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Aysun Özkan
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Abstract
Life cycle assessment (LCA) methodology was used to determine the optimum municipal solid waste (MSW) management strategy for
Eskisehir city. Eskisehir is one of the developing cities of Turkey where a total of approximately 750 tons/day of waste is generated. An
effective MSW management system is needed in this city since the generated MSW is dumped in an unregulated dumping site that has no
liner, no biogas capture, etc. Therefore, five different scenarios were developed as alternatives to the current waste management system.
Collection and transportation of waste, a material recovery facility (MRF), recycling, composting, incineration and landfilling processes
were considered in these scenarios. SimaPro7 libraries were used to obtain background data for the life cycle inventory. One ton of muni-
cipal solid waste of Eskisehir was selected as the functional unit. The alternative scenarios were compared through the CML 2000 method
and these comparisons were carried out from the abiotic depletion, global warming, human toxicity, acidification, eutrophication and
photochemical ozone depletion points of view. According to the comparisons and sensitivity analysis, composting scenario, S3, is the
more environmentally preferable alternative.
In this study waste management alternatives were investigated only on an environmental point of view. For that reason, it might be
supported with other decision-making tools that consider the economic and social effects of solid waste management.
Ó 2008 Elsevier Ltd. All rights reserved.
0956-053X/$ - see front matter Ó 2008 Elsevier Ltd. All rights reserved.
doi:10.1016/j.wasman.2007.12.006
M. Banar et al. / Waste Management 29 (2009) 54–62 55
a MSW
100 %
Scavengers, 3 %
97 %
MRF
Papercardboard Papercardboard
3.40 % 2.04 %
Plastic Glass
2.00 % 0.71 %
Glass Aluminum
1.18 % 0.25 %
Aluminum
0.42 %
Others
90 %
Landfill
Recycling
(in other city)
Landfill
(in other city)
b MSW
100 %
Source separation, 9.72 %
90.28 %
MRF
Papercardboard Paper-cardboard
4.53 % 5.04%
Plastic Plastic
2.53% 2.81%
Glass Glass
1.12 % 1.25 %
Aluminum Aluminum
0.57 % 0.63 %
Others
81.53 %
Landfill
Recycling
(in other city)
Landfill
(in other city)
Fig. 1. Flowcharts of the scenarios (after efficiencies). (a) Scenario 1 (S1): 7.5% recycling + 92.5% landfilling. (b) Scenario 2 (S2): 15% recycling + 85%
landfilling. (c) Scenario 3 (S3): 15% recycling + 77% composting + 8% landfilling. (d) Scenario 4 (S4): 15% recycling + 85% incineration and (e) Scenario 5
(S5): 100% incineration. (The percentages represent the proportion of the total municipal solid waste stream.)
M. Banar et al. / Waste Management 29 (2009) 54–62 57
c MSW
100 %
Source separation, 9.72 %
90.28 %
MRF
Papercardboard Paper-cardboard
4.53 % 5.04%
Plastic Plastic
2.53% 2.81%
Glass Glass
1.12 % 1.25 %
Aluminum Aluminum
0.57 % 0.63 %
Organics
76.69 % Recycling
(in other city)
Others
4.84 %
Landfill
Composting (in other city)
Landfill Residuals
d MSW
100 %
Source separation, 9.72%
90.28 %
MRF
Papercardboard Paper-cardboard
4.53 % 5.04%
Plastic Plastic
2.53% 2.81%
e
Glass Glass
1.12 % 1.25 % MSW
Incineration Landfill
(100 %)
(100 %) Residuals
Aluminum Aluminum
0.57 % 0.63 %
Others
81.53 %
Incineration
Recycling
(in other city)
Residuals
Landfill Landfill
(in other city)
Fig. 1 (continued)
58 M. Banar et al. / Waste Management 29 (2009) 54–62
scavengers is sent to the MRF, which was located on the major stages: goal and scope definition, life cycle inventory,
landfill site. The rest of the recyclables (4.30%) was sepa- life cycle impact analysis and interpretation of the results.
rated in the MRF. These two parts were processed sepa-
rately since their qualities are different. After separation, 3.1. Goal and scope definition
recyclable materials are sent to the recycling facilities
located in other cities. Recycling efficiencies for these mate- The aim of this study is to select an optimum waste man-
rials are 80% and 70% for the materials brought by scav- agement system for Eskisehir by evaluating, from an envi-
engers and those separated in the MRF, respectively. The ronmental point of view, alternatives to the existing system.
residuals after the recycling process were landfilled in the It is thought that the results of the study would be helpful
city where the recycling was undertaken. The restwaste for the Metropolitan municipality and submunicipalities of
(92.70%) was landfilled in Eskisehir. Eskisehir.
Scenario 2: In this scenario a source separation system
with efficiency of 50% was added as an improvement to 3.1.1. Functional unit
Scenario 1. The recyclables obtained from source separa- The functional unit selected for the comparison of the
tion (9.72%) were sent to the MRF, and after processing alternative scenarios is the management of 1 ton of munici-
they were sent to the recycling facilities in other cities to pal solid waste of Eskisehir.
recycle, at an efficiency of 92%. The recyclables mixed in
organic waste were also processed and sent to the recycling 3.1.2. System boundaries
facility with an efficiency of 70%. After the recycling pro- The system of the study starts with collection of MSW
cess, residuals are sent to the landfills. from residential areas and includes waste transport, waste
Scenario 3: This scenario emphasizes the recovery of the treatment alternatives (recycling, composting and incinera-
biologically degradable fraction. The flow of the system is tion) and landfilling of waste. The system was limited at the
similar to Scenario 2 for recyclable materials, while organic landfilling of residual materials after treatment processes.
fraction (77%) from the MRF is transported to the compo- Life cycle analyses of the secondary materials obtained
sting facility. The residue from the MRF is sent to the land- from the recycling and composting processes were not con-
fill (8.24%). sidered. Fig. 2 shows the system boundaries.
Scenario 4: An incineration process was added to system
instead of a composting facility. In this case, all organic 3.2. Life cycle inventory
wastes and the wastes from the separated recyclables are
transported to the incinerator (85%). The data for life cycle inventory was gathered from
Scenario 5: In this scenario it was considered that all actual applications in Eskisehir, literature and the database
MSW is sent to the incineration facility (100%). of the SimaPro7. The database of the software was
adjusted to the conditions in Turkey. The DQI (Data Qual-
3. Methodology ity Indicators) option of the software was used to select the
most suitable system for data quality indicators such as
The LCA methodology has been used to conduct an time, geography, technology and representativeness.
environmental comparison of the alternative scenarios to
the current waste management system. This evaluation 3.2.1. Collection and transport
was conducted according to TSE EN ISO 14040 (1996). There are two submunicipalities in Eskisehir; Tepebasi
According to TSE ISO 14040, an LCA comprises four and Odunpazari. Tepebasi and Odunpazari were divided
Waste source
Transport
Atmospheric
Transport emissions
Recycling facility / facilities
Waterborme
MRF Transport emissions
Raw
Materials
Solid emissions
Compost Composting Incineration Energy
Energy
Residuals
Landfilling Energy
into 26 and 25 districts, respectively, according to the data 96 (2004) data for Turkey in collaboration with these
gathered from these submunicipalities. Half of the MSW in ratios. This average data was also used to calculate the
Odunpazari is collected on even days and the other part is emissions saved by energy displaced by energy from waste,
collected on single days of the week; the district where the i.e. landfill gas and incineration.
waste generation is high is collected every night. The MSW
is collected every day in Tepebasi. 3.2.3. Recycling and material recovery facility (MRF)
In this study, new infrastructure was considered to be Mixed recyclables and separated recyclables (depending
located at the same site to take advantage of economic on the scenario) were sent to a MRF. Electricity consump-
and environmental cost savings; therefore, it was assumed tion of the MRF for sorting equipment and compressing
that the MRF, compost facility, incinerator and landfill bales was 0.059 kW h/ton (Bovea and Powell, 2006).
were at the same site, which would decrease the environ- It was considered that processes before recycling were
mental and economic effects of transport. carried out in three ways scavengers, source separation
Private recycling facilities licensed by the Turkey Min- and MRF. Recycling data was obtained from the Buwal
istry of Environment and Forestry were investigated, and 250 library of the SimaPro7. Also, different efficiencies that
the closest recycling facilities were selected since there are were used for different collection types are given as
no facilities of this type in Eskisehir. The recycling facil-
ities in Ankara city (233 km) were selected for paper, Source separation of recyclables: 50%.
plastic and aluminum recycling, while Kocaeli city Separation of recyclables from mixed waste: 70%.
(219 km) was selected for glass recycling. The calculated Recycling of recyclables after source separation: 92%.
total recycling rates and transport distances are given in Recycling of recyclables collected by scavengers: 80%.
Table 3. Recycling of recyclables after separation of recyclables
from mixed waste: 70%.
3.2.2. Electrical energy
The source ratios used in electric generation in Turkey
are given in the Table 4, according to the 2006 program 3.2.4. Composting
of TEIAS (The Transmission System Operator of Turkey). A chemical formula (C333H528O195N16PS) for composta-
A medium voltage mixed electricity profile of the city has ble waste (that includes food and yard waste) based on the
been created by using Buwal 250 (2004) and ETH-ESU Eskisehir MSW composition was formed by using elemen-
tal analysis (C, H, O, N, S, P) results taken from Tchoba-
noglous et al. (1993). Furthermore, N and P values for
Table 3 the compost produce were calculated by using this chemical
Total recycling rates and transport distances for the scenarios formula (28.2 kg N/ton waste; 3.9 kg P/ton waste). The
Collection (km/ Transport for recycling organic material obtained from the composting process is
ton MSW) Total recycling Transport used as a fertilizer. The avoided material is a chemical fer-
rates (%) distance (km) tilizer containing an equivalent amount of nutrients (N and
Scenario 1 4.11 Paper– 5.44 233 P). Also, CO2 and NH3 emissions after composting were
cardboard calculated by using the same chemical formula (1.85 ton
Plastic 2.00 233 CO2/ton waste; 0.37 ton NH3/ton waste).
Glass 1.89 219
Aluminum 0.67 233
The life cycle inventory data for the chemical N and P
Scenarios 4.11 Paper– 10.07 233 fertilizer avoided is obtained from the IDEMAT 2001
2/3/4 cardboard library of the SimaPro7. According to Bovea and Powell
Plastic 5.62 233 (2006), the energy consumption during the composting
Glass 2.49 219 process is due to electricity demand (54.4 MJ/ton of input
Aluminum 1.26 233
Scenario5 4.11 –
to the composting process) and the consumption of diesel
in the wheel loader, mills and strainers (555.5 MJ/ton of
Return of the collection vehicle from the waste area was not considered.
input to the composting process).
3.2.5. Incineration
Table 4
Electrical energy sources and their contributions in Turkey The incineration process was considered in scenarios 4
and 5. Scenario 5 does not have a recycling process. The
Energy sources Contribution of energy sources (%)
Buwal 250 library for the 2000 data was used for incinera-
Fuel-oil 2.9
tion of plastic, glass, paper and aluminum. Buwal 250
Coal 7.6
Lignite 21.8 (2000) data reflects the future technology, and the inciner-
Natural gas 44.7 ator of the year 2000 has a more advanced flue gas treat-
Hydraulic energy 23.0 ment and mainly catalytic deNOx treatment. It was
Total 100.0 determined that the incinerator of the year 2000 supplies
Source: calculated from 2006 program of TEIAS. the requirements of 2007.
60 M. Banar et al. / Waste Management 29 (2009) 54–62
Atmospheric emissions from the incineration of organic of 100 years (GWP100), in kg carbon dioxide/kg emission
waste were calculated by using the chemical formula (Goedkoop et al., 2004).
(C333H528O195N16PS) of the organic fraction of MSW.
3.3.3. Human toxicity
3.2.6. Landfilling Characterization factors, expressed as Human Toxicity
Landfill processes for the scenarios were performed by Potentials (HTP), are calculated with USES-LCA, describ-
using the Buwal 250 library of the SimaPro7. In these land- ing fate, exposure and effects of toxic substances for an infi-
fill processes, production of biogas is at 200 m3/ton wastes nite time horizon. For each toxic substance, HTPs are
(47% methane, 37% carbon dioxide, 13% nitrogen); 47% is expressed as 1,4-dichlorobenzene equivalents/kg emission
directly emitted into the air and 53% is combusted. Energy (Goedkoop et al., 2004).
production from biogas combustion is regarded as a co-
product without emissions. The use of methane produced 3.3.4. Acidification
by the landfill is 31% of the total gas production for pro- The major acidifying pollutants are SO2, NOx, HCl and
duction of electricity and heat. The final efficiency is only NH3. What acidifying pollutants have in common is that
11% of the total energy content of the gas produced. The they form acidifying H+ ions. A pollutant’s potential for
energy production is deducted in the energy use of the total acidification can thus be measured by its capacity to form
system and is product specific allocated, depending on the H+ ions. The acidification potential is defined as the num-
degradability of the materials. ber of H+ ions produced per kg substance relative to SO2
(Bauman and Tillman, 2004).
3.3. Life cycle impact assessment
3.3.5. Eutrophication
In this study, six impact categories included by the Eutrophication is a phenomenon that can influence ter-
CML 2000 method (CML 2 baseline 2000 method is restrial as well as aquatic ecosystems. Nitrogen (N) and
an update from the CML 1992 method) were investi- phosphorus (P) are the two nutrients most implicated in
gated: abiotic depletion, global warming, human toxicity, eutrophication. Eutrophication potentials are often
acidification, eutrophication, and photochemical oxida- expressed as PO4 3 equivalents (Bauman and Tillman,
tion. Characteristics of the impact categories are dis- 2004).
cussed below.
3.3.6. Photochemical oxidation
3.3.1. Depletion of abiotic resources This impact indicator defines substances with the poten-
This impact category indicator is related to extraction of tial to contribute to photochemical ozone formation as vol-
minerals and fossil fuels due to inputs in the system. The atile organic compounds (VOCs), which contain hydrogen
Abiotic Depletion Factor (ADF) is determined for each (not fully substituted) and/or double bond (s) (unsatu-
extraction of minerals and fossil fuels (kg antimony equiv- rated). The impact potentials are expressed as an equiva-
alents/kg extraction) based on concentration of reserves lent emission of the reference substance ethylene, C2H4
and rate of deaccumulation (Goedkoop et al., 2004). (Hauschild and Wenzel, 1998).
Table 5
Characterization results
Scenarios S1 S2 S3 S4 S5
Abiotic depletion 0.437 1.11 1.08 1.15 0.16
(kg Sb eq/ton waste managed)
Global warming (GWP100) 6990 6950 1360 1370 1510
(kg CO2 eq/ton waste managed)
Human toxicity 135 271 269 182 91.9
(kg 1.4 DB eq/ton waste managed)
Acidification 43.6 42.6 41.4 36.7 38.3
(kg SO2 eq/ton waste managed)
Eutrophication 37.9 37.8 9.13 9.89 9.98
(kg PO4 3 eq/ton waste managed)
Photochemical oxidation 1.63 1.57 0.0857 2.06 2.14
(kg C2H4/ton waste managed)
M. Banar et al. / Waste Management 29 (2009) 54–62 61
1000
100
10
1
EI99 EPS EI95
the table, the investigated results for each impact category These orders show that the composting scenario, S3, is
are as follows: the more environmentally preferable. EPS’00 and EI’95
Abiotic depletion: S5 is higher than the other scenarios; show the same order, while EI’99 has other results for
S2, S3 and S4 are lower due to avoided raw material usage S1, S2 and for S4, S5.
through the recycling process. In this study, waste management alternatives were inves-
Global warming: Methane is the most important impact tigated from only an environmental point of view. For that
for landfill scenarios (S1 and S2). The global warming effect reason, it might be supported with other decision-making
for S4 and S5 mostly results from CO2. S3 is the best sce- tools that consider the economic and social effects of solid
nario for this impact category. waste management.
Human toxicity: S5 has the highest human toxicity effect
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