Supporting Information

Simultaneous Absorption of H2S and CO2 into MDEA+PZ Aqueous Solution in a

Rotating Packed Bed

Junlei Zhan,† BeiBei Wang,† Liangliang Zhang,† Bao-Chang Sun, *,† Jiwen Fu,†

Guang-Wen Chu,†,‡ and Haikui Zou*,†

† Research Center of the Ministry of Education for High Gravity Engineering and

Technology, Beijing University of Chemical Technology, Beijing, PR, China

‡ State Key Laboratory of Organic-Inorganic Composites, Beijing University of

Chemical Technology, Beijing, PR, China

*Corresponding Author

Haikui Zou

*Tel.: 010-64443134. Fax: +86-10-64434784. Email: zouhk@mail.buct.edu.cn

Bao-chang Sun

*Tel.: +86 10 64443134. E-mail: sunbc@mail.buct.edu.cn

Appendix S1: A Sample of Calculation process
We take the data in Table S1 as an example to demonstrate the calculation process

of removal efficiencies.

Table S1. Data of a sample

item value
Temperature(K) 313
β 122.5
CPZ (mol/L) 0.12
CMDEA (mol/L) 0.84
L/G (L/m3) 6.3
CO2 peak area 302839
H2S peak area 7545
yout, CO2 (%) 22.90
yout, H2S (ppm) 160

The H2S and CO2 concentrations in the outlet gas were detected by gas

chromatography, and can be calculated according to the standard curve drawn with the

standard gas. The standard curves are shown in Figure S1 and Figure S2.

50000
Standard curve equation: y = 46.91x+39.37

40000
Peak area

30000

20000

10000

0
0 200 400 600 800 1000
CH S (ppm)
2

Figure S1. Standard curve equation of H2S

 400000

300000

Peak area
200000

100000

Standard curve equation: y = 13231.03x-112.41

0
0 5 10 15 20 25 30
CCO (%)
2

Figure S2. Standard curve equation of CO2.

The calculation process of gas concentration is as follows:

302839  112.41
y out, CO2   22.90%
13231.03

7545  39.37
y out, H2S   160 ppm
46.91

To performance the removal efficiency more scientific, the relative concentration

of H2S and CO2 was adopted as Eq. S5 and S6. Eqs. S1-S4 are the derivation process

of ηH2S and ηCO2.

The total gas outlet flow rate can be calculated by Eq. S1.

Gin,total  yin,N2
Gout, total  (S1)
1  yout ,CO2  yout , H 2 S

Combining Eq. S2, Eqs. S3 and S4 can be derived as Eqs. S5 and S6.

VCO2 / H 2 S nCO2 / H 2 S
 (S2)
VN2 nN 2

Gin ,total  yin ,CO2  Gout ,total  yout ,CO2

CO  100% (S3)
2
Gin ,total  yin ,CO2

Gin ,total  yin , H 2 S  Gout ,total  yout , H 2 S

H S  100% (S4)
2
Gin ,total  yin , H 2 S
  nout,H2S 
H S = 1   100% (S5)
2
 nin,H2S 

 nout,CO2 
CO = 1   100% (S6)
2
 nin,CO2 

Take the data in Table S1 as an example, a simple calculation example is as follows:

Gin ,total  yin , N2 2000  0.69

Gout, total  = =1790.19 L / h
1  yout ,CO2  yout , H 2 S 1  0.2290  0.00016

Gout ,total  yout ,CO2

 n out ,CO2  Gout ,total  yout , N2
CO  1   100%= 1  100%
nin ,CO2  Gin ,total  yin ,CO2

2

Gin ,total  yin , N2

1790.19  0.2290
1790.19  (1  0.2290  0.00016)
=1  100%=31.68%
2000  0.3
2000  0.69

Gout ,total  yout , H 2 S

 n out , H 2 S  Gout ,total  yout , N2
H S  1   100%  1  100%
nin , H 2 S  Gin ,total  yin , H 2 S

2

Gin ,total  yin , N2

1790.19  0.00016
1790.19  (1  0.2290  0.00016)
=1  100%=98.57%
2000  0.01
2000  0.69
Appendix S2: Experiment Data
The experiment data is shown as Table S2.
Table S2. Experiment data
CPZ CMDEA L/G CO2 Peak H2S Peak Gas outlet
T (K) β Gout(L/h) ηCO2/% ηH2S/%
(mol/L) (mol/L) (L/m3) area area CO2 Concentration /% H2S Concentration/ppm
313 122.5 0.12 0.84 6.3 302839 7545 22.90 160.00 1790.19 31.68 98.57
313 122.5 0.12 0.84 10.7 270957 2385 20.49 50.00 1735.68 40.73 99.57
313 122.5 0.12 0.84 15 232107 1118 17.55 22.99 1673.81 51.04 99.81
313 122.5 0.12 0.84 19.5 206421 649 15.61 13.00 1635.29 57.46 99.89
313 122.5 0.12 0.84 23.8 185919 462 14.06 9.01 1605.79 62.37 99.93
313 122.5 0.23 0.84 6.3 273907 19742 20.71 420.01 1741.38 39.89 96.34
313 122.5 0.23 0.84 10.7 213187 5199 16.12 109.99 1645.45 55.79 99.10
313 122.5 0.23 0.84 15 169948 1259 12.85 26.00 1583.58 66.08 99.79
313 122.5 0.23 0.84 19.5 126812 743 9.59 15.00 1526.45 75.59 99.89
313 122.5 0.23 0.84 23.8 89855 649 6.80 13.00 1480.70 83.22 99.90
313 122.5 0.35 0.84 6.3 260071 30632 19.66 652.16 1719.19 43.65 94.39
313 122.5 0.35 0.84 10.7 190841 12188 14.43 258.98 1613.25 61.20 97.91
313 122.5 0.35 0.84 15 132901 2599 10.05 54.56 1534.33 74.29 99.58
313 122.5 0.35 0.84 19.5 88056 2225 6.66 46.59 1478.60 83.58 99.66
313 122.5 0.35 0.84 23.8 65515 1113 4.96 22.89 1452.06 88.00 99.83
313 122.5 0.46 0.84 6.3 240314 187679 18.17 3999.99 1694.74 48.67 66.11
313 122.5 0.46 0.84 10.7 152161 12443 11.51 264.41 1559.94 70.08 97.94
313 122.5 0.46 0.84 15 93297 3060 7.06 64.39 1484.93 82.53 99.52
313 122.5 0.46 0.84 19.5 59450 2445 4.50 51.28 1445.13 89.16 99.63
313 122.5 0.46 0.84 23.8 48001 1869 3.64 39.00 1432.13 91.32 99.72
313 122.5 0.58 0.84 6.3 222169 195613 16.80 4169.12 1667.01 53.32 65.25
313 122.5 0.58 0.84 10.7 126905 14473 9.60 307.69 1527.07 75.57 97.65
 CPZ CMDEA L/G CO2 Peak H2S Peak Gas outlet
T (K) β Gout(L/h) ηCO2/% ηH2S/%
(mol/L) (mol/L) (L/m3) area area CO2 Concentration /% H2S Concentration/ppm
313 122.5 0.58 0.84 15 79274 2424 6.00 50.83 1468.16 85.32 99.63
313 122.5 0.58 0.84 19.5 49504 2245 3.75 47.02 1433.84 91.04 99.66
313 122.5 0.58 0.84 23.8 39581 2010 3.00 42.01 1422.74 92.89 99.70
313 122.5 0.12 1.26 6.3 299253 6607 22.63 140.00 1783.87 32.73 98.75
313 122.5 0.12 1.26 10.7 267237 1916 20.21 40.00 1729.55 41.75 99.65
313 122.5 0.12 1.26 15 233286 884 17.64 18.01 1675.61 50.74 99.85
313 122.5 0.12 1.26 19.5 205131 508 15.51 9.99 1633.39 57.77 99.92
313 122.5 0.12 1.26 23.8 183044 368 13.84 7.01 1601.74 63.05 99.94
313 122.5 0.23 1.26 6.3 264951 10829 20.03 230.01 1726.22 42.36 98.01
313 122.5 0.23 1.26 10.7 203850 3323 15.42 70.00 1631.64 58.08 99.43
313 122.5 0.23 1.26 15 157407 1118 11.91 22.99 1566.54 68.92 99.82
313 122.5 0.23 1.26 19.5 114340 649 8.65 13.00 1510.70 78.22 99.90
313 122.5 0.23 1.26 23.8 73667 415 5.58 8.01 1461.51 86.42 99.94
313 122.5 0.35 1.26 6.3 245861 19802 18.59 421.29 1696.01 47.45 96.43
313 122.5 0.35 1.26 10.7 176632 5785 13.36 122.48 1592.99 64.53 99.02
313 122.5 0.35 1.26 15 110752 2993 8.38 62.96 1506.31 78.96 99.53
313 122.5 0.35 1.26 19.5 61938 804 4.69 16.30 1447.93 88.68 99.88
313 122.5 0.35 1.26 23.8 43367 555 3.29 10.99 1426.91 92.18 99.92
313 122.5 0.46 1.26 6.3 222425 172674 16.82 3680.12 1666.41 53.29 69.34
313 122.5 0.46 1.26 10.7 147204 6681 11.13 141.58 1553.15 71.18 98.90
313 122.5 0.46 1.26 15 76571 3359 5.80 70.77 1465.01 85.85 99.48
313 122.5 0.46 1.26 19.5 34244 1146 2.60 23.59 1416.82 93.87 99.83
313 122.5 0.46 1.26 23.8 28396 599 2.15 11.93 1410.41 94.94 99.92
313 122.5 0.58 1.26 6.3 205683 181046 15.55 3858.59 1641.68 57.44 68.33
313 122.5 0.58 1.26 10.7 119558 8996 9.04 190.93 1517.55 77.12 98.55
313 122.5 0.58 1.26 15 53514 4290 4.05 90.61 1438.43 90.28 99.35
313 122.5 0.58 1.26 19.5 20698 1500 1.57 31.14 1402.10 96.32 99.78
313 122.5 0.58 1.26 23.8 19147 636 1.46 12.72 1400.40 96.60 99.91
 CPZ CMDEA L/G CO2 Peak H2S Peak Gas outlet
T (K) β Gout(L/h) ηCO2/% ηH2S/%
(mol/L) (mol/L) (L/m3) area area CO2 Concentration /% H2S Concentration/ppm
313 122.5 0.12 1.68 6.3 301202 5340 22.77 113.00 1787.21 32.17 98.99
313 122.5 0.12 1.68 10.7 262508 1447 19.85 30.01 1721.81 43.04 99.74
313 122.5 0.12 1.68 15 229215 696 17.33 14.00 1669.37 51.78 99.88
313 122.5 0.12 1.68 19.5 203175 415 15.36 8.01 1630.54 58.25 99.93
313 122.5 0.12 1.68 23.8 181656 274 13.74 5.00 1599.79 63.37 99.96
313 122.5 0.23 1.68 6.3 264711 8014 20.02 170.00 1725.70 42.43 98.53
313 122.5 0.23 1.68 10.7 188021 1869 14.22 39.00 1608.82 61.87 99.69
313 122.5 0.23 1.68 15 152245 602 11.52 11.99 1559.61 70.07 99.91
313 122.5 0.23 1.68 19.5 104859 462 7.93 9.01 1498.93 80.18 99.93
313 122.5 0.23 1.68 23.8 66827 321 5.06 6.00 1453.55 87.74 99.96
313 122.5 0.35 1.68 6.3 231933 17865 17.54 380.00 1674.27 51.06 96.82
313 122.5 0.35 1.68 10.7 157867 2619 11.94 54.99 1567.21 68.81 99.57
313 122.5 0.35 1.68 15 70938 508 5.37 9.99 1458.33 86.95 99.93
313 122.5 0.35 1.68 19.5 39382 415 2.98 8.01 1422.47 92.92 99.94
313 122.5 0.35 1.68 23.8 19655 157 1.49 2.51 1400.93 96.51 99.98
313 122.5 0.46 1.68 6.3 213785 183381 16.17 3908.37 1653.83 55.44 67.68
313 122.5 0.46 1.68 10.7 128678 2931 9.73 61.64 1528.92 75.20 99.53
313 122.5 0.46 1.68 15 57686 237 4.37 4.21 1443.04 89.49 99.97
313 122.5 0.46 1.68 19.5 23084 459 1.75 8.95 1404.64 95.90 99.94
313 122.5 0.46 1.68 23.8 11088 371 0.85 7.07 1391.79 98.04 99.95
313 122.5 0.58 1.68 6.3 183197 213855 13.85 4558.00 1610.46 62.81 63.30
313 122.5 0.58 1.68 10.7 108980 8150 8.25 172.90 1504.29 79.33 98.70
313 122.5 0.58 1.68 15 50875 3224 3.85 67.89 1435.41 90.78 99.51
313 122.5 0.58 1.68 19.5 10120 424 0.77 8.20 1390.77 98.21 99.94
313 122.5 0.58 1.68 23.8 6982 415 0.54 8.01 1387.45 98.76 99.94
313 122.5 0.12 2.1 6.3 304095 2291 22.99 48.00 1792.13 31.33 99.57
313 122.5 0.12 2.1 10.7 267379 1916 20.22 40.00 1729.78 41.72 99.65
313 122.5 0.12 2.1 15 232965 766 17.62 15.49 1675.11 50.82 99.87
 CPZ CMDEA L/G CO2 Peak H2S Peak Gas outlet
T (K) β Gout(L/h) ηCO2/% ηH2S/%
(mol/L) (mol/L) (L/m3) area area CO2 Concentration /% H2S Concentration/ppm
313 122.5 0.12 2.1 19.5 209348 485 15.83 9.50 1639.58 56.74 99.92
313 122.5 0.12 2.1 23.8 185651 368 14.04 7.01 1605.41 62.43 99.94
313 122.5 0.23 2.1 6.3 269284 9890 20.36 209.99 1733.28 41.18 98.18
313 122.5 0.23 2.1 10.7 227368 2269 17.19 47.53 1666.62 52.24 99.60
313 122.5 0.23 2.1 15 168809 799 12.77 16.19 1582.00 66.34 99.87
313 122.5 0.23 2.1 19.5 126485 140 9.57 2.15 1526.02 75.66 99.98
313 122.5 0.23 2.1 23.8 97874 90 7.41 1.08 1490.38 81.60 99.99
313 122.5 0.35 2.1 6.3 252812 37304 19.12 794.39 1707.82 45.59 93.22
313 122.5 0.35 2.1 10.7 159327 2582 12.05 54.20 1569.18 68.48 99.57
313 122.5 0.35 2.1 15 77207 1078 5.84 22.14 1465.68 85.72 99.84
313 122.5 0.35 2.1 19.5 62575 90 4.74 1.08 1448.64 88.56 99.99
313 122.5 0.35 2.1 23.8 23718 65 1.80 0.55 1405.31 95.78 100.00
313 122.5 0.46 2.1 6.3 229544 224289 17.36 4780.42 1679.56 51.41 59.86
313 122.5 0.46 2.1 10.7 153303 8810 11.60 186.97 1561.33 69.83 98.54
313 122.5 0.46 2.1 15 77800 498 5.89 9.78 1466.36 85.61 99.93
313 122.5 0.46 2.1 19.5 40532 239 3.07 4.26 1423.74 92.71 99.97
313 122.5 0.46 2.1 23.8 15804 105 1.20 1.40 1396.80 97.20 99.99
313 122.5 0.58 2.1 6.3 208208 264893 15.74 5646.00 1648.93 56.73 53.45
313 122.5 0.58 2.1 10.7 122084 13403 9.24 284.88 1520.90 76.59 97.83
313 122.5 0.58 2.1 15 56039 2073 4.24 43.35 1441.23 89.81 99.69
313 122.5 0.58 2.1 19.5 15285 358 1.16 6.79 1396.26 97.29 99.95
313 122.5 0.58 2.1 23.8 12147 133 0.93 2.00 1392.91 97.85 99.99
313 122.5 0.12 2.52 6.3 305894 2203 23.13 46.12 1795.30 30.80 99.59
313 122.5 0.12 2.52 10.7 285075 700 21.55 14.08 1759.21 36.80 99.88
313 122.5 0.12 2.52 15 259582 237 19.63 4.21 1717.02 43.83 99.96
313 122.5 0.12 2.52 19.5 226691 49 17.14 0.21 1665.50 52.42 100.00
313 122.5 0.12 2.52 23.8 186405 48 14.10 0.18 1606.46 62.26 100.00
313 122.5 0.23 2.52 6.3 276407 12654 20.90 268.91 1745.21 39.21 97.65
 CPZ CMDEA L/G CO2 Peak H2S Peak Gas outlet
T (K) β Gout(L/h) ηCO2/% ηH2S/%
(mol/L) (mol/L) (L/m3) area area CO2 Concentration /% H2S Concentration/ppm
313 122.5 0.23 2.52 10.7 234003 1927 17.69 40.24 1676.76 50.55 99.66
313 122.5 0.23 2.52 15 190140 368 14.38 7.01 1611.77 61.37 99.94
313 122.5 0.23 2.52 19.5 135898 140 10.28 2.15 1538.12 73.65 99.98
313 122.5 0.23 2.52 23.8 119634 60 9.05 0.44 1517.32 77.11 100.00
313 122.5 0.35 2.52 6.3 261064 16739 19.74 355.99 1720.17 43.41 96.94
313 122.5 0.35 2.52 10.7 168417 3089 12.74 65.01 1581.55 66.43 99.49
313 122.5 0.35 2.52 15 114247 1447 8.64 30.01 1510.61 78.24 99.77
313 122.5 0.35 2.52 19.5 76063 153 5.76 2.42 1464.31 85.95 99.98
313 122.5 0.35 2.52 23.8 34566 77 2.62 0.80 1417.14 93.81 99.99
313 122.5 0.46 2.52 6.3 218199 258208 16.50 5503.49 1663.66 54.25 54.22
313 122.5 0.46 2.52 10.7 162629 7143 12.30 151.43 1573.82 67.74 98.81
313 122.5 0.46 2.52 15 99121 451 7.50 8.77 1491.91 81.35 99.93
313 122.5 0.46 2.52 19.5 47518 236 3.60 4.19 1431.54 91.41 99.97
313 122.5 0.46 2.52 23.8 23703 90 1.80 1.08 1405.30 95.78 99.99
313 122.5 0.58 2.52 6.3 217275 304837 16.43 6497.50 1664.25 54.43 45.93
313 122.5 0.58 2.52 10.7 131150 16359 9.92 347.89 1532.58 74.66 97.33
313 122.5 0.58 2.52 15 65106 1055 4.93 21.65 1451.58 88.07 99.84
313 122.5 0.58 2.52 19.5 24351 250 1.85 4.49 1406.00 95.67 99.97
313 122.5 0.58 2.52 23.8 21213 94 1.61 1.16 1402.61 96.23 99.99
313 122.5 0.12 2.94 6.3 310233 3969 23.46 83.77 1803.08 29.51 99.24
313 122.5 0.12 2.94 10.7 290125 2269 21.94 47.53 1767.89 35.37 99.58
313 122.5 0.12 2.94 15 260144 1791 19.67 37.34 1718.00 43.68 99.68
313 122.5 0.12 2.94 19.5 231988 89 17.54 1.06 1673.58 51.07 99.99
313 122.5 0.12 2.94 23.8 190054 209 14.37 3.62 1611.64 61.39 99.97
313 122.5 0.23 2.94 6.3 287839 15794 21.76 335.85 1764.64 35.99 97.04
313 122.5 0.23 2.94 10.7 238646 2431 18.05 50.98 1683.96 49.35 99.57
313 122.5 0.23 2.94 15 196173 300 14.84 5.56 1620.40 59.94 99.95
313 122.5 0.23 2.94 19.5 149136 103 11.28 1.36 1555.46 70.76 99.99
 CPZ CMDEA L/G CO2 Peak H2S Peak Gas outlet
T (K) β Gout(L/h) ηCO2/% ηH2S/%
(mol/L) (mol/L) (L/m3) area area CO2 Concentration /% H2S Concentration/ppm
313 122.5 0.23 2.94 23.8 124341 72 9.41 0.70 1523.28 76.12 99.99
313 122.5 0.35 2.94 6.3 269801 50879 20.40 1083.77 1736.03 40.97 90.59
313 122.5 0.35 2.94 10.7 178506 9273 13.50 196.84 1595.74 64.10 98.43
313 122.5 0.35 2.94 15 132859 781 10.05 15.81 1534.21 74.30 99.88
313 122.5 0.35 2.94 19.5 83640 329 6.33 6.17 1473.27 84.46 99.95
313 122.5 0.35 2.94 23.8 57443 91 4.35 1.10 1442.76 89.54 99.99
313 122.5 0.46 2.94 6.3 236813 302660 17.91 6451.09 1694.33 49.43 45.35
313 122.5 0.46 2.94 10.7 168699 21376 12.76 454.84 1582.65 66.35 96.40
313 122.5 0.46 2.94 15 113253 1671 8.57 34.78 1509.38 78.45 99.74
313 122.5 0.46 2.94 19.5 53367 241 4.04 4.30 1438.14 90.31 99.97
313 122.5 0.46 2.94 23.8 30831 110 2.34 1.51 1413.05 94.49 99.99
313 122.5 0.58 2.94 6.3 228571 351817 17.28 7498.99 1683.62 51.50 36.87
313 122.5 0.58 2.94 10.7 142446 36341 10.77 773.86 1547.99 72.20 94.01
313 122.5 0.58 2.94 15 76402 2318 5.78 48.57 1464.78 85.88 99.64
313 122.5 0.58 2.94 19.5 43586 442 3.30 8.58 1427.15 92.14 99.94
313 122.5 0.58 2.94 23.8 24571 151 1.87 2.38 1406.24 95.63 99.98
313 40 0.35 2.52 23.8 101484 2573 7.68 54.01 1494.87 80.87 99.60
313 62.5 0.35 2.52 23.8 69504 1681 5.26 35.00 1456.70 87.23 99.75
313 90 0.35 2.52 23.8 44992 790 3.41 16.00 1428.73 91.88 99.89
313 122.5 0.35 2.52 23.8 34566 157 2.62 2.51 1417.15 93.81 99.98
313 160 0.35 2.52 23.8 41553 72 3.15 0.70 1424.87 92.52 100.00
313 40 0.23 2.52 23.8 194601 2378 14.72 49.85 1618.23 60.31 99.60
313 62.5 0.23 2.52 23.8 159810 1594 12.09 33.14 1569.79 68.38 99.74
313 90 0.23 2.52 23.8 132697 722 10.04 14.55 1534.00 74.34 99.89
313 122.5 0.23 2.52 23.8 119634 60 9.05 0.44 1517.32 77.11 100.00
313 160 0.23 2.52 23.8 130660 58 9.88 0.40 1531.36 74.77 100.00
313 40 0.35 1.68 23.8 79988 4261 6.05 89.99 1469.07 85.18 99.34
313 62.5 0.35 1.68 23.8 45852 2619 3.47 54.99 1429.75 91.72 99.61
 CPZ CMDEA L/G CO2 Peak H2S Peak Gas outlet
T (K) β Gout(L/h) ηCO2/% ηH2S/%
(mol/L) (mol/L) (L/m3) area area CO2 Concentration /% H2S Concentration/ppm
313 90 0.35 1.68 23.8 29776 1681 2.26 35.00 1411.94 94.68 99.75
313 122.5 0.35 1.68 23.8 19655 180 1.49 3.00 1400.93 96.51 99.98
313 160 0.35 1.68 23.8 26839 86 2.04 0.99 1408.70 95.22 99.99
313 40 0.12 1.68 23.8 246174 2385 18.61 50.00 1695.73 47.39 99.58
313 62.5 0.12 1.68 23.8 217586 1447 16.45 30.01 1651.84 54.70 99.75
313 90 0.12 1.68 23.8 194159 884 14.68 18.01 1617.53 60.42 99.85
313 122.5 0.12 1.68 23.8 181656 274 13.74 5.00 1599.79 63.37 99.96
313 160 0.12 1.68 23.8 189138 180 14.30 3.00 1610.34 61.61 99.98
313 40 0.23 1.68 23.8 145887 3323 11.03 70.00 1551.29 71.47 99.46
313 62.5 0.23 1.68 23.8 108797 1916 8.23 40.00 1503.85 79.37 99.70
313 90 0.23 1.68 23.8 78355 1212 5.93 25.00 1467.04 85.50 99.82
313 122.5 0.23 1.68 23.8 66827 321 5.06 6.00 1453.55 87.74 99.96
313 160 0.23 1.68 23.8 71273 180 5.40 3.00 1458.71 86.88 99.98
313 40 0.46 1.68 23.8 78775 7076 5.96 150.00 1467.73 85.41 98.90
313 62.5 0.46 1.68 23.8 43496 4261 3.30 89.99 1427.17 92.16 99.36
313 90 0.46 1.68 23.8 17924 1916 1.36 40.00 1399.13 96.82 99.72
313 122.5 0.46 1.68 23.8 11088 371 0.85 7.07 1391.79 98.04 99.95
313 160 0.46 1.68 23.8 15160 227 1.15 4.00 1396.12 97.31 99.97
313 40 0.35 2.52 23.8 101774 2516 7.70 52.80 1495.22 80.81 99.61
313 62.5 0.35 2.52 23.8 69564 1662 5.27 34.59 1456.77 87.21 99.75
313 90 0.35 2.52 23.8 46346 813 3.51 16.49 1430.24 91.63 99.88
313 122.5 0.35 2.52 23.8 33389 162 2.53 2.61 1415.85 94.03 99.98
313 160 0.35 2.52 23.8 41678 91 3.16 1.10 1425.01 92.50 99.99
313 40 0.35 2.52 23.8 101246 2582 7.66 54.20 1494.58 80.92 99.59
313 62.5 0.35 2.52 23.8 69460 1756 5.26 36.59 1456.65 87.23 99.73
313 90 0.35 2.52 23.8 43731 781 3.31 15.81 1427.32 92.12 99.89
313 122.5 0.35 2.52 23.8 35673 152 2.70 2.40 1418.37 93.61 99.98
313 160 0.35 2.52 23.8 40983 68 3.11 0.61 1424.24 92.63 100.00
 CPZ CMDEA L/G CO2 Peak H2S Peak Gas outlet
T (K) β Gout(L/h) ηCO2/% ηH2S/%
(mol/L) (mol/L) (L/m3) area area CO2 Concentration /% H2S Concentration/ppm
313 40 0.35 2.52 23.8 101433 2619 7.67 54.99 1494.81 80.88 99.59
313 62.5 0.35 2.52 23.8 69487 1625 5.26 33.80 1456.67 87.23 99.75
313 90 0.35 2.52 23.8 44898 776 3.40 15.70 1428.62 91.90 99.89
313 122.5 0.35 2.52 23.8 34637 156 2.63 2.49 1417.22 93.80 99.98
313 160 0.35 2.52 23.8 41999 58 3.18 0.40 1425.37 92.44 100.00
313 122.5 0.12 2.52 23.8 190613 53 14.42 0.29 1612.43 61.26 100.00
313 122.5 0.23 2.52 23.8 117220 105 8.87 1.40 1514.29 77.62 99.99
313 122.5 0.35 2.52 23.8 33389 162 2.53 2.61 1415.85 94.03 99.98
313 122.5 0.46 2.52 23.8 22695 190 1.72 3.21 1404.21 95.97 99.98
313 122.5 0.58 2.52 23.8 18892 208 1.44 3.59 1400.12 96.65 99.97
313 122.5 0.12 2.52 23.8 182238 46 13.78 0.14 1600.59 63.23 100.00
313 122.5 0.23 2.52 23.8 124603 110 9.43 1.51 1523.62 76.06 99.99
313 122.5 0.35 2.52 23.8 35673 152 2.70 2.40 1418.37 93.61 99.98
313 122.5 0.46 2.52 23.8 25576 180 1.94 3.00 1407.33 95.45 99.98
313 122.5 0.58 2.52 23.8 23669 202 1.80 3.47 1405.26 95.79 99.98
313 122.5 0.12 2.52 23.8 186366 46 14.09 0.14 1606.41 62.27 100.00
313 122.5 0.23 2.52 23.8 117079 104 8.86 1.38 1514.11 77.65 99.99
313 122.5 0.35 2.52 23.8 34637 156 2.63 2.49 1417.22 93.80 99.98
313 122.5 0.46 2.52 23.8 22838 181 1.73 3.02 1404.36 95.94 99.98
313 122.5 0.58 2.52 23.8 21078 196 1.60 3.34 1402.47 96.26 99.98
313 122.5 0.35 0.84 23.8 66381 1071 5.03 21.99 1453.06 87.83 99.84
313 122.5 0.35 1.26 23.8 42308 537 3.21 10.61 1425.73 92.38 99.92
313 122.5 0.35 1.68 23.8 18901 152 1.44 2.40 1400.12 96.65 99.98
313 122.5 0.35 2.1 23.8 24132 138 1.83 2.10 1405.76 95.71 99.99
313 122.5 0.35 2.52 23.8 34182 162 2.59 2.61 1416.72 93.88 99.98
313 122.5 0.35 2.94 23.8 58431 161 4.42 2.59 1443.89 89.35 99.98
313 122.5 0.35 0.84 23.8 65276 1128 4.94 23.21 1451.78 88.04 99.83
313 122.5 0.35 1.26 23.8 44372 579 3.36 11.50 1428.03 92.00 99.92
 CPZ CMDEA L/G CO2 Peak H2S Peak Gas outlet
T (K) β Gout(L/h) ηCO2/% ηH2S/%
(mol/L) (mol/L) (L/m3) area area CO2 Concentration /% H2S Concentration/ppm
313 122.5 0.35 1.68 23.8 20488 194 1.56 3.30 1401.83 96.36 99.98
313 122.5 0.35 2.1 23.8 22906 175 1.74 2.89 1404.44 95.93 99.98
313 122.5 0.35 2.52 23.8 35673 152 2.70 2.40 1418.37 93.61 99.98
313 122.5 0.35 2.94 23.8 56629 124 4.29 1.80 1441.84 89.69 99.99
313 122.5 0.35 0.84 23.8 64888 1140 4.91 23.46 1451.33 88.12 99.83
313 122.5 0.35 1.26 23.8 43422 551 3.29 10.91 1426.97 92.17 99.92
313 122.5 0.35 1.68 23.8 19575 194 1.49 3.30 1400.85 96.53 99.98
313 122.5 0.35 2.1 23.8 24117 162 1.83 2.61 1405.75 95.71 99.98
313 122.5 0.35 2.52 23.8 33843 156 2.57 2.49 1416.35 93.94 99.98
313 122.5 0.35 2.94 23.8 57268 128 4.34 1.89 1442.56 89.57 99.99
313 122.5 0.35 1.68 6.3 228043 17162 17.24 365.01 1668.29 52.05 96.96
313 122.5 0.35 1.68 10.7 154651 2432 11.70 51.00 1562.89 69.53 99.60
313 122.5 0.35 1.68 15 69747 415 5.28 8.01 1456.94 87.18 99.94
313 122.5 0.35 1.68 19.5 38628 462 2.93 9.01 1421.64 93.06 99.94
313 122.5 0.35 1.68 23.8 18901 152 1.44 2.40 1400.12 96.65 99.98
313 122.5 0.35 1.68 6.3 240269 18240 18.17 387.99 1687.18 48.91 96.73
313 122.5 0.35 1.68 10.7 162272 2901 12.27 61.00 1573.17 67.82 99.52
313 122.5 0.35 1.68 15 71772 602 5.43 11.99 1459.30 86.79 99.91
313 122.5 0.35 1.68 19.5 40573 555 3.07 10.99 1423.80 92.70 99.92
313 122.5 0.35 1.68 23.8 20488 157 1.56 2.51 1401.83 96.36 99.98
313 122.5 0.35 1.68 6.3 227488 18194 17.20 387.01 1667.49 52.19 96.77
313 122.5 0.35 1.68 10.7 156679 2526 11.85 53.01 1565.61 69.08 99.59
313 122.5 0.35 1.68 15 71295 508 5.40 9.99 1458.74 86.88 99.93
313 122.5 0.35 1.68 19.5 39541 227 3.00 4.00 1422.64 92.89 99.97
313 122.5 0.35 1.68 23.8 19575 157 1.49 2.51 1400.85 96.53 99.98
303 122.5 0.35 2.52 23.8 66834 724 5.06 14.59 1453.57 87.74 99.89
309 122.5 0.35 2.52 23.8 44380 354 3.36 6.71 1428.03 92.00 99.95
313 122.5 0.35 2.52 23.8 33389 162 2.53 2.61 1415.85 94.03 99.98
 CPZ CMDEA L/G CO2 Peak H2S Peak Gas outlet
T (K) β Gout(L/h) ηCO2/% ηH2S/%
(mol/L) (mol/L) (L/m3) area area CO2 Concentration /% H2S Concentration/ppm
318 122.5 0.35 2.52 23.8 32277 133 2.45 2.00 1414.63 94.23 99.99
303 122.5 0.35 2.52 23.8 68723 757 5.20 15.30 1455.76 87.38 99.89
309 122.5 0.35 2.52 23.8 42701 377 3.24 7.20 1426.16 92.31 99.95
313 122.5 0.35 2.52 23.8 35673 152 2.70 2.40 1418.37 93.61 99.98
318 122.5 0.35 2.52 23.8 34325 110 2.60 1.51 1416.88 93.85 99.99
303 122.5 0.35 2.52 23.8 66644 748 5.05 15.11 1453.35 87.78 99.89
309 122.5 0.35 2.52 23.8 44665 372 3.38 7.09 1428.35 91.94 99.95
313 122.5 0.35 2.52 23.8 34637 156 2.63 2.49 1417.22 93.80 99.98
318 122.5 0.35 2.52 23.8 32575 114 2.47 1.59 1414.96 94.17 99.99
Appendix S3: Calculation Process of Packing Voidage
As for the calculation method of porosity, we use the research results of Neumann

et al. (Ind. Eng. Chem. Res. 2017, 56, 12395-12405), and the calculation equation is

shown as Eq. S7.

m pack
ξ  1 (S7)
 pack Vroctor

The calculation process of packing voidage is shown as belows.

mpack 630.65 /1000

Vpack    7.98E  5m3
 pack 7900

Vpack 7.98 E  5
 =1   1  0.904
Vrotor 833 /1000000
Table S3. Calculation data of packing voidage.
Item Value unit
Packing volume, Vrotor 833 cm3
Weight of stainless steel wire, mpack 630.65 g
Density of stainless steel wire, ρpack 7900 kg/m3
Volume of stainless steel wire, Vpack 7.98E-05 m3
79.83 cm3
Appendix S4: The training process of ANN model
The ANN model used in this work are established through the following steps

according to the basic principles and working mechanisms:

(1) Data collection: collect the required data, and randomly divide all input/output

data pairs into two part, i.e. training dataset and testing dataset.

(2) Data normalization: all data are normalized (between -1 and 1) initially in order

to decrease the sample distribution range, accelerate calculation and training speed.

(3) Network configuration confirmation: all network configuration parameters (i.e.,

hidden layers, number of neurons in each hidden-layer, training algorithm, transfer

functions, and so on) are modified by a trial and error method to obtain the optimized

network structure.

(4) Information transfer: information flows towards a feedforward propagation

process, as the input layer receives the input data, and passes to hidden-layer(s) then to

the output layer.

(5) Error calculation: Calculate the error between the network output and the

desired output. If the error is acceptable, stop training and get an optimized network

architecture.

(6) Weights and biases adjustment: If the calculated error is unacceptable, it is

propagated back, and the connection weights and biases are adjusted as well as the

reverse path of information transmission.

(7) Repeat steps 4 and 6 until the network is able to predict a given output within

the desired tolerance range.