Professional Documents
Culture Documents
Authors:
DEPARTMENT OF CHEMISTRY
THE FACULTY OF MATHEMATICS AND NATURAL SCIENCE
LAMPUNG UNIVERSITY
2018
1
TABLE OF CONTENTS
Unit 5. ENERGY.............................................................................................20
Unit 1
Activity 1.
CHEMISTRY TODAY
To make it simple, chemistry is the study of matters, their properties, their changes,
and the energy which accompany any change of matter (1). The effects of chemistry,
for better or worse, are all around you and within you (2). Your body functions by a
complicated series of chemical processes, which are only partly understood (3).
There are thousands of man-made chemicals to treat the symptoms or even the causes
of illness, to eliminate a headache, or even to stop the spread of a cancer (4). You
walk on carpets of synthetic fibers, and the same synthetic fibers are in many kinds of
clothing (5). You also use household chemicals to clean, polish, and bleach (6). To
feed the expanding population of our earth, agriculture must be expanded and made
more efficient (7). The discovery of a process to manufacture ammonia cheaply has
had a enormous impact on the world, since ammonia and its salts are necessary for
making fertilizers (8). Since then, chemists have developed herbicides, pesticides,
and fungicides, without which large-scale production of foodstuffs would simply not
be possible (9). The continuous development of chemistry we see today is possible
as a result of contribution of many chemists, who devoted their life to this field (10).
As an example, the American chemist Linus Pauling was awarded the Noble Prize in
Chemistry in 1954 for developing new ideas on the bonding of atoms, helping the
synthesis of numerous chemicals we know today (11). In this modern era, we can see
that every aspect of live, even politics and international relations, is affected by
chemistry (12).
3
Questions:
1. According to the passage, what is the main object of chemistry?
2. How the discovery of ammonia affects the agriculture?
3. What are the examples of household chemicals we use in every day live?
4. What are the examples of man-made chemicals mentioned in the text?
5. What is an example of chemical process in our body?
Activity 2.
Learn the following words and use them in your own sentences.
1. Chemical .................................................................................................
2. Synthetic .................................................................................................
3. Chemical process ...................................................................................
4. Impact .....................................................................................................
5. Expand ....................................................................................................
6. Discovery ................................................................................................
Noun Verb
Development
Fertilizers
Clothing
Production
Food
4
Direction: Choose the correct answer in the incomplete sentences, and choose the
incorrect answer in the underlined choices.
4. The labor organization……….by the workers ten years ago has grown to a
current membership of more than two million.
A. found
B. founded
C. was found
D. was founded
5
5. According to the law in Indonesia, if a person does not have an attorney, the court
…….one.
A. will appoint
B. appointed
C. would appoint
D. appointing
6. On the first try, most people are failing to pass the test for driving
A B C D
license.
10. Indonesia has import all carpet wools in recent years because
A B C
domestic wools are too fine and soft for carpet
D
6
Present Tenses
Intermezzo:
The end of a Dream
Tired of sleeping on the floor, a young man saved up for years to buy a real bed. For
the first time in his life, he became the proud owner of a bed which had springs and a
mattress. Because the weather was very hot, he carried the bed on to the roof of his
house. He slept very well for the first two nights, but on the third night, a storm blew
up. A gust of wind swept the bed off the roof and sent it crashing into the courtyard
below. The young man did not wake up until the bed had struck the ground.
Although the bed was smashed to pieces, the man was miraculously unhurt. When he
woke up, he was still on the mattress. Glancing at the bits of wood and metal that lay
around him, the man sadly picked up the mattress and carried it into his house. After
he had put it on the floor, he promptly went to sleep again
7
Unit 2
Activity 1.
Read the following text and answer the exercise that follows.
The general definition of matter is anything that has mass and occupies space,
consists not only of things that we can see and touch, but also such things as air,
which we cannot see (2). Matter can exist in three phases, namely solid, liquid, and
gas, but several kinds of matter can exist in all three phases, even simultaneously
under special conditions (3). A solid consists of particles arranged into a definite and
rigid shape that does not change much with temperature (4). A liquid also has a
definite volume, but unlike a solid, a liquid does not have a shape of its own (5). The
particles making up a liquid may flow to assume the shape of the container (6). A
liquid changes volume only to a small extent, although often to a greater extent than a
solid (7). In contrast with a solid or liquid, the particles of a gas completely fill any
container (8). If the container is not rigid, changes in temperature can lead to large
changes in the volume of a gas (9). Another important difference is that gases can be
expanded and compressed over enormous ranges of volume (10). This property
suggests that the particles of a gas are much more widely separated from one another
than the particles of a liquid or solid (11).
Exercise:
1. Write the basic properties of solid mentioned in the text.
2. What is special conditions in sentence 3 refer to?.
3. What is the similarity of solid and liquid mentioned in the text?.
4. What is the meaning of compressed mentioned in sentence 10?.
5. What are the differences between gas and solid and liquid mentioned in the
text?.
8
Activity 2.
Learn the following words and use them in your own sentences.
1. Solid ........................................................................................................
2. Liquid ......................................................................................................
3. Gas .........................................................................................................
4. Phase ......................................................................................................
5. Particles ..................................................................................................
6. Simultaneously........................................................................................
Verb Noun
Change
Arrange
Suggest
Compress
Expand
Direction: Choose the correct answer in the incomplete sentences, and choose the
incorrect answer in the underlined choices
Past Tenses
2.
a. I was watching Extravaganza at eight o’clock Past
last Saturday. Continuous
Tense
b. Kartini was dining with grilled petai while Kartono
(6)
was smooking Gudang Garam last night.
c. Kartini was frying salted fish when Kartono came
to visit her”
3. After Kartini had finished her homework, Past Perfect Tense (7)
she went to bed”.
Past Perfect
4. Neng Geulies had been studying for two years
ContinuousTense
at the University of Antah Berantah before
(8)
she enrolled in Chemistry Department in 2006”.
11
Unit 3
Activity 1.
Read the following text and answer the exercise that follows
One of the requirements for successful studying of chemistry is to realize that there
are many terms that we must learn to use, and some of them are necessary from the
beginning (1). It is then important to know some basic definitions we need from the
beginning of the study (2). Atom is the smallest particle of an element that retains the
chemical properties of the element (3). All matter is composed of different kinds of
atoms, and matter that is composed of only one kind of atom is known as an element
(4). In modern time, each of more than a hundred known elements is given a name
and chemical symbol, to simplify the presentation of elements in many purposes (5).
A compound is composed of two or more atoms chemically combined in definite
proportions (6). A molecule is the smallest unit of a compound that retains the
chemical characteristics of the compound (7). Most of the research done in chemistry
involves the study of the transformation of one compound into another, so you will
spend much of your time examining molecules: their shapes, the forces holding them
together, and their chemical and physical properties (8). A substance is a form of
matter that has a definite composition (9). Table salt or sugar, the oxygen and
nitrogen of the air, or diamonds (pure carbon) are several examples of substance (10).
Each of these substances differs from the other by its composition, its taste or smell,
or its ability to dissolve in water (11). A mixture is a combination of two or more
substances in which each substance retains its identity (12). A cup of coffee, with
sugar and milk, is a mixture of many substances, as is a soft drink, or a piece of
cement (13). A mixture can be homogeneous or heterogeneous (14). A homogeneous
12
mixture has the same composition throughout the mixture (15). If you stir table salt
into pure water, the salt dissolves and the mixture is a homogenous solution (16). A
solution is homogeneous mixture of two or more substance (17). The material
dissolved is called the solute and the medium in which it is dissolved is solvent (18).
A mixture of solid grains of a compound salt and grains of sand is heterogeneous,
since particles of each component of the mixture remain separate and can be observed
as individual substance (19). In either a homogeneous or a heterogeneous mixture,
the components can be separated into pure substances by physical means, that is,
without changing the specific atom ratios within the particles (20). For example, the
component of the solution of nickel in water could be separated by evaporating the
water to leave the nickel compound as a green solid (21). Pure liquid water can be
recovered by condensing water vapor (22). Components of a heterogeneous mixture
can also be separated physically (23). The component of a mixture can also be
separated by chemical means, but this involves changing the atom ratio within the
compounds (25). This is often done in chemical analysis, where the components of a
mixture are transformed into new substances that can in turn be observed or separated
by physical means (26).
Activity 2.
Use your own word as much as possible to write the definition of the following
terms.
1. Molecule .................................................................................................
2. Solution ...................................................................................................
3. Solute ......................................................................................................
4. Mixture ....................................................................................................
5. Physical means .......................................................................................
6. Chemical means .....................................................................................
13
Choose the word or phrase from column 2 which best indicates the meaning of the
word in column 1 based on the text above.
Column 1 Column 2
5.Not only…….generates electrical energy, but it also produces energy for other
fission reactors.
A. A nuclear breeder reactor
B. It is a nuclear breeder reactor
C. Is a nuclear breeder reactor
D. Does a nuclear breeder reactor
6. Some metals such gold, silver ,copper, and tin occur naturally d
A B C
and are easy to work
D
7. In Indonesia, rice is cultivated more than any the other food
A B C
crops.
D
8 Because the price of fossil fuels, and the concern that they
A B
might run out, many countries have been investigating alternative
C D
sources of energy.
15
Future Tenses
1. At the end of this semester, Inem will marry Simple Future Tense
the sleepy Kartono. (9)
Unit 4
Activity 1.
Read the following text and answer the exercise that follows
Your friends recognize you by your physical appearance: height, weight, hair color,
and so on (1). The same is true for chemical substance (2). Each substance has a set
of physical properties, properties that can be measured and observed without
changing the atom ratios within the substance (3). Such properties include color, the
temperature in which a substance melts or boils, density, and physical state (4). As
an example, elemental bromine and iodine clearly differ from one another in their
color and physical state (5). Chemical properties, on the other hand, are properties
that matter exhibits when it undergoes a change in atom ratios within the particles (6).
When gasoline burns in your automobile engine or metals corrode, their chemical
composition changes (7) The physical properties of substance can be classified
further as extensive and intensive (8). Extensive properties are those that depend on
the amount of matter present (9). Thus, the volume and mass of a sample are
extensive properties, as they both are directly proportional to the amount matter in the
sample (10). In contrast, intensive properties do not depend on the amount of sample;
they are the same, no matter what the sample size (11). The temperature at which a
sample melts and the color of a material is both intensive properties (12). Water is
colorless and freezes at 00 C, whether you have a spoonful or a ton of it (13). No two
substances have the same combination of chemical and physical properties under the
same conditions, so we can use these differences to identify substances (14). Many of
the physical properties of oxygen and nitrogen are very similar; for example, both are
17
colorless gases at room temperature (15). However, a burning match will go out if it
is put into a flask of nitrogen, but it will burn brightly in oxygen (16). Thus, although
have the same physical properties, the two gases have different chemical properties
(17).
Activity 2.
Learn the following words and use them in your own sentences.
1. Colorless .................................................................................................
2. Exhibit .....................................................................................................
3. Physical properties ................................................................................
4. Extensive properties ...............................................................................
5. Undergoes ..............................................................................................
6. Corrode ...................................................................................................
7. Composition
8. Melt
Fill column 2 with the synonym of the words in column 1 in the following table.
Column 1 Column 2
Exhibit
Classified
Amount
Properties
Present
Measured
Size
Ratio
18
Direction: Choose the correct answer in the incomplete sentences, and choose the
incorrect answer in the underlined choices.
1. The Health Department will not permit the usage of a new drug until it has been
proven conclusively that the effects …… rats can be generalized for human
beings.
A. in
B. at
C. for
D. on
2 . ……… a statistician is employed to tabulate the variables, the effectiveness of a
project on a general population is difficult to measure.
A. Unless
B. With
C. Because
D. Since
3. In biology, the classification of plants begins with those …….the simplest
structures and progresses up to the most highly organized forms.
A. which having
B. that having
C. having
D. are having
4. With …….. .. technology for desalination, saline water could be treated to obtain
fresh water.
A. developing of
B. developed of
C. the development of
D. developed for
19
7. The visible range of lights for human beings lying between 400
A B C
and 900 nanometer wavelength.
D
Unit 5
Activity 1.
Read the following text and answer the exercise that follows
ENERGY
Energy can be defined as the capacity for doing work, where work is simply the
process of causing matter to move against an opposing force (1). For example, when
we pump up a bicycle tire, we are doing work-we are moving matter (the air in the
pump) against the opposing force of the air already in the tire (2). Like matter,
energy exists in different forms (3). The energy for running the pump to carry out the
work of pumping up a tire could be chemical energy released in our muscles as we
use a hand pump, electrical energy used to drive an electric motor on a compressor, or
heat used in a steam engine running a compressor. Light is also a form of energy (4).
Solar cells can convert light into electrical energy, which could run our compressor or
do other work (5).
Energy can be further classified as either potential energy or kinetic energy (6). Since
one definition of energy is the capacity for doing work, potential energy is the
potential for doing work (7). A piece of matter is said to possess potential energy by
virtue of its position, condition or composition (8). Water at the top of a waterfall
possesses potential energy because of its position; if it falls in a hydroelectric plant, it
does work that leads to the production of electricity (9). A compressed spring,
because of its condition, possesses potential energy and can do work such as making
a clock run (10). Natural gas possesses potential energy (11). Because of its
composition, it will burn, producing heat, another kind of energy (12). When a body
21
is in motion, it also has energy, or the capacity for doing work (13). The energy that a
body possesses because of its motion is called kinetic energy (14). As water falls
from the top of a waterfall, its potential energy becomes kinetic energy (15).
Questions:
1. According to the passage, what is the opposing force?.
2. How the body produce work?.
3. What are the examples of energy mentioned in the text?.
4. How does the waterfall produce electrical energy?.
5. What is the opposing force when you climb a tree?.
Activity 2.
Learn the following words and use them in your own sentences.
1. Capacity .................................................................................................
2. Waterfall ..................................................................................................
3. Compressor ............................................................................................
4. Heat ........................................................................................................
5. Potential ..................................................................................................
Fill column 2 with the synonym of the words in column 1 in the following table.
Column 1 Column 2
Definite
Make up
Enormous
Widely
Lead to
posses
22
Direction: Choose the correct answer in the incomplete sentences, and choose the
incorrect answer in the underlined choices
1. With the support of high technology, microwaves are used for many purposes
including cooking, telecommunications, and………….
A. To diagnose medically
B. Medical diagnosing
C. Diagnosed medically
D. Medical diagnosis
4. When subjected to very high temperature, many metals produce flame with the
color depends on the heat and…….
A. how much energy produced
B. the energy it produces
C. production of the energy
D. producing energy
5. Liquid natural gas is produced from natural gas, which often occurs
in the sandstone and limestone…..
A. both together with petroleum
B. both together petroleum
C. together with petroleum
D. both with petroleum
23
6. Antioxidants are not only popular in the United States but also in
A B C
many countries around the world.
D
7. As a first aid for treating minor diarrhea, drink plenty of liquids,
A B
such as, tea, eat soup and banana, and avoiding milk and butter.
C D
9. The maintenance of posture and move the body are the main
A B C
functions of the cerebellum.
D
10. Blood plasma it is the transportation system for all of the widely
A B C
separated organs in the human body.
D
24
Unit 6
Activity 1.
Read the following text and answer the exercise that follows
CHEMICAL EQUATION
The main functions of the equation are to represent the change that have taken place
in the substance involved and tell the reader as much as possible about these changes
(8). The type of equations to be used depends upon how much information is need in
a given situation (9). Each type of equation conveys a different message as shown by
the following reaction between calcium chloride and sodium phosphate (10).
The reaction above tells us that, when calcium chloride and sodium phosphate react
together, they do so in the proportion of 3 moles of calcium chloride to 2 moles of
sodium phosphate (11). The products of this reaction are sodium chloride and
25
calcium phosphate in the proportion of 6 moles to 1 mole (12). Assuming that the
reactants and the products are known, the most important point to be considered in a
chemical equation is the relative quantity of each substance involved in the reaction
(13). An equal number of each kind of atom present in the reactant must appear in the
product, as required by the conservation of mass principle (14).
Activity 2.
Learn the following words and use them in your own sentences.
Activity 3.
Write true (T) or false (F) for each of the following statements.
Direction: Choose the correct answer in the incomplete sentences, and choose the
incorrect answer in the underlined choices
1. Some measurement units from ancient time, such as the barrel and the
pound,………..in modern practices.
A. still are in use
B. are still in use
C. which are still in use
D. which are in use still
2. Paper money ………..by the government in order to reduce cost and avoid misuse
of metallic coins.
A. was issuing
B. which was issued
C. was issued
D. issued
3. Even during favorable conditions for growth, the observations by botanists have
revealed ………..a period of dormancy.
A. that seeds exhibiting
B. that seeds exhibit
C. which seeds exhibit
D. seed that exhibit
4. The jet stream………..commonly takes place at latitude of about thirty to sixty
degrees.
A. a narrow band of wind that
B. is a narrow band of wind that
C. a narrow band of wind which
D. it is a narrow band of wind which
27
5. Dew usually …….. at around seven o’clock when the sun rises up.
A. disappearing
B. disappear
C. disappeared
D. disappears
6. The plastic arts, such as ceramics and accessories, which are
A B C
produced by modeling or molding the materials into interesting
D
shapes and sizes
7. Water currents in the oceans which help transfer of heat from the
A B
equator regions to the poles, thereby maintaining the global
C
environment in a balanced condition.
D
8. Water that streams away from fountains on a mountain forming one
A B
or more rivers that may extend for hundreds of miles.
C D
9. The larva of the weevil insect, which it feeds on the young pods of
A B
cacao plant often destroying an entire crop.
C D
Unit 7
Activity 1.
Read the following text and answer the exercise that follows
STOICHIOMETRY 1
The above equation does not merely say that butane can be oxidized to carbon
dioxide and water but rather that 2 moles of butane react with 13 moles of oxygen to
produce 8 moles of carbon dioxide and 10 moles of water (5). It is then clear that
because of the quantitative information they contain, balanced molecular equations
can serve as the basis for the calculations which necessarily precede any laboratory
work involving a chemical reaction (6). If we need, it is relatively simple to convert
the mole relationships into grams, pounds, and other quantitative expressions (7).
The overall conversion from Quantity A to Quantity B requires three basic steps
described below (4). Each of the steps may require one or more unit conversion
factors in order to fulfill the requirement of mass balance as well as energy balance
(11).
In order to determine the volume of 0.750 M solution that we can prepare, we need
the number of moles of HCl(g) that are available to make the solution (17). The
chemical equation tells us the relationship between the number of moles of gaseous
HCl produced and the number of moles of NaCl reacting (18). The number of moles
of NaCl can be determined from the mass of NaCl used and its formula weight (19).
Solution of the problem requires the following steps (20):
1. Conversion of the quantity of NaCl from grams to moles, using the formula
weight of NaCl (58.5 g/mol) as a conversion factor (21).
1 mol NaCl
25.0 g NaCl x 0.4278 mol NaCl
58.5 g NaCl
30
4. Final calculation using the relationships described in step 3 will give the
answer of 0, 570 L as the volume of HCl 0,750 M we can prepare from the
given amount of NaCl (26).
Activity 2.
Learn the following words and use them in your own sentences.
Activity 3.
Write true (T) or false (F) for each of the following statements
1. Conversion factor for converting a quantity of compound measured in grams
into a mole is formula weight
2. In a balanced reaction, the number of moles of a second substance can be
determined from the mass ratio of the substances involved.
3. The volume of concentrated sulphuric acid required to make a certain volume
and concentration of sulphuric acid solution is determined by the density and
the purity of the concentrated sulphuric acid.
4. In addition to formula weight, ionic charge of the substance can be used to
balance a chemical reaction.
5. The number of moles of a substance can be determined from the its mass and
its formula weight
Intermezo:
TIT FOR TAT
A woman in blue jeans stood at the window of an expensive shop. Though she
hesitated for a moment, she finally went in and asked to see a dress that was in the
window. The assistant who served her did not like the way she was dressed.
Glancing at her scornfully, he told her that the dress was sold. The woman walked
out of the shop angrily and decided to punish the assistant the next day. She returned
to the shop the following morning dressed in a fur coat, with a handbag in one hand
and a long umbrella in the other. After seeking out the rude assistant she asked for
the same dress she wanted to see the day before. Not realizing who she was, the
assistant was eager to serve her this time. With great difficulty, he climbed into the
shop window to get the dress. As soon as she saw it, the woman said she did not like
it. She enjoyed herself making the assistant bring almost everything in the window
before finally buying the dress she had first asked for.
32
Unit 8
Activity 1.
Read the following text and answer the exercise that follows
STOICHIOMETRY 2
In addition to the basic steps previously explained, there are several common
operations in stoichiometric calculations (1). Conversion of a measured quantity of a
substance to moles of the substance, or the reserve conversion, may involve one or
more of the unit and their cancellations will be a great help in correctly setting up the
calculations.(2)
Rearrangement of this expression gives an equation that can be used to find the
mass of A that corresponds to a given amount of A in moles (4)
Molar Mass A
Mass A Mol A x
1 mol A
mass A
Percent A x 100
mass Sample
100 g Sample
Mass Sample Mass A x
gA
Moles A
Molarity
Volume of solution
Activity 2.
Solve the following problems using step by step stoichiometric operation following
the guideline provided.
2. If you burn 454 g of propane as fuel for your car, how much oxygen is
required to burn this amount of fuel completely and how much carbondixide
and water wolud be produced?.
35
Unit 9
Activity 1.
Read the following text and answer the exercise that follows
If the reaction involves both metals and nonmetals, the products are
commonly known as salts (6). Thus the products in equations (2), (3), and (4)
are salts (7)
2. Decomposition reaction. A decomposition reaction occurs when one
compound breaks down (decomposes) into two or more substances (8).
Several examples are given below (9).
2 HgO 2 Hg + O2 (5)
CaCO3 CaO + CO2 (6)
Cu(NO3)2 2 CuO + 4 NO2 + O2 (7)
36
Hydrogen ions are transferred from H2SO4 to the hydroxide ions in Mg(OH)2
in this acid-base reaction (3). In general, an acid-base reaction gives a high
yield of product when either a strong acid or a weak acid is added to a strong
base, when a strong acid is added to a weak base, or when a strong acid is
added to a salt containing the anion of a weak acid (4). These reactions occur
when the pure substances or their solutions are mixed (5)
two opposing directions, and that the two opposing reactions take place
simultaneously (12)
Activity 2.
Use your own word as much as possible to write the definition of the terms given in
column 1.
Terms Definition
Addition reaction
Decomposition reaction
Redox reactions
Reducing agent
Oxidizing agent
Acid-base reaction
Reversible reaction
Forward reaction
Reverse reaction
Simultaneous reaction
Oxidized state
Reduced state
Yield of reaction
Opposing reactions
39
Unit 10
Activity 1.
Read the following text and answer the exercise that follows
If you want to understand how gases behave—such as why fresh air rushes into your
lungs when certain chest muscles contract or how gases in a car’s engine move the
pistons and power the car—you need a clear mental image of the model chemists use
to explain the properties of gases and the relationships between them (1). Gases
consist of tiny particles widely spaced, as shown in figure below (2).
Under typical conditions, the average distance between gas particles is about ten
times their diameter (3). Because of these large distances, the volume occupied by the
particles themselves is very small compared to the volume of the empty space around
them (4). For a gas at room temperature and pressure, the gas particles themselves
occupy about 0.1% of the total volume (5). The other 99.9% of the total volume is
40
empty space (whereas in liquids and solids, about 70% of the volume is occupied by
particles) (6). Because of the large distances between gas particles, the attractions or
repulsions among them are weak (7).
The particles in a gas are in rapid and continuous motion (8). For example, the
average velocity of nitrogen molecules, N2, at 20 °C is about 500 m/s (9). As the
temperature of a gas increases, the particles’ velocity increases (10). The average
velocity of nitrogen molecules at 100 °C is about 575 m/s (11). The particles in a gas
are constantly colliding with the walls of the container and with each other (12).
Because of these collisions, the gas particles are constantly changing their direction of
motion and their velocity (13). In a typical situation, a gas particle moves a very short
distance between collisions (14). For example, oxygen, O2, molecules at normal
temperatures and pressures move an average of 10-7 m between collisions (15).
Activity 2.
1. The volume occupied by the particles of a gas is very small compared to the
volume of the empty space around them because........................
.................................................................................................................
2. The gas particles are constantly changing their direction of motion and their
velocity because .............................................................................
.................................................................................................................
3. Since the distance between gas particles is very large,
................................................................................................................
4. At room temperature and pressure, ........................................................
.................................................................................................................
5. As the temperature of a gas increases, the particles’ velocity increases
because ..................................................................................
41
Activity 3. Fill column 2 in the following table with the synonym of the words given
in column , based on the passage.
Column 1 Column 2
Distance
Velocity
Motion
Collide
Space
Occupied
Short
Intermezzo:
The former Prime Minister, Mr. Wentworth Lane, was defeated in the recent
elections. He is now retiring from political life and has gone abroad. My friend,
Crawley, has always been a fanatical opponent of Mr. Lane’s political party. After
the elections, Crawley went to the former Prime Minister’s resident. When he asked
if Mr. Lane lived there, the policeman on duty told him that since his defeat, the ex-
Prime Minister had gone abroad. On the following day, Crawley went to the house
again. The same policeman was just walking slowly past the entrance, when Crawley
asked the same question. Though a little suspicious this time, the policeman gave him
the same answer. The day after, Crawley went to the house once more and asked
exactly the same question to the same policeman on duty. This time, the policeman
lost his temper. ‘ I told you yesterday and the day before yesterday,’ he shouted, ‘Mr.
Lane was defeated in the elections. He has retired from political life and gone to live
abroad!’ ‘I know, answered Crawley, ‘but I love to hear you say it!’.
42
Unit 11
THE PROPERTIES OF IDEAL GASES
Activity 1.
Read the following text and answer the exercise that follows
If we want to explain why a weather balloon carrying instruments into the upper
atmosphere expands as it rises, we need to consider changes in the properties of the
gases (pressure, volume, temperature, or number of gas particles) inside and outside
the balloon (1). For example, as the balloon rises, the pressure outside of it, called the
atmospheric pressure, decreases (2). But, there are also variations in temperature, and
the balloon might have small leaks that change the number of gas particles it contains
(3).
In a real situation, pressure, temperature, and number of gas particles may all be
changing, and predicting the effect of such a blend of changing properties on gas
volume is tricky (4). Therefore, before we tackle predictions for real world situations,
such as the weather balloon, we will consider simpler systems in which two of the
four gas properties are held constant, a third property is varied, and the effect of this
variation on the fourth property is observed (5). For example, it is easier to
understand the relationship between volume and pressure if the number of gas
particles and temperature are held constant (6). The volume can be varied, and the
effect this has on the pressure can be measured (7). An understanding of the
relationships between gas properties in controlled situations will help us to explain
and predict the effects of changing gas properties in more complicated, real situations
(8).
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Figure below shows a laboratory apparatus that can be used to demonstrate the
relationships between the properties of gas (9). It consists of a cylinder with a
movable piston, a thermometer, a pressure gauge, and a valve through which gas may
be added to the cylinder’s chamber or removed from it (10).
The apparatus can be used to determine the relationship between gas volume and
pressure (11). This can be done by holding the number of gas particles constant (by
closing the valve) and holding the temperature constant (by allowing heat to transfer
in or out so that the apparatus remains the same temperature as the surrounding
environment), then we move the piston to change the volume, and finally we observe
the change in pressure (12). When we decrease the gas volume, the pressure gauge on
our system shows us that the gas pressure increases (13). When we increase the gas
volume, the gauge shows that the pressure goes down (14).
For an ideal gas (in which the volume of particles is neglected and the particles
experience no attractions or repulsions), gas pressure and volume are inversely
proportional (15). This means that if the temperature and the number of gas particles
are constant and if the volume is decreased to one-half its original value, the pressure
of the gas will double (16). If the volume is doubled, the pressure decreases to one-
half its original value (17). The following expression summarizes this inverse
relationship (18):
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The observation that the pressure of an ideal gas is inversely proportional to the
volume it occupies if the number of gas particles and the temperature are constant is
a statement of Boyle’s Law (19). This relationship can be explained in the following
way. When the volume of the chamber decreases but the number of gas particles
remains constant, there is an increase in the concentration (number of particles per
liter) of the gas (20). This leads to an increase in the number of particles near any
given area of the container walls at any time and to an increase in the number of
collisions against the walls per unit area in a given time (21). More collisions mean
an increase in the force per unit area, or pressure, of the gas (22). The general
relationship between the properties of ideal gas is summarized in equation of PV = n
RT, which is commonly known as ideal gas equation or the ideal gas law (23). The
constant (R) in this equation is called the universal gas constant and is the same for
all ideal gases (24).
Activity 2.
1. What is the purpose of closing the valve of the apparatus mentioned in the
text?.
2. What is the purpose of allowing heat transfer in or out of the apparatus
mentioned in the text?.
3. What are the requirements to determine the relationship between volume and
pressure of a gas?.
4. According to the apparatus, how can you change the volume of a gas?.
5. What happen if the volume of the chamber decreases while the number of gas
particles remains constant?.
6. What happen if the volume of an ideal gas is decreased to one-half its
original value, while the temperature and the moles gas are held constant?.
45
Activity 3.
Arrange the following words to form correct sentences..
Activity 4.
Fill column 3 with referent of each of the words in column 1 from the text above.
Unit 12
Activity 1.
Read the following text and answer the exercise that follows
The relationships between gas properties can be used to explain how we breathe in
and out, as shown in the figure below (1).
When the muscles of your diaphragm contract, your chest expands, and the volume of
your lungs increases (2). This change leads to a decrease in the number of particles
per unit volume inside the lungs, leaving fewer particles near any given area of the
inner surface of the lungs (3). Fewer particles means fewer collisions per second per
unit area of lungs and a decrease in force per unit area, or gas pressure (4). During
47
quiet, normal breathing, this increase in volume decreases the pressure in the lungs to
about 0.4 kilopascals lower than the atmospheric pressure (5). As a result, air moves
into the lungs faster than it moves out, bringing in fresh oxygen (6). When the
muscles relax, the lungs return to their original, smaller volume, causing the pressure
in the lungs to increase to about 0.4 kilopascals above atmospheric pressure (7). Air
now goes out of the lungs faster than it comes in (8).
Total lung capacity is dependent upon many factors such as weight, sex, age and
activity (9). For example, females tend to have a 20-25% lower capacity than males
(10). Tall people tend to have a larger total lung capacity than shorter people (11).
Heavy smokers have a drastically lower total lung capacity than nonsmokers (10).
Some people, such as elite athletes, have a total lung capacity well above average
(11). The average total lung capacity of an adult human male is about 6 liters of air,
also known as the vital capacity, but only a small amount of this capacity is used
during normal breathing (12).
The amount of air taken into the lungs in a single breath is known as tidal volume
(13). In the average adult, tidal volume is about 0.5 liters (14). The average human
respiratory rate is 30-60 breaths per minute at birth decreasing to 12-20 breaths per
minute in adults (15). Oxygen is the essential component of all breathing gases (16).
The air we inhale is roughly composed of (by volume): 78% nitrogen, 21% oxygen,
0.96% argon, and 0.04% carbon dioxide, helium, and water vapor (17).
Activity 2.
3. During normal breathing, what is the maximum volume of the air used by an
adult for 5 minutes?.
4. During normal breathing, what is the maximum volume of oxygen used by an
adult for 5 minutes?.
5. What is the lung capacity of a female according to the passage?.
Activity 3.
Use the following words in your own sentences to show that you understand their
meaning and use.
1. Breathing ...............................................................................................
2. Expand ....................................................................................................
3. Pressure .................................................................................................
4. Relax .......................................................................................................
5. Lung capacity ..........................................................................................
6. Vital capacity ...........................................................................................
7. Tidal volume ...........................................................................................
8. Breathing gases ......................................................................................
9. Respiration ..............................................................................................
10. Inhale ......................................................................................................
Unit 13
Activity 1.
Read the following text and answer the exercise that follows
Liquid gasoline is a mixture of hydrocarbons, with from five to twelve carbon atoms
in each molecule (2). It evaporates to form a gas, which is mixed with air and injected
50
into the engine’s cylinders (cylinder 1) (3). The movement of the engine’s pistons
turns a crankshaft that causes the piston in one of the cylinders containing the
gasoline-air mixture to move up, compressing the gases and increasing the pressure of
the gas mixture in the cylinder (cylinder 2) (4). A spark ignites the mixture of
compressed gases in a cylinder, and the hydrocarbon compounds in the gasoline react
with the oxygen in the air to form carbon dioxide gas and water vapor (cylinder 3)
(4). A typical reaction is (5)
In this representative reaction, a total of 27 moles of gas are converted into 34 moles
of gas (6). The increase in moles of gas leads to an increase in number of collisions
per second with the walls of the cylinder, which creates greater force acting against
the walls and a greater gas pressure in the cylinder (7). The pressure is increased even
more by the increase in the temperature of the gas due to the energy released in the
reaction (8). The increased temperature increases the average velocity of the gas
particles, which leads to more frequent collisions with the walls and a greater average
force per collision (8). The increased pressure of the gas pushes the piston down
(cylinder 4) (9). This movement of the pistons turns the crankshaft, which, through a
series of mechanical connections, turns the wheels of the car (10).
Activity 2.
Activity 3.
Fill column 2 in the following table with the effects of each of the events
provided in column 1.
vent Effect
Injection of gaseous
gasoline into cylinder 1
Combustion of gasoline
Unit 14
Activity 1.
Read the following text and answer the exercise that follows
Objective:
The objective of this experiment is to become familiar with making solutions and to
titrate an acid with a base. One solution will be prepared from a solid and one
solution will be prepared by dilution of a concentrated solution.
Materials needed:
Safety precautions:
Wear approved eye protection in the laboratory at all times. Concentrated
hydrochloric acid is corrosive. In the event of skin contact, wash well with water. If
the skin is blistered or broken, seek professional medical treatment. The dilute
hydrochloric acid is less reactive, but one should exercise similar precautions.
Sodium hydroxide is caustic. Do not handle the solid with your hands. In the event of
skin contact, wash well with water. If the skin is irritated or broken, seek professional
medical treatment. The dilute sodium hydroxide solution is less caustic, but one
should exercise similar precautions. When diluting the hydrochloric acid, remember
53
to add the concentrated acid to water to avoid splattering. Take care in handling the
container as the dilution will generate heat. Dissolving of sodium hydroxide generates
heat. Take care in handling the dilution container.
Disposal:
All solutions in this experiment should be disposed of in the proper waste containers
as provided in the laboratory.
Preparing solutions:
Prepare 1000 mL of 0.1 M hydrochloric acid solution starting with 12 M HCl, using
distilled or deionized water. The solution will be prepared in a 1000-mL volumetric
flask. To prepare the hydrochloric acid solution, determine the amount of 12 M
hydrochloric acid needed. Fill the volumetric flask approximately 75% full with
water. Use a funnel add the hydrochloric acid to the volumetric flask. Carefully, rinse
any residual hydrochloric acid from the graduated cylinder and the funnel into the
volumetric flask using three 5 mL portions of distilled water from a wash bottle.
Stopper the volumetric flask and gently shake the solution. Fill the volumetric flask to
the 1000-mL mark. Stopper the flask and gently shake the solution. If necessary,
adjust the volume of the solution to 1000 mL using distilled water, and shake again.
Label the volumetric flask.
Prepare 500 mL of 0.1 M sodium hydroxide solution starting with solid sodium
hydroxide using distilled or deionized water. The solution will be prepared in a 500-
mL volumetric flask. To prepare the solution, determine the mass of sodium
hydroxide needed. Fill the volumetric flask approximately 75% full with water. Use a
funnel add the sodium hydroxide to the volumetric flask. Stopper the volumetric flask
and gently shake the solution. After the sodium hydroxide has dissolved, fill the
volumetric flask to the 500-mL mark. Stopper the flask and gently shake the solution.
If necessary, adjust the volume of the solution to 500 mL using distilled water, and
shake again. Label the volumetric flask.
54
Diluting solutions:
Procedure:
Rinse a buret with 5 mL of 0.1 M hydrochloric acid solution. Discard the rinse
solution. Repeat the rinsing two more times. Fill the buret with 0.1 M HCl solution.
Adjust the volume to the zero mark. Use a piece of labeling tape to identify this as the
HCl or acid buret. Rinse a second buret with 5 mL of 0.1 M sodium hydroxide
solution. Discard the rinse solution. Repeat the rinsing two more times. Fill the buret
with 0.1 M NaOH solution. Adjust the volume to the zero mark. Use a piece of
labeling tape to identify this as the NaOH or base buret. If necessary, clean the 125-
mL Erlenmeyer flasks. Rinse well with water. Give the flask a final rinse with
distilled or deionized water. The flasks may be left wet for the titrations. Measure 20
mL of 0.1 M HCl into a 125-mL Erlenmeyer flask. Add 3 to 5 drops of
phenolphthalein indicator solution. Record the volume of 0.1 M HCl used. Titrate the
HCl solution with 0.1 M NaOH until the solution just turns pink and the pink color
persists for 30 seconds without fading. Record the volume of 0.1 M NaOH used.
Rinse the 125-mL Erlenmeyer flask well with water. Give the flask a final rinse with
distilled or deionized water. The flask may be left wet for another titration. Repeat the
titration procedure, above, 2 more times. Calculate the molarity of the NaOH solution
for each of the three titrations. If the values of the molarities do not agree, try another
titration.
55
CALCULATIONS:
Assuming the HCl solution is 0.1 M exactly, calculate the concentration of the NaOH
solution using the formula:
MNaOH VNaOH = MHCl VHCl
where MNaOH = molarity of the NaOH solution
VNaOH = volume of the NaOH solution
MHCl = molarity of the HCL solution
VHCl = volume of the HCl solution
Activity 2.
Unit 15
Activity 1.
Read the following text and answer the exercise that follows
Objective:
Materials needed:
Stomach antacid tablets. sodium bicarbonate (baking soda), hydrochloric acid, HCl,
0.1 M, sodium hydroxide, NaOH (previously prepared and standardized),
bromphenol blue solution, 100 mL graduated cylinder, 250-mL Erlenmeyer flasks,
mortar and pestle, burettes, 25 or 50 mL, small funnels to fit the burettes
Safety precautions:
Wear approved eye protection in the laboratory at all times. Hydrochloric acid is
corrosive. In the event of skin contact, wash well with water. If the skin is blistered or
broken, seek professional medical treatment. Sodium hydroxide is caustic. In the
event of skin contact, wash well with water. If the skin is irritated or broken, seek
professional medical treatment. Stomach antacid tablets used in this experiment have
57
been stored under laboratory conditions and may be contaminated. Do not taste any
materials used in this experiment.
Disposal:
All solutions in this experiment should be disposed in the proper containers provided
in the laboratory. Solid waste can be disposed of in the trash.
Procedure:
Crush one antacid tablet using a mortar and pestle. Weigh the crushed tablet to the
nearest 0.001 g (or the precision of your balance) and transfer it to a 250-mL
Erlenmeyer flask. Add exactly 100 mL of 0.10 M HCl to the flask (you may use a
graduated cylinder to measure the HCl solution) and gently swirl the flask to dissolve
the crushed tablet as completely as possible. Add 2-5 drops of bromphenol blue
indicator solution to the flask. At this point the solution should be yellow, if it is blue,
add additional 0.1 M HCl in 10 mL increments until the solution is yellow.
Titrate the solution with your standardized NaOH until the indicator just turns blue
(this color change is not distinct). Record the volume of NaOH solution required to
neutralize the excess acid. Repeat this procedure two more times using the same
brand of antacid tablet. Repeat the above procedure three more times using a different
brand of antacid tablet or using 0.70 gram portions of sodium bicarbonate (baking
soda) in place of the antacid tablet. (Note: If sodium bicarbonate is used, add the acid
to the sodium bicarbonate very slowly to prevent excess frothing.) At the conclusion
of the experiment, empty the burettes and rinse them three times with distilled or
deionized water.
Calculations:
The moles of 0.1 M HCl consumed by the antacid tablet (or by the sodium
bicarbonate) is given by the formula:
58
Activity 2.
1. List the chemicals required for the experiment and their function.
2. List the apparatus required for the experiment and their function.
3. Based on the text, what is the main component of antacid tablet?
4. What is the main reaction involved in this experiment?
5. What is the secondary reaction involved in this experiment?
6. What is the initial color of the sample in this experiment?
7. What is the final color of the sample in this experiment?.
59
Unit 16
Read the following text and answer the questions that follow
CARBON DIOXIDE
Because H2CO3 is a weak acid, solution of carbon dioxide in pure water is slightly
acidic (5). For this reason, the rain that falls even in non-polluted environments is
slightly acidic, and therefore commonly explained as acid rain (6). Because the
solubility of carbon dioxide in water, the oceans are thought to hold roughly 60 times
700 billion tons of carbon in different forms, including carbonic acid, solid metal
carbonates such as calcium carbonate and magnesium carbonate, and organic matter
(7).
Stored
60
Questions:
Carbon dioxide is being generated in ever increasing amounts, in part due to the
increase in the population of the earth, in part due to the clearing of forests, and in
61
part due to increased combustion of fossil fuels (1). Indeed, there is fear that this
could lead to a global warming trend caused by the greenhouse effect (2). This effect
is associated with the nature of our atmosphere (3). The atmosphere is transparent
to sunlight in the visible region and at some wavelengths in the ultraviolet region (4).
When the earth’s surface absorbs and reradiates this energy, the infrared energy is
absorbed by carbon dioxide in the atmosphere (5). The energy thus trapped in the
atmosphere could cause a warming of the entire earth, perhaps enough to melt part of
the polar ice caps and raise the level of the oceans and turn part of the now temperate
zones into desert (6). Scientists are still debating the probability of this outcome (7).
Fortunately, the amount of CO2 in the atmosphere is not increasing as rapidly as
might be expected, largely because the ocean is a great CO2 sink (8). As the partial
pressure of CO2 increases, its solubility increases, and it is estimated that the sea has
absorbed roughly half of the increase in CO2 (9). Although this should lead in turn to
an increase in hydrogen ion concentration, it can be controlled through reaction with
carbonate ion (10). The oceans are known to contain enormous quantities of calcium
carbonate produced by sea creatures, part of which decomposes into calcium ions and
carbonate ions (11). Carbonate ion produced from this reaction then reacts with
water to produce bicarbonate ion and hydroxyl ion, which in turn reacts with calcium
ion to produce calcium hydroxide (12). When carbon dioxide enters the seawater,
this gas will react with calcium hydroxide to produce solid calcium carbonate (13).
The whole process then takes place repeatedly (14).
Questions:
One of biological processes involving CO2 is photosynthesis (1). It has long been
known that when exposed to light under suitable conditions of temperature and
moisture, the green parts of plants use CO2 from the atmosphere and release oxygen
to it (2). These exchanges are the opposite of those that occur in respiration (3). The
process is called photosynthesis (4). In photosynthesis, carbohydrates are synthesized
from carbon dioxide and water by the chloroplast of plant cells in the presence of
light (5). In most plants, the water used in photosynthesis is absorbed from soil by
the roots and translocated through the xylem of the root and stem to the leaves (6).
63
Except for the usually small percentage used in respiration, the oxygen released in the
process diffuses out of the leaf into the atmosphere through the stomates (7).
Oxygen is the product of the reaction (8). For each molecule of carbon dioxide used,
one molecule of oxygen is released (9). A summary of chemical equation for
photosynthesis is (10):
6CO2 .+ 6H2O C6H12O6 + 6O2
As a result of this process, radiant energy from the sun is stored as chemical energy
(11). In turn the chemical energy is used to decompose carbon dioxide and water
(12). The products of their decomposition are recombined into a new compound,
which is successively built up into more and more complex substances (13). After
many intermediate steps, sugar is produced (14). At the same time, a balance of
gases is preserved in the atmosphere (15).
Questions:
11. The ideas in this passage is best expressed by the title:
A. A chemical Equation
B. The Process of Photosynthesis
C. The Parts of Vascular Plants
D. The Production of Sugar
C. Diffusion
D. Respiration
14. The combination of carbon dioxide and water to form sugar results in excess of
A. Water
B. Oxygen
C. Carbon
D. Chlorophyll
15. The word stored in sentence 11 is closet in meaning to
A. Retained
B. Converted
C. Discovered
D. Specified
16. In photosynthesis, energy from the sun is
A. changed to chemical energy
B. conducted from the xylem to the leaves of green plants
C. not necessary to the process
D. released one to one for each molecule of carbon dioxide used
17. The word their in sentence 13 refers to
A. Radiant energy and chemical energy
B. Carbon dioxide and water
C. Products
D. Complex substances
18. The word successively in sentence 13 is closet in meaning to
A. with effort
B. in a sequence
C. slowly
D. carefully
19. Besides the manufacture of food for plants, another benefit of photosynthesis is:
A. It produces solar energy
B. It diffuses additional carbon dioxide into the air
65