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General Chemistry 1
First Quarter-Module 9:
Gas Laws
This module was designed and written with you in mind. It is here to help you
master the nature of Matter. The scope of this module permits it to be used in many
different learning situations. The language used recognizes the diverse vocabulary
level of students. The lessons are arranged to follow the standard sequence of the
course. But the order in which you read them can be changed to correspond with
the textbook you are now using.
Learning Competencies
Define pressure and give the common units of pressure
(STEM_GC11G-Ihi-43)
Use the gas laws to determine pressure, volume, or temperature of a gas
under certain conditions of change (STEM_GC11G-Ihi-45)
Use the ideal gas equation to calculate pressure, volume, temperature or
number of moles of a gas (STEM_GC11G-Ihi-46)
Use Dalton’s law of partial pressures to relate mole fraction and partial
pressures of gases in a mixture (STEM_GC11DLIi-47)
Choose the letter of the best answer. Write the chosen letter on a separate sheet of
paper.
1. Which of the following gas laws state that pressure and absolute temperature are
directly related to each other at constant volume?
A. Avogadro’s Law
B. Boyle’s Law
C. Charles’ Law
D. Gay - Lussac’s Law
2. What happened to the pressure of a gas if the volume is doubled?
A. 2x as large
B. 1/2 of its value
C. Doesn’t change
D. Becomes zero
3. If the absolute temperature of a gas increases, what will happened to its
volume?
A. Decreases
B. Increases
C. Becomes zero
D. Remains constant
4. What is the general gas equation, in which all the collisions between atoms and
molecules are perfectly elastic?
A. Boyle’s Law
B. Charles’s Law
C. Gay - Lussac’s Law
D. Ideal Gas Law
5. A balloon occupies 4.50 L at 32°C, how much will it occupy at 50°C?
A. 2.25 L
B. 3.05 L
C. 4.77 L
D. 7.88 L
6. A gas has a pressure of 0.370 atm at 293 K. What is the absolute temperature
at 0.545 atm?
A. 432 K
B. 453 K
C. 523 K
D. 620 K
7. A gas having a pressure of 800 mmHg is being compressed from 6 L to 4 L, what
will be its final pressure?
A. 300 mmHg
B. 550 mmHg
C. 1000 mmHg
D. 1,200 mmHg
What’s In
You have studied about the states of matter: A solid has a fixed shape and
volume, its particles are tightly packed and vibrate at a fixed point. Liquids have an
indefinite shape but definite volume, its particles are tightly packed but far enough
to slide over to one another. Gas has indefinite shape and volume, its particles of
are very far apart and move freely. Plasma is an ionized gas.
Gases behave differently from solids and liquids due to their differences in
their molecular behavior. From this behavior of gases as explained by kinetic
theory, gas laws are derived.
What’s New
Gas laws relate to its volume, pressure, temperature and number of moles of
a gas. To understand fully the concept of gas laws, describe the principle in each
picture.
1. 2. 3.
Source: Hot air balloon summer heat festival /Paul J Everett/Flickr. Accessed July 10, 2020.
https://www.flickr.com/photos/paul_everett82/2580917932 https://www.peakpx.com/495550/white-syringe
https://freesvg.org/pressure-cooker
Gas Laws:
1. Boyle’s Law: states that the pressure of a gas is inversely proportional to its
volume at a constant temperature. It was discovered by Robert Boyle.
Formula: P1V1 = P2V2
where: P1, P2 = initial and final pressure; atm, mmHg or torr
V1, V2 = initial and final volume; ml, L
Example:
A sample of oxygen gas has a volume of 15 L at 630 mm Hg. What is the new
volume when the pressure changes to 210 mmHg?
Given:
P1 = 630 mmHg P2 = 210 mmHg
V1 = 15 L
Required: V2 = ?
Solution:
V2 = V1 x P1
P2
V2 = 15 L x 630 mmHg = 45 L
210 mmHg
Answer:
V2 = 45 L (as pressure decreases, volume increases)
2. Charles’ Law: states that the volume of a gas is directly proportional to its
absolute temperature at constant pressure. It was discovered by Jacques-
Alexandre Charles.
Formula: V1 = V2
T1 T2
where: T1, T2 = initial and final absolute temperature; K
V1, V2 = initial and final volume; ml, L
Example:
A balloon has a volume of 870 ml at 17°C. At what temperature will the volume of
the balloon be 450 ml?
Given:
V1 = 870 ml V 2 = 450 ml
T1 = 17 + 273 = 290 K
4. Avogadro’s Law: states that the volume of a gas is directly proportional to the
number of moles at constant pressure and temperature. It was discovered by
Amedeo Avogadro.
Formula: V1 = V2
n1 n2
where: V1, V2 = initial and final volume; ml, L
n1, n2 = initial and final number of moles, mol
Example:
3.2 L of a gas has 0.54 mole. How many moles of this gas are present in 6.8 L of a
gas?
Given:
V1 = 3.2 L V 2 = 6.8 L
n1 = 0.54 mole
Required: n2 = ?
Solution:
n2 = n1 x V2
V1
5. Ideal Gas Law: is also called the general gas equation. It was first stated by
Emile Clapeyron in 1834. It is the combination of Boyle’s Law, Charles’ Law,
Avogadro’s Law and Gay-Lussac’s Law
Formula:
PV = nRT 0r PV = mRT
Mm
where:
P = pressure (in atm) V = volume (in L)
T = absolute temperature (in K) n = moles (mol)
m = mass (g) Mm = molar mass (g/mol)
R = universal gas constant, 0.08205 L atm
mol K
Examples:
1) How many moles of O2 is in a 3.50 L sample of O2 measured at 1.25 atm and
20°C?
Given:
V = 3.50 L P = 1.25 atm
T = 20 + 273 = 293 K
R = 0.08205 L atm
mol K
Required: n = ?
Solution:
n = PV
RT
= 1.25 atm x 3.50 L
(0.08205 L atm/mol K) x 293 K
Answer:
n = 0.18 moles
2. Calculate the volume of 2.25 mol of SO 2(g) measured at 27 C and 0.8 atm.
Given:
n = 2.25 mol P = 0.8 atm
T = 27 + 273 = 300 K
R = 0.08205 L atm/mol K
Required: V = ?
Solution:
V = nRT
P
= 2.25 mol x 0.08205 L atm/mol K x 300 K
0.8 atm
Answer:
V = 69.23 L
What’s More
Solve the following problems using Gas Law equation and determine what law it
applies. Write your answer on a separate sheet of paper.
What I Can Do
Activity 1.5:
Based on the gas laws you have learned, give an example of an application of gas
law by illustrating it, then explain the concept.
Illustration Explanation
RUBRICS
Choose the letter of the best answer. Write the chosen letter on a separate sheet of
paper.
Additional Activities
Complete the concept map below by filling up the right formula of each gas laws.
What’s In
In the previous lesson, you gained an idea about pressure and gas laws specifically
ideal gas law. Gases as you have learned behave differently, when they mixed in a
closed container they act independently. They exert individual pressures on the wall
of the container. In this lesson, we will continue discussing another gas law dealing
with partial pressure …. Dalton’s law of partial pressure.
What’s New
Activity 2.1. Analyze the picture below and solve:
1. What is the total pressure of air based on the given? Show your solution.
2. What is the pressure of a mixture of hydrogen (H 2) and helium (He), if the partial
pressure of H2 is 2.9 atm and the partial pressure of He is 7.2 atm? What is the total
number of moles of the mixture if H 2 has 0.60 mol and He has 1.50 mol? Show your
solution.
Dalton's law of partial pressure states that the total pressure of a mixture
of gases is equal to the sum of the partial pressures of each gas. The pressure
exerted by an individual gas in a mixture is known as its partial pressure. It was
discovered by John Dalton. According to him, each gas in a mixture acts
independently with one another in exerting a force on the wall of the container.
Formula:
PT = Pgas1 + Pgas2 + Pgas3 + …
where:
PT = total pressure
Pgas1, Pgas2,Pgas3 = partial pressure of each gas
Assuming we have a mixture of ideal gases, we can use the ideal gas law to solve
problems involving gases in a mixture
P = nRT
V
Dalton's law can also be expressed using the mole fraction of a gas,
Formula:
mole fraction = pressure fraction
n1 = P1
nT PT
where:
n1 = number of moles of a gas
nT = total number of moles of gas mixture
P1 = partial pressure of a gas
PT = total pressure of gas mixture
Example:
1. What is the total pressure in atmospheres of mixture of three gases with partial
pressures of 1.25 atm, 0.55 atm and 0. 32 atm?
Given:
P1 = 1.25 atm
P2 = 0.55 atm
P3 = 0.32 atm
Required: PT = ?
Solution:
PT = P1 + P2 + P3
= 1.25 atm + 0.55 atm + 0.32 atm
= 2.12 atm
Answer: PT = 2.12 atm
Activity 2.2
Problem Solving: Solve the following using Dalton’s Law of Partial Pressure.
1. What is the partial pressure of hydrogen gas in a mixture of hydrogen and
helium if the total pressure is 540 mm Hg and the partial pressure of helium is 325
mm Hg?
2. What is the total pressure of gases (in atm) in a container, having partial
pressures of 2.52 atm, 950 mmHg, and 174.8 torrs?
3. The mixture of 0.46 mol of neon (Ne) and 0.14 mol of argon (Ar) has a total
pressure of 4.78 atm. What is the partial pressure of both gases?
What’s More
Give one example of Dalton’s law of partial pressure by representing gases inside
the container to get the total pressure.
What I Can Do
Activity 2.5
Air is composed of the following gases. Compute for the partial pressure of each
gas, if the total pressure is 760 mmHg.
Components of Air % Composition Partial Pressure
in mmHg
Nitrogen 78%
Oxygen 21%
Argon 0.93%
Carbon dioxide 0.04%
Other gases 0.03%
A) Amedeo Avogadro
B) Jacques Charles
C) John Dalton
D) Robert Boyle
3. Which of the following gas exerts the greatest pressure, if 10 g of each gas was
used at 273 K occupying 2 L of a container?
A) He
B) H2
C) N2
D) O2
4. What state of matter when mixed together, acts independently inside the
container?
A) Gas
B) Liquid
C) Plasma
D) Solid
5. What is the total pressure of 2 gases having partial pressures of 0.8 atm and 912
mmHg?
A) 0.5 atm
B) 1.8 atm
C) 2.0 atm
D) 3.2 atm
6. Air mixture has a total pressure of 760 mmHg, if the partial pressure of O2 is
159.6 mmHg and N2 is 592.8 mmHg, what is the partial pressure of the other gas?
A) 2.4 mmHg
B) 5.7 mmHg
C) 6.4 mmHg
D) 7.6 mmHg
7. If a balloon is filled with pure oxygen, how much pressure does it have?
A) Same as atmospheric pressure
B) Less than atmospheric pressure
C) Greater than atmospheric pressure
D) All of the above
Additional Activities
Give one example of an application of Dalton’s Law of partial pressure and explain
the concept.
Illustration Explanation
RUBRICS
1. What gas law which states that the volume of a gas is directly proportional to the
number of moles at constant pressure and temperature?
A. Avogadro’s Law
B. Boyle’s Law
C. Charles’ Law
D. Gay – Lussac’s Law
2. What is the general gas equation, in which all the collisions between atoms and
molecules are perfectly elastic?
A. Boyle’s Law
B. Charles’s Law
C. Gay - Lussac’s Law
D. Ideal Gas Law
3. A gas having a pressure of 800 mmHg is being compressed from 6 L to 4 L, what
will be its final pressure?
A. 300 mmHg
B. 550 mmHg
C. 1000 mmHg
D. 1,200 mmHg
4. How many moles of gas are present in 5 L cylinder if the pressure of the gas is at
2.5 atm and the temperature is 32°C?
A. 0.4 moles
B. 0.5 moles
C. 1.2 moles
D. 1.5 moles
5. A gas has a pressure of 0.370 atm at 293 K. What is the absolute temperature
at 0.545 atm?
A. 432 K
B. 453 K
C. 523 K
D. 620 K
6. If the absolute temperature of a gas increases, what will happened to its
volume?
A. Decreases
B. Increases
C. Becomes zero
D. Remains constant
7. Which of the following gas laws state that pressure and absolute temperature are
directly related to each other at constant volume?
A. Avogadro’s Law
B. Boyle’s Law
C. Charles’ Law
D. Gay - Lussac’s Law
(1) Calculate Pressure of a Gas Using Van Der Waal's Equation." ThoughtCo.
Accessed July 14, 2020. https://www.thoughtco.com/ideal-vs-non-ideal-gas-
example-problem-609507.
(2) Cervantes, Charry Vida R., & Dizon, Reynald D., 2016. “General Chemistry 1”,
Lorimar Publishing Inc.: pp. 86-104
(3) Gas Laws." Wikipedia, the Free Encyclopedia. Last modified April 8, 2002.
https://en.wikipedia.org/wiki/Gas_laws#Other_gas_laws.
(4) Mendoza, Estrella E., & Religioso, Teresita F., 2001. “Chemistry III (Second
Edition)”, SIBS Publishing House,Inc.: pp 163 - 186
(6) Use Boyle's Law to Find the Volume of a Gas." ThoughtCo. Accessed July 14,
2020. https://www.thoughtco.com/boyles-law-example-problem-607551.
Elisa O. Cerveza
Chief, Curriculum Implementation Division
OIC, Office of the Assistant Schools Division Superintendent