducing Z-pins requires an ingress. Finally there is the question over the long-term use
extra step in the fabrication process and will need to be used of such layers; once damaged they no longer impart impact
selectively since the pin costs are very high. As with tolerance to the component.
stitching, if the Z-pins are used at the skin/stiffener
interface, secondary bonding is problematic and co-curing
is required leading to difficulties in controlling the stiffener 5. Discussion
shape [7]. There are also concerns as to the durability of Z-
pinned structures [28], and how to inspect and repair them. Impact is considered to be one of the critical threats for
Finally, an important aspect is the ‘fail-safe’ properties, PMCs in aerospace applications. The impact tolerance is
which the Z-pins impart. As with stitching, the pins inhibit, controlled by a number of material (such as impact
or even arrest delamination, which is very beneficial for conditions, material properties, lay-up and geometry) and
designing highly impact tolerant structures. structural (such as structural geometry, proximity to
E. Greenhalgh, M. Hiley / Composites: Part A 34 (2003) 151–161 159

the substructure and boundary conditions) parameters. can be expensive, time consuming and may not improve
When determining the criticality of an impact threat (impact impact resistance significantly. Finally, three-dimensional
resistance) or impact damage (impact damage tolerance), all fabrics will improve impact resistance but are relatively
these factors must be considered. For improving impact immature since the test methods to characterise these types
tolerance, increasing the delamination toughness of a of material are not well developed yet.
material is an important factor, but properties such as Impact damage tolerance. This is a property in which the
compressive stiffness and strength are also critical, particu- load-carrying capability of the structure is critical, so
larly in primary structures. Many of the concepts described mechanical properties such as stiffness and strength are of
in this paper demonstrated not only improvements in the paramount importance. In particular, the capacity to carry
delamination toughness, but also exhibited a degradation in compressive load, and tolerate high out-of-plane forces
the undamaged performance. This combination could have (induced through panel buckling) are important. As well as
an overall detrimental effect on the impact tolerance of a damage tolerance, the main requirement for an impact
composite structure. damage tolerant structure will be low weight and high
Improving the impact tolerance of a structure by undamaged mechanical performance, with cost and ease of
changing the material can be an expensive and time fabrication of secondary importance. Z-pinning and stitch-
consuming process; often requiring qualification of the ing show the most promise as an impact damage tolerant
new material [1]. An alternative cheaper approach is to keep concept for skin-stringer panels. If the pin size and
the material the same as the original component and to distribution are optimised, it can demonstrate the least
improve the impact tolerance purely through redesign; this reduction in undamaged compressive properties, and
should always be considered before changing material. exhibits considerable reductions in damage growth under
However, if the improvements imparted by these design load. The only disadvantages are the high cost and some
options are limited, changing the material should be fabrication issues. Woven fabrics and stitched laminates
pursued. A further aspect is that of the location on the exhibit too large a reduction in undamaged properties
component to use the concept. This is particularly pertinent although these can be recovered to a limited extent by using
to expensive concepts such as Z-pins, or those that incur a mixed-woven laminates. Selective interlayers and protec-
significant weight penalty, such as protective layers. For tive surface layers can impart significant damage tolerance,
some material concepts, such as 3D fabrics, it may be although they can have a high weight penalty. For future
difficult to use the material selectively, and the entire structures, 3D woven materials show a lot of promise for
component may need to be fabricated from the new impact damage tolerant design although the qualification of
material. The choice of the location of the new material such components may be expensive.
will be driven by a number of factors such as cost, weight To compare the concepts, it is important to consider how
penalty, manufacturing issues, property degradation, they will be used; either as a replacement in structures
inspection and repair. Finally, the use of different combi- already in-service, or for future structures.
nations of damage tolerant concepts should be considered, In-service structures. The high cost of inspection and
although may not always be beneficial to the structure [12]. repair has led to the current demand for structures to be
Also, introducing more than one material concept will incur impact resistant, particularly secondary components in civil
further costs and timescales for qualification, as well as aerospace structures [1]. Increasing impact resistance will
having implications for repair. allow an increase in the time between inspections and less
The two aspects of impact tolerance (impact resistance need for repair or replacement. One of the important factors,
and impact damage tolerance) are considered in turn. which limit using new materials, is the increased cost and
Impact resistance. This property does not require any timescales they incur for qualification. For impact resistant
load-carrying capability, so mechanical properties such as structures, which are not required to carry any significant
strength will be of relatively little importance. As well as load, this may not be such an important issue. However, for
impact resistance, the main requirements for an impact damage tolerance, the reduction in undamaged properties,
resistant structure will be low cost, low weight and ease of which many of the concepts exhibit, will make using them
fabrication. For impact threats in excess of the threshold problematic. This would suggest that the most efficient
threat for damage formation, the component will need to be method of improving impact tolerance might be to redesign
easy to inspect and repair. Based on these requirements, the the component rather than changing material. The best
best material concepts for impact resistance are planar impact tolerant option for replacing materials in current
woven and NCF materials. These are relatively cheap and structures is probably to use tougher resin systems or (non-
not time consuming to manufacture. Tougher matrix load carrying) protective surface layers, although the latter
systems will also impart some increase in impact resistance could incur significant weight penalties. By optimisation to
but these can be expensive. Concepts such as selective minimise reductions in undamaged properties, selective use
interlayers, hybrids and protective layers can improve of Z-pins would be a very attractive option although for
impact resistance, but may be expensive and will add primary structures the requalification and material costs
parasitic weight to the component. Stitching and Z-pinning associated with using this concept may be an issue. Woven
160 E. Greenhalgh, M. Hiley / Composites: Part A 34 (2003) 151–161

materials and stitching incur too high a reduction in 4. The cost and weight penalties that many of these material
undamaged properties and qualification costs to be attrac- concepts incur means that the siting of the impact
tive, whilst the test methods used to characterise 3D tolerant material on the component is critical. Some new
materials are not yet mature enough to enable these materials could be used in combination, although this
composites to be used in-service. could incur high costs and increased timescales due to
Future structures. For future structures there is scope for qualification requirements.
allowing for a reduction in undamaged properties in the 5. For impact resistant applications, the best material
design process. In addition, qualification costs will not be concepts are planar woven and NCF materials since
overly prohibitive since such this would need to be done they are relatively cheap and offer ease of fabrication. For
anyway. The main drivers for using new materials in future impact damage tolerance applications, Z-pinning offers
structures will be cost, weight, ease of fabrication, impact the most promise if configurations can be used which
tolerance and inspection/repairability. Recent work [30,31] minimise the reduction in undamaged performance.
showed that 3D architecture in combination with stitching is 6. For replacement of current in-service structures, the best
one of the most promising concepts. Similarly, Z-pinning in impact tolerant options are using improved toughness
combination with mixed-woven laminates could be used to resins, Z-pinning or protective layers at critical sites. The
produce efficient and highly impact tolerant structures. In other options would introduce too high a cost due to the
comparison, the long-term gains of tougher resin systems, redesign of the component, which would be required.
are limited [12,21,44]. Concepts such as protective layers 7. For future structures, materials such as 3D, NCF and 2D
and interlayers could be used on highly critical sites, but may woven in combination with stitching or Z-pins are
not be cost or weight effective enough for widespread use. attractive options, although these areas are currently not
mature enough to be used.

6. Conclusions

A range of new materials and processes have been Acknowledgements


considered to improve the impact tolerance of stringer-
stiffened composite structures. The factors, which contrib- The authors would like to acknowledge the support of the
ute to impact performance, have been discussed and the DTI Aeronautics Research Programme (CARAD). The
critical material parameters that contribute to impact authors would also like to acknowledge the help and advice
tolerance of skin-stringer structures identified. New of Andy Foreman and Andrew Clarke from QinetiQ.
materials and processes, which could be used for improving
composite toughness, have been described and their
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