OBJECTIVE CHEMISTRY PART-I 1

BASIC CONCEPTS
1
MULTIPLE CHOICE QUESTIONS

1. The mass of one mole of electron is:

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(a) 1.008 mg (b) 0.184 mg

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(c) 0.54 mg (d) 0.054 mg
2. 27 g of Al will react with how much mass of O2 to produce Al2O3:
(a) 8 g of oxygen (b) 16 g of oxygen
(c) 32 g of oxygen (d) 24 g of oxygen
3. The number of moles of NO2 which contains 16 g of oxygen:

4.
(a) 0.25
(c) 1.0
O (b) 0.50
(d) 1.50
The volume occupied by 2.0 g of Ne at STP:
(a) 2.24 dm3 (b) 22.4 dm3
O
(c) 1.12 dm3 (d) 112 cm3
5. A sample in the ionization chamber of mass spectrometer is ionized by:
(a) Electrons (b) Proton
H

(c) Neutron (d) Nucleus

6. Which one of the following pair is not iso-electronic:
(a) CO, N2 (b) Na+, Ne
SC

(c) Ca, Ar (d) K+, Ar

7. Which one of the following is not a molecular ion:
+ +
(a) N2 (b) CH4
+ +
(c) C6H8 (d) NH4

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OBJECTIVE CHEMISTRY PART-I 2
8. 180 g of glucose contains number of hydrogen atoms:
(a) 3.6  1023 (b) 6.0  1023
(c) 7.2  1023 (d) 7.2  1024
9. Who first of all determined atomic masses of elements:
(a) J. Berzelius (b) J.J. Thomson
(c) Johon Dalton (d) Democritus
10. The mass of H-atom is 1.008 a.m.u. Its mass in kg should be :
1.008
(a) 1.008  1.661  1023 kg (b) kg
1.661  1027
(c) 1.008  1.661  1027 kg (d) 1.661  1027 kg

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11. The atomicity of one molecule of Haemoglobin is:

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(a) 10,000 (b) 68,000
(c) 17,000 (d) 100,000
12. Formation of uninegative ion is:
(a) Exothermic (b) Endothermic
(c) Both (a) & (b) (d) None of these
13.

(c) Cd
O
Which of the following elements has nine isotopes:
(a) Ca (b)
(d)
Pd
Sn
O
14. Which of the following will form single peak in mass spectrograph:
(a) Iodine (b) Arsenic
(c) Fluorine (d) All of these
H

15. Which one of the following contains maximum no. of molecules:

(a) 16.0 g of CH4 (b) 16.0 g of O2
(c) 16.0 g of SO2 (d) 16.0 g of H2O
SC

16. Atoms of all the elements always contain in nucleus:

(a) Proton (b) Proton and neutron
(c) Neutron (d) Electron and neutron
17. Actual yield of a chemical reaction is always less than theoretical yield
because:

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OBJECTIVE CHEMISTRY PART-I 3
(a) Side reactions (b) Wastage of products
(c) Reversible reactions (d) All of these
18. Mass of sodium in 53 g of Na2CO3 is:
(a) 23 g (b) 46 g
(c) 92 g (d) 106 g
19. 20 moles each of Mg and O2 react to form MgO. The amount of MgO formed
would be:
(a) 20 g (b) 400 g
(c) 800 g (d) 1600 g
20. The number of peaks obtained in mass spectrometry shows:

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(a) Charge on isotope (b) Mass of isotope

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(c) Number of isotopes (d) Relative abundance of isotopes
21. Molecular mass of water (18 g) means:
(a) Mole (b) Gram mole
(c) Gram molecule (d) All of these
22. Which of the following ion formation is always exothermic:

23.
(a)
(c)
Uninegative
Dinegative
O (b)
(d)
Unipositive
Dipositive
The number of isotopes of elements with even mass number and even atomic
O
number are:
(a) 280 (b) 300
(c) 154 (d) 54
H

24. Which one of the following is not the mono isotopic element:
(a) Arsenic (b) Uranium
(c) Iodine (d) Gold
SC

25. Percentage of oxygen in calcium carbonate is:

(a) 40% (b) 48%
(c) 12% (d) 16%
26. Which one of the following substances is used as CO2 absorber in combustion
analysis:

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OBJECTIVE CHEMISTRY PART-I 4
(a) Mg(ClO4)2 (b) 50% KOH
(c) Lime water (d) Dilute NaOH
27. Which one of the following properties is always in whole number:
(a) Atomic mass (b) Atomic radius
(c) Atomic volume (d) Atomic number
28. What is the mass of one mole of Iodine:
(a) 53 g (b) 74 g
(c) 127 g (d) 254 g
29. 0.5 moles of H2SO4 contains “X” moles of oxygen atoms “X” is:
(a) 0.5 (b) 1.0

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(c) 2.0 (d) 4.0

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30. What will weigh more:
(a) 2 mole N2 (b) 1 mole O3
(c) 2 mole O2 (d) 2 mole CO2
31. The number of electrons in one mole of H2 is:
6.02  1023 3.01  1023

32.
(a)
(c)
+
12.04  1023
CO is an example of:
O (b)
(d) Indefinite
O
(a) Free radical (b) Cationic molecular ion
(c) Anionic molecular ion (d) Stable molecule
33. Relative atomic mass is the mass of an atom of an element as compared to the
mass of one atom of:
H

(a) Oxygen (b) Hydrogen

(c) Nitrogen (d) Carbon
SC

34. Percentage of oxygen in H2O is:

(a) 80% (b) 88.8%
(c) 8.8% (d) 9.8%
35. Large no of isotopes are known for the elements whose masses are multiple of:
(a) Two (b) Four

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OBJECTIVE CHEMISTRY PART-I 5
(c) Six (d) Eight
36. The least no of molecules is present in 30 g of:
(a) N2O (b) NO
(c) NO2 (d) N2O3
37. How many atoms of carbon are present in 18 g of glucose C6H12O6:
(a) 6.02  1022 (b) 3.6  1023
(c) 6.0  1023 (d) 3.6  1024
38. The relative atomic mass of oxygen according to C 12.000 a.m.u standard is:
(a) Less than 16 (b) More than 16

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(c) 16 only (d) No relationship
39. An organic compound contains 2% of sulphur. The molar mass of compound is:

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(a) 200 (b) 800
(c) 1600 (d) 3200
40. The mass of 0.5 mole of Aluminium is:
(a) 13 g (b) 13.5 g
(c) 14 g
O
(d) 27 g

answers
O
1. (c) 2. (d) 3. (b) 4. (a) 5. (a)
6. (c) 7. (d) 8. (d) 9. (a) 10. (c)
11. (a) 12. (a) 13. (c) 14. (d) 15. (a)
H

16. (a) 17. (d) 18. (a) 19. (c) 20. (c)
21. (d) 22. (a) 23. (c) 24. (b) 25. (b)
26. (b) 27. (d) 28. (d) 29. (c) 30. (d)
SC

31. (c) 32. (b) 33. (d) 34. (b) 35. (b)
36. (d) 37. (b) 38. (a) 39. (c) 40. (b)

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OBJECTIVE CHEMISTRY PART-I 235

CHEMICAL EQUILIBRIUM
8
MULTIPLE CHOICE QUESTIONS
1. The pOH of 103 mol. dm3 of H2SO4 solution is:

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(c) Ka (d) All of these
3. Strength of an acid is directly related to the value of:
(a) pKa (b) pH

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(c) Ka
The value of PKw at 25C is:
(a) 1014
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(b) 1014
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(c) 10 (d) 2  107
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(c) Moderate KC value (d) None of these
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(c) 1.85  1015 (d) 1.85  1020
8. The unit of “KC” for the reaction

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2 5(s)
2SO2(g) + O2(g) 2SO3(g) is:
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(c) 4 (d) Zero
10. pH of human blood is:
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(c) 7.85 (d) 6.65

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(c) 1014 (d) 14
13.

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(c) 3
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(c) Basic (d) Highly basic
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(c) Catalyst (d) None of these
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
(c) CaF2 2+
Ca + 2F (d) PbCl2 Pb2+ + 2Cl
17. The pH of soft drink is:
(a) > 7 (b) <7
(c) 7 (d) Zero

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OBJECTIVE CHEMISTRY PART-I 237
18. If [Salt] = [Acid] then pH of an acidic buffer will be:
(a) Equal to pKa (b) Less than pKa
(c) More than pKa (d) No effect on pH
19. For N2 + 3H2 2NH3
(a) KC = Kp (b) Kp = KC(RT)1
(c) Kp = KC(RT)2 (d) Kp = KC(RT)1
20. pH of a buffer solution having 0.01M CH3COONa and 0.1M CH3COOH
(pKa = 4.74) is:
(a) 4.74 (b) 3.74
(c) 5.74 (d) 0

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21. For which system does the equilibrium constant, KC has units of
(concentration)1:

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(a) N2 + 3H2 2NH3 (b) H2 + I2 2HI
(c) 2NO2 N2O4 (d) 2HF H2 + F2
22. The pH of 103 mol.dm3 of H3BO3 solution is:
(a) 3.0 (b) 2.7

23.
(c) 2.0

Ag+1 ions in the solution is:

O (d) 10.5
The Ksp of AgCl is 2.0  1010 mol2.dm6. The maximum concentration of
O
(a) 2.0  1010 mol-dm3 (b) 1.41  105 mol-dm3
(c) 1.0  105 mol-dm3 (d) 4.0  1020 mol-dm3
24. Unit of Kw are:
H

(a) mol-dm3 (b) mol2-dm6

(c) mol2-dm3 (d) mol2-dm+3
25. Buffer action can be explained by:
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(a) Common ion effect (b) Law of mass action

(c) Le-Chatlier’s principle (d) All of these
26. Solubility of Ca(OH)2 is exothermic, its solubility will increase:
(a) At high temperature (b) At low temperature

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OBJECTIVE CHEMISTRY PART-I 238
(c) Temperature independent (d) None
27. The substance which increases the rate of reaction, but remains unchanged
at the end of reaction is called:
(a) Indicator (b) Promoter
(c) Catalyst (d) Activated complex
28. The suppression of ionization of weak electrolyte in the presence of strong
electrolyte with one same ion is called:
(a) Hydration (b) Common ion effect
(c) Hydrolysis (d) Electrolysis
29. Which of the following will form a stable acidic buffer:

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(a) CH3COOH + NaOH (b) H2S + NaOH

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(c) NH4OH + HCl (d) Ca(OH)2 + HCl
30. Which of the following efforts will change KC for the reaction:
(a) Adding catalyst (b) Decreasing pressure
(c) Increasing concentration (d) Increasing temperature

1. (b) 2. (d)
O
answers
3. (c) 4. (c) 5. (d)
O
6. (a) 7. (a) 8. (b) 9. (a) 10. (b)
11. (c) 12. (d) 13. (a) 14. (a) 15. (a)
16. (a) 17. (b) 18. (a) 19. (c) 20. (b)
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21. (c) 22. (a) 23. (b) 24. (b) 25. (d)
26. (b) 27. (c) 28. (b) 29. (a) 30. (d)
SC

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OBJECTIVE CHEMISTRY PART-I 271

SOLUTIONS
9
MULTIPLE CHOICE QUESTIONS

1. 18 g glucose is dissolved in 90 g of water. The relative lowering of vapour

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pressure is equal to:

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1
(a) 5 (b) 5.1

1
(c) (d) 6
51
2. A solution of glucose is 10%. The volume to which 1g mole of it dissolved will be:

3.
(a) 1 dm3
(c) 200 cm3
O (b) 1.8 dm3
(d) 900 cm3
Which of the following liquid pairs will obey the Raoult’s law:
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(a) C2H5OH + H2O (b) CH3COCH3 + CHCl3
(c) C2H5I + C2H5Br (d) HCl + H2O
3
4. 10g of NaOH has been dissolved per dm of solution. The molarity of solution is:
(a) 0.5 M (b) 0.25 M
H

(c) 1 M (d) 2 M
5. The sum of mole fraction of all the components of solution is always equal to:
SC

(a) Unity (b) 100

(c) Less than one (d) Less than 100
6. Which of the following concentration unit is used for very dilute solutions:
(a) Molarity (b) Normality
(c) Molality (d) ppm

educatedzone.com
OBJECTIVE CHEMISTRY PART-I 272
7. Which of the following is affected by temperature change:
(a) Molality (b) Molarity
(c) Mole fraction (d) None of these
8. The substance which has water of crystallization in it, is called:
(a) Hydrate (b) Hydride
(c) Hydrolysis (d) Complex
9. Hydrolysis of CH3COOK will produce:
(a) Acidic solution (b) Basic solution
(c) Neutral solution (d) None of these
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10. The molarity of 2% NaOH solution is:

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(a) 2 (b) 0.25
(c) 0.05 (d) 0.5
11. If 9.8g H2SO4 is present in one dm3 of solution, the solution is:
(a) 0.1 N (b) 0.1 M
(c) 0.1 m (d) 0.5 M
12.

(c) Na2SO4
O
Which one of the following salts do not hydrolyse:
(a) CuSO4 (b)
(d)
Na2CO3
Al2(CO3)3
O
13. An aqueous solution boil at 100.52C. It should freeze at:
(a) 0C (b) 1.86C
(c) 2C (d) +1.86C
H

14. 15g urea is dissolved in 180 cm3 of water. The relative lowering of vapour
pressure will be:
(a) 0.024 (b) 25.024
SC

(c) 2.5 (d) 10.25

15. Which has maximum freezing point:
(a) 1m NaCl (b) 1m KCl
(c) 1m CaCl2 (d) 1m Urea
16. Which cation has least heat of hydration:

educatedzone.com
OBJECTIVE CHEMISTRY PART-I 273
+ +
(a) Li (b) Na
+
(c) K (d) Mg+2
17. 10% aqueous solution of glucose freezes at:
(a) 0C (b) Less than 0C
(c) Greater than 0C (d) Greater than 10C
18. A mixture of benzene and toluene form:
(a) Ideal solution (b) Non-ideal solution
(c) Azeotropic mixture (d) Suspension
19. Which pair of mixture is called ideal solution:
(a) C6H5Cl + C6H5Br (b) H2O + C2H5OC2H5

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(c) C2H5OH + H2O (d) HCl + H2O

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20. In a solution 7.8g benzene and 46g toluenc (C6H5CH3) is present, the mole
fraction of benzene is:
1 1
(a) 2 (b) 3

1 1
(c) (d)
5 6
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answers
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1. (c) 2. (b) 3. (c) 4. (b) 5. (a)
6. (d) 7. (b) 8. (a) 9. (b) 10. (d)
11. (b) 12. (c) 13. (b) 14. (a) 15. (d)
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16. (c) 17. (b) 18. (a) 19. (a) 20. (d)
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