MCQ:-

1. From -12 is
a. CF2CL2 B. CF2CL C. CFCL3 4. CF3CL
2. Which has the maximum dipole moment?
A. CH3 F B. CH3 CL C. CCL4 D. CH3I
3. How many chiral carbon atoms are present in 2, 3, 4 – trichloropentane?
a. 3 b. 2 3. 1 4. 4
4. Ethyl chloride on treatment with aqueous alkali gives:-
a. Ethane b. Ethane c. Ethanal d. Ethanal.
5. Which of the following reagents cannot be used for preparing alkyl chloride from alcohol?
a. HCL+ ANHYD . ZNCL2 B. NACL C. PCL5 D. SOCL2
6. Which metal is used in ullman reaction?
A Na b. Mg c. Cu d. Zn
7. A cyanide is formed by reacting KCN with
a. Ethanol b. chlorocthane c. chlorobenzene d. Bromobenzene
8. Among the following phenols, the strongest is:
a. P- chlorophenol b. m- nitrophenol c. p-nitrophenol d. O- nitrophenol
02/ Ag steam
9. CH2 = CH2 X y the compound y is
head 473 k
a. Ethanal b. Ethanal c. Epoxyethane d. Ethylene glycol
10. Which has highest pka value ?
a. Phenol b. Ethanol c. O- nitrophenol d. O- cresol
11. Distinction between primary , secondary and teriary alcohols can be done by.
a. Hinsberg’ s test b. Lucas test c. tollen’s test d. Fehling’s test
12. How many primary alcohols are represented by the formula C 5H11OH?
a. 4 b. 5 c. 3 d. 6
13. Which of the following polymer is stored in the liver of animals?
a.Amylose b. Cellulose c. Amylopectin

14. Which of the following bases is not present in DNA?

a. Adenine b. Thymine c. cytosine d. Uracil

15. Nucleic acids are the polymers of :

a. Nucleosides b. Nucleotides c. Bases d. Sugars

16. Which of the following acids is a vitamin?

a. Aspartic acid b. Ascorbic acid c. Adipic acid d. Saccharic acid

17. The reason for double helical structure of DNA is operation of

a. electrostatic attractions b. vander waal’s forces c. dipole – dipole interactions d.

hydrogen bond
18. Muta –rotation does not occur in:

a. sucrose b. D- glucose c. L- glucose d. None of these

19. Heterocyclic amino acid among the following is :

a. Lysine b. Tyrosine c. Proline d. Serine

20. Purine derivative in the following bases is:

A. Guanine b. cytosine c. Thymine d. uracil

II. Assertion – Reason Type Question :-

The question given below consist of Assertion(A) and Reason(R) . Use the following key to
select the correct answer.

a. If both A and R are correct and R is correct explanation of A.

b. If both A and R are correct but R is not correct explanation for A.
c. If A is correct but R is incorrect.
d. If A is incorrect but R is correct.

21. Assertion : Nucleophilic substitution in aryl holides is easier than in alkyl halides.

Reason :- C-X bond in aryl halides has partial double – bond character due to conjugation.

a. If both A and R are correct and R is correct explanation of A.

b. If both A and R are correct but R is not correct explanation for A.
c. If A is correct but R is incorrect.
d. If A is incorrect but R is correct.

22. Assertion : Addition of Br2 to but -1 eni gives two optical isomers.

Reason : The product contains one asymmetric carbon.

a. If both A and R are correct and R is correct explanation of A.

b. If both A and R are correct but R is not correct explanation for A.
c. If A is correct but R is incorrect.
d. If A is incorrect but R is correct.

23. Assertion :1,2 – dichloroethane is optically active

Reason: Meso compounds are optically inactive.

a. If both A and R are correct and R is correct explanation of A.

b. If both A and R are correct but R is not correct explanation for A.
c. If A is correct but R is incorrect.
 d. If A is incorrect but R is correct.

24. Assertion : Chloroform is generally stored in dark coloured bottles filled to the brim.

Reason : Chloroform reacts with glass in the presence of sunlight.

a. If both A and R are correct and R is correct explanation of A.

b. If both A and R are correct but R is not correct explanation for A.
c. If A is correct but R is incorrect.
d. If A is incorrect but R is correct.

25. Assertion : Ethyl chloride is more reactive than vinyl chloride towards nucleophilic substitution.

Reason: Vinyl group is electron donating in nature.

a. If both A and R are correct and R is correct explanation of A.

b. If both A and R are correct but R is not correct explanation for A.
c. If A is correct but R is incorrect.
d. If A is incorrect but R is correct.

26. Assertion : Addition reaction of water to but -1-ene in acidie medium yields butan-1-ol.

Reason :-Addition of water in acidic medium proceeds through the formation of primary
carbocation.

a. If both A and R are correct and R is correct explanation of A.

b. If both A and R are correct but R is not correct explanation for A.
c. If A is correct but R is incorrect.
d. If A is incorrect but R is correct.

27. Assertion : Boiling points of alcohols and ethers are high.

Reasoning They can form intermolecular hydrogen bonding

a. If both A and R are correct and R is correct explanation of A.

b. If both A and R are correct but R is not correct explanation for A.
c. If A is correct but R is incorrect.
d. If A is incorrect but R is correct.

28. Assertion : Ethanol is weaker acid than phenol.

Reason: Sodium ethoxide may be prepared by the reaction of ethanol with aq. NaOH.

a. If both A and R are correct and R is correct explanation of A.

b. If both A and R are correct but R is not correct explanation for A.
c. If A is correct but R is incorrect.
d. If A is incorrect but R is correct.

29. Assertion : Bond angle in ethers is slightly less than the tertrahedral angle.
 Reasoning : There is a repulsion between the two bulky R groups.

a. If both A and R are correct and R is correct explanation of A.

b. If both A and R are correct but R is not correct explanation for A.
c. If A is correct but R is incorrect.
d. If A is incorrect but R is correct.

30. Assertion :- Phenol forms 2, 4,6 – tribromphenol on treatment with Br 2 in CS2 at 273k

Reason : Bromine polarises in CS2

a. If both A and R are correct and R is correct explanation of A.

b. If both A and R are correct but R is not correct explanation for A.
c. If A is correct but R is incorrect.
d. If A is incorrect but R is correct.

31. Assertion : Ethers have specific dipolemoment values.

Reason The C-O bond is of polar nature.

a. If both A and R are correct and R is correct explanation of A.

b. If both A and R are correct but R is not correct explanation for A.
c. If A is correct but R is incorrect.
d. If A is incorrect but R is correct.

32. Assertion: Cleavage of anisole with HI at 373K Gives phenol and CH 3I.

Reason Due to resonance , O- C6 H5 bond is stronger than O-CH3 bond.

a. If both A and R are correct and R is correct explanation of A.

b. If both A and R are correct but R is not correct explanation for A.
c. If A is correct but R is incorrect.
d. If A is incorrect but R is correct.

33. Assertion : Depxyribose C5H10O4 is not a carbohy drate.

Reason: Carbohy drates are hydrates of carbon. So compounds which follow C x(H2O)y formula
are carbohydrates.

a. If both A and R are correct and R is correct explanation of A.

b. If both A and R are correct but R is not correct explanation for A.
c. If A is correct but R is incorrect.
d. If A is incorrect but R is correct.

34. Assertion : Glycine must be taken through diet

Resoning : It is an essential amine acid .

a. If both A and R are correct and R is correct explanation of A.

 b. If both A and R are correct but R is not correct explanation for A.
c. If A is correct but R is incorrect.
d. If A is incorrect but R is correct.

35. Assertion: All naturally occurring X- amino amine acids except glycine are optically active.

Reasoning: Most occurring X- amino amine acids have L- configuration.

a. If both A and R are correct and R is correct explanation of A.

b. If both A and R are correct but R is not correct explanation for A.
c. If A is correct but R is incorrect.
d. If A is incorrect but R is correct.

36. Assertion : Glycosides are hydrolysed in acidic conditions:

Reasoning : Glycosides are acetals

a. If both A and R are correct and R is correct explanation of A.

b. If both A and R are correct but R is not correct explanation for A.
c. If A is correct but R is incorrect.
d. If A is incorrect but R is correct.

37. Assertion ; Fructose reduces Fehling solution.

Reason :- Fructuse does not contain any aldehydic group

a. If both A and R are correct and R is correct explanation of A.

b. If both A and R are correct but R is not correct explanation for A.
c. If A is correct but R is incorrect.
d. If A is incorrect but R is correct.

38. Assertion: Cellulose is not digested by human beings.

Reasoning: Cellulose is a polymer of β -D glucose.

a. If both A and R are correct and R is correct explanation of A.

b. If both A and R are correct but R is not correct explanation for A.
c. If A is correct but R is incorrect.
d. If A is incorrect but R is correct.

39. Assertion: Sucrose is a non- reducing sugar.

Reason: Sucrose has glycosidic linkage.

a. If both A and R are correct and R is correct explanation of A.

b. If both A and R are correct but R is not correct explanation for A.
c. If A is correct but R is incorrect.
d. If A is incorrect but R is correct.
40. Assertion: After using CCl4 to extinguish fire , the room must be well – ventilated.

Reason: Atmospheric Oxygen can convert CCL4 into poisonous phosgene gas.

a. If both A and R are correct and R is correct explanation of A.

b. If both A and R are correct but R is not correct explanation for A.
c. If A is correct but R is incorrect.
d. If A is incorrect but R is correct.

III. Case based Question:-

A Chloroform is well known organic compound and is a useful solvent for oils, fats , waxes and
also for many organic compounds . Some of the Compounds of it are also quite important For
example – Chloropicrin ( Cl3 CNO2) is used in warfare and also acts as insecticide. Similarly ,chloret
one is used as a sleep inducing medicine or as hynotic chloroform was earlier used as an
anaesthetic . But now it has been almost discarded.

41. Why is storage of chloroform difficult ?

42. How is chloroform preserved?

43. How is chloropicrin from chloroform?

44. What is halo ethane? Write its chemical formula?

45. What is the use of chloroform earlier?

B. In 1985, a British chemist Alec Jeffryo developed a technique called DNA fingerprinting . We
known that every individual has unique fingerprints. They appear as circles on the tips of fingers
and are used for the identification of individuals. It is argved that every person has his own
sequence of bases in DNA . It cannot match with those of any other person.

46. What is the full form of DNA?

47. Which basic is present in DNA and not in RNA?

48. Which base is present in RNA and not in DNA?

49. What type of linkage is present in nucleic acids?

50. What is the significance associated with DNA fingerprinting?