Professional Documents
Culture Documents
COURSE OUTLINE
OUTLINE : CRI 311 FORENSIC CHEMISTRY
Credits: 3 Units
Assessment Task Submission Submission of assessment tasks shall be on 3 rd, 5th, 7th, and 9th week
of the term. Indicate the name of the Course Facilitator, date of
submission, and name of the student. The document should be emailed
to the Course Facilitator. It is also expected that you already paid your
tuition and other fees before the submission of the assessment task. If
the assessment task is done in real-time through the features in the
Blackboard Learning Management System, the schedule shall be
arranged ahead of time by the Course Facilitator Since this course is
included in the criminology licensure examination for criminologists,
you will be required to take the Multiple-Choice Question exam during
the oncampus/onsite sessions. This should be scheduled ahead of time
by the Course Facilitator.
Please note that academic dishonesty such as cheating and
commissioning other students or people to complete the task for
you have severe punishments (reprimand, warning, expulsion).
Penalties for Late Assignments/ The score for assignments submitted after the designated time on the
Assessments due date, without an approved extension of time, will be reduced
by 5% of the possible maximum score each day or part day. However,
if the late submission of assignment has a valid reason, a letter of
explanation should be submitted and approved by the Course
Facilitator. If necessary, you will also be required to present/attach
evidence.
Return of Assignments/ Assessments Assessment tasks will be returned to you two (2) weeks after the
submission. This will be returned by email or via Blackboard portal.
Assignment Re-submission You should request in writing addressed to the Course Facilitator
his/her intention to resubmit an assessment task. The re-submission is
premised on the student’s failure to comply with the similarity index
and other reasonable grounds such as academic literacy standards or
other reasonable circumstances e.g. illness, accidents financial
constraints. Please note if ever re-submission of assignment is
granted the grade shall not be higher to the lowest grade given to
complied students.
Grading System All culled from BlackBoard sessions and traditional contact
Course discussions/exercises – 30%
1st formative assessment – 10%
2nd formative assessment – 10%
3rd formative assessment – 10%
All culled from on-campus/onsite sessions (TBA):
Final exam – 40%
Submission of the final grades shall follow the usual University system
and procedures.
Student Communication Students are required to create a umindanao email account which is a
requirement to access the BlackBoard portal. Then, the Course
Facilitator shall enroll the students to have access to the materials and
resources of the course. All communication formats: chat, submission
of assessment tasks, requests etc. shall be through the portal and other
university recognized platforms.
You can also contact your teacher/Course Facilitator via traditional
contact or social media for communication. For related concerns, the
students can contact the Dean, Program Head, Library, and Guidance
Help Desks. For students who have not created their umindanao
account and LMS account, please contact the Course Facilitator or
Program Head for further instructions.
Students with Special Needs Students with special needs shall communicate with the Course
Facilitator about the nature of his or her special needs. Depending on
the nature of the need, the Course Facilitator, with the approval of the
Program Head, may provide alternative assessment tasks or extension
of the deadline of submission of assessment tasks. However, the
alternative assessment tasks should still be in the service of achieving
the desired course learning outcomes.
Online Tutorial Registration You are required to undergo a tutorial on this course. Upon enrolment
(if available and necessary) and the registration of your name to Blackboard LMS, the Course
Coordinator will contact you on the a specific tutorial time for this
course by registering to ccje@umindanao.edu.ph. You will be
informed by the Course Coordinator on the exact schedule of the
tutorial. Please note that there is a deadline for enrollment.
Instructional Help Desk Dean Dr. Carmelita B. Chavez
Email: carmelita_chavez@umindanao.edu.ph
Contact Details ccje@umindanao.edu.ph
Asst. Dean Dr. Nestor C. Nabe
Email: nestor_nabe@umindanao.edu.ph
Program Head Dr. Roberto R. Magbojos
Email: Roberto_magbojos@umindanao.edu.ph
Phone (082)300-5456
Email: library@umindanao.edu.ph
CO: Before we go on becoming a criminologist, we have to be fully equipped to be able to do our job
with competence, hence in this course, we are going to explain the ways that crime impacts victims and
the various methods developed to assist victims in dealing with the effects of crime and with the
criminal justice agencies.
Let’s Begin!
Big Picture
Unit Learning Outcomes (ULO): At the end of the unit, you are expected to
Big Picture in Focus: ULOa Explain how forensic examination help the
possible solution of the crime
Metalanguage
The most essential terms relevant to the study of this course and to demonstrate ULOa
are operationally defined to establish a common frame of reference as to how the texts work in
the course. You will encounter these terms as we go through the study of course. Hence, to be
able to fully appreciate the topics presented in this course, unlocking the meaning of these terms
is crucial
Forensic Chemistry - Is define as that branch of Chemistry which deals with application of
chemical principles in the solution of crimes.
Forensic Medical Examination - is a careful and diligent examination looking for injuries and
taking samples that may be used as evidence in a police investigation and any subsequent
prosecution
Forensic investigation - is the gathering and analysis of all crime-related physical evidence in
order to come to a conclusion about a suspect.
Forensic science - is the application of science to criminal and civil laws, mainly on the criminal
side during criminal investigation, as governed by the legal standards of admissible evidence and
criminal procedure
Essential Knowledge
To perform the aforesaid big picture (unit learning outcomes) for the first three (3) weeks
of the course, you need to fully understand the following essential knowledge that will be laid
down in the succeeding pages. The topics presented in this section is taken from the approved
textbook of the course. Please note that you are not limited to exclusively refer to the
resources. Thus, you are expected to utilize other books, research articles and other
resources that are available in the university’s library e.g. e-library, search.proquest.com, etc.
Until 1840, poisoning was often thought to be a way to “get away with murder”, and it
worked because there were no visible signs of foul play. In that year, a French woman named
Marie Lafarge became the first person to be convicted of murder by poisoning thanks to new
methods for arsenic testing, and the field of forensic toxicology was born.
Poisons were employed by early Egyptians and ancient Greeks and Romans. Democritus
was probably the first chemist to study poisons, and he communicated some of his findings
to Hippocrates .
Poisons were used both for murder and as a means of execution; the philosopher Socrates was
condemned to death by drinking hemlock . Ancient Roman civilization had laws against poisoning
in 82 B.C.E. Before the development of systematic, scientific criminal investigation, guilt was
determined largely by circumstantial evidence and hearsay.
Arsenic was a popular poison in Roman times. It was referred to as inheritance powder in early
France. The Blandy trial of 1752 was the first instance of an actual chemical test for poison, and
the Marsh test, developed in 1836, was the first reliable analysis that could show scientifically
that arsenic was present in the body of a victim
August Vollmer, chief of the Los Angeles Police, established the first American police
crime laboratory in 1924. When the Federal Bureau of Investigation (FBI) was first founded in
1908, it didn't have its own forensic crime laboratory that wasn't set up until 1932.
The word forensic has its origin from the Latin word “forensis” which stands for a
forum.Forensic Science is basically used in tandem with any discipline that has associations with
the legal system. In a nutshell, forensic science is the application of scientific methods and
principles to questions of law.In layman’s terms, forensic science is a discipline used by a forensic
investigator to solve crimes.
History of Autopsy (Familiar with the word “mummification)
Egyptian civilization back in 3000 BC performed the first instance of an ‘autopsy They
performed the religious practice of the removal and examination of the internal organs of
humans after their death. Thus, they are the earliest civilization to perform an autopsy.
Interestingly, the first officially recorded autopsy was performed way back in 44 BC This
was when a Roman physician, Antistius, examined the slain body of Roman politician and general,
Julius Ceaser. The autopsy revealed that though stabbed 23 times, his death actually resulted
from one wound through this chest
Role of Forensic Chemist in the Scientific Investigation
A forensic Chemist, As a man of science, performs laboratory examination on physical evidence
submitted to the crime laboratory in order to expedite the investigation of a crime by the
investigating party. He or She has the following responsibilities:
❖ Go slowly
❖ Be through
❖ Take Notes
❖ Consult others
❖ Use imagination
❖ Avoid complicated theories
Go slowly
Good work cannot be hurried, therefore, take all the time necessary to make the case
complete, no matter how urgent it may appear.
Be through
Make careful and minute examination of everything and do not be satisfied with a
quantitative analysis if a quantitative one is possible. It always [pays to do too much rather than
too little and it is difficult to foresee what will or will not be required in court.
Take Notes
Keep a full neat and clean record of everything seen and done
Consult others
Many cases will lead the expert into paths with which he is not familiar and when this
happens he should consult those who know better
Use imagination
An expert with a wide and uncontrollable imagination is considered as the most
dangerous creature. Though his being imaginative is sometimes useful, an expert witness does
not have to be solely imaginative, but he has to be skilled in the field of forensic Science. He
must bear witness within the limits of science.
In responding the crime incident are one of the essential events since collection and
preservation of any traces of evidence that may be possibly found at the scene of the crime is a
great important in any forensic crime investigation most specifically evidence which is considered
as fragile such as biological fluids, semen, saliva blood, firearms, and slugs that may possibly lost
or contaminated if may not be protected as early by the forensic investigator. Forensically sound
preservation of evidence can also easily be overlooked by an incident responder due to the rapid
and changing nature of the incident being investigated, which can potentially have a huge impact
on the effective of conducting forensic analysis and may lost potential legal position.
As mention by comprehensive laws on drug of the country ( R.A. 9165 ), after the anti-
illegal drug operation made by the law enforcement agency all confiscated suspected drugs must
be immediately inventoried and transported to the nearest crime laboratory for forensic analysis
and examination, and the assigned forensic examiner is mandated to submit a his/her partial and
unofficial quantity and quality of substance of drug within twenty-four (24) hours.
Method of examination
There are two main types of tests used to determine whether an illegal drug is present in
a substance: presumptive tests and confirmatory tests. Presumptive tests are less precise and
indicate that an illegal substance may be present. Confirmatory tests provide a positive
identification of the substance in question.
Presumptive testing may be conducted in the field by law enforcement officers or in the
laboratory once the seized material is accepted. Confirmatory tests involve a battery of
instrumental tests using techniques such as Gas Chromatograph-Mass Spectrometry (GC-MS) or
infrared spectroscopy that separate individual compounds in the substance and positively
identify the chemical signature of the illegal substance(s) within the material.
Presumptive testing - is usually colorimetric, meaning the test will indicate that the suspected
substance is present or not present by changing color. If the substance is present, the test kit will
turn one color, if not, it turns a different color. Presumptive testing by law enforcement is
typically followed up with laboratory tests that confirm with certainty the presence of the
suspected substance. Presumptive testing is also performed in the laboratory as part of the
analysis process.
Confirmatory testing - uses instrumental analysis to positively identify the contents of submitted
material. This typically requires a multi-step process to separate the individual compounds,
determine the chemical characteristics of the compounds, and compare them against reference
materials to make a positive identification. This is called qualitative analysis, and determines
what substances are present and if one of more of those substances is illegal.
The analyst may have an idea, based on information from presumptive tests or the
submitting agency, of what type of drug is contained in the sample. This information, as well as
the laboratory policies in place, will determine what tests the analyst will use. A typical battery
of tests will include separation techniques to separate the various compounds and spectroscopy
instruments to identify the chemical characteristics. Confirmatory tests, depending on the lab
requirements, may also include quantitative analysis of the sample to determine the amount, or
purity, of the illegal substance.
Color Tests for Dangerous Drugs Usage of Hand - made Simon reagent Kit
Note: You must examine not only Simon reagent but also
marquis reagent..
Gunshot Residues
Black Powder
Potassium Nitrate- 75%
Charcoal- 15%
Sulfur - 10%
Smokeless Powder
Nitrocellulose - 60%
Charcoal - 35%
Vaseline- 5%
Detection of Gunshot Residue
The following are common methods used by most crime laboratories to detect gunshot residue:
Paraffin test
Lead residue ( detection limit: up to 30 feet and always present on the opposite sides of the
penetrated target). (Messler and Armstrong, 1978). Gunpowder residue examination (detection
limit: highly variable up to 20cm, and up to 21 inches is common)
Other examinations
History of paraffin test/dermal nitrate or Diphenylamine test
Paraffin test was originated from Cuba when DR. Gonzalo Iturrios first used paraffin for
collecting gunpowder residues from discharged firearms. In 1933, Teodoro Gonzales of Criminal
Identification laboratory, Mexico City introduced the test in the United States.
In this test, the hands were coated with a layer of melted paraffin. After cooling, the casts
were removed and treated with Diphenylamine (5% DPA in 60% sulfuric).
Paraffin wax
Paraffin wax is a white, translucent, tasteless, odorless solid consisting of a mixture of
solid hydrocarbons of high molecular weight. It is insoluble in water and acids and soluble in
benzene, ligroin, warm alcohol, chloroform, turpentine, carbon disulfide, and olive oil.
Combustible, auto ignition temperature 473 F (245 degree C). The melted paraffin wax
penetrates the minute crevices of the skin upon application, thus, adhering if there are particles
present. When the casts are peeled, the burned and partially burned particles are extracted. A
person firing a gun will likely have the particles located above the thumb and forefingers since
these are the surfaces exposed to the gun.
False Positive Reaction
Smear of blue color or a conglomeration of blue specks on both dorsal and palm aspects
of the hand.
Gunshot Range (GSR) Determination
When a firearm is discharged, gunpowder residue may also be deposited on the clothing
of the victim. The size and density of the pattern of gunpowder residue found on the clothing are
the main factors considered in determining the approximate distance of the shooter to the
victim. As the distance to the victim increases, the size of pattern expands while density
decreases and vice-versa.
Distance Determination
The method of determining the distance between the firearm and the target. This is
usually based on the distance of the powder patterns or the spread of the shot pattern.
The investigator needs to establish the Importance of distance determination of the residue
impregnated to the victim in order to established the connection to self-defense pleas, In the
distinction murder and suicide. In ascertaining the gunshot range (GSR) the examiner should
note and observe the following:
Entrance and exit holes
Powder residue pattern (Burning, Scorching, Smudging, Tattooing – a black coarsely
eppered/scattered pattern)
Burning