instruction : null

question : In the analysis of a 2.72g sample containing potassium iodide(KI) (FW=166), 0.0720g of
barium iodate, Ba(IO₃ )₂ , (FW=487.1) was recovered. Express the results
of this analysis as percent potassium iodide.(Ba-137, I-127, O-16, K-39)

weight : 2

option : 1.2%

option : 2.8%

answer : 1.8%

option : 2.0%

R
question : Manganese in a 1.52 g sample was precipitated as Mn₃O₄ (FW
O
= 228.8) weighing 0.126 g. Find percentage of Mn (FW = 54.94) in the sample.

weight : 2
P
option : 8.97%
M

option : 6.97%

answer : 5.97%
A

option : 7.97%
S

question : A 2.5g sample of limestone containing Ca²⁺ (aq) is dissolved in HCl and
reacted with excess ammonium oxalate solution, (NH4₎ 2C₂
O₄ (aq), to precipitate the calcium ions as calcium oxalate,
CaC₂O₄ (s) (FW = 128).The precipitate was filtered, dried and weighed
to a constant mass of 3.23g. Determine the percentage by mass of calcium in the limestone
sample. (Ca-40, C-12, O-16)

weight : 2

option : 38.7%

option : 28.2%

option : 36.3%

answer : 40.3%
question : What is the value of the gravimetric factor for the conversion of SO₃ to
BaSO₄ (Ba-137, S-32, 0-16)?

weight : 2

answer : 0.3433

option : 0.2516

option : 0.4321

option : 0.2448

question : The following measurements were obtained for a metal bar: 4.012g, 4.022g, 4.019g,
4.011g, 4.017g, 4.018g and 4.024g. Calculate the mean.

R
weight : 2

option : 4.0175g

answer : 4.018g
O
option : 4.01757g
P
option : 4.017g
M

question : 3000ml of a 20ppm solution of ethanol contains how many mg of ethanol?

A

weight : 2

option : 20mg
S

option : 40mg

answer : 60mg

option : 80mg

question : A method of analysis yields weights for gold that are low by 0.3mg. Calculate the percent
relative error caused by this uncertainty if the weight of gold in the sample is 800mg.

weight : 2

option : 0.04%

option : 0.0375%

option : 0.038%
answer : -0.04%

question : A titre value of 38.8cm3 of a solution containing 0.4563g HCl in 250cm3 was obtained
when the acid was titrated against 25.0cm3 of calcium hydroxide solution. What is the molarity and
concentration in gdm-3 of the base? <br /> (Ca=40.0 Na=23, C=12, O=16, Cl=35.5, H=1.00)

weight : 2

option : 0.078 , 5.74

option : 0.039 , 2.21

answer : 0.039 , 2.87

option : 2.87,0.039

R
question : C is a solution of hydrochloric acid containing 3.65g of HCl per dm³ of
O
solution and D is a solution of impure sodium carbonate. If 25cm³ of D requires
22.7cm³ of C for complete reaction, what is the molarity and concentraion of sodium
carbonate?
P
weight : 2
M

option : 0.045M, 3.74 gdm-3

option : 0.091M, 9.65 gdm-3

A

option : 0.182M, 19.29 gdm-3

answer : 0.045M, 4.81 gdm-3

S

question : The colour change of a chemical indicator requires an overtitration of 0.03ml. Calculate
the percent relative error if the total volume of titrant is 50.00ml.

weight : 2

option : 0.03%

answer : 0.06%

option : 6%

option : - 0.06%
question : The volume of methanol in a 2-litre water solution containing 80% methanol (assuming
volumes are additive)

weight : 2

option : 400ml

option : 800ml

option : 1200ml

answer : 1860ml

question : The number of significant figures in 0.0030900 and 0.002008 are?

weight : 2

R
answer : 5 and 6

option : 4 and 5 O
option : 7and 7
P
option : 6 and 4
M

question : A sample of water has a mass of 234.9g at 25^o C what is the volume of the
water in cubic meters, given that the density of water at 25^o C is 0.99707g/ml?
A

weight : 2

option : 235.590ml
S

option : 236.6m³

answer : 0.0002356m³

option : 0.0023559m³

question : Round off 21.9994 and 27845 to four significant figures

weight : 2

option : 21.99 and 2.784 x10⁴

option : 22.00 and 2.784 x10-4

answer : 22.00 and 2.785 x10⁴

option : 22.00 and 2.784 x104

question : 38.80cm³ of 0.05M H₂SO₄ was used for complete

neutralization when it was titrated against 25.0cm³ of sodium hydroxide. What is the
concentration of sodium carbonate in gdm^-3 ?

weight : 2

answer : 6.4

option : 3.2

option : 1.6

option : 64

R
question : Solution X contains 2.100g H₂ SO₄ in 250cm³ and
O
Y is a solution of sodium hydrogen carbonate. If 25cm³ of Y requires 26.8cm³ of X for complete neutralization, what is the general name for Y and its concentration?
P
weight : 2

option : analyte , 0.184gdm^-3

M

option : titrant , 0.184gdm^-3

option : titrant , 18.400gdm^-3

A

answer : analyte , 15.434gdm^-3

S

question : What is the normality in a redox reaction of 0.100molar solution of NaHC₂

O₄ ?

weight : 2

option : 0.200N

answer : 0.100N

option : 0.050N

option : 0.0250

question : Solution A contains 2.5g H₂SO₄ in 250cm³ and B

is solution of sodium hydrogen carbonate. If 25cm³ of B requires
19.50cm³ of A for complete reaction, what is the concentration of B in gdm^-
3 ? <br /> <br /> (H=1.00 Na=23, O=16.00, C= 12.0, S=23.0)

weight : 2

option : 3.9

answer : 13.44

option : 0.16

option : 0.08

question : In the analysis of chromium in three samples of stainless steel, the following results were
obtained <br /> A 6.25% 6.24% 6.26% <br /> <br /> B 6.71% 6.72% 6.71% <br />
<br /> C 6.05% 6.57% 6.32% <br /> <br /> Suppose the true value is 6.25%,how precise

R
and accurate are the result?

weight : 2 O
option : A, B, C are accurate and precise
P
answer : Only A is accurate and precise

option : A and B are accurate and precise

M

option : A and C are accurate and precise

A

question : Solution A is 0.050M HNO₃ and B is a solution of sodium carbonate. If

25.0cm³ of B requires 19.70cm³ of A in a titration to methyl orange end
S

point, what is the concentration of B in mole per litre ? <br /> <br /> (Ca =40.0 Na=23, C=12, O=16,
Cl=35.5, H=1.00 , N=14)

weight : 2

answer : 0.02mol/L

option : 2.09g/dm³

option : 0.04mol/L

option : 4.18g/L

question : Volumetric titration is best described as a class of experiment where <br /> <br /> I. A
known property of one solution is used to infer an unknown property of another solution. <br /> <br
/> II. Titrant , analyte and product involve volume measurement <br /> <br /> III. Chemical
indicator must be used to locate the end-point <br /> <br /> IV. A known concentration of one
solution is used to infer an unknown concentration of another solution

weight : 2

answer : I

option : II

option : IV

option : III

question : A sample of pure potassium chloride was analyzed for chloride ion (Cl^- )
with the following results 47.24, 47.08,47.31,47.42,47.29 and 47.38. Calculate the standard
deviation and percentage relative standard deviation.

R
weight : 2

option : 0.18 and 0.38%

O
option : 0.19 and 0.40%
P
answer : 0.12 and 0.25%
M

option : 0.13 and 0.27%

A

question : A is a solution of hydrochloric acid containing 1.825g per dm³ of solution. B

is a solution of impure sodium carbonate. 25cm³ of B requires 22.7cm³
of A for complete reaction. What is the concentration of B and the percentage by mass of pure B if
S

5.00g impure B is dissolved in 1dm³ of solution

weight : 2

answer : 2.41 gdm^-3 , 48.20%

option : 4.81 gdm^-3 , 96.20%

option : 9.63 gdm^-3 , 60.3%

option : 4.81gdm^-3 , 48.20%

question : Calculate the mean and standard deviation of the following set of analytical results:
15.67g, 15.69g and 16.03g.

weight : 2
answer : 15.80 and 0.20

option : 1.580 and 2.0

option : 15.80 and 2.0

option : 15.80 and 0.04

question : Calculate the percent by weight of solution that weighs 200g and contains 25g of sodium
sulphate.

weight : 2

option : 25% (w/v)

option : 12.5% (w/v)

R
option : 25%(w/w)

answer : 12.5%(w/w) O
P
question : Consider the following set of data: 2.4, 2.1, 2.1, 2.3, and 1.5, Calculate the mean and
absolute error if the accepted is 2.0.
M

weight : 2

option : 2.06 and -2.08

A

answer : 2.08 and 0.08

option : 2.08 and -0.08

S

option : 2.06 and 0.08

question : If a 2.62g sample of material is analyzed to be 2.52g, what is the absolute error?

weight : 2

option : 0.10g

option : 0.01g

answer : - 0.10g

option : 0.100g
question : Manganese content of an earthcrust is determined by converting the Mn to
Mn₃O₄ . 1.52g of the sample produces Mn3O4 and ignited to
Mn₂O₃ . Calculate the percentage of Mn in the sample.

weight : 2

option : 5.90%

answer : 5.97%

option : 6.0%

option : 6.27%

question : Calculate the percentage of Ba in pure BaSO₄ ? ( Ba = 137.3, S=32, O=16)

R
weight : 2

answer : 59%

option : 70%
O
option : 57%
P
option : 60%
M

question : Solution A is 0.050M H₂ SO₄ , B is a solution of sodium

A

hydroxide .The titre value obtained for the titration of A against 25cm³ of B using
phenolphthalein indicator was 38.80cm³ . Calculate the molarity and concentration of
solution B
S

weight : 2

answer : 0.16M, 6.4 gdm-3

option : 0.08M,3.2 gdm-3

option : 0.04M, 1.6 gdm-3

option : 0.16M, 3.2 gdm-3

question : A titre value of 28.6cm³ of a solution containing 0.4562g HCl per

250cm³ was obtained when the acid was titrated against 25.0cm³ of
sodium hydroxide . What is the molarity and concentration in gdm^-3 of sodium
hydroxide?

weight : 2
answer : 0.06 , 2.29

option : 2.29 , 0.06

option : 0.11 , 4.4

option : 0.05 , 2.00

question : A loss of 0.4mg of Zn occurs in the course of an analysis for that element. Calculate the
relative error due to this loss if the weight of Zn in the sample is 400mg.

weight : 2

option : 1.0%

answer : -1.0%

R
option : 0.1%

option : 0.2% O
P
question : Solution E is 0.100M HCl. F is a solution of sodium carbonate. If 25cm³ of F
requires 23.5cm³ of E in titration using methyl orange indicator, what is the
M

concentration of F in g/dm³ ? <br /> <br /> (Na=23, H=1.00, Cl=35.5, O=16, C=12)

weight : 2
A

answer : 4.982gdm^-3

option : 0.047gdm^-3
S

option : 4.0982 gdm^-3

option : 0.470gdm^-3

question : A solution with pH= 2 is more acidic than one with a pH=6 by a factor of?

weight : 2

option : 4

option : 12

option : 400

answer : 10,000
question : Evaluate the addition of 0.0631, 0.0226 and 0.0821 to the correct number of significant
figures.

weight : 2

option : 1.01678

option : 0.01678

option : 1.6780

answer : 0.1678

question : A is a solution of hydrochloric acid containing 3.650g of HCl in 1dm³ of

solution B is a solution of impure sodium carbonate . 25cm³ of B require
22.7cm³ of A for complete reaction . Given that 5.00g of impure B was dissolved

R
in1dm³ solution, what is the percentage by mass of pure sodium carbonate in the
impure sample ? <br /> <br /> (Na=23, C=12, O=16, Cl=35.5, H=1.00)

weight : 2
O
answer : 80.2%
P
option : 78.6%
M

option : 40.2%

option : 60.2%
A

question : Solution A contains 7.000g H₂ SO₄ in 1dm³ and B

S

is a solution of sodium hydrogen carbonate. If 25cm³ of B requires

26.9cm³ of A for complete neutralization, what is the concentration of B in gdm^-
3 ? (S=32, Na=23, H=1.00, C=12, O=16)

weight : 2

option : 12.752 gdm^-3

option : 15.300 gdm^-3

answer : 12.852 gdm^-3

option : 15.400 gdm^-3

question : 25cm³ of a solution containing 2.10g of sodium hydrogen carbonate was
titrated against a dilute hydrochloric acid solution and obtained 27.50cm³ ,titre value
calculate the concentration in mole per dm³

weight : 2

option : 0.91

option : 0.46

option : 3.32

answer : 0.09

question : If three litres of a solution of H₃ PO₄ contains 294grammes of

H₃ PO₄ , what is the normality of the solution? Atomic weights: H=1 O=16

R
P=31

weight : 2 O
option : 0.1
P
option : 1.0

answer : 3.0
M

option : 9.8
A

question : The true volume of a liquid is 2.55cm³ and the measured value is
2.58cm³ , calculate the relative error.
S

weight : 2

option : 0.03

option : 1.2

answer : 0.012

option : 0.12

question : Using an analytical procedure, the percentages of chloride (Cl^-) content in a

standard milk sample were found to be 54.01, 54.24, 54.05,54.27and 54.11. If the accepted true
value of the chloride content of the standard milk sample is 54.20, calculate the absolute error.

weight : 2
answer : -0.06

option : 0.07

option : 0.06

option : 0.11

question : Calculate the relative error of the following set of data: 2.4, 2.1, 2.1 ,2.3, and 1.5 if the
accepted value is 2.0.

weight : 2

option : 40

answer : 0.04

R
option : 0.4

option : 0.004 O
P
question : 25.0cm³ of tetraoxosulphate(VI) acid requires 32.30cm³ of
0.1M sodium hydroxide for complete neutralization. What is the concentration in gdm<sup>-
M

3</sup> and general name of tetraoxosulphate(VI) acid

weight : 2
A

option : 6.21 , titrant

option : 0.06 , analyte

S

answer : 6.21 , analyte

option : 0.06, titrant

question : The sum of 0.508, 110.1, and 21.27 gives

weight : 2

option : 131.878

option : 131.88

answer : 131.9

option : 131.90
question : Consider the following set of data: 4.4, 4.1, 4.2, 4.3, and 4.5, Calculate the mean and
relative error if the accepted is 4.0.

weight : 2

answer : 4.3 and 0.075

option : 4.3 and 0.3

option : 4.3 and 75%

option : 4.3 and 7.5%

question : 1.5g of pyrite (impure FeS₂ ) is analysed for sulphur. If 1.14g of

BaSO₄ <br /> <br /> is precipitated out. Calculate the percentage of sulphur ion in the
sample

R
weight : 2

option : 5.05%
O
answer : 10.4%
P
option : 15.6%
M

option : 21.0%
A

question : The Ksp of AgCl at 25^o C is 1.0 x 10^-10 , calculate the molar
solubility of AgCl
S

weight : 2

option : 1.0 x 10^-4

answer : 1.0 x 10^-5

option : 1.0 x 10^-6

option : 1.0 x 10^-7

question : 4.00 g of sodium hydroxide is dissolved completely in 500cm³ volumetric

flask, the concentration is (Na=23 , O=16 )

weight : 2

answer : 0.2mol/dm³
option : 5mol/dm³

option : 2.0mol/dm³

option : 0.50g/dm³

question : The volume of ethanol in a 3-litre water solution containing 80% methanol (assuming
volumes are additive) is

weight : 2

option : 400ml

answer : 2400ml

option : 1200ml

R
option : 1600ml

O
question : Round off 36.9645 and 297846 to five significant figures
P
weight : 2

option : 36.964 and 2.9785x10⁴

M

answer : 36.965 and 2.9785x10⁵

A

option : 36.964 and 2.9785 x10⁵

option : 36.964 and 2.9784 x10⁶

S

question : Silver ion forms a stable 1: 1 complex with methylenetetramine called “trien” .Calculate
the silver ion concentration at equilibrium when 25mL of 0.010M silver nitrate is added to 50mL of
0.015M trien. (Kf =5.0 x 10⁷ )

weight : 2

option : 9.8 x 10^-11 M

option : 9.8 x 10^-10 M

answer : 9.8 x 10^-9 M

option : 9.8 x 10^-8 M

question : The formation constant for CaY^2- is 5.0 x 1010 .At pH 10, ? 4 is calculated to
be 0.35 to give a conditional constant of 1.8 x 1010. Calculate pCa in 100mL of a solution of 0.100M
Ca²⁺ at pH 10 after addition of 0mL EDTA .

weight : 2

answer : 1.00

option : 2.00

option : 0.10

option : 0.15

question : What must be the concentration of added Ag+ to just start the precipitation of AgCl in a
1.0 x 10^-3 M solution NaCl ?[ ksp for AgCl= 1.0 x 10-10].

R
weight : 2

option : 1.0 x 10^-5

O
option : 1.0 x 10^-6
P
answer : 1.0 x 10^-7
M

option : 1.0 x 10^-8

A

question : 1500ml of a 15ppm solution of potassium hydroxide contains how many mg of potassium
hydroxide?
S

weight : 2

option : 30mg

option : 15mg

answer : 22mg

option : 25mg

question : Consider the following set of data: 4.4, 4.1, 4.2, 4.3, and 4.5, Calculate the absolute error
if the accepted is 4.0.

weight : 2

option : 4.3
answer : 6.3

option : 2.5

option : 1.0

question : A divalent metal M²⁺ reacts with a ligand L to form a 1: 1 complex. Calculate
the concentration of M²⁺ in a solution prepared by mixing equal volumes of 0.20M
M²⁺ and 0.20M L. (Kf =1.0 x 10⁸ )

weight : 2

option : 3.2 x 10^-4 M

answer : 3.2 x 10^-5 M

R
option : 3.2 x 10^-3 M

option : 3.1 x 10^-5 M

O
question : A divalent metal ion M²⁺ reacts with a ligand L to form a 1: 1 complex
P
according to the reaction M²⁺ + L? ML²⁺ . Calculate the concentration
of M²⁺ in a solution prepared by mixing equal volume of 0.20 mol M²⁺
M

and 0.20 mol <br /> (Kf = 1.0x10⁸ )

weight : 2
A

answer : 3.2x10^-5 mol

option : 3.2x10^-4 mol

S

option : 3.2x10^-3 mol

option : 2.9x10^-5 mol

question : Gravimetric factor (GF) for the conversion of Ca2+ to CaC2O4 precipitate is <br /> <br />
(Ca-40, C-12, 0-16)

weight : 2

answer : 0.3125

option : 0.4125

option : 0.1125

option : 0.2125
instruction : null

question : Common determinate errors are --------- except?

weight : 2

answer : Accidental error

option : Instrumental error

option : Errors of methods

option : Operative errors

R
question : The oxidation number of an element in an uncombined state is

weight : 2

option : 1
O
option : 2
P
option : 3
M

answer : 0
A

question : C is a solution of hydrochloric acid containing 3.65g of HCl per dm³ of

solution and D is a solution of impure sodium carbonate. If 25cm³ of D requires
22.7cm³ of C for complete reaction, what is the molarity and concentraion of sodium
S

carbonate?

weight : 2

option : 0.045M, 3.74 gdm^-3

option : 0.091M, 9.65 gdm^-3

option : 0.182M, 19.29 gdm^-3

answer : 0.045M, 4.81 gdm^-3

question : In gravimetric determination, co-precipitated impurities can be removed by

weight : 2

option : Peptization
answer : Washing

option : Coagulation

option : Post precipitation

question : Oxidation number of sulphur in Na₂SO₄ is ?

weight : 2

answer : +6

option : +8

option : -6

R
option : +5

O
question : A is a solution of hydrochloric acid containing 2.92mol per litre of solution and B is a
solution of an impure sodium carbonate. If 25cm³ of B requires 26.4cm³
of A using methyl orange indicator, what is the molarity and concentration in g/dm³
P
of solution B? <br /> <br /> (Na =23.0, C=12.0, O =16.0, H=1.0, Cl=35.5)
M

weight : 2

option : 4.48 , 0.04

A

option : 0.09 , 9.54

option : 0.08 , 9.01

S

answer : 0.04 , 4.48

question : Which of the following techniques can be a very selective process?

weight : 2

option : gravimetric method

answer : precipitation method

option : colorimetric method

option : titrimetric method

question : The titre value obtained in an acid-base titration of 25cm³ of sodium
hydrogen carbonate with HCl solution was 27.50cm³ . Given that 4.20g of
NaHCO₃ was dissolved in 500cm3 H₂ O, what is the molarity and
concentration of HCl? <br /> <br /> (Na=23.00, C=12, H=1.00, O=16, Cl=35.5)

weight : 2

option : 909M, 33.18 gdm^-3

option : 0.909, 3.322 gdm^-3

answer : 0.091M, 3.322 gdm^-3

option : 0.046M, 1.679 gdm^-3

question : Source of contamination of precipitate in gravimetric analysis could be from ?

R
weight : 2

option : Washing
O
option : Igniting
P
answer : Surface adsorption
M

option : Weighing
A

question : The quantitative determination of a substance by precipitation followed by isolation and

weighing of the precipitate is called?
S

weight : 2

option : qualitative analysis

answer : gravimetric analysis

option : titrimetric analysis

option : colorimetric analysis

question : The following factors are needed for achieving selectivity in complexometric titrations
except

weight : 2

option : The use of appropriate masking agent

option : The pH control

answer : The temperature variation

option : All of the above

instruction : null

question : The following requirements must be met for a successful gravimetric determination
except

weight : 2

option : The desired substance must be completely precipitated

option : The weighed form of the precipitate should be a stoichiometric compound of known

R
composition

option : The precipitate must be pure and easily filtered

O
answer : Nucleation followed particle growth in precipitate formation
P
question : Which of these is not true of the primary adsorbed ion?
M

weight : 2

option : Held by chemical bond

A

option : The lattice ion that is in excess

answer : Held by electrostatic attraction

S

option : Fixed on separate surface

question : Which of the following is not included in the group of analyses based on the amount of
sample taken?

weight : 2

option : macroanalyses

answer : single constituent analyses

option : microanalyses

option : ultra-microanalyses
question : Express 3.00g/ml x1.207ml to the correct number of significant figures.

weight : 2

answer : 3.62g

option : 3.621g

option : 3.62g/ml

option : 3.621g/ml

question : The following statements are true about random error except

weight : 2

R
option : They are indeterminate or accidental errors

answer : The error can be predicted or estimated

O
option : The error follow a normal distribution or Gaussian curve

option : Some of the error arises from statistical nature of things.

P
M

question : Chloride ion in 3.10g iron III chloride sample is converted to the hydrous <br /> <br />
oxides and ignited to iron II oxide. If the oxide weighed 1.53g, calculate <br /> <br /> the
percentage of iron in the sample. <br /> <br /> (Fe=56, Cl=35.5, O=16.0 H=1.0)
A

weight : 2

option : 16.0%
S

answer : 18.0%

option : 20.0%

option : 22.0%

question : The experimental error in which its source cannot be traced is known as

weight : 2

option : definite error

answer : Indeterminate or second class error

option : Determinate error

option : Systematic error

question : The error in weighing an hygroscopic sample can be described by all the following except
one.

weight : 2

option : Systematic error

option : Determinate error

option : Positive error

answer : Random error

R
question : In gravimetric analysis, measurement are based on?

weight : 2 O
option : volume
P
option : density

answer : mass
M

option : pressure
A

question : In precipitation gravimetric methods, analyte is converted to

S

weight : 2

answer : a sparingly soluble precipitate of known composition

option : a colloidal precipitation of known composition

option : a soluble precipitation of known composition

option : a precipitate that reacts with atmospheric constituents

instruction : null
question : In the precipitation of chloride ion as silver chloride, all these ions are interferences
except?

weight : 2

option : Cyanide ion

answer : Nitrate ion

option : Bromide ion

option : Iodide ion

question : The first step in precipitation is the formation of very tiny particles of precipitate called
nuclei. The process of forming these particles is called

R
weight : 2

answer : nucleation

option : nucleiation
O
option : nuclation
P
option : nucliation
M

question : The following are correct on counter ion except?

A

weight : 2

answer : Held by chemical bond

S

option : Held by electrostatic attraction

option : Opposite in charge to primary adsorbed ion

option : Loosely held in solution surrounding precipitate

question : The Ksp for the ionization of AgCl in water is given by

weight : 2

option : [H+][ Cl-]

option : [Ag+][ OH-]

answer : [Ag+][ Cl-]

option : [H+][ OH-]

question : The titration useful for determining chloride in neutral or unbuffered solutions such as
drinking water is?

weight : 2

option : Volhard titration

option : Acid- base

option : Adsorption indicator

answer : Mohr titration

R
question : In the Mohr titration, the ideal pH is ?

weight : 2 O
option : 4
P
option : 12

answer : 8
M

option : 5
A

question : ..................... method is the most recent and accurate among the precipitation titration
methods?
S

weight : 2

answer : Adsorption indicator

option : Mohr

option : Volhard

option : Amperometric

question : In the Mohr titration method, the chloride is titrated with standard AgNO₃
solution using an indicator. Which of these is the indicator?

weight : 2

option : iron (III) (red at the eqiuvalence point

option : Diclorofluorescein (Yellow at the equivalence point)

option : Ag₂ CrO₄ (yellow at the equivalence point)

answer : Potassium chromate (yellow before the equivalence point)

question : Completeness of a precipitate reaction is determined by?

weight : 2

answer : the solubility of the precipitate formed

option : the duration taken for the reaction to occur

option : the concentrations of the reacting mixtures

R
option : the colour of the precipitate formed

question : The p- function is

O
weight : 2
P
option : the log to base 10 of the molar concentration of that specie
M

option : the function of activity in precipitation reactions

answer : the negative log to base 10 of the molar concentration of that specie
A

option : unity always

S

question : The different types of precipitation titrations include all except

weight : 2

option : Mohr

option : Adsorption indicators

option : Fajans

answer : None of the above

question : In Mohr titration, there is precipitation of some ---- with more alkaline solutions.

weight : 2
option : Silver carbonate

option : silver hydroxide

answer : Silver carbonate or Silver hydroxide

option : None of the above

question : Precipitating reagent should react with the analyte,

weight : 2

answer : either specifically or, at least selectively to form a precipitate

option : neither specifically nor selectively

R
option : to give a coloured solution

option : none of the above

O
question : Precipitate must be
P
weight : 2
M

answer : readily filterable and washable

option : filterable and soluble

A

option : filterable and not washable

option : not filterable, not washable

S

question : In the titration of Silver nitrate with chloride ion during precipitation titration, before the
equivalence point we have?

weight : 2

answer : excess Chloride ion

option : excess of silver ion

option : equal amount of silver ion and chloride ion

option : None of the above

instruction : null
question : The pH at equivalence point of a weak acid / strong base titration depends on <br /> <br
/> I. The dissociation constant and concentration of the weak species <br /> <br /> II. The
dissociation constant and concentration of the strong species. <br /> <br /> III. The dissociation
constant of the acid and concentration of the base <br /> <br /> IV. The dissociation constant of
the base and the concentration of the acid

weight : 2

answer : I only

option : II only

option : III only

option : IV only

R
question : An ultrapure compound that serves as the reference materials for a titrimetric method of
analysis is known as <br /> <br /> A. I only B. II only C. III only D. IV only

weight : 2
O
option : A secondary standard
P
answer : A primary standard.
M

option : A standard solution

option : A pure solution

A

question : Equivalence point in an acid-base titration occurs when. <br /> <br /> I. Stoichiometric
S

amount of titrant is added to analyte. <br /> <br /> II. Equivalence quantity of titrant is added to
analyte <br /> <br /> III. A noticeable change in the property of either titrant or analyte occurs
<br /> <br /> IV. Excess of titrant produces produce indicator colour change

weight : 2

option : I and IV

option : II and III

answer : I and II

option : I and III

question : The volume of a cylindrical rod is given by the equation V= &pi;r² h, where r
= radius, h =height and &pi; =3.143. If the values for r = 4.5 +0.1cm and h =11.7+ 0.02cm, calculate
the percentage error in the volume.

weight : 2

option : 7%

answer : 6%

option : 10%

option : 9%

question : The following statement is/are true of indicator behavior in an <br /> <br /> acid/base
titration. <br /> <br /> I. Most people cannot read colour change until more than 1 tenth of the

R
indicator has been converted to its conjugate form. <br /> <br /> II. The indicator act as second
acid or base and titrate after the primary titrant. <br /> <br /> III. An acid indicator acts as a

acid that react with the primary base.

O
conjugate base that react with primary acid. <br /> <br /> IV. A base indicator acts as a conjugate

weight : 2
P
option : I and IV
M

option : II and III

option : III and IV

A

answer : I and II
S

question : Which of these is not a unit of concentration?

weight : 2

option : mg/L

option : ppm

option : normality

answer : moles

question : Which of the following statement is true of end-point of acid-base titration ; <br /> <br />
I. Equivalence quantities of reactants have been brought into reaction <br /> <br /> II. The
presence of excess of titrant that give rise to indicator reaction <br /> <br /> III. The presence of
excess of analyte that gives rise to indicator reaction <br /> <br /> IV. Equimolar quantities of
analyte and titrant that give rise to indicator reaction.

weight : 2

option : I

answer : II

option : III

option : IV

question : What marks the sudden change in oxidation potential <br /> in the neighbourhood of the
equivalent point in an oxidation reduction titration?

R
weight : 2

option : Acid base indicators

answer : Oxidation reduction indicators

O
option : Oxidant
P
option : Reductant
M

question : An acid – base indicator <br /> <br /> I. Is an organic dyes which are weak acids having
A

different colours for dissociated and undissociated forms. <br /> <br /> II. Is a weak acid or base
having different colours for dissociated and undissociated forms. <br /> <br /> III. Is an organic
acid or base having different colours for dissociated and undissociated forms <br /> <br /> IV. Is
S

any chemical that produce different colours for dissociated and undissociated forms

weight : 2

answer : III only

option : II only

option : II and III only

option : IV only

question : A primary standard solution is one which contains <br /> <br /> I. A known amount of
reagent in a definite volume of solvent. <br /> <br /> II. A known mass of analytically pure
substance of it in a suitable solvent. <br /> <br /> III. A known mass of solute in a given volume of
solvent. <br /> <br /> IV. A known mass of analytically pure substance of it.
weight : 2

answer : II only

option : I and II

option : II and III

option : IV only

question : Titration of 0.1M ammonia with 0.1M hydrochloric acid solution may occur at equivalence
point of between ?

weight : 2

answer : 5 - 6

R
option : 6 - 7

option : 7 - 8 O
option : 4 - 5
P

question : During a typical acid - base titration, which of these colour changes would be observed at
M

pH transition of 1.2 - 2.8 from acidic to basic medium when thymol blue indicator is used?

weight : 2
A

option : Yellow to green

answer : Red to yellow

S

option : yellow to blue

option : Blue to colourless

question : During a typical acid - base titration, which of these colour changes would be observed at
pH transition of 3.0 - 5.0 from acidic to basic medium when congo red indicator is used?

weight : 2

option : Red to yellow

option : Yellow to blue

answer : Blue to red

option : Colourless to pink

question : At what pH range is expected for methyl orange indicator to change from red to yellow
(acidic to basic transition)?

weight : 2

option : 3.0 to 4.6

option : 3.0 to 5.0

answer : 3.2 to 4.4

option : 3.8 to 5.4

question : Which of the following indicator is suitable for the titration of ethanedioic acid with

R
sodium hydroxide solution ?

weight : 2

option : Methyl orange

O
option : Congo red
P
answer : phenolphthalein
M

option : No suitable indicator

instruction : null
A

question : Which of these is not a unit of concentration?

S

weight : 2

option : mg/L

option : ppm

answer : moles

option : Molarity

question : Calculate the average titre value from these sets of volume of acid used in a typical acid -
base titration. <br /> <br /> 26.50cm³ ,26.95cm³ ,26.55cm³
,26.54cm³ ,

weight : 2
answer : 26.53cm³

option : 26.64cm³

option : 26.68cm³

option : 26.67cm³

question : In acid - base titration of NaOH versus HCl, methyl red indicator changes colour from

weight : 2

option : pink-red

option : pink-yellow

R
answer : yellow-red

option : red-yellow
O
question : Which of these indicators can be used for a weak acid and a weak base?
P
weight : 2
M

option : methyl orange and phenolpthalein

option : methyl red and methyl orange

A

option : Phenolpthalein and methyl red

answer : no suitable indicator

S

question : Potassium permanganate solution is normally stored in ?

weight : 2

option : White bottle

option : Yellow bottle

answer : Brown bottle

option : Pink bottle

question : Which of these pair compounds have the same oxidation states with that of common
elements?
weight : 2

answer : SO₃ / H₂ SO₄

option : K₂ Cr₂ O₇ & Cr (OH)₃

option : CO & CO₂

option : FeO & Fe₂ O₃

question : Calculate the concenteration in mol dm^-3 of a solution containing 36.5g of
hydrogen chloride in 4.00dm³ of solution.

weight : 2

option : 2.5 x 10-4mol dm^-3

R
option : 2.5 x 10-3mol dm^-3

answer : 2.5 x 10-1mol dm^-3 O

option : 2.5 x 10-2mol dm^-3
P

question : 5.6g of Na₂ CO₃ was dissolved in 250cm³

M

standard flask with distilled water. 25 cm³ of the solution was titrated against
H₂ SO₄ .The titre value was 15.0cm³ . Calculate the
concentration of H₂ SO₄ .
A

weight : 2
S

option : 0.4M

option : 0.30M

option : 0.25M

answer : 0.35M

question : Why do you standardize the KMnO₄ solution before use in redox
experiment?

weight : 2

option : To ensure its quality

option : To know the actual concentration

option : KMnO₄ decomposes after some time

answer : All of the above

question : In precipitation titration, the titration of chloride using adsorption indicator is called?

weight : 2

option : Volhard method

option : Potentiometric method

answer : Fajan's method

option : Mohr method

R
question : What amount in gram of potassium hydroxide must be weghed inorder to prepared 1.0 M
O
in 1000cm³ of the solution ? <br /> <br /> [KOH =56.1g/mol

weight : 2
P
option : 0.56g

option : 5.60g
M

answer : 56.1g
A

option : 0.056
S

question : Which of these is a suitable indicator for titration involving sodium hydroxide and
hydrochloric acid solution?

weight : 2

option : Any indicator

answer : methyl red

option : phenolphthalein

option : congo red

question : To choose a suitable indicator for acid-base titration, it depends on ?

weight : 2
answer : The strength of acid and base

option : The basicity of acid and base

option : The molarity of acid and base

option : The molality of acid and base

question : A well labelled sample bottle describes ?

weight : 2

answer : the concentration of the solution

option : the location of the solution

R
option : the colour of the solution

option : the level of the solution

O
question : Indicator commonly used for potassium permanganate titration is ?
P
weight : 2
M

option : redox indicator

answer : self indicator

A

option : starch indicator

option : couple indicator

S

question : During acid- base titration a point is reached when equivalent amounts of acid and base
have been added together.This is called?

weight : 2

option : end point

option : neutralization point

answer : equivalence point

option : titration point

question : Standardization of KMnO₄ solution by sodium oxalate
Na₂C₂O₄ is done in ...........medium

weight : 2

answer : acid

option : basic

option : neutral

option : salty

question : A solution of accurately known concentration is called ?

weight : 2

R
option : Molar solution

option : Normal solution O

answer : Standard solution
P
option : Formal solution
M

question : Twenty (20) students are to be supplied each with 100ml of 0.05M NaOH solution in the
laboratory.What quantity of NaOH is requred to be weighed for this for this purpose? [NaOH] =
A

40gmol^-1

weight : 2
S

option : 4.5g

answer : 4.00g

option : 5.00g

option : 5.50g

question : In volumetric analysis,the symbol M is often used for?

weight : 2

option : mol cm^-3

option : mmol cm^-3

answer : mol dm^-3

option : g cm^-3

question : A solid A of mass 5.00kg was gently dipped into a measuring cylinder containing water,
the level of water increased from 60cm³ to 100cm³ . Calculate the density
of solid A.

weight : 2

option : 0.125g/cm³

answer : 125g/cm³

option : 12.5g/cm³

option : 1.25g/cm³

R
question : Iodimetry titration deals with......

weight : 2
O
answer : Indirect method of iodine estimation
P
option : Direct method of iodine estimation
M

option : Addition of iodine

option : Removal of iodine

A

question : What mass of the solute must be used in order to prepare 500 cm³ of
S

0.0100 mol/dm³ NaOH(aq) from NaOH(s)?

weight : 2

option : 2.0g

answer : 0.2g

option : 2.55g

option : 0.210g

question : Which of these steps is not necessary in acid-base titration?

weight : 2

option : To rinse the burrette and the pipette with the solution to be used in them
option : To remove the funnel from the burette before titration

answer : To rinse the titration flask with the solution it is to hold

option : All the above steps are not necessary

question : 250cm³ of 0.8M NaOH was diluted to 1 litre. Calculate the amount of solute
in 200cm³ of the dilute solution.

weight : 2

option : 0.64 moles

option : 1.00 moles

option : 0.02 moles

R
answer : 0.04 moles

O
question : A solution which normally resist changes in pH when a small quantity of either acid or
base is being added is known as?
P
weight : 2
M

option : Normal solution

option : Molar solution

A

answer : Buffer solution

option : Concentrated solution

S

question : Which of these is not true of K₂ Cr₂O₇ titration?

weight : 2

answer : It cannot be used in the presence of HCl or its salts

option : colour change from deep green to blue

option : diphenylamine in concentrated H₂ SO₄ is reduced

option : K₂ Cr₂ O₇ is reduced

question : Primary standards used in redox titrimetry include

weight : 2

option : Ferrous ammonium sulphate

option : Potassium dichromate

option : Potassium iodate

answer : any of the above

question : Which of these acids is not suitable for potassium permanganate redox titration?

weight : 2

answer : Both HCl and HNO₃

R
option : HCl and H₂ SO₄

option : HCl only

option : H₂SO₄ only

O
P
question : Calculate the amount in moles of solute in 250cm³ of sodium hydroxide
solution containing 1.00moldm^-3
M

weight : 2
A

option : 0.20moles

option : 0.30moles
S

answer : 0.25moles

option : 0.03moles

question : The oxidation state of Chlorine in HOCl₂ , HClO₃ and

HClO₄ are respectively.

weight : 2

option : +7 +5 and +1

answer : +1 +5 and +7

option : +1 , +3 and +4

option : -1 -5 and +7
question : Reducing agent X reacts with oxidizing agent Y, the true statement is

weight : 2

option : X is reduces

option : Y is oxidises

option : X gains electron

answer : Y gains election

question : Last drop at the pipette tip should not be blown to avoid <br /> <br /> I using more
volume II breaking the glassware <br /> <br /> III adulterating the sample

R
weight : 2

answer : I only O
option : I and II only
P
option : I and III only

option : I, II and III

M

question : Arrange the following compounds of manganese in order of increasing oxidation state of
A

manganese KMnO₄ , MnCl₂ & MnO₂

weight : 2
S

option : MnCl₂ , MnO₂ and KMnO₄

option : MnCl₂ , MnO₂ , KMnO₄

answer : KMnO₄ , MnO₂ , MnCl₂

option : MnO₂ KMnO₄ MnCl₂

question : Clamping the burette in vertical position is a precaution for which of the following
reasons?

weight : 2

option : To avoid leakage

option : to allow proper flow of content

answer : To avoid error due to parallax

option : To allow direct contact centrally in the conical flask content

question : Which of the followings affects the determination of density of gases and liquid?

weight : 2

option : concentration

answer : temperature

option : solubility

option : pressure

R
question : What volume of 0.20M NaOH when diluted to 600cm³ will produce a
solution of concentration 0.05M? O
weight : 2
P
option : 2400cm³

answer : 150cm³
M

option : 100cm³
A

option : 200cm³
S

question : Which of the following correctly describe the use of a crucible in the laboratory?

weight : 2

option : To dry the sample

option : To ash the sample

option : To evaporate the sample

answer : all of the above

instruction : null

question : The following are true of complexometric titration except?

weight : 2

option : The technique is useful for the determination of a larger number of metals

option : Many metal ions form slightly soluble salts or slightly dissociated complexes

option : It offers ease of metal ions and anions at the millimole level

answer : It is independent of pH

question : The number of molecules of the complexing agent is called?

weight : 2

answer : Ligand

R
option : Stability constant

option : Formation constant

option : Lewis acid

O
P
question : The ligand often depend on <br /> <br /> I. The co-ordination number of the metal
<br /> <br /> II. The number of complexing groups on the ligand molecule <br /> <br /> III.
M

The bonding site

weight : 2
A

option : I only

option : II only
S

option : I and III only

answer : I and II only

question : Ammonia is a simple complexing agent with one pair of unshared electrons that may
complex with which of these ions ?

weight : 2

answer : Silver

option : Calcium

option : Sulphate

option : Nitrate
question : Simple complexing agent such as ammonia are rarely used as titrating agents, because

weight : 2

answer : a sharp endpoint corresponding to a stoichiometric complex is generally difficult to achieve

option : a sharp end point is obtained at equilibrum

option : the stepwise formation constant is large

option : all of the above

question : An organic agent that has two or more groups capable of complexing with a metal ion is
called?

R
weight : 2

answer : a chelating agent O

option : a chelate
P
option : a complex

option : a ligand
M
A

question : Which of the following is not true of ethylenediamine tetra acetic acid?

weight : 2
S

option : it has six complexing groups

option : it is a tetraprotic acid

option : it has four ionizable hydrogen on the four carboxyl groups

answer : it has four complexing groups

question : Which of these is a suitable indicator used in complexometric titration?

weight : 2

option : methyl orange

answer : Eriochrome Black T

option : methyl red

option : phenolphthalein

question : Consider the reaction: Zn + CuSO₄ &rarr; ZnSO₄ + Cu.

Name the reducing agent in the above reaction

weight : 2

answer : Zn

option : CuSO₄

option : ZnSO₄

option : Cu

R
O
P
M
A
S