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(PREN)
What Does Pitting Resistance Equivalent Number (PREN) Mean?
The pitting resistance equivalent number (PREN) is a measure of the relative pitting
corrosion resistance of stainless steel in a chloride-containing environment. The
pitting resistance of stainless steel is primarily determined by its composition. The
elements which have a significant impact are chromium, molybdenum, and nitrogen.
The formula, which quantifies their respective contribution, is:
The factor for nitrogen varies according to the source. Some variants of the equation
also include tungsten (W).
PREN values are useful for ranking stainless steel grades according to their pitting-
corrosion resistance. However, this comparison is only meaningful within the same
stainless steel family (austenitic, ferritic, duplex). PREN cannot be interpreted as an
absolute value.
Steels with PREN values above 32 are considered resistant to seawater corrosion.
Duplex steel with PREN values 40 or above is used in hydrogen sulfide environments. It
is standard in the oil and gas extraction industries. An exception is stainless steels
with molybdenum content equal to or above 1.5%; these may have a PREN value 30 or
more. In these cases the PREN value takes into account tungsten (W) in the alloy and
is defined with the formula:
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PREN can change depending on the individual elements in the steel or alloy steel
composition.
Studies of corrosion failures of stainless steel have indicated that pitting and crevice
corrosion types are major problems, and together account for perhaps 25% of all
corrosion failures. One reason why pitting corrosion is so serious is that once a pit is
initiated there is a strong tendency for it to continue to grow, even though the
majority of the surrounding steel is still untouched.