Experimetal Values of Liquid Phase Properti

P (kPa) x1 y1 x2 y2 γ1
68.728 0 0 1 1
72.278 0.0287 0.0647 0.9713 0.9353 1.681791
75.279 0.057 0.1295 0.943 0.8705 1.765274
77.524 0.0858 0.1848 0.9142 0.8152 1.723433
78.951 0.1046 0.219 0.8954 0.781 1.706136
82.528 0.1452 0.2694 0.8548 0.7306 1.580432
86.762 0.2173 0.3633 0.7827 0.6367 1.497196
90.088 0.2787 0.4184 0.7213 0.5816 1.395935
93.206 0.3579 0.4779 0.6421 0.5221 1.284584
95.017 0.405 0.5135 0.595 0.4865 1.243455
96.365 0.448 0.5512 0.552 0.4488 1.223754
97.646 0.5052 0.5844 0.4948 0.4156 1.165856
98.462 0.5432 0.6174 0.4568 0.3826 1.155098
99.811 0.6332 0.6772 0.3668 0.3228 1.101788
99.95 0.6605 0.6926 0.3395 0.3074 1.081772
100.278 0.6945 0.7124 0.3055 0.2876 1.061697
100.467 0.7327 0.7383 0.2673 0.2617 1.044897
100.999 0.7752 0.7729 0.2248 0.2271 1.03937
101.059 0.7922 0.7876 0.2078 0.2124 1.037025
99.877 0.908 0.8959 0.092 0.1041 1.017144
99.799 0.9448 0.9336 0.0552 0.0664 1.017866
96.885 1 1 0 0 1
 Caculated Values by U
ues of Liquid Phase Properties A12 0.71
γ2 ln γ1 ln γ2 GE/RT x1 ln γ1
1 0 0 0.66149
1.012675 0.519859 0.012595 0.027154 0.0287 0.623315
1.011107 0.568306 0.011046 0.04281 0.057 0.586944
1.005832 0.544318 0.005815 0.052019 0.0858 0.551202
1.001977 0.534231 0.001975 0.057649 0.1046 0.52855
1.02632 0.457698 0.02598 0.088665 0.1452 0.481427
1.026917 0.403594 0.026561 0.10849 0.2173 0.403629
1.056919 0.333564 0.055358 0.132894 0.2787 0.343126
1.10271 0.250435 0.09777 0.152409 0.3579 0.272631
1.130403 0.217894 0.122575 0.161179 0.405 0.23464
1.139986 0.201923 0.131016 0.162782 0.448 0.202472
1.193347 0.153455 0.176762 0.164987 0.5052 0.163359
1.199924 0.144186 0.182258 0.161577 0.5432 0.139677
1.278053 0.096934 0.245338 0.151369 0.6332 0.090876
1.31678 0.078601 0.275189 0.145343 0.6605 0.078097
1.373566 0.059869 0.31741 0.138548 0.6945 0.063503
1.431181 0.043919 0.3585 0.128006 0.7327 0.048862
1.484582 0.038615 0.395133 0.11876 0.7752 0.03477
1.50297 0.036356 0.407443 0.113468 0.7922 0.029786
1.644352 0.016999 0.497346 0.061191 0.908 0.005954
1.746713 0.017708 0.557736 0.047518 0.9448 0.002158
0 1 0
Caculated Values by Using the Wilson Equations
A21 0.681
ln γ2 γ1 γ2 P (Kpa) y1 (P_ex - P_cal)^(2)
0 1.937678 1 68.728 0 0
0.000555 1.8651 1.000555 71.97868 0.07205 0.089591200923259
0.002183 1.798484 1.002185 74.88418 0.132632 0.155885421498365 Pxy data a
0.004931 1.735338 1.004943 77.56712 0.185973 0.001858989058958
0.007314 1.696471 1.007341 79.18313 0.217121 0.053884721175913 105
0.014039 1.618381 1.014138 82.34618 0.276478 0.03305827184009 100
0.031256 1.497248 1.03175 87.02306 0.362223 0.068154635833689 95
0.051207 1.409346 1.052541 90.23309 0.421741 0.021049872737711
90
0.08412 1.313415 1.087759 93.54594 0.48685 0.115559489456181

P (kPa)
85
0.107548 1.264454 1.113544 95.15152 0.521433 0.018094688993029
80
0.131471 1.224426 1.140505 96.41388 0.551223 0.002389678411891
0.167088 1.17746 1.181859 97.8233 0.589147 0.031435728700591 75

0.19318 1.149902 1.213102 98.60225 0.613749 0.019668999605361 70

0.262905 1.095133 1.300703 99.97376 0.672014 0.026491080604049 65
0 0.1 0.2
0.286312 1.081228 1.331508 100.2588 0.690119 0.095357205384763
0.316973 1.065563 1.372966 100.5255 0.713233 0.06124270837406 P-x1 (Corr)
0.353458 1.050075 1.423983 100.7023 0.740225 0.055377091845479
0.396644 1.035381 1.486827 100.7341 0.771959 0.070154323816869
0.414702 1.030234 1.513919 100.6941 0.785277 0.133120204051166
0.550135 1.005972 1.733487 99.45771 0.889794 0.175806875708711
0.597929 1.002161 1.818349 98.63317 0.93006 1.35916635193577
0.674193 1 1.962449 96.885 1 0 1
RMS Deviation 0.34293834
 Pxy data and their correlation (The Wilson Equation)

105

100

95
90
P (kPa)

85

80

75

70

65
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
x1 , y1
P-x1 (Corr) P-x1 (Exp) P-y1 (Corr) P-y1 (Exp)