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Designation: C242 − 15

Standard Terminology of
Ceramic Whitewares and Related Products1
This standard is issued under the fixed designation C242; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. A
superscript epsilon (´) indicates an editorial change since the last revision or reapproval.

1. Scope absorbance—the logarithm of that fraction of an incident light


1.1 This terminology pertains to the terminology used in beam that is dissipated in the sample, being neither trans-
ceramic whitewares and related products. mitted nor reflected.

1.2 Words adequately defined in standard dictionaries are absorbed moisture—water held mechanically in the material
not included. Included are words that are peculiar to this and having physical properties not substantially different
industry. Double words, hyphenated words, or phrases are from ordinary water at the same temperature and pressure.
listed alphabetically under the first word; additional important absorption—(1) the relationship of the weight of the water
words are cross-referenced. absorbed by a ceramic specimen, subjected to prescribed
1.3 For definitions of terms relating to surface imperfec- immersion procedure, to the weight of the dry specimen.
tions on ceramics, refer to Terminology F109. (2) the capacity of a substance to take up a substance,
usually a liquid or gas, with the formation of an apparently
2. Referenced Documents homogeneous mixture.
2.1 ASTM Standards:2 adsorption—the capacity of a substance to accept and retain
D1129 Terminology Relating to Water on its surface a layer of another substance, usually a gas or
E180 Practice for Determining the Precision of ASTM a liquid.
Methods for Analysis and Testing of Industrial and Spe- agglomerate—a jumbled mass or collection of two or more
cialty Chemicals (Withdrawn 2009)3 particles or aggregates, or a combination thereof, held
F109 Terminology Relating to Surface Imperfections on together by relatively weak cohesive forces caused by weak
Ceramics chemical bonding or an electrostatic surface charge gener-
F465 Practice for Developing Precision and Accuracy Data ated by handling or processing.
on ASTM Method for the Analysis of Meat and Meat DISCUSSION—Common usage in powder technology (and British
Products (Withdrawn 1993)3 Standard BS 2955) has the terms “aggregate” and “agglomerate”
2.2 British Standard:4 interchanged in meaning from the definitions presented here, and care
must be taken to determine in context which definition is in use.
BS 2955 Glossary of Terms Relating to Powders
aggregate—a dense mass of particles held together by strong
3. Terminology intermolecular or atomic cohesive forces that is stable to
normal mixing techniques, including high-speed stirring and
absolute or true density—See absolute or true density under
ultrasonics.
density.
alumina porcelain—See alumina porcelain under porcelain.
alumina whiteware—See alumina whiteware under ceramic
1
This terminology is under the jurisdiction of ASTM Committee C21 on whiteware.
Ceramic Whitewares and Related Productsand is the direct responsibility of andalusite—a polymorph, along with sillimanite and kyanite,
Subcommittee C21.01 on Editorial and Terminology. of composition Al2O3·SiO2 which on firing dissociates to
Current edition approved March 1, 2015. Published March 2015. Originally
approved in 1950. Last previous edition approved in 2014 as C242 – 14. DOI:
yield principally mullite.
10.1520/C0242-15.
2
For referenced ASTM standards, visit the ASTM website, www.astm.org, or
apparent or pycnometric density—See apparent or pycnomet-
contact ASTM Customer Service at service@astm.org. For Annual Book of ASTM ric density under density.
Standards volume information, refer to the standard’s Document Summary page on apparent porosity—See apparent porosity under porosity.
the ASTM website. average particle size—a single value representing the entire
3
The last approved version of this historical standard is referenced on
www.astm.org. particle-size distribution.
4
Available from British Standards Institute, 2 Park St., London, England DISCUSSION—It is essential to specify the basis under which the
W1A 2B5. average is obtained.

Copyright © ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959. United States

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ball clay—a secondary clay, commonly characterized by the calcine—a ceramic material or mixture fired to less than fusion
presence of organic matter, high plasticity, high dry strength, for use as a constituent in a ceramic composition.
long vitrification range, and a light color when fired.
capillary action—the phenomenon of intrusion of a liquid into
ball milling—a method of grinding and mixing material, with interconnected small voids, pores, and channels in a solid,
or without liquid, in a rotating cylinder or conical mill resulting from surface tension.
partially filled with grinding media such as balls or pebbles.
cassiterite (SnO2)—an inorganic mineral of the tetragonal
basalt ware—a black unglazed vitreous ceramic ware having form used as a source of tin and tin oxide.
the appearance of basalt rock.
casting—a process for forming ceramic ware by introducing a
Belleek china—a highly translucent whiteware composed of a body slip into a porous mold which absorbs sufficient water
body containing a significant amount of frit and normally (or other liquid) from the slip to produce a semirigid article.
having a luster glaze. drain casting (hollow casting)—forming ceramic ware by
bentonite—a distinct type of fine-grained clay containing not introducing a body slip into an open porous mold, and then
less than 85 % montmorillionite clay having the formula draining off the remaining slip when the case has reached the
(OH)4Si8Al4O20nH2O and composed of units made up of desired thickness.
two silica tetrahedral sheets with a central alumina octahe- solid casting—forming ceramic ware by introducing a body
dral sheet. slip into a porous mold which usually consists of two major
sections, one section forming the contour of the outside and the
beryllium oxide (beryllia) (BeO)—an inorganic material of other forming the contour of the inside of the ware and
exceptionally high thermal conductivity which is toxic in the allowing a solid cast to form between the two mold faces.
powder form.
ceramic article—an article having a glazed or unglazed body
bias—a constant or systematic error, as opposed to a random of crystalline or partly crystalline structure, or of glass,
error, manifesting itself as a persistent positive or negative which body is produced from essentially inorganic, nonme-
deviation of the method average from the accepted reference tallic substances and either is formed from a molten mass
value. E180; F465 which solidifies on cooling, or is formed and simultaneously
binder—a cementing medium; either a material added to the or subsequently matured by the action of the heat.
mixture to increase the green or dry strength as compacted, ceramic mosaic tile—an unglazed tile formed by either the
and which may be expelled during sintering or calcining, or dust-pressed or plastic method, usually 1⁄4 to 3⁄8 in. (6.4 to 9.5
a material added to a mixture for the purpose of cementing mm) thick, and having a facial area of less than 6 in.2 (39
together particles. cm2) and which is usually mounted on sheets approximately
DISCUSSION—A binder may be either a permanent addition, or a 1 by 2 ft (0.3 by 0.6 m) to facilitate setting.
temporary additive to a ceramic product. DISCUSSION—Ceramic mosaic tile may be of either porcelain or
natural clay composition and may be either plain or with an abrasive
bisque fire—See bisque fire under firing.
mixture throughout.
blackbody—the ideal, perfect emitter and absorber of thermal
radiation which emits radiant energy at the maximum rate ceramic paste—a French term synonymous with “ceramic
possible, as a consequence of its temperature, and absorbs all body.”
incident radiation.
ceramic process—the production of articles or coatings from
blistering—the development during firing of enclosed or essentially inorganic, nonmetallic materials, the article or
broken macroscopic vesicles or bubbles in a body, or in a coating being made permanent and suitable for utilitarian
glaze or other coating. and decorative purposes by the action of heat at temperatures
sufficient to cause sintering, solid-state reactions, bonding,
bloating—substantial swelling produced by a heat treatment or conversion partially or wholly to the glassy state.
that causes the formation of a vesicular structure.
ceramics—a general term applied to the art or technique of
blunging—the wet process of blending, or suspending ceramic producing articles by a ceramic process, or to the articles so
material in liquid by agitation. produced.
body—the structural portion of a ceramic article, or the ceramic whiteware—a fired ware consisting of a glazed or
material or mixture from which it is made. unglazed ceramic body which is commonly white and of fine
bone ash—calcined bone consisting essentially of calcium texture, designating such product classifications as tile,
phosphate. china, porcelain, semivitreous ware and earthenware.
alumina whiteware—any ceramic whiteware in which alu-
bone china—a translucent china made from a ceramic white- mina (Al2O3) is an essential crystalline phase.
ware body composition containing a minimum of 25 % bone
ash. cordierite whiteware—any ceramic whiteware in which
cordierite (2MgO·2Al2O3·5SiO2) is the essential crystalline
bright glaze—See bright glaze under glaze. phase.

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forsterite whiteware—any ceramic whiteware in which for- comminution—the act or process of reduction of particle size
sterite (2MgO·SiO2) is the essential crystalline phase. with attendant increase in surface area and population of
steatite whiteware—any ceramic whiteware in which mag- particles, usually but not necessarily by grinding, milling, or
nesium metasilicate (MgO·SiO2) is the essential crystalline pulverizing.
phase. conductive ceramic tile—tile made from special body com-
titania whiteware—any ceramic whiteware in which titania positions or by methods that result in specific properties of
(TiO2) is the essential crystalline phase. electrical conductivity while retaining other normal physical
zircon whiteware—any ceramic whiteware in which zircon properties of ceramic tile.
(ZrO2·SiO2) is the essential crystalline phase. connected porosity—See connected porosity under porosity.
chemical porcelain—See chemical porcelain under porcelain. cordierite porcelain—See cordierite porcelain under porce-
china—a glazed or unglazed vitreous ceramic whiteware made lain.
by the china process and used for nontechnical purposes, cordierite whiteware—See cordierite whiteware under ce-
designating such products as dinnerware, sanitary ware, and ramic whiteware.
artware when they are vitreous. (See also bone china.) corundum—a naturally occurring hexagonal mineral of the
composition Al2O3, which can also be prepared synthetically
china clay—See kaolin. to high purity; noted for its hardness (9 on Mohs scale) and
china process—the method of producing glazed ware by refractoriness (M.P. = 2045°C).
which the ceramic body is fired to maturity, following which DISCUSSION—It forms the gem varieties ruby and sapphire with
the glaze is applied and matured by firing at a lower appropriate impurities. It may contain associated minerals such as
temperature. diaspore or various silicates, or both. Commonly coarsely crystalline,
sometimes microcrystalline.
china sanitary ware (sanitary plumbing fixtures)—glazed,
vitrified whiteware fixtures having a sanitary service func- covering power—the ability of a glaze to cover the surface of
tion. the fired ware uniformly and completely.

clay—a natural mineral agglomerate, consisting essentially of crawling—a parting and contraction of the glaze on the surface
hydrous aluminum silicates; plastic when sufficiently wetted, of ceramic ware during drying or firing, resulting in un-
rigid when dried en masse, and vitrified when fired to a glazed areas bordered by coalesced glaze.
sufficiently high temperature. crazing—the cracking that occurs in fired glazes or other
clear glaze—See clear glaze under glaze. ceramic coatings as a result of tensile stresses. May also
closed porosity—See closed porosity under porosity. occur in the surface portion of uncoated (unglazed) white-
coefficient of friction—the ratio of the parallel component of ware bodies.
force required to overcome or have a tendancy to overcome crystalline glaze—See crystalline glaze under glaze.
the resistance to relative motion of two surfaces in physical deagglomeration—the process of breaking down, usually by
contact one with another, but otherwise unconstrained, to the physical means, the masses of particles that are held together
normal component of the force—usually the force as a result by relatively weak cohesive forces resulting in a final system
of gravity—applied through the object which tends to cause of aggregates or primary particles, or both.
the friction.
deairing—the process of removing entrapped air, or absorbed
color difference—(1) the magnitude and character of the air from a mass or slurry, usually by application of a vacuum.
difference between two colors, described by such terms as
redder, bluer, lighter, darker, grayer, or cleaner. (2) the decorated—adorned, embellished, or made more attractive by
magnitude and direction of the difference between a sample means of color or surface detail.
and a standard, computed from tristimulus values, or chro- decorating fire—See decorating fire under firing.
maticity coordinates and luminance factor, by means of a decoration:
specified set of color difference equations. inglaze decoration—a ceramic decoration applied on the
color space—a three dimensional arrangement for represent- surface of an unfired glaze and matured with the glaze.
ing all possible colors; for example, in the color space overglaze decoration—a ceramic or metallic decoration
defined by the color scales L, a, and b used to describe the applied and fired on the previously glazed surface of ceramic
color of opaque specimens, scale L is a measure of lightness, ware.
a is a measure of redness (plus) or greenness (minus), and b polychrome decoration—a multicolor decoration.
is a measure of yellowness (plus) or blueness (minus).
underglaze decoration—a ceramic decoration applied di-
color standard—a plaque or other physical standard of estab- rectly on the surface of ceramic ware and subsequently covered
lished color value, against which standardization of an with a transparent glaze.
instrument is made.
DISCUSSION—It may be a reference standard at a calibration deflocculate—to separate agglomerates in a slurry by chemical
laboratory, a transfer standard used to calibrate a particular instrument, and physical means to achieve and maintain particle-to-
or a working standard for routine use. particle separation.

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DISCUSSION—A surface-active wetting agent (cationic, anionic, or dry mix—See dry process under process.
nonionic type) to coat the particle surface with like ionic charges to dry pressing—See dry pressing under pressing.
induce repulsion of the surfaces is usually effective.
dry process—See dry process under process.
deformation eutectic—See eutectic, deformation. dunting—the cracking that occurs in fired ceramic bodies as a
delft ware—a calcareous earthenware having an opaque white result of thermally induced stresses.
glaze and monochrome overglaze decorations. (Originated
in Delft, Holland.) dynamic coefficient of friction—the ratio of the parallel
component of force applied to a moving body that maintains
density: constant relative motion of two surfaces in physical contact
absolute or true density—the weight divided by the volume one with another, but otherwise unconstrained, to the normal
excluding open and closed pores. component of the force—usually the force caused by
apparent or pycnometric density—the weight divided by the gravity—applied to the body under clean, dry conditions.
volume excluding open pores, but including closed pores.
earthenware—a glazed or unglazed nonvitreous ceramic
tap density—the apparent density of a powdered or granu- whiteware.
lated material resulting when the receptacle containing the
material is vibrated or tapped under standard or specified eggshelling—the texture of a fired glaze similar in appearance
conditions. to the surface of an eggshell.
diameter: electrical porcelain—vitrified whiteware having an electrical
arithmetic mean diameter—that diameter located at the insulating function.
centroid of the distribution of size.
embossed—decorated in relief on the surface of the ware.
equivalent diameter (sphere)—the diameter of a theoretical
sphere of a material which under identical physical conditions embossment—a decoration in relief or excised on the ware
yields the same value of the particular fineness characteristic as surface.
the actual irregularly shaped dispersed particle of the same
material. emissivity—the ratio of the radiation given off by the surface
of a body to the radiation given off by a perfect black body
median diameter—that diameter at which the area under the at the same temperature.
curve of size versus frequency is divided into two equal parts.
engobe—a slip coating applied to a ceramic body for imparting
diatomaceous earth—See diatomite.
color, opacity, or other characteristics, and subsequently
diatomite (diatomaceous earth)—amorphous lightweight si- covered with a glaze.
liceous material having the theoretical formula SiO2·nH2O,
occurring naturally as the fossil remains of tiny plants equilibrium eutectic—See eutectic, equilibrium.
termed diatoms; also known as kiesel-guhr, tripolite, and equivalent diameter (sphere)—See equivalent diameter
infusorial earth. (sphere) under diameter.
dinnerware—ceramic whiteware made in a given pattern and equivalent spherical diameter—See equivalent diameter
in a full line of articles comprising a dinner service. (sphere) under diameter.
eutectic:
dispersion—in a fine particle suspension, the condition which
deformation eutectic—the composition within a system of
results when a stable suspension of particles is achieved by
two or more components that, on heating under specified
physical or chemical means in which no evidence of
conditions, develops sufficient liquid to cause deformation at
reflocculation or reagglomeration of the particles is ob-
the minimum temperature.
served.
equilibrium eutectic—the composition within any system of
dolomite—the double carbonate of lime and magnesia having two or more crystalline phases that melts completely at the
the general formula CaCO3·MgCO3. minimum temperature, or the temperature at which such a
drag—the resistance to shrinkage of the foot or base of a composition melts.
ceramic article during drying or firing as a result of friction faience mosaics—faience tile that are less than 6 in.2 (39 cm2)
with the setter, slab, or sagger on which it rests. in facial area, usually 5⁄16 to 3⁄8 in. (8 to 9.5 mm) thick, and
drain casting—See drain casting under casting. usually mounted to facilitate installation.
draining—in ceramic manufacture, the process of removing
faience tile—glazed or unglazed tile, generally made by the
excess slip from dipped or cast items by gravity flow.
plastic process, showing characteristic variations in the face,
dry edging—rough edges and corners of glazed ceramic ware edges, and glaze that give a handicrafted, nonmechanical,
caused by insufficient glaze coating. decorative effect.
drying—removal by evaporation, of uncombined water or faience ware—formerly a decorated earthenware with an
other volatile substance from a ceramic raw material or opaque glaze, but currently designating a decorated earthen-
product, usually expedited by low-temperature heating. ware having a transparent glaze.

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feldspar—a mineral aggregate consisting chiefly of DISCUSSION—There are a few materials in which chemically bound
microcline, albite, or anorthite or combination thereof. water volatilizes below 105°C.

fineness—a measurement number designating the particle size friction—the resistance developed between the physical
of a material, usually reported as percent passing a screen of contacting, but otherwise unconstrained, surfaces of two
a particular standard size. bodies when there is movement or tendancy for movement
of one body relative to the other parallel to the plane of
fines—the portions of a powder composed of particles smaller contact. (See also coefficient of friction, dynamic coeffi-
than a specified size. cient of friction, in service coefficient of friction, and
static coefficient of friction.)
fire—See bisque fire; decorating fire; glost fire; single fire
under firing. frit—a product made by quenching and breaking up a glass of
firing—the controlled heat treatment of ceramic ware in a kiln a specific composition, used customarily used as a compo-
or furnace, during the process of manufacture, to develop the nent of a glaze, body, or porcelain enamel.
desired properties.
fritted glaze—See fritted glaze under glaze.
bisque fire—the process of kiln-firing ceramic ware before fusion—the process of melting; usually the result of interaction
glazing. of two or more materials.
decorating fire—the process of firing ceramic or metallic glaze—a ceramic coating matured to the glassy state on a
decorations on the surface of glazed ceramic ware. formed ceramic article, or the material or mixture from
firing curve—a diagram or table showing the time and which the coating is made.
temperature planned or experienced by ware going through a bright glaze—a colorless or colored ceramic glaze having
firing operation. high gloss.
firing cycle—the time required for one complete firing clear glaze—a colorless or colored transparent ceramic
operation (cold-to-cold). glaze.
firing range—the range of firing temperature within which a crystalline glaze—a glaze containing macroscopic crystals.
ceramic composition develops properties which render it fritted glaze—a glaze in which a part or all of the fluxing
commercially useful. constituents are prefused.
glost fire—the process of kiln-firing bisque ware to which leadless glaze—a ceramic coating matured to a glassy state
glaze has been applied. on a formed article, or the material or the mixture from which
single fire—the process of maturing an unfired ceramic body the coating is made, to which no lead has been deliberately
and its glaze in one firing operation. added.
DISCUSSION—This does not imply that the glaze is nontoxic or that it
flocculate—a grouping of primary particles, aggregates, or contains no lead. Because of plant practices and conditions, a small
agglomerates having weaker bonding than either the aggre- percentage of lead, 0.1 to 0.2 % (by dry weight), expressed as lead
gate or agglomerate structures. monoxide, may be present.
DISCUSSION—Flocculates are usually formed in a gas or liquid mat glaze—a colorless or colored ceramic glaze having low
suspension, and those formed in a liquid can generally be broken up by gloss.
gentle shaking or stirring.
opaque glaze—a nontransparent colored or colorless glaze.
fluorite (CaF2) (fluorspar)— an inorganic mineral of the raw glaze—a glaze compounded primarily from raw
isometric form, used as a source of fluorine for fluxing of constituents, that is, containing no prefused materials.
glasses, and glazes.
semi-mat glaze—a colorless or colored glaze having moder-
flux—a substance that promotes fusion in a given ceramic ate gloss.
mixture. slip glaze—a glaze consisting primarily of a readily fusible
forming—the shaping or molding of ceramic ware. clay or silt.
vellum glaze—a semi-mat glaze having a satin-like appear-
forsterite (2MgO·SiO2)—a magnesium silicate mineral, usu- ance.
ally produced synthetically as a ceramic raw material; may
be a reaction-produced phase in fired ceramics. glazed ceramic mosaic tile—ceramic mosaic tile with glazed
faces.
forsterite porcelain—See fosterite porcelain under porcelain.
forsterite whiteware—See fosterite whiteware under ceramic glazed tile—tile with a fused impervious facial finish com-
whiteware. posed of ceramic materials, fused with the body of the tile
free moisture—that water, which is not chemically bound, and which may be a nonvitreous, semivitreous, vitreous, or
that is loosely bound to a material, but which can be impervious body resulting in a surface that may be clear,
removed by drying at 105°C, for a time to achieve constant white, or colored.
weight, expressed as a percent of the initial weight of the glazed interior tile—a glazed tile with a body that is suitable
material. for interior use and which is usually nonvitreous, and is not

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required or expected to withstand excessive impact or be jasper ware—a vitreous, opaque, colored, unglazed ceramic
subject to freezing and thawing conditions. ware having white or contrasting relief decorations and
glazed tile, extra duty glaze—tile with a durable glaze that is containing a substantial amount of barite.
suitable for light-duty floors and all other surfaces on interiors jiggering—forming ceramic ware from a plastic body by
where there is no excessive abrasion or impact. differential rotation of a profile tool and mold, the mold
glaze fit—the stress relationship between the glaze and body of having the contour of one surface of the ware and the profile
a fired ceramic product. tool that of the other surface.
kaolin (china clay)—a refractory clay consisting essentially of
glost fire—See glost fire under firing.
minerals of the kaolin group and which fires to a white or
glossy, or bright glaze—a glaze which exhibits essentially full nearly white color.
specular reflection.
knockings—the oversize residue obtained in screening a
grindability: ceramic slip.
absolute grindability index—a characteristic number ex-
pressed as the change in specific surface area of a material per kyanite (Al2O3·SiO2)—the most abundant of the mineral
unit of time in a specific comminution system. polymorphs that include andalusite and sillimanite, com-
monly used as a source of mullite in ceramics.
relative grindability index—a characteristic number ex-
pressed as the change in specific surface area or other criteria laser light scattering—a phenomenon suitable for the mea-
such as particle size or fineness of a material per unit of time, surement of particle size in that particles illuminated by a
mill revolutions or other standard with respect to a known collimated laser beam cause the light to be scattered through
standard sample in a specific comminution system. angles which are inversely proportional to the size (generally
DISCUSSION—Grindability is an intrinsic property of material hard- expressed as a diameter) of the particles.
ness or friability that may be experimentally determined by measuring
the change in specific surface area, ∆As, generated per unit of grinding leadless glaze—See leadless glaze under glaze.
time, t; the grindability index being determined from the slope of the lightness—(1) The attribute by which a perceived color is
plot of ∆As in m2/g versus grinding time, t, in hours or other unit of judged to be equivalent to a member of a series of grays
time. ranging from black to white. (2) The attribute of color
healing power—the ability of a glaze to heal surface blem- perception by which a non-luminous body is judged to
ishes during firing. reflect more or less light.
limestone—a sedimentary carbonate rock, composed chiefly
hollow casting—See drain casting under casting.
of calcite (CaCO3), but sometimes containing appreciable
hot pressing—See hot pressing under pressing. dolomite.
hue—the attribute of color perception by means of which a
color is judged to be red, orange, yellow, green, blue, purple, liquid suspension—the system resulting from the intimate,
or intermediate between adjacent pairs of these, considered physical mixing of a liquid and particulate solids or dispers-
in a closed ring, red and purple being an adjacent pair (white, able materials, to form a time-stable, uniform, fluid mixture.
gray, and black possess no hue). loss on ignition—the percent loss in weight of a material on
ilmenite—a mineral having the theoretical composition being calcined at a temperature sufficiently high, and for a
FeO·TiO2 used principally in the production of titanium time long enough, to achieve constant weight without
oxide. melting, expressed as a percent of the initial weight of the
dry material (without free moisture).
impervious—that degree of vitrification evidenced visually by
complete resistance to dye penetration. magnesia—magnesium oxide (MgO), calcined or hard burned
D ISCUSSION —The term impervious generally signifies zero as periclase loosely applied also to the hydrate Mg(OH)2,
absorption, except for floor and wall tile which are considered and made synthetically from seawater or brine, or (impure)
“impervious” up to 0.5 % water absorption. from magnesite.
incised—decorated by cutting or indenting the ware surface. majolica—formerly an earthenware with an opaque luster
glaze and overglaze colored decorations, but currently des-
inglaze decoration—See inglaze decoration under decoration. ignating any decorated earthenware having an opaque glaze.
in service coefficient of friction—a coefficient of friction
measured under a specified condition of use, which may not major tile facial dimensions—the overall length or width of
be clean and dry, and hence, not a property of the ceramic the tile, including the lugs on opposite sides.
surface. major tile thickness—the thickness of tile, including any
DISCUSSION—For example, measurement of a ceramic tile coated maximum protuberances or ridges on the back.
with grease is a measurement of the grease-tile system and not a
property of the ceramic tile. masking power—the ability of a fired glaze to mask visually
the body on which it is applied.
ironstone ware—(stone china, white granite ware)—historic
terms for a durable English earthenware. mat glaze—See mat glaze under glaze.

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matte glaze—a glaze which does not exhibit specular reflec- nepheline syenite—a mineral aggregate consisting chiefly of
tion. albite, microcline, and nephelite, each in significant amount.
maturing range—the time-temperature range within which a nonplastic ceramics—nonclay ceramic materials that when
ceramic body, glaze, or other composition may be fired to mixed with water do not exhibit the rheological property-
yield specified properties. plasticity.
mean coefficient of thermal expansion, α (mm/mm·°C or nonvitreous (nonvitrified)—that degree of vitrification evi-
in./in.·°C)—from temperature T1 to temperature TT1 < T2): denced by relatively high water absorption.
DISCUSSION—The term nonvitreous generally signifies more than
0.01P 10.0 % water absorption, except for floor and wall tile which are
α5 (1)
T2 2 T1 considered nonvitreous when water absorption exceeds 7 %.
where P = percent linear thermal expansion, as defined opaque glaze—See opaque glaze under glaze.
below. open porosity—See open porosity under porosity.
orangepeel—a pitted texture of a fired glaze resembling the
mean diameter, arithmetic—See arithmetic mean diameter
surface of rough orange peel.
under diameter.
median diameter—See median diameter under diameter. oven ware—ceramic whiteware for culinary oven use.
melt—to change a solid into a liquid by the application of heat; overglaze decoration—See overglaze decoration under deco-
or the liquid resulting from such action. ration.
mineralizer—a processing additive that promotes either the particle—a minute quantity or fragment of matter whose size
recrystallization or the partial fusion or sintering of certain and shape depend on the forces of cohesion. It is usually
mineral or ceramic materials, often facilitating the desired only a single crystal or a unit of matter with a specific gravity
conversion at a lower temperature. approximating that of a single crystal.

minor tile facial dimension—the length or width of the tile particle shape—a characterization of the shape or configura-
exclusive of the lugs. tion of a particle fitting it into any one of ten basic classes,
as follows:
minor tile thickness—the thickness of tile that does not Class
include maximum protuberances or ridges.
A acicular—needle shaped
moisture expansion—an increase in dimension or bulk vol- B angular—sharp-edged or having roughly polyhedral shape
C crystalline—of geometric shape freely developed
ume of a ceramic article caused by reaction with water or D dendritic—having a branched crystalline shape
water vapor. E fibrous—regularly or irregularly threadlike
DISCUSSION—This reaction may occur in time at atmospheric tem- F flakey—lamellar, plate-like
G granular—having an approximately equidimen-
perature and pressure, but is expedited by exposure of the article to sional but irregular shape
water or water vapor at elevated temperatures and pressures. H irregular—lacking any symmetry
I nodular—having a rounded irregular shape
monochrome decoration—a single color decoration. J spherical—globule shaped

mottling—the presence in the surface of a glaze or body of particle size—See average particle size.
irregularly shaped, randomly distributed areas that vary in particle-size distribution—a profile of the sizes of particles
color, gloss, or sheen causing the surface to be nonuniform contained in a material in which the quantities must be
in appearance. expressed on some basis which may be total number, total
surface, or total weight or volume of the particles in the
mullite—a rare mineral of theoretical composition material.
3Al2O3·2SiO2, a relatively stable phase in ceramics pro-
duced by the high temperature reaction of alumina and silica paste—a prepared mixture consisting of a suspension of
or by the thermal decomposition of alumina-silica minerals undissolved solid(s) in a liquid medium sufficiently viscous
such as kyanite, sillimanite, andalusite, and various clay that it cannot achieve a level surface without application of
minerals. external force; not a slurry.

mullite porcelain—a vitreous ceramic whiteware for technical pate dure (hard paste)—a French term designating ceramic
application in which mullite (3Al2O3·2SiO2) is the essential whitewares fired at relatively high temperatures.
crystalline phase. pate tendre (soft paste)—a French term designating ceramic
mullite whiteware—any ceramic whiteware in which mullite whitewares fired at relatively low temperatures.
(3Al2O3·2SiO2) is the essential crystalline phase. pavers—unglazed porcelain or natural clay tile formed by the
dust-pressed method and similar to ceramic mosaics in
natural clay tile—a tile made by either the dust-pressed
composition and physical properties but relatively thicker
method or the plastic method, from clays that produce a
with 6 in.2 (39 cm2) or more of facial area.
dense body having a distinctive, slightly textured appear-
ance. peeling—Seeorangepeel; shivering.

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percentile—one of the values in a series dividing the distri- steatite porcelain—a vitreous ceramic whiteware for techni-
bution of the variable in the series into 100 groups of equal cal application in which magneisum metasilicate (MgO·SiO2)
frequency or size. is the essential crystalline phase.
percent linear thermal expansion—the change in length per titania porcelain—a vitreous ceramic whiteware for techni-
unit length as temperature is changed from temperature T1 to cal application in which titania (TiO2) is the essential crystal-
temperature T2 (T1 < T2), expressed as a percent: line phase.
P 5 @ ~ L 2 2 L 1 ! /L o # 3 1001A (2) zircon porcelain—a vitreous ceramic whiteware for technical
application in which zircon (ZrO2·SiO2) is the essential crys-
where: talline phase.
Lo = sample length at To (between 20 and 30°C),
L1 = sample length at T1, porcelain process—the method of producing glazed ware by
L2 = sample length at T2, and which a ceramic body and glaze are matured together in the
A = instrument correction. same firing operation.
permeability—the measure through a material of fluid flow, porcelain tile—a ceramic mosaic tile or paver that is generally
gas, or liquid. made by the dust-pressed method of a composition resulting
in a tile that is dense, fine-grained, and smooth with sharply
petalite—a lithium mineral of theoretical composition formed face, usually impervious and having colors of the
Li2O·Al2O3·8SiO2 which transforms on heating to a beta porcelain type which are usually of a clear, luminous type or
spodumene-silica solid solution product of very low or nil granular blend thereof.
thermal expansion.
porosity—the volume fraction of voids contained in a solid,
photosedimentation—a technique of fine particle measure-
often expressed as a percent.
ment wherein the size and number (or volume) of particles in
DISCUSSION—It has meaning only for a consolidated form of solid,
a sedimenting suspension are determined by the effect of the whether that be a particle, agglomerate, grain, or formed object such as
presence of sedimenting particles on the intensity of a beam nodule, pellet, or larger monolithic mass. Since pores can be described
of light or X-ray or laser beam transmitted through the in various specific ways, there is an equal number of corresponding
suspension as a function of settling time of the particles. expressions for porosity: macroporosity, microporosity, open or appar-
ent porosity, connected porosity, closed or blind porosity, and total
photozone counter—a stream counter in which the interroga- porosity, the sum of open and closed porosity. Porosity may also be
tion zone is monitored for changes in a light signal because expressed as determined by a given instrument or technique, for
of the presence of a particle. example, mercury porosimetry, which approximates open porosity, or
water absorption, which also approximates open porosity.
pinholes—imperfections in the surface of a ceramic body or closed porosity—the volume fraction of all pores within a
glaze resembling pin pricks. solid mass that are closed off by surrounding solid and, hence,
plastic—a descriptive term applied to a material that exhibits are inaccessible to each other and to the external surface: they
the property of plasticity or stickiness, where plasticity is the thus are not detectable by gas or liquid penetration.
ability of a material to undergo substantial deformation connected porosity—the volume fraction of all pores, voids,
without fracturing. and channels within a solid mass that are interconnected with
plastic pressing—See wet pressing under pressing. each other.
polychrome decoration—See polychrome decoration under open porosity—the volume fraction of all pores, voids, and
decoration. channels within a solid mass that are interconnected with each
porcelain—a glazed or unglazed vitreous ceramic whiteware other and communicate with the external surface, and thus are
made by the porcelain process, and used for technical measurable by gas or liquid penetration (Syn. apparent poros-
purposes, designating such products as electrical, chemical, ity).
mechanical, structural, and thermal wares when they are
porosity, apparent—See open porosity under porosity.
vitreous.
pottery—all fired ceramic wares that contain clay when
alumina porcelain—a vitreous ceramic whiteware for tech- formed, except technical, structural, and refractory products.
nical application in which alumina (Al2O3) is an essential
crystalline phase. precision—the agreement of repeated measurements of the
same parameter expressed quantitatively as the standard
chemical porcelain—vitreous ceramic whitewares used for
deviation computed from the results of a series of controlled
containing, transporting, or reacting of chemicals.
determinations. D1129
cordierite porcelain—a vitreous ceramic whiteware for tech-
nical application in which cordierite (2MgO·2Al2O3·5SiO2) is pressing:
the essential crystalline phase. dry pressing—forming ceramic ware in dies from powdered
forsterite porcelain—a vitreous ceramic whiteware for tech- or granular material by direct pressure.
nical application in which forsterite (2MgO·SiO2) is the hot pressing—a jiggering process wherein a heated profile
essential crystalline phase. tool or plunger is used.

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wet pressing (plastic pressing)—forming ceramic ware in semivitreous (semivitrified)—that degree of vitrification evi-
dies from a plastic body by direct pressure. denced by a moderate or intermediate water absorption.
DISCUSSION—The term semivitreous generally signifies 0.5 to 10.0 %
primary clay (residual clay)—a clay that remains geologi- water absorption, except for floor and wall tile which are considered
cally at its site of formation. semivitreous when water absorption is between 3.0 and 7.0 %.
process: shape factor—a dimensionless ratio of lengths, surface areas,
dry process (dry mix)—the method of preparation of a or volumes of the particles, useful for characterizing or
ceramic body wherein the constituents are blended dry, follow- comparing particles that otherwise have similar physical
ing which liquid may be added as required for subsequent properties.
processing.
wet process (slip process)—the method of preparation of a ship and galley tile—a special quarry tile having an indented
ceramic body wherein the constituents are blended in sufficient pattern on the face of the tile to produce an antislip effect.
liquid to produce a fluid suspension for use as such or for shivering (peeling)—the splintering that occurs in fired glazes
subsequent processing. or other ceramic coatings as a result of critical compressive
pyrophyllite—a hydrated aluminum silicate mineral of the stresses.
theoretical composition Al2O3·4SiO2·H2O, having physical sieve—a standard wire mesh or screen, especially when used in
properties in the raw state resembling mineral talc. graded sets to determine the mesh size or particulate size
quarry tile—glazed or unglazed tile, made by the extrusion distribution of particulate or granular solids.
process from natural clay or shale usually having 6 in.2 (39 sieve analysis—the particle size distribution of a particulate or
cm2) or more of facial area. granular solid or sample thereof, when determined by weight
raw glaze—See raw glaze under glaze. percent passage through, or retention on, a graded set of
repeatability—the standard deviation of results obtained by sieves.
the same operator using the same instrument in successive
silica (SiO2)—the common oxide of silicon usually found
measurements on the same sample.
naturally as quartz or in complex combination with other
reproducibility—the standard deviation of results obtained by elements as silicates.
different operators using the same or different instruments in DISCUSSION—Various polymorphs and natural occurrences of silica
different laboratories on the same sample. include cristobalite, tridymite, cryptocrystalline chert, flint, chalcedony,
and hydrated opal.
resistazone counter—the generic name used to describe
stream counters in which the interrogation zone is monitored sillimanite—Seeandalusite.
for changes in electrical resistance as a result of the presence single fire—See single fire under firing.
of a particle. sinter—a ceramic material or mixture fired to less than
complete fusion, resulting in a coherent mass, or the process
Rockingham ware—a semivitreous ware or earthenware hav- involved.
ing a brown or mottled brown bright glaze.
size—the representative dimension that best describes the
rutile—a mineral form of titanium oxide (TiO2) (tetragonal
extent in space of a particle, agglomerate, or aggregate.
crystallization), but usually produced chemically for use in
DISCUSSION—This term is not recommended to be used by itself. For
ceramics and other products. example, use, Martin’s diameter or Stokes’ diameter.
salt glaze—a glaze produced by the reaction, at elevated slip—a slurry containing chemical additives to control rheol-
temperature, between the ceramic body surface and salt ogy.
fumes produced in the kiln atmosphere.
slip casting—See drain casting and solid castingunder casting.
sanitary ware—See china sanitary ware.
slip coating—a ceramic material or mixture other than a glaze,
saturation—(1) the attribute by which the a percieved color is
applied to a ceramic body and fired to the maturity required
judged to depart from a neutral gray of equal lightness
to develop specified characteristics.
toward a pure hue. (2) Attribute of a visual sensation that
permits a judgment to be made of the proportion of pure slip glaze—See slip glaze under glaze.
chromatic color in the total sensation. slip process—See wet process under process.
satin glaze—a glaze which exhibits a non-zero specular slip resistance—the frictional force opposing movement of an
reflection reduced by at least 50 percent. object across a surface.
secondary clay (sedimentary clay)—a clay that has been slurry—a prepared mixture consisting of a free-flowing sus-
geologically transported from its place of formation. pension of undissolved solid(s) in a liquid medium; not a
paste.
semi-mat glaze—See semi-mat glaze under glaze.
semi-porcelain—a trade term designating semivitreous din- smelt (n)—a specific batch or lot of frit.
nerware. (v)—the act of melting a batch of frit.

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smelter—a furnace in which the raw materials of a frit batch tailings—the (size) residue, coarse or fine, removed from a
are melted. separation process.
solid casting—See solid casting under casting. talc—a phyllosilicate mineral having the general formula
special-purpose tile—a tile, either glazed or unglazed, made 3MgO-4SiO2-H2O and noted for its extreme softness, low
to meet or to have specific physical design or appearance thermal and electrical conductivity, and fire resistance. (See
characteristics such as size, thickness, shape, color, or also steatite talc.)
decoration; keys or lugs on backs or sides; special resistance
tap density—See tap density under density.
to staining, frost, alkalies, acids, thermal shock, physical
terra sigillata—a porous, red clay ware characterized by
impact, high coefficient of friction, or electrical properties.
embossed decorations of the same color and a satin-like
spitout—a glaze defect of the pinhole type developed in the unglazed surface.
decorating kiln, as a result of the evolution of minute gas texture—a roughness or lack of smoothness of a surface,
bubbles from body or glaze. which is visually apparent and often deliberately created.
spodumene (alpha spodumene)—a lithium mineral of the thermal expansion—See mean coefficient of thermal expan-
theoretical composition Li2O·Al2O3·4SiO2 (monoclinic sion; percent linear thermal expansion.
crystallization) which on heating inverts to beta spodumene, thermal shock—a condition of stress brought about by a large
a form having very low or nil thermal expansion. temperature difference across a body or glaze. (See also
static coefficient of friction—the ratio of the parallel compo- thermal shock failure; thermal shock resistance testing.)
nent of force applied to a stationary body that just overcomes DISCUSSION—Do not confuse thermal shock with phase change
the friction or resistance to relative motion of two surfaces in shock.
physical contact one with another, but otherwise thermal shock failure—mechanical failure of a glaze or body,
unconstrained, to the normal component of the force— as a result of the stress caused by a large temperature
usually the force caused by gravity—applied to the body difference across the ware.
under clean, dry conditions.
thermal shock resistance testing—the act of exposing ware to
steatite porcelain—See steatite porcelain under porcelain. a rapid temperature change to determine the temperature
steatite talc—massive talc or the pulverized product thereof difference a glaze or body can withstand without mechanical
having the general formula 3MgO·4SiO2·H2O. failure.
steatite whiteware—See steatite whiteware under ceramic ∆T max 5 σ/Tα (3)
whiteware. where:
stiction—a wet adhesion which causes the force to start motion σ = stress,
between two surfaces in frictional contact to be greater than E = Young’s Modulus, and
the force to continue motion between the surfaces. α = mean coefficient of thermal expansion.
stoneware—a vitreous or semivitreous ceramic ware of fine
texture, made primarily from nonrefractory fire clay. tile—a ceramic surfacing unit, usually relatively thin in rela-
tion to facial area, made from clay or a mixture of clay and
stream counter—an instrument in which the particles to be other ceramic materials, called the body of the tile, having
characterized are presented to an interrogation zone as a either a “glazed” or “unglazed” face and fired above red heat
one-dimensional stream, the size of the particle being in the course of manufacture to a temperature sufficiently
deduced from the physical changes it causes in the interro- high to produce specific physical properties and character-
gation zone. (See also resistazone and photozone.) istics. (See also ceramic mosaic tile; conductive ceramic
tile; faience tile; glazed ceramic mosaic tile; glazed
substrate—a body, board, or layer of material on which some
interior tile; glazed tile; glazed tile, extra duty glaze;
other active or useful material or component may be
major tile facial dimensions; major tile thickness; minor
deposited or laid, as for example, an electronic circuitry laid
tile facial dimension; minor tile thickness; porcelain tile;
on an alumina ceramic board.
unglazed tile; wedging of tile.)
surface area—the total area of the surface of a powder or solid
tin oxide (SnO2)—in finely ground form used in glazes as an
including both external and accessible internal surfaces
opacifier.
(from voids, cracks, open porosity, and fissures).
DISCUSSION—The area may be calculated by the B.E.T. (Brunauer, titania porcelain—See titania porcelain under porcelain.
Emmett, and Teller) equation from gas adsorption data obtained under titania whiteware—See titania whiteware under ceramic
specified conditions. It is useful to express this value as the specific whiteware.
surface area, for example, surface area per unit weight of sample
(m2/g). trimmers—units of various shapes consisting of such items as
bases, caps, corners, mouldings, angles, and so forth, nec-
suspension, liquid—See liquid suspension. essary or desirable to make a complete installation and to
tableware—all utensils and decorative articles used on the achieve sanitary purposes as well as architectural design for
table for meal service. all types of tile work.

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underglaze decoration—See underglaze decoration under water of hydration or combined water—that water in a
decoration. material that cannot be removed by drying at 110°C, as it is
unglazed tile—a hard, dense tile of homogeneous composition chemically bound, expressed as a percent of the weight of
throughout, deriving color and texture from the materials of the material.
which the body is made. The colors and characteristics of the
tile are determined by the materials used in the body, the wedging of tile—the difference between two spaced measure-
method of manufacture, and the thermal treatment. ments of the length or width of a tile, expressed as a percent
of the distance between points of measurement.
vellum glaze—See vellum glaze under glaze.
viscosity—the property of fluids that opposes the relative wetting agent—a chemical additive that reduces the surface
motion of adjacent portions of a given fluid producing a type tension of a fluid, inducing it to spread readily on a surface
of internal friction and exhibiting a resistance to flow. to which it is applied, thus causing wetting of the surface of
the solid with the fluids.
vitreous (vitrified)—that degree of vitrification evidenced by
low water absorption. (See also impervious; nonvitreous; wet pressing—See wet pressing under pressing.
semivitreous.) wet process—See wet process under process.
DISCUSSION—The term vitreous generally signifies less than 0.5 % whiteware—See ceramic whiteware.
absorption, except for floor and wall tile and low-voltage electrical
whiting—calcium carbonate powder of high purity.
porcelain which are considered vitreous up to 3.0 % water absorption.
vitreous slip—a slip coating matured on a ceramic body wollastonite—a calcium metasilicate mineral with the formula
producing a vitrified surface. CaSiO3 containing theoretically 48.3 % lime (CaO) and
51.7 % silica (SiO2), occurring in acicular masses of elon-
vitrification—the progressive reduction and elimination of gated triclinic crystals, usually white or pale gray.
porosity of a ceramic composition, with the formation of a
glass phase, as a result of heat treatment. yellow ware—a yellow semivitreous ware or an earthenware
with a colorless, clear glaze.
vitrification range—the maturing range of a vitreous body.
void space—ratio of the volume of voids in a powder bed to Zahn cup—an apparatus for the measurement of liquid or
that of the overall volume of the powder bed. slurry viscosity expressed as the number of seconds required
for the liquid or slurry to drain from the cup through a hole
warpage—curvature of a flat specimen measured as deviation of definite diameter.
of the specimen surface from a true plane along the edges or
the diagonals and at the mid-length of an edge or diagonal, zircon porcelain—See zircon porcelain under porcelain.
expressed as a percent of the length of the edge or diagonal, zircon whiteware—See zircon whiteware under ceramic
and called convex or concave with respect to the face of the whiteware.
specimen.

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