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Material Safety Data Sheet

According to Regulation (EC) No. 1907/2006

ARKARESIN 651 CONC

Version:1.1 Revision Date: 08.06.2020 Print Date: 08.06.2020

SECTION 1: Identification of the substance/mixture and of the company/undertaking


1.1 Product identifier
Trade Name : ARKARESIN 651 CONC

1.2 Relevant identified uses of the substance or mixture and uses advised against
Use of the Substance/Mixture : Textile auxiliary

1.3 Details of the supplier of the safety data sheet


Company : PT. ARKATAMA PRIMA WARNA
Address : Pondok Bukit Agung F/16.
Sumurboto. Banyumanik.
Semarang. 50269. Central Java.

Telephone : +62 24 76405553


Fax : +62 24 76406152
E-mail address : arkatamaprimawarna@gmail.com

SECTION 2: Hazards identification


2.1 Classification of the substance or mixture
Classification (REGULATION (EC) No 1272/2008)
No hazard classification according to GHS Guidelines.

2.2 Label elements


Labelling (REGULATION (EC) No 1272/2008)
Hazard pictograms :

Signal word : Warning


Hazard statements : H302 Harmful if swallowed

Precautionary statements : Prevention:


P264 Wash skin thoroughly after handling.
P270 Do not eat, drink or smoke when using
this product
P280 Wear protective gloves and eye/face
protection.
P243 Take precautionary measures
against static discharge

Response:
P301+P330+P331 IF SWALLOWED: Rinse mouth. Do
NOT induce vomiting
P304+P312+P340 Remove person to fresh air and keep
comfortable for breathing.

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Material Safety Data Sheet
According to Regulation (EC) No. 1907/2006

ARKARESIN 651 CONC

Version:1.1 Revision Date: 08.06.2020 Print Date: 08.06.2020

IF SKIN AND EYE CONTACT:


Rinse immediately with plenty water.
Call a POISON CENTER or
doctor/physician if you feel unwell.
Disposal:
P501 Dispose of contents/ container to
an approved waste disposal plant.
2.3 Other hazards
The substance/mixture contains no components considered to be either persistent,
bioaccumulative and toxic (PBT) or very persistent and very bioaccumulative (vPvB) at levels
of 0.1% or higher.

SECTION 3: Composition/information on ingredients


3.1 Mixtures
Chemical nature : Bis (methoxymethyl)dihydroxyethylene urea with
specific catalyst.

SECTION 4: First aid measures


4.1 Description of first aid measures
General advice : If you feel unwell, seek medical advice (show the label
where possible).
Show this safety data sheet to the doctor in attendance.
Take off contaminated clothing and shoes immediately.
If inhaled : Move to fresh air.
If breathing is difficult, remove victim to fresh air and
keep at rest in a position comfortable for breathing.
Obtain medical attention.
In case of skin contact : Immediately wash with water and soap.
Take off contaminated clothing and shoes immediately.
If symptoms persist, call a physician immediately.
In case of eye contact : If easy to do, remove contact lens, if worn.
Rinse immediately with plenty of water, also under
the eyelids.
Get medical attention immediately.

If swallowed : IF SWALLOWED: Rinse mouth. Do NOT induce


vomiting.
IF SWALLOWED: Immediately call a POISON
CENTER/doctor.
If a person vomits when lying on his back, place him in
the recovery position.
Material Safety Data Sheet
According to Regulation (EC) No. 1907/2006

ARKARESIN 651 CONC

Version:1.1 Revision Date: 08.06.2020 Print Date: 08.06.2020

4.2 Most important symptoms and effects, both acute and delayed
Symptoms : No information available.
Risks : No information available.
4.3 Indication of any immediate medical attention and special treatment needed
Treatment : No information available.

SECTION 5: Firefighting measures


5.1 Extinguishing media
Suitable extinguishing media : Product is compatible with standard fire-fighting
agents
5.2 Special hazard arising from the substance or mixture
Specific hazards during : Do not use a solid water stream as it may scatter and
firefighting spread fire.
Hazardous decomposition products formed under fire
conditions.
Exposure to decomposition products may be a hazard
to health.
5.3 Advice for firefighters
Special protective equipment : Wear self-contained breathing apparatus
for firefighters for firefighting if necessary.
Further information : Standard procedure for chemical fires.
Use extinguishing measures that are appropriate to
local circumstances and the surrounding
environment. In the event of fire and/or explosion do
not breathe fumes.
Collect contaminated fire extinguishing water
separately. This must not be discharged into
drains. Fire residues and contaminated fire
extinguishing
water must be disposed of in accordance with
local regulations.

SECTION 6: Accidental release measures


6.1 Personal precautions, protective equipment and emergency procedures
Personal precautions : Use personal protective equipment. Avoid contact
with skin and eyes.
6.2 Environmental precautions
Environmental precautions : Do not flush into surface water or sanitary
sewer system.
Prevent further leakage or spillage if safe to do so.
If the product contaminates rivers and lakes or
Material Safety Data Sheet
According to Regulation (EC) No. 1907/2006

ARKARESIN 651 CONC

Version:1.1 Revision Date: 08.06.2020 Print Date: 08.06.2020

drains inform respective authorities.


Material Safety Data Sheet
According to Regulation (EC) No. 1907/2006

ARKARESIN 651 CONC

Version:1.1 Revision Date: 08.06.2020 Print Date: 08.06.2020

6.3 Methods and material for containment and cleaning up


Methods for cleaning up : Soak up with inert absorbent material (e.g. sand,
silica gel, acid binder, universal binder, sawdust).
Keep in suitable, closed containers for
disposal. Clean contaminated surface
thoroughly.
6.4 Reference to other sections
For personal protection see section 8., For disposal considerations see section 13.

SECTION 7: Handling and storage


7.1 Precautions for safe handling
Local / Total Ventilation : Use only with adequate ventilation.
Advice on safe handling : For personal protection see section
8. Do not breathe vapor or spray
mist. Avoid contact with skin and
eyes.
Advice on protection against fire : Normal measures for preventive fire protection.
and explosion
Hygiene measures : Handle in accordance with good industrial hygiene
and safely practice. Avoid contact with skin, eyes and
clothing. When using do not eat, drink or smoke.
Wash hands before breaks and at the end of
workday. Wash contaminated clothing before re-
use.
Dust explosion class : Not applicable.
7.2 Conditions for safe storage, including any incompatibilities
Requirements for storage : Keep containers tightly closed in a dry, cool and well-
areas and containers ventilated place.
Advice on common storage : Keep away from food and drink.
Storage class (TGRS 510) : No data available.
Other data : Protect from heat and direct sunlight.
7.3 Specific end use(s)
Specific end use(s) : For further information, refer to the product technical
data sheet.

SECTION 8: Exposure Controls/ Personal Protection


8.1 Control parameters
Material Safety Data Sheet
According to Regulation (EC) No. 1907/2006

ARKARESIN 651 CONC

Version:1.1 Revision Date: 08.06.2020 Print Date: 08.06.2020

Occupational Exposure Limits


The product does not contain any relevant quantities of materials with critical values that
have to be monitored at the workplace.
8.2 Exposure controls
Personal protective equipment
Eye protection : Googles
Hand protection
Material : Protective gloves complying with EN 374.
Remarks : Choose gloves to protect hands against chemicals
depending on the concentration and quantity of the
hazardous substance and specific to place of work.
For special applications, we recommend clarifying the
resistance to chemicals of the aforementioned
protective gloves with the glove manufacturer.
Skin and body protection : Choose body protection according to the amount
and concentration of the dangerous substance at
the workplace.

Respiratory protection : In case of insufficient ventilation, wear suitable


respiratory equipment.

Protective measures : Handle in accordance with good industrial hygiene and


safety practice.
Follow the skin protection plan.

SECTION 9: Physical and chemical properties


9.1 Information on basic physical and chemical properties
Designation Value
Appearance : Clear to turbid liquid
Colour : Yellowish
Odour : Weak, characteristic
Odour Threshold : No data available.
pH Value : 2.0 – 3.0
Melting point/freezing point : No data available.
Initial Boiling Point/ Boiling : > 100oC
range
Flash point : > 100oC (DIN 51 758)
Auto-ignition : > 200oC (DIN 51 794)
Evaporate rate : Not determined
Flammability (solid, gaseous) : Product is not inflammable
Evaporation rate : No data available.
Upper explosion limit : No data available.
Lower explosion limit : No data available.
Vapour pressure : No data available.
Material Safety Data Sheet
According to Regulation (EC) No. 1907/2006

ARKARESIN 651 CONC

Version:1.1 Revision Date: 08.06.2020 Print Date: 08.06.2020

Relative density : No data available.


Density (25oC) : 1.270 – 1.320 g/cm3
Water solubility : Emulsifiable (20°C)
Partition coefficient; n-octanol/ : No data available.
water
Self-inflammability : Product is not self-igniting
Decomposition temperature : No data available.
Viscosity, kinematic : No data available.
Explosive properties : No data available.
Oxidizing properties : No data available.

9.2 Other information


Dust explosion class : Not applicable.

SECTION 10: Stability and reactivity


10.1 Reactivity
No decomposition if stored and applied as directed.
10.2 Chemical stability
No decomposition if stored and applied as directed.
10.3 Possibility of hazardous reactions
Hazardous reactions : No dangerous reactions known.
10.4 Conditions to avoid
Conditions to avoid : No decomposition if used according to specifications.
10.5 Incompatible materials
Materials to avoid : Strong acids.
10.6 Hazardous decomposition products
Hazardous : No decomposition if stored and applied as
decomposition products directed. Thermal decomposition can lead to
release of irritating gases and vapours.
In case of fire hazardous decomposition products
may be produced such as:
Carbon dioxide (CO2), carbon monoxide (CO), oxides
of nitrogen (NOx), dense black smoke.
Other hazardous decomposition products may
be formed.

SECTION 11: Toxicological information


11.1 Information on toxicological effects
Acute toxicity
Acute oral toxicity : LD/LC50: > 2000 mg/kg
Material Safety Data Sheet
According to Regulation (EC) No. 1907/2006

ARKARESIN 651 CONC

Version:1.1 Revision Date: 08.06.2020 Print Date: 08.06.2020

Acute inhalation toxicity : No data available.


Acute dermal toxicity : No data available.

Skin corrosion/irritation
Skin corrosion/ irritation : Not irritating.
Serious eye damage/eye irritation
Serious eye damage/eye irritation : Not irritating.
Respiratory or skin sensitisation
Respiratory or skin sensitisation : No sensitizing effect known.

Germ cell mutagenicity


Germ cell mutagenicity- : No data available.
Assessment
Carcinogenicity
Carcinogenicity-Assessment : No data available.
STOT –single exposure
STOT –single exposure : No data available.
STOT –repeated exposure
STOT –repeated exposure : No data available.
Aspiration toxicity
Aspiration toxicity : No data available.
Further information
Further information : When used and handled according to
specifications, the product does not have any
harmful effects, according to our experience and
the information provided to us.

SECTION 12: Ecological information


12.1 Toxicity
Toxicity to fish : LD 50 (Brachydanio rerio): 960 mg/l
Exposure time: 96 hrs
Method: OECD Test Guideline 203
Toxicity to daphnia and : EC50 (Daphnia magna (Water Flea)): : 7740 mg/l
other aquatic invertebrates Exposure time: 24 hrs
Result: immobilization
Method: OECD Test Guideline 202
Toxicity to bacteria : EC50 (Photobacterium phosphoreum): 13.700 mg/l
Material Safety Data Sheet
According to Regulation (EC) No. 1907/2006

ARKARESIN 651 CONC

Version:1.1 Revision Date: 08.06.2020 Print Date: 08.06.2020

Remarks: If contamination effluent water is properly


entered into the sewage system, any interference
with the degrading activity of the activated sludge
organisms must not be expected.

12.2 Persistence and degradability


Biodegradability : The product is slightly biodegradable.
Degree of elimination 66% (COD elimination, method
OECD 302B (Zahn-Wellens-Test, 28 d).

Biological Oxygen Demand : 27 mg/g


(BOD) Incubation time: 5 d

Chemical Oxygen Demand : 508 mg/g


(BOD) Incubation time: 5 d

12.3 Bioaccumulative potential


Bioaccumulation : No data available.

12.4 Mobility in soil


Mobility : Medium: soil
No data available.

12.5 Results of PBT and vPvB assessment


Assessment : No data available.

12.6 Other adverse effects


Adsorbed organic halogens : The product does not increase the AOX-values in the
(AOX) wastewater

Additional ecological : According to our knowledge, the product does not


information contain heavy metals and other compounds of the
EC Directive 2000/60 EC.
The product should not be allowed to enter
drains, water courses or the soil.

SECTION 13: Disposal considerations


13.1 Waste treatment methods
Product : Product must be disposed of according to local
regulations pertaining to the disposal of
hazardous waste.

Contaminated packaging : Empty containers should be taken an approved


waste handling site for recycling or disposal.
Dispose of as unused product.
Material Safety Data Sheet
According to Regulation (EC) No. 1907/2006

ARKARESIN 651 CONC

Version:1.1 Revision Date: 08.06.2020 Print Date: 08.06.2020

SECTION 14: Transport information


14.1 UN number
ADR : Not dangerous goods
RID : Not dangerous goods
IMDG : Not dangerous goods
IATA : Not dangerous goods
14.2 Proper shipping name
ADR : Not dangerous goods
RID : Not dangerous goods
IMDG : Not dangerous goods
IATA : Not dangerous goods
14.3 Transport hazard class
ADR : Not dangerous goods
RID : Not dangerous goods
IMDG : Not dangerous goods
IATA : Not dangerous goods
14.4 Packing group
ADR : Not dangerous goods
RID : Not dangerous goods
IMDG : Not dangerous goods
IATA : Not dangerous goods
14.5 Environmental hazards
ADR : Not dangerous goods
RID : Not dangerous goods
IMDG : Not dangerous goods
IATA : Not dangerous goods
14.6 Special precautions for user
Not applicable.
14.7 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable for product as
supplied.

SECTION 15: Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or
mixture
REACH - Candidate List of Substances of Very : Not applicable.
High Concern for Authorisation (Article 59).

Regulation (EC) No 1005/2009 on substances that : Not applicable.


deplete the ozone layer
Material Safety Data Sheet
According to Regulation (EC) No. 1907/2006

ARKARESIN 651 CONC

Version:1.1 Revision Date: 08.06.2020 Print Date: 08.06.2020

Regulation (EC) No 850/2004 on persistent organic : Not applicable.


pollutants

Seveso III: Directive 2012/18/EU of the European Parliament and of the Council on the
control of major-accident hazards involving dangerous substances.
: Not applicable.

Designation according to EC : The product has been classified and labelled in


guidelines accordance with EC Directive and the Ordinance on
Hazardous Materials (CHIP) Observe the normal
safety regulations when handling chemicals.
15.2 Chemical Safety Assessment
No data available.

SECTION 16: Other information


Full text of H-Statements
H302 : Harmful if swallowed.

The information provided in this Safety Data Sheet is correct to the best of our knowledge,
information and belief at the date of its publication. The information given is designed only
as a guidance for safe handling, use, processing, storage, transportation, disposal and release
and is not to be considered a warranty or quality specification. The information relates only
to the specific material designated and may not be valid for such material used in
combination with any other materials or in any process, unless specified in the text.
This safety datasheet only contains information relating to safety and does not replace any
product information or product specification.

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