Volumen de Vol

NaOH pH Promedio ∆pH ∆V

0 2.41 0.25 0.12 0.5

0.5 2.53 0.75 0.04 0.5
1 2.57 1.25 0.02 0.5
1.5 2.59 1.75 0.04 0.5
2 2.63 2.25 0.03 0.5
2.5 2.66 2.75 0.03 0.5
3 2.69 3.25 0.05 0.5
3.5 2.74 3.75 0.06 0.5
4 2.8 4.25 0.09 0.5
4.5 2.89 4.75 0.11 0.5
5 3 5.25 0.12 0.5
5.5 3.12 5.75 0.2 0.5
6 3.32 6.25 0.36 0.5
6.5 3.68 6.75 0.67 0.5
7 4.35 7.25 0.850000000000001 0.5
7.5 5.20 7.75 0.59 0.5
8 5.79 8.25 0.39 0.5
8.5 6.18 8.75 0.24 0.5
9 6.42 9.25 0.1 0.5
9.5 6.52 9.75 0.16 0.5
10 6.68 10.25 0.2 0.5
10.5 6.88 10.75 0.12 0.5
11 7 11.25 0.11 0.5
11.5 7.11 11.75 0.23 0.5
12 7.34 12.25 0.100000000000001 0.5
12.5 7.44 12.75 0.18 0.5
13 7.62 13.25 0.13 0.5
13.5 7.75 13.75 0.16 0.5
14 7.91 14.25 0.19 0.5
14.5 8.1 14.75 0.24 0.5
15 8.34 15.25 0.26 0.5
15.5 8.6 15.75 0.24 0.5
16 8.84 16.25 0.4 0.5
16.5 9.24 16.75 0.26 0.5
17 9.5 17.25 0.300000000000001 0.5
17.5 9.8 17.75 0.01 0.5
18 9.81 18.25 0.029999999999999 0.5
18.5 9.84 18.75 0.01 0.5
19 9.85 19.25 0.1 0.5
19.5 9.95 19.75 0.17 0.5
20 10.12 20.25 0.050000000000001 0.5
20.5 10.17 20.75 0.060000000000001 0.5
21 10.23 21.25 0.07 0.5
21.5 10.3 21.75 0.09 0.5
22 10.39 22.25 0.039999999999999 0.5
22.5 10.43 22.75 0.040000000000001 0.5
23 10.47
Derivada Primera Derivada Segunda Curva titulación - Método Directo
(∆pH/∆V) ∆(∆pH/∆V)
12

0.239999999999999 -0.319999999999998
10
0.08 -0.08
0.04 0.08 8
0.08 -0.039999999999999
6

pH
0.060000000000001 -1.77635683940025E-15
0.06 0.080000000000002 4
0.100000000000001 0.039999999999997
0.119999999999999 0.120000000000003 2
0.180000000000001 0.079999999999998
0
0.22 0.040000000000001 0 5 10 15
0.24 0.319999999999998 Vol. NaOH (ml)
0.4 0.640000000000002
0.720000000000001 1.24
1.34 0.720000000000004
Derivada Primera (∆pH/∆V)
1.7 -1.04
1.8
∆pH/∆V
1.18 -0.800000000000001
1.6
0.779999999999999 -0.599999999999998
0.48 -0.560000000000002 1.4
0.199999999999999 0.240000000000002 1.2
0.32 0.16 1
0.4 -0.32
0.8
0.24 -0.039999999999999
0.220000000000001 0.479999999999997 0.6

0.459999999999999 -0.519999999999996 0.4

0.200000000000001 0.319999999999997 0.2
0.359999999999999 -0.199999999999999
0 Vol. NaOH (ml)
0.26 0.120000000000001 0 5 10 15
0.32 0.119999999999997
0.379999999999999 0.200000000000003
0.48 0.079999999999998
0.52 -0.079999999999998 Derivada Segunda ∆(∆pH/∆V)
∆(∆pH/∆V)

0.48 0.640000000000001 1.5

0.800000000000001 -0.560000000000002
1
0.52 0.160000000000004
0.600000000000001 -1.16
0.5
0.02 0.079999999999998
0.059999999999999 -0.079999999999998
0
0.02 0.359999999999999 0 5 10 15
0.199999999999999 0.280000000000001
-0.5
0.34 -0.479999999999997
0.100000000000001 0.039999999999999 -1
Vol. NaOH (ml)
-1.5
 0 5 10 15

-0.5

-1
0.120000000000001 0.039999999999999
Vol. NaOH (ml)
0.140000000000001 0.079999999999998 -1.5
0.18 -0.200000000000003
0.079999999999998 7.105427357601E-15
0.080000000000002 0.003516483516484
rva titulación - Método Directo
Método
Directo
Primera derivada
Segunda derivada

5 10 15 20
Vol. NaOH (ml)

Derivada Primera (∆pH/∆V)

Vol. NaOH (ml)

5 10 15 20

Derivada Segunda ∆(∆pH/∆V)

5 10 15 20

Vol. NaOH (ml)

5 10 15 20

Vol. NaOH (ml)

1er punto equivalencia 2do punto de equivalencia
7 ml 16,5 ml
7,25 ml 17,25 ml
6,25 ml 15,75 ml