2012

4E EA&fiT(t*|lf'++€)
E+Sg+EEtilm
EXAMINATION
OUAUFYING FORAPPUCANTS
FORJAPANESE

(MONBUKAGAKUSHO)
GOVERNMENT SCHOLARSHIPS
20i2

+Fl-;{&
EXAMINA]'ION QUESTIONS

(+F[E+e)
UN-DERGRADUAIE
STUDENTS

I t +
CHEMISTRY

,*f *firt6li! ri 60t.

?LEASENOTE : THE TESTPERIODIS 60 MINUTES.

CHEMISTRY (Pleas prinl tull .mq u.derlinine

I w.ile the r€feEncc numherof lhe cotmt mswer in lhe answerbox. Us lhe following values
for alomicweighls:tl= L0, C=12.0,O=16.0.

(l) Which ofthe ioft or aton I ) to 4) hasthe snallesl mdius?

l ) F 2) Ne 3) Na-

12\ ln rhe$lid sEk yhich olrhe sLbsEn!esl) ro!) hasJrehiehe{ elecr'.,lcondtcriviryl

2) silveriodd€ l) rl(on

(3) wnicn of 1hesubstancd l) 104) hasa lin€d mol4uld shape?

(1) which olthe m@h l) b4) n insolublein bJdrocflo_cacdl

2) mea€sim ) lin

(s) Wnichof the solutioN l) to 4) exhibitsa pH valueoI2?

l) 0.01novl-aqueous
solulion
of rcelicacid
2) 0.05noL/Lsultuic acid
3) 0.01noL/Lhydrcchbncacid
4) I xl0 " novl lqueoussolutionofsodiun hydroxide
 (6) tnwhichollhcreactions
1)lo4)lheunderlinedelenenlhoxidiad?

l) CuSOa + H$- CnS+ H:SOa

2) Cl?+ SOz+ 2H,O+ 2HCl+ Hrsoa
3) SO:+ 2H2S+ 2HrO+ lS
4) loKcl + 2(M!O4 + 8H,Sor r sclr + 2U!SO4+ 6K:SO.+8HrO

nixture oINorand NrOr h scalcdin,l iderticalve$eh wilh Dovablepistons.

(7) A saseous
Whentheconditio.sc nodifiedasd6dibed in L)to 4), in whichconditiondoesthenolar
Fdo ofNoi to NrO4remainunchmgcdafter a lons line enoughto reachequilibrium?

l) Total pe$ure k inoeasedby noring lhe phlon al a conslanttenpe6tuE.

2) TenpmtuE is increasedwhilc keepins the lolal pressureconsttnl by movi.g the

3) additional NO, is intodnced nom oulsidewbile keepingrbe ror,l piessurccon$ant by

soving drepisron al a constanttenperature.
4) Addirional N2 is intoduced fiom ontsidewhile keeping the totll ptssure conslantby
noring lhc pisbn at s constanltenperatur€.

II !tlues for(
C'\e rhcappropnare

I mol of graphite is conpl€tely oxidized lo carbondioxide wnib evolvins I94 Lr of heal and I
nol ofcarbonnonoxideis conpletelyoxidizcdto carbondioxidewhileevolving281rJ orheal
Ar |) "c. und€rI atm,( a ) L ofoxys€n is Equitd to oxidiz I nol of8raphilelo carbon
nonoxidewilh theheatcvolutionof( b )U.

G)
III ?roedur$ (i) to (iii) des6h€ expdmentsto &paEte indiYidualnelal ions ft6n a ndhd
wril€ the apprcpriale@los for ( !
whicbc@raic Ag', cu" &d z." )
I )ad( 2 )-
apprcpriatechenicaltumulafor(

(i) Upon addition of hydmchloric acid ) p@ipitates fomed. The

cheni@l fomula ofthe pr€ciPibtesis (
(ii) To the suFndtant obbined liom ) ws bubbl€d in to fom

(iii)To d€ supemtdt obiaircd ft@ vd add.d md ( 2 )wd

bnbbledin to fm white Peipit t€3

(b)

(2)

IV write lhe mrect answ€rto theqEstom belowlo two signifisnr figues

{l) 9.0g ofeln@se, CiHDO6. wN disslv€din l0Og of Mt€i Theftezing Poi't ofthe
glucosesoluiror wd detemined ro be 094'C Det€min' the mohr n€sins point
depresionofwater in theunit of (K ke / mol)
(2i A saltis conposd ofcation M' md anionr' ed perf€ctlvdissociales whehdissolv€d
in sater 2-Ogofthiseli w6 disslvedin 100g ofwarer Tn' tuaing poirt ofthe sall
'C- D€t€min€$e f@uls nas of th€salt'
solutionwd deteminedto be-l 3

0) (2)
 Our|redheredrecy4rhecpmceseroroetuccmpodndrArsse'lheque,tronsr.rmdL

.n| fi;8.. ,.o

l - l
l=;_] F_l FI

frt
I
,o,| *"o.

f;_-]
I l"
lil

_
.",**"1
Ca(OHt _
I c | .t c -- CHTCOOH
(c) L

(l) Select6e sltuctml fomulas for d€ compoudsA lo J non (r)-(25).Ifiece$ary.

nunber Mn be usedtwice.

(2) CH3CH3 (3) CH3CHTOH i l ( s )

(/) (cH3coo),ca(s) cH3cH,Bf (s)
o2) (cH3cH'ohca
03) c.c'
OH
r''r "."o
1,er 9H3
6)cHo
(22)
(21)cH3cH,cH,oH oo,O"oo"oo
Oi**o, O""'o'

B c D E

F G II
(2) Lookine back at the diagrm of syntheticprocesss of organicconpounds show. abovo,label
thc rypesofrerctions repEsentedby rhe lerte( (a) to (d) fton the lisr (1) to (8). Ifnec6sary, the
sanenunbercanbe usedtwice

(l) oxidation (2) hydiogenarion (3) dehydalion (4) lddirion

(s) additionpolymeriation (6) subsriLuLioi (7) deconposition (8)neutmliation

VI s e l e dr h ed p p u p n d e . , r m l o ' r r m n d , . o m p o u r d , ' , r , \ )f io m ( l ' ' 8 r .

G G G G
G G G G
(l) u h a neut.ll liquid and gives a negltive esult on lhe silver nimr lest. u reach with
carboxyliclcids to giYees!e$.
{2) ll is solublein waterandils aqueous
solutionis sftonglyacidic
(3) 11is slighllysolublein walcr a.d ils aqu€oussoluliodis slightlyrcidic. It underyoes
color
'edc.or b bluepurple{irl- oqreoh iron(lll).hlond.
(4) ft is n€utral liquid, and il giles a positile siller miror test Esult and a negativeFehli.e s rcst

(5) Il h insoluble in waler. bul soluble in dilnt€ hydrochloricacid Ii undergoesa colo. reaclion to
reddish pnqlc s ith aqu€ous calciun hr"ochlorite.
(6) ll h insolublein coldwater,but solublein hot waterIt eactsNith alcoholto siveest€n.
(7) Ir is insolublein walerandjtgivesa negatileesull on thesilvdminorlest. It G E€n€rally
uscd

(8) Il is jnsolublein wat€randycllow Oncofthc dcrivalivcs

is us€dasexplosives.
(c)

(c)
VII wben ai o€anic codpouhdx 124ng. qhich consislsof onlv carbon,hvdrosen.andoxrgen
aroFswasconplelely I76 msofcor and103mgofHro rere fomed Answer
conbusted,
(l) and(2).Userhcfouowingvalu* for anrmicweights:
tbequestions H: l0' C: 120.O:

(l) wtat is tbeenpnicalfomula ofthe coDpoundx?

(2) A rapo. densiryofthe organiccompoundal thc saneleDpetatur€undcrlhe sameprcssut s
approxinatelytwicethatol oxysen.Wharis lhc moleculdequalionoftne compound
X?

o) (2)