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Abstract: Sugarcane bagasse ash (SCBA) is an industrial by-product generated in large quantities from sugar industries employing the
cogeneration process. It is commonly disposed of in landfills. The use of cogeneration plants, and subsequently the quantity of ash generated
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and disposed, has increased significantly in India and other developing economies. Moreover, disposal of sugarcane bagasse ash causes
environmental pollution and reduction of useful land area. A number of earlier research studies have reported on the excellent pozzolanic
characteristics of sugarcane bagasse ash in concrete. The present study is focused on the performance evaluation of sugarcane bagasse ash as
an ingredient in construction materials such as alkali-activated concrete, paver blocks, and unburnt bricks. Results from the study showed
significant improvement in the characteristics, specifically strength and durability of bagasse ash blended specimens. Sugarcane bagasse
ash and slag-based ambient-cured geopolymer specimens showed enhancement in compressive strength and workability in comparison with
slag-based geopolymer. No efflorescence was observed in SCBA-based unburnt bricks, but water absorption in SCBA unburnt bricks was
higher compared with fly ash bricks. Sugarcane bagasse ash blended paver block specimens exhibited significant resistance against water
penetration and sorption compared with control specimens. DOI: 10.1061/(ASCE)MT.1943-5533.0001999. © 2017 American Society of
Civil Engineers.
Author keywords: Sugarcane bagasse ash; Blast furnace slag; Paver blocks; Alkali activation; Unburnt bricks; Crusher sand; Supplementary
cementitious material; Durability.
Frias et al. 2007). In major sugar-producing nations such as Brazil, • For unburnt bricks, raw bagasse ash was kept for 24 h in a 100°C
India, and Thailand, a number of research studies have been con- temperature-controlled oven to remove the moisture and directly
ducted to explore the potential for utility of SCBA (Chusilp et al. used in brick production; and
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2009; Somna et al. 2012; Paya et al. 2002; Bahurudeen and • For paver blocks, the sieved bagasse ash was further ground to
Santhanam 2015). However, proper performance evaluation and cement fineness as well as blended with cement to make
processing of bagasse ash for other construction materials such blended cements (10 and 20% replacement by weight of cement,
as alkali-activated concrete, paver blocks, and unburnt bricks were named as 10% PPC and 20% PPC).
not effectively investigated in the earlier research studies. In addi- In addition to bagasse ash, ground granulated blast furnace slag
tion to material characterization, performance evaluation in different (GGBFS) was used as a source material for alkali-activated binary
applications is necessary to reach scientific insight as well as maxi- blends. The slag was sourced as a proprietary product from Jindal
mum utilization of SCBA. Steel, Bellary, Karnataka, India. The physical and chemical char-
Crusher sand is a by-product of the aggregate crushing industry. acteristics of the SCBA and slag were determined according to the
It is used in small quantities as a fine aggregate replacement; relevant standards as shown in Table 1. Standard consistency and
nevertheless, it has not gained substantial acceptance due to the initial and final setting time were determined in accordance with IS
higher presence of fines and the resultant increase in water demand 4031-2005 (BIS 1988a) using the mixture of supplementary ce-
(Elyamany et al. 2014). Previous studies have demonstrated the use menting materials and ordinary portland cement (53 grade) in
of the material as a replacement of fine aggregate in the production the proportion of 0.2N∶0.8, where N is the ratio of specific gravity
of lightweight blocks and tiles (Safiuddin et al. 2007). Due to the of supplementary cementing materials (as collected SCBA, proc-
abundance of availability of both sugarcane bagasse ash and essed SCBA, and slag) to the specific gravity of cement, as indi-
crusher sand in India, this study was conducted in order to ascertain cated in IS 1727 (BIS 2004). Although considerable variations are
their utility as a construction material for making activated con- observed in characteristics, all are well below the permissible limit
crete, paver blocks, and unburnt bricks. The present study inves- specified in the standard.
tigated bagasse ash as a precursor in binary alkali-activated Oxide composition of raw bagasse ash, processed bagasse ash,
mortar due to its increased fineness (300 m2 =kg) and significantly slag, and blended cements was determined using X-ray fluores-
high SiO2 and K2 O. Moreover, performance evaluation of SCBA cence (XRF) spectroscopy and is presented in Tables 2 and 3.
blended concrete paver blocks and bricks was also conducted. Alkali activators used in this study were NaOH þ Na2 SiO3 and
KOH þ K2 SiO3 . The molarities of the alkali used were 6M, 8M,
and 10M. Hydroxide and silicate were used in the ratio of 2∶3 based
Materials
Sugarcane bagasse ash was collected from a single disposal site Table 2. Oxide Composition of SCBA and Slag
(Madras Sugar Limited, Villupuram, Tamil Nadu, India) and it was Oxide Raw SCBA Processed SCBA GGBS
used throughout the study. Generally, bagasse is burnt at 500°C in composition (%) (%) (%)
the cogeneration boiler as a fuel. In earlier research studies, further SiO2 72.95 75.67 32.38
calcination was suggested between 600 and 800°C (Cordeiro et al. Al2 O3 1.68 1.52 21.06
2009a, b; Ganesan et al. 2007) to enhance pozzolanic activity. In Fe2 O3 1.89 2.29 1.87
this study, raw bagasse ash (as collected) was kept for 24 h in a CaO 7.77 6.62 31.46
temperature-controlled oven at 100°C to remove moisture. The MgO 1.98 1.87 8.57
dried bagasse ash was directly used for the brick production. K2 O 9.28 9.59 —
The dried ash was additionally processed based on an earlier re- Na2 O 0.02 0.12 0.36
search study to remove unburnt fibrous fractions and obtain supe-
rior reactive materials (Bahurudeen and Santhanam 2015). As
per the earlier study, the dried bagasse ash was sieved through a Table 3. Oxide Compositions of OPC and Blended Cements Using XRF
300-μm sieve and the sieved ash was further ground to cement fine- Spectroscopy
ness (300 m2 =kg). The processed SCBA was blended with cement Oxide OPC 10% PPC 20% PPC
(10 and 20% replacement by weight of cement) to produce SCBA composition (%) (%) (%)
blended cements for paver block study. Moreover, the processed SiO2 20.42 25.48 35.48
bagasse ash was directly used with slag for alkali-activated mortar Al2 O3 4.07 5.45 5.34
study. Summing up Fe2 O3 5.37 4.05 4.01
• For alkali-activated mortar, raw bagasse ash was placed in a CaO 59.61 55.10 48.29
temperature-controlled oven at 100°C for 24 h and then sieved MgO 0.82 0.94 0.99
through a 300-μm sieve to remove the unburnt fibrous matter K2 O 0.27 0.31 0.99
Na2 O 0.23 0.2 0.2
and then ground to cement fineness (300 m2 =kg);
were used on top and bottom surfaces to ensure even surface for
loading. The specimens were tested at a uniform loading rate of Results and Discussion
15 3 N=mm2 =min. The average compressive strength of three
specimens is reported.
Sugarcane Bagasse Ash–Based Alkali-Activated Mortar
Abrasion Resistance Slag and bagasse ash blended alkali-activated mortars were cast and
tested as described in the previous section and results are discussed
To determine the loss in wear due to abrasion, square cut specimens in the following passages. The influence of the following four
of 70 × 70 mm with 25-mm thickness were used. The specimens parameters was evaluated to develop suitable GGBS-SCBA-based
were conditioned by being placed in a well-ventilated oven for 24 h alkali-activated mortars with good workability retention and suffi-
at the temperature of 105 5°C until constant mass was attained. cient strength at ambient curing:
To evaluate the resistance against abrasion, the specimen was sub- • Type of curing: Ambient curing and heat curing;
ject to 16 cycles of abrasion. Each cycle involved 22 revolutions of • Type of activator: Sodium and potassium based;
the standard grinding disc strewn with 20 g of alumina abrasive • Level of replacement of GGBFS with SCBA: 10 and 20%; and
powder. The mass loss at the end of each cycle was noted. The • Molarity of activator: 6M, 8M, and 10M.
abrasive wear was calculated by determining loss in volume di-
vided by surface area of paver specimens. Effect of Curing on Strength of Alkali-Activated Binder
To investigate the influence of type of curing on strength develop-
Breaking Load under Flexure ment of alkali-activated binders, the specimens were subjected to
heat curing and ambient curing as described previously and results
For determination of breaking load, the sample was polished to a are shown in the Fig. 1. Ambient-cured mortar specimens showed
good smoothness without any surface projections as per the stan- higher strength compared with heat-cured specimens. Although
dard IS 15658 (BIS 2006). The prepared concrete paver specimens heat-cured specimens showed an increase in strength with respect
were placed on two rollers at 50 mm from either edge of the block to curing duration, lower strength was clearly observed compared
and midpoint loading was applied at a uniform loading rate of with ambient-cured specimens for the same curing duration. The
60 kN=min. The loading was continued until the specimen failed observed reduction in strength for heat-cured specimens is due
under flexure and the corresponding breaking load was noted. to the loss of water, which possibly causes a reduction in the level
of slag hydration.
Water Absorption
For testing water absorption, the specimens were immersed in water
for 24 h. Afterward, the specimens were taken from the water and
any trace of surface moisture was wiped off. The blocks were al-
lowed to air dry for another 3 min and then the weight of specimens
was measured. Then the blocks were placed in an oven for 24 h at
the temperature of 105 5°C and dry weight was measured.
Water Permeability
Water permeability test was carried out in accordance with DIN
1048-5 (DIN 1994), where concrete specimens of 150-mm cube
size were tested after 28 days of curing. A constant water pressure
0.5] MPa (5 bar)] was applied for a duration of 72 h using a proper
valve and gasket arrangement. After 3 days, the specimen was bro-
ken into two halves and the depth of penetration of water was mea-
sured and average depth of penetration was reported.
Compressive Strength
Sugarcane bagasse ash–river sand paver specimens showed mar-
ginally higher compressive strength compared with SCBA–crusher
sand paver specimens after 7 and 56 days of curing as shown in
Fig. 7. This could probably be attributed to the increase in fines
in the crusher sand, which increased the water demand in the
crusher sand mixes as well as decreased the compressive strength
at a later stage of curing. Although less compressive strength was
observed for SCBA blended specimens, the reduction in compres-
sive strength was only marginal and the strength was well above
the minimum requirement (35 MPa) specified in IS 15658 (BIS
Fig. 8. Comparison for breaking load under flexure
2006). Moreover, significant increase in compressive strength was
Acknowledgments
The authors wish to gratefully acknowledge the Department of
Science and Technology for funding this study. The authors also
wish to thank M/S Madras Sugar Limited, Tamil Nadu, for provid-
ing raw material, and M/S Excon Pavers and M/S Devi Bricks,
Chennai, for their expert comments and providing molds and
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References
Fig. 12. Comparison of sorptivity index
Alexander, M. G., Ballim, Y., and Mackechnie, J. R. (1999). “Guide to the
use of durability indexes for achieving durability in concrete structures.
Achieving durable and economic concrete construction in the South
pore connectivity. However, higher porosity due to crusher sand African context.” Res. Monogr., 2, 5–11.
incorporation might be the cause for marginal reduction in the ASTM. (2011a). “Standard test method for compressive strength of
sorptivity index of crusher sand compared with river sand mixes. hydraulic cement mortars using 50 mm cube specimens.” ASTM
However, SCBA blended concrete specimens had sorptivity index C109-11, West Conshohocken, PA.
less than 6 and all the specimens can be categorized as excellent ASTM. (2011b). “Standard test method for fineness of hydraulic cement by
with respect to sorptivity (The Concrete Institute 2009; Alexander air-permeability apparatus.” ASTM C204-11, West Conshohocken, PA.
et al. 1999). ASTM. (2013). “Standard test method for flow of hydraulic cement
mortar.” ASTM C1437-13, West Conshohocken, PA.
ASTM. (2014). “Standard test method for compressive strength of masonry
prisms.” ASTM C1314-2014, West Conshohocken, PA.
Conclusions
ASTM. (2016). “Standard test methods for sampling and testing fly ash or
natural pozzolans for use in portland-cement concrete.” ASTM C311/
Performance of SCBA was evaluated in three systems, namely,
C311M-16, West Conshohocken, PA.
alkali-activated mortars, paver blocks, and unburnt bricks, and Bahurudeen, A., Kanraj, D., Dev, V. G., and Santhanam, M. (2015).
the main observations drawn from the study are summarized as “Performance evaluation of sugarcane bagasse ash blended cement
follows: in concrete.” Cem. Concr. Compos., 59, 77–88.
• Replacement of GGBFS with SCBA decreased the strength of Bahurudeen, A., Marckson, A. V., Kishore, A., and Santhanam, M. (2014).
alkali-activated binder for the same curing duration. However, “Development of sugarcane bagasse ash based Portland pozzolana
to achieve good workability retention of slag-based alkali cement and evaluation of compatibility with superplasticizers.” Constr.
activators, blending with other silica rich sources like SCBA is Build. Mater., 68, 465–475.
imperative. Bahurudeen, A., and Santhanam, M. (2014). “Sugarcane bagasse ash—An
• Ambient-cured specimens exhibited superior strength compared alternative supplementary cementitious material.” Proc., Int. Conf. on
with heat-cured specimens as a result of the loss of water and Advances in Civil Engineering and Chemistry of Innovative Materials,
microcrack formation during heat curing. SRM Univ., Chennai, India, 837–842.
Bahurudeen, A., and Santhanam, M. (2015). “Influence of different
• Compressive strength increased with increase in molarity of
processing methods on the pozzolanic performance of sugarcane
the activator due to increase in alkali oxide concentration. bagasse ash.” Cem. Concr. Compos., 56, 32–45.
Potassium-based activator results in higher strength for SCBA Batra, V. S., Urbonaite, S., and Svensson, G. (2008). “Characterization of
blends compared with sodium-based activator due to higher unburnt carbon in bagasse fly ash.” Fuel, 87(13–14), 2972–2976.
K2 O content in SCBA. BIS (Bureau of Indian Standards). (1988a). “Methods of physical tests for
• River sand specimens with blended cements showed marginally hydraulic cement. Determination of initial and final setting times.”
lesser abrasion resistance compared with control concrete IS 4031 Part 5, New Delhi, India.
specimens at 28 days. In the case of durability performance, BIS (Bureau of Indian Standards). (1988b). “Methods of physical tests
SCBA blended concrete paver specimens performed better than for hydraulic cement: Determination of density.” IS 4031 Part 11,
control specimens in terms of water permeability and water New Delhi, India.
sorptivity, which is attributable to the pozzolanic performance BIS (Bureau of Indian Standards). (1991). “Specification for Standard Sand
of SCBA. Similarly, SCBA blended concrete paver blocks for Testing of cement.” BIS 650, New Delhi, India.
performed better than control specimens with respect to water BIS (Bureau of Indian Standards). (1992a). “Methods of tests of burnt clay
building bricks: Determination of compressive strength.” IS 3495 Part 1,
absorption.
New Delhi, India.
• SCBA unburnt bricks with crusher sand had higher compressive BIS (Bureau of Indian Standards). (1992b). “Methods of tests of burnt
strength compared with SCBA–river sand brick specimens and clay building bricks: Determination of efflorescence.” IS 3495 Part 3,
fly ash brick specimens with similar proportion. No efflores- New Delhi, India.
cence was observed in SCBA-based unburnt bricks, which is BIS (Bureau of Indian Standards). (1992c). “Methods of tests of burnt clay
desirable in comparison with burnt clay bricks. Water absorp- building bricks: Determination of warpage.” IS 3495 Part 4, New Delhi,
tion in SCBA unburnt bricks was higher compared with fly India.