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This module was designed and written with you in mind. It is here to help
you master the concepts and ideas in Chemistry. The scope of this module permits
it to be used in many different learning situations. The language used recognizes
the diverse vocabulary level of students. The lessons are arranged to follow the
standard sequence of the course.
Learning competencies
1. Which period in the periodic table can you find the element oxygen?
A. 1 B. 2 C. 3 D. 4
2. Which group in the periodic table can you find the element carbon?
A. 1A B. 2A C. 3A D. 4A
5. He believed that no two electrons can have the same four quantum numbers.
A. Erwin Schrödinger C. Niels Bohr
B. Louis de Broglie D. Wolfgang Pauli
6. Which among the following quantum number tells us the energy level an atom is in?
A. Principal Quantum Number C. Magnetic Quantum Number
B. Angular Quantum Number D. Spin Quantum Number
7. Which among the following quantum number tells us the specific orbital an
atom is in?
A. Principal Quantum Number C. Magnetic Quantum Number
B. Angular Quantum Number D. Spin Quantum Number
8. Which among the following quantum number tells us the shape of the atomic orbital?
A. Principal Quantum Number C. Magnetic Quantum Number
B. Angular Quantum Number D. Spin Quantum Number
9. What region of an atom has the highest probability where an electron can be found?
A. Shells C. Energy level
B. Subshells D. Atomic orbital
14. Which among the following is the correct orbital diagram of nitrogen atom?
15. Which among the following is known as an atom with unpaired electrons?
A. Paramagnetic C. Diamagnetic
B. Ferromagnetic D. Both A and B is correct
What’s In
Electrons are negative (e-) charged particles that hae negligible mass and
revolves around the nucleus at a very high speed. In an ordinary state atom are
electrically neutral, that is the number of electrons which revolve around the
nucleus is equal to the number of protons in the nucleus.
Niels Bohr’s nuclear model of an atom shows that electrons revolve around
the nucleus at a specific energy level (quantum number) or orbit. Energy levels
(electron shells/orbitals) are regions surrounding the nucleus of an atom where an
electron can be found. Erwin Schrödinger’s quantum mechanical model of an
atom describes the probable location of an electron in an atom. Schrödinger’s used
his wave equation to describe the probability of finding an electron in a certain
position which introduced the concept of sub-energy levels.
Bohr’s and Schrödinger’s work introduced us to the concept of quantum
number. Quantum numbers are numbers that are used to describe and trace the
movement of each electron within an atom. There are four types of quantum
numbers: Principal Quantum Number, Magnetic Quantum Number, Angular
Quantum Number and Spin Quantum Number.
What’s New
Pauli Exclusion Principle states that no two electrons can share the same
combination of four quantum numbers. Each electron in an atom has a unique set
of quantum numbers.
Table 1.1 Quantum numbers and its possible values
Quantum number Symbol Possible Values
Principal Quantum Number n From 1 to 7
Angular Quantum Number l Between 0 and n- 1
Magnetic quantum number ml - l to + l
Spin Quantum Number ms +1/2
-1/2
Complete the table below by writing the missing quantum numbers of the given
energy level.
N l ml ms
1 0 0 +1/2
-1/2
2 0 0
1 +1/2
-1/2
3
1 -1, 0, +1
What Is It
As mentioned, quantum numbers can be used to describe the size, shape, and
orientation in space of the orbital on an atom. Energy levels or Atomic orbital
describes a region of space in which there is a high probability of finding the electron.
Each electron in an atom is described by four different quantum numbers.
The angular quantum number describes the shape of the electron shell.
There are four types of subshells within an electron shell. Each subshell has its
own unique size and shape as shown in figure 1.2 below.
1. Sharp or s subshell
2. Principal or p subshell
3. Diffuse or d subshell
4. Fundamental or f subshell
Table 1.2 shows the values of l and the type of s, p, d, f subshell found in
each angular quantum number.
Example:
1. What is the orbital diagram of nitrogen? (atomic number = 7)
Number of electrons =7
Notice that the electrons in nitrogen occupy all the empty 2p subshells
instead of pairing up while in oxygen the extra electron paired up with the first
electron in the 2p subshell.
To find the value of ms, you have to take note which spin entered last in the
orbitals, if +1/2 is the last electron then it is said that the ms value of the element
is +1/2 and if - 1/2 is the last electron then it is said that the ms value of the
element is – 1/2.
Example.
1. What is the ms value of nitrogen? Answer = +1/2
2. What is the ms value of oxygen? Answer = -1/2
Referring to the orbital diagram above the last electron of nitrogen that
entered the orbital is a spin up that is why the ms value of nitrogen is +1/2 while in
What’s More
Activity 1.2 Determining quantum numbers
B. Identify the principal quantum number (n) and Angular Quantum Number
( l ) of the following oritals.
Example; 3s n = 3, l = 0
1. 3p n = ____, l = __________
2. 4s n = ____, l = __________
3. 5d n = ____, l = __________
1. Carbon ________
2. Neon ________
3. Fluorine ________
What I Have Learned
What I Can Do
Activity 1. 4
A. True or false. Write (+) if the following statement is true or write (0) if the
following statement is false.
1. 1s orbital is shape like a sphere.
2. The maximum number of electrons a p orbital can carry is 10.
3. The maximum number of electron in an orbital is 2.
4. To completely describe the behavior of electrons around an atom
its four quantum numbers must be known.
5. d orbital has 3 possible size and shape.
Assessment
Read each question carefully. Choose the letter of the correct answer.
1. How many electrons can a f orbital carry?
A. 2 B. 6 C. 10 D. 14
Additional Activities
Identify the highest orbital that each of the following elements can enter.
Example: Boron – 2p
What’s New
What Is It
1. The Aufbau principle. Electrons fill orbitals starting at the lowest available
energy state before filling up higher states.
2. Pauli exclusion principle. The number of electrons that can occupy each
orbital is limited. An orbital can only carry two electrons and that they must
have opposing spins. (spin up and spin down).
Example.
Orbital diagram of magnesium
3. Hund’s rule. If multiple orbitals of the same energy are available, the
unoccupied orbitals will be filled before occupied orbitals are reused.
Example.
Comparing orbital diagram of nitrogen and oxygen.
The steps in determining the magnetism of a given atom are the following.
Step 1. Identify the electron configuration of the given atom.
Step 2. Illustrate the orbital diagram of the given atom.
Example
Identify if the following elements are paramagnetic or diamagnetic.
1. Helium (He)
Step 1. Electron configuration of He. (atomic number =2)
Answer: 1s2
1 refers to the highest energy level occupied by the valence electron of
helium
Superscript 2 refers to the number of electrons found in each
subshell. The following are the maximum number of electrons found
in each subshell.
1. s subshell = 2 electrons
2. p subshell = 6 electrons
3. d subshell = 10 electrons
4. f subshell = 14 electrons
2. Carbon (C)
Step 1. Electron configuration of C. (atomic number = 6)
Answer: 1s2 2s2 2p2
3. Sodium (Na)
Step 1. Electron configuration of Na. (atomic number = 11)
1s2 2s2 2p6 3s1
Step 2. Orbital diagram.
4. Neon (Ne)
a. 1s2 2s2 2p6
b.
c. Diamagnetic
5. Nickel (Ni)
a. 1s2 2s2 2p6 3s2 3p6 4s2 3d8
b.
c. Paramagnetic
In the given last example, notice that the electron configuration and orbital
diagram of nickel were already very long. To shorten this there is a shorthand
c. Paramagnetic
The noble gas before cobalt in the periodic table is argon which
has 20 electrons. The electron configuration of argon is 1s2 2s2
2p6 3s2 3p6, that is why the remaining configuration started at 4s2
and 3d7 to complete the 27 electrons of cobalt.
b.
c. Paramagnetic
What’s More
1. Silver __________________________________________________________
2. Thorium __________________________________________________________
3. Xenon __________________________________________________________
4. Yttrium __________________________________________________________
5. Platinum __________________________________________________________
Activity 2. 3
Identify what is being asked in the following questions. Write your answer on the
space provided before each number.
Activity 2. 4
Assessment
Read each question carefully. Encircle the letter of the correct answer.
1. What is the highest orbital can a transition element occupies?
A. s subshell C. d subshell
B. p subshell D. f subshell
Determine if the following is valid or invalid. If invalid write the rule that is
violated in the given.
1. 1s2 2s2 2p6 3s2 3p6 4s2 3d10 ___________________________
2. [Ra] 3d⁸ 4s² ___________________________
3. .
___________________________
4. 1s 2s 2p 2s 3p
2 2 6 2 6
___________________________
5. Vanadium is paramagnetic. ___________________________
Posttest
Read each question carefully. Choose the letter of the correct answer.
1. In the periodic table, principal quantum number (n) is equal to the assigned
______________number of an atom.
A. Mass B. Period C. Atomic D. Group
3. Which among the following is the correct orbital diagram of nitrogen atom?
5. Which period in the periodic table can you find the element oxygen?
A. 1 B. 2 C. 3 D. 4
6. Which among the following quantum number tells us the shape of the
atomic orbital?
A. Principal Quantum Number C. Magnetic Quantum Number
B. Angular Quantum Number D. Spin Quantum Number
7. What region of an atom has the highest probability where an electron can be found?
8. Which group in the periodic table can you find the element carbon?
A. 1A B. 2A C. 3A D. 4A
9. He believed that no two electrons can have the same four quantum numbers.
A. Erwin Schrödinger C. Niels Bohr
B. Louis de Broglie D. Wolfgang Pauli
10. Which among the following quantum number tells us the energy level an
atom is in?
A. Principal Quantum Number C. Magnetic Quantum Number
B. Angular Quantum Number D. Spin Quantum Number
11. Which among the following quantum number tells us the specific orbital an
atom is in?
A. Principal Quantum Number C. Magnetic Quantum Number
B. Angular Quantum Number D. Spin Quantum Number
12. He explained that electrons in an atom move in a wave like behavior, which
become an important cornerstone of the quantum theory.
A. Erwin Schrödinger C. Niels Bohr
B. Louis de Broglie D. Wolfgang Pauli
(5) Exploring the magnetism of a single atom. (2014, May 8). Phys.org – News
and Articles on Science and Technology.
https://phys.org/news/2014-05-exploring-magnetism-
atom.html#:~:text=In%20an%20atom%2C%20magnetism%20arises,di
rectionality%20and%20stability%20to%20magnetization
(6) How to tell if an element is paramagnetic or diamagnetic. (n.d.). ThoughtCo.
https://www.thoughtco.com/paramagnetism-and-diamagnetism-
problem-
609582#:~:text=If%20there%20are%20unpaired%20electrons,edta)3%
5D2%2D
(7) Magnetic properties of matter. (n.d.). Encyclopedia Britannica.
https://www.britannica.com/science/magnetism/Magnetic-
properties-of-matter
(8) Magnetic properties. (2020, July 14). Chemistry LibreTexts.
https://chem.libretexts.org/Bookshelves/Physical_and_Theoretical_C
hemistry_Textbook_Maps/Supplemental_Modules_(Physical_and_The
oretical_Chemistry)/Physical_Properties_of_Matter/Atomic_and_Molec
ular_Properties/Magnetic_Properties
Elisa O. Cerveza
Chief, Curriculum Implementation Division
OIC, Office of the Assistant Schools Division Superintendent