Experimetal Values of Liquid Phase Properties

P (kPa) x1 y1 x2 y2 γ1
68.728 0 0 1 1
72.278 0.0287 0.0647 0.9713 0.9353 1.681791
75.279 0.057 0.1295 0.943 0.8705 1.765274
77.524 0.0858 0.1848 0.9142 0.8152 1.723433
78.951 0.1046 0.219 0.8954 0.781 1.706136
82.528 0.1452 0.2694 0.8548 0.7306 1.580432
86.762 0.2173 0.3633 0.7827 0.6367 1.497196
90.088 0.2787 0.4184 0.7213 0.5816 1.395935
93.206 0.3579 0.4779 0.6421 0.5221 1.284584
95.017 0.405 0.5135 0.595 0.4865 1.243455
96.365 0.448 0.5512 0.552 0.4488 1.223754
97.646 0.5052 0.5844 0.4948 0.4156 1.165856
98.462 0.5432 0.6174 0.4568 0.3826 1.155098
99.811 0.6332 0.6772 0.3668 0.3228 1.101788
99.95 0.6605 0.6926 0.3395 0.3074 1.081772
100.278 0.6945 0.7124 0.3055 0.2876 1.061697
100.467 0.7327 0.7383 0.2673 0.2617 1.044897
100.999 0.7752 0.7729 0.2248 0.2271 1.03937
101.059 0.7922 0.7876 0.2078 0.2124 1.037025
99.877 0.908 0.8959 0.092 0.1041 1.017144
99.799 0.9448 0.9336 0.0552 0.0664 1.017866
96.885 1 1 0 0 1

GE/x1x2RT Vs. x1
GE/x1x2RT

1.1
1
0.9
0.8
0.7
f(x) = − 0.018166642769691 x + 0.707709904887286
0.6 R² = 0.003407288527829

0.5
0.4
0.3
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
x1
 Caculated Values by Using the Margu
quid Phase Properties A12 0.7077 A21
γ2 ln γ1 ln γ2 GE/RT GE/x1x2RT x1 ln γ1 ln γ2
1 0 0 0.7077 0
1.012675 0.519859 0.012595 0.027154 0.974072344 0.0287 0.666675 0.000597
1.011107 0.568306 0.011046 0.04281 0.796447121 0.057 0.627477 0.002352
1.005832 0.544318 0.005815 0.052019 0.663177495 0.0858 0.588858 0.005321
1.001977 0.534231 0.001975 0.057649 0.615523919 0.1046 0.56434 0.007901
1.02632 0.457698 0.02598 0.088665 0.714367065 0.1452 0.513243 0.015193
1.026917 0.403594 0.026561 0.10849 0.637876058 0.2173 0.428705 0.033903
1.056919 0.333564 0.055358 0.132894 0.661078299 0.2787 0.36292 0.055595
1.10271 0.250435 0.09777 0.152409 0.663203605 0.3579 0.286408 0.091314
1.130403 0.217894 0.122575 0.161179 0.668861949 0.405 0.245324 0.116648
1.139986 0.201923 0.131016 0.162782 0.658247986 0.448 0.21067 0.142418
1.193347 0.153455 0.176762 0.164987 0.66002042 0.5052 0.168762 0.180576
1.199924 0.144186 0.182258 0.161577 0.651169792 0.5432 0.143547 0.208354
1.278053 0.096934 0.245338 0.151369 0.651726603 0.6332 0.092115 0.281803
1.31678 0.078601 0.275189 0.145343 0.648157261 0.6605 0.078799 0.306193
1.373566 0.059869 0.31741 0.138548 0.653005117 0.6945 0.06369 0.33793
1.431181 0.043919 0.3585 0.128006 0.653590149 0.7327 0.048659 0.375381
1.484582 0.038615 0.395133 0.11876 0.681490611 0.7752 0.034338 0.419262
1.50297 0.036356 0.407443 0.113468 0.689276323 0.7922 0.029314 0.437464
1.644352 0.016999 0.497346 0.061191 0.732511322 0.908 0.00571 0.571229
1.746713 0.017708 0.557736 0.047518 0.911123332 0.9448 0.002052 0.617274
0 1 0 0.6895

286

0.7 0.8 0.9 1

Values by Using the Margules Equations
0.6895
γ1 γ2 P (Kpa) y1 (P_ex - P_cal)^(2)
2.029318 1 68.728 0 0
1.947751 1.000597 72.21129 0.075001 0.004450155230876
1.872878 1.002354 75.30597 0.137345 0.000727205538334 Pxy data a
1.80193 1.005335 78.14531 0.191681 0.386020126199925 (The Marg
105
1.758286 1.007932 79.84594 0.223164 0.800921088633192
1.6707 1.015309 83.15097 0.282653 0.388090091794904 100
1.535268 1.034484 87.9706 0.36742 1.46071325924756
1.43752 1.05717 91.22332 0.425502 1.28896100674237 95
1.331636 1.095612 94.52431 0.488495 1.73795183856644
1.278036 1.123723 96.10072 0.521829 1.17444821310438 90

1.234505 1.153059 97.32762 0.550543 0.926646336722502

P (kPa)
85
1.183838 1.197907 98.68127 0.587188 1.07177423876896
1.154361 1.23165 99.41923 0.611065 0.916285799639121 80
1.09649 1.325517 100.6826 0.66811 0.759641299912993
1.081986 1.358244 100.9312 0.686003 0.962706282602171 75
1.065762 1.402043 101.1494 0.708967 0.759377355183512
1.049862 1.455546 101.2671 0.735948 0.640122771220986 70

1.034934 1.520839 101.226 0.767875 0.051539282809448

65
1.029748 1.548774 101.1546 0.781334 0.009140840378044 0 0.1 0.2 0.3
1.005727 1.770441 99.66981 0.887685 0.042926384138749
1.002054 1.853867 98.75811 0.928784 1.08344819834803
P-x1 (Corr) P
1 1.992719 96.885 1 0
RMS Deviation 0.81088873
 Pxy data and their correlation
(The Margules Equation)

0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1

x1 , y1
P-x1 (Corr) P-x1 (Exp) P-y1 (Corr) P-y1 (Exp)