Professional Documents
Culture Documents
International Congress
on Ancient Bronzes
Resource, reconstruction,
representation, role
EDITED BY
PHILIPP BAAS
B A R I N T E R NAT I O NA L S E R I E S 2 9 5 8 2019
Published in 2019 by
BAR Publishing, Oxford
doi https://doi.org/10.30861/9781407355894
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Preface.............................................................................................................................................................................. viii
Carol C. Mattusch
Vorwort.............................................................................................................................................................................. ix
Philipp Baas
Part I. Reconstruction
1. Innovation and Tradition – Greek Bronzecasting Workshops...................................................................................3
Gerhard Zimmer
2. Casting large statuary in Classical Antiquity: Thoughts from India and Egypt....................................................13
Paul Craddock
3. Past and Recent Metal Analyses of the Germanicus Statue from Amelia...............................................................25
Alessandra Giumlia-Mair, John Pollini
4. The Brescia Winged Victory: Ongoing Diagnostic Work, Conservation Treatment and Restoration..................35
Francesca Morandini, Stefania Agnoletti, Annalena Brini, Andrea Cagnini, Monica Galeotti, Anna Patera,
Simone Porcinai
5. Projet d’une nouvelle étude technologique de l’Aurige de Delphes: les premiers résultats..................................45
Sophie Descamps-Lequime, Benoît Mille, Nancy Psalti
6. The Bronze Antikythera Ephebe Revisited: Technical Features and Casting Technique......................................57
Kosmas A. Dafas
7. Bronze Cast on Decorated Iron Sheets. An Unusual Manufacturing Technique in Iron Age Italy......................67
Joachim Weidig, Nicola Bruni, Fabio Fazzini
8. Artful illumination: Technical study of four Hellenistic bronze lamps from the eastern Black Sea site
of Vani................................................................................................................................................................................75
Jeffrey Maish, David Saunders, Nino Kalandadze, Marc Walton
9. Corinthian Helmets in the Hermitage Museum.........................................................................................................87
Nadezda Gulyaeva
10. A New Look at an Old Technology: Insights into the Metallurgy of Tin Bronze during the Iron Age of
Luristan..............................................................................................................................................................................91
Omid Oudbashi
11. Drahtziehen in der Bronzezeit? Zu den drei Ziehbronzen aus dem Hort von Isleham, Cambridgeshire........101
Ilyas Özşen
12. Bronze Circulation in the Aegean in the 2nd millennium BC: Technological Investigations of Bronze
Finds from the Minoan Peak Sanctuary at Ayios Yeoryios sto Vouno, Kythera.......................................................107
Emilia Banou, Aikaterini Panagopoulou
13. La Tomba Principesca di Roscigno: Greci e indigeni nelle élites dell’Italia Meridionale..................................117
Silvia Pacifico, Rossella Luciano
14. Authepsa: A Singular Brass Container from Augusta Emerita (Mérida, Spain). History and
Interpretation of the Object...........................................................................................................................................125
Rafael Sabio González, Cristina Isabel Mena Méndez
15. Technology Matters: The Kal-e Chendar Bronze Statuary from the Seleucid to the Parthian Periods...........131
Gunvor Lindström
v
Proceedings of the XXth International Congress on Ancient Bronzes
vi
Contents
35. Paphian obstacles to powerful Death. A set of surgical tools found in the Agora of Paphos.............................359
Maciej Wacławik
36. About Löwenkannen: La Löwenkanne del Museo Archeologico di Verona........................................................367
Marina Castoldi
37. Bronze Vessels from the Etruscan Necropolises of Bologna (540 – 350 BC): Preliminary Notes......................373
Giulia Morpurgo
38. The Kegs from the “Celtic” Graves of Santa Paolina di Filottrano. Misadventures and
misunderstandings..........................................................................................................................................................381
Nicoletta Frapiccini
39. Bronzeobjekte aus der römischen Garküche auf dem Monte Iato (PA)..............................................................389
Eva Riediker-Liechti
40. Roman bronzes of Augusta Emerita (Spain). A functional approach...................................................................397
Nova Barrero Martín, Rafael Sabio Ganzález
Previous International Bronze Congresses and Publications.....................................................................................405
vii
Preface
Since 1970, the International Bronze Congress has been the major forum for scholars whose
research enhances our knowledge of the art, culture, and technology of bronzes in the Classical
world. The twentieth International Congress on Ancient Bronzes was held from April 17 to 21,
2018, at the Institute for Classical Archaeology of Eberhard Karls Universität in Tübingen, at the
generous invitation of the Institutsdirektor Professor Dr. Thomas Schäfer.
Carol C. Mattusch
Chair, Advisory Board
viii
Vorwort
Philipp Baas
Vom 17.–21.04.2018 fand am Institut für Klassische Kolleginnen und Kollegen besprechen Objekte, Befunde,
Archäologie der Eberhard Karls Universität Tübingen Werkprozesse, Analysewerkzeuge und Kontexte.
der „XXth Congress on Ancient Bronzes“ statt. Diese Abgerundet wird diese Zusammenschau durch bspw. eine
Veranstaltung blickt auf eine lange Tradition zurück, die eher ethnologische Analyse (Craddock) und Beiträge,
1970 mit dem ersten „Congress on Ancient Bronzes“ in die vor allem auf antike Verwendungs-, aber auch
Nijmegen begann. Die breit aufgestellten Konferenzen Recyclingpraxis abzielen (Treister, Schweizer, Willer et al.)
bringen und brachten seitdem nicht nur Forschende und so den Lebenszyklen und Verwendungsbiographien
verschiedener Disziplinen, sondern auch Expertinnen der Objekte nachspüren.
und Experten aus ganz Europa, und im Falle Tübingens,
Georgien, Großbritannien, dem Iran, Israel, Russland, der Bei einem solchen Band stellt sich häufig die Frage
Schweiz und den USA zusammen. nach der inhaltlichen Klammer oder der übergeordneten
Fragestellung: Dieser Band soll als Plattform fungieren, die
Unter den Oberthemen „Resource, Reconstruction, neue Funde und Objekte zeigt, Bekanntes in ein neues Licht
Representation, Role“ trafen sich 120 Wissenschaftler rückt und schließlich Altes wie Neues kontextualisiert.
und Wissenschaftlerinnen sowie Interessierte, die den 78 Doch vor allem soll er als Plädoyer für eine Pluralität
Vorträgen lauschten. Der Band ist nach diesen Oberthemen der Methoden verstanden werden. Es gilt zu zeigen, was
gegliedert. Dazu seien zwei Anmerkungen erlaubt. Da möglich ist, sowohl mit traditionellen als auch innovativen
die Themen so offen formuliert waren und sind, war es Ansätze, aber auch wo die jeweiligen Methoden an ihre
eine Herausforderung die eingegangen Beiträge einem Grenzen stoßen. Der Blick soll nicht eingeengt werden
bestimmten Themenkreis zuzuweisen. So kann man auf eine einzelne Region, Epoche, Gattung oder Methode,
beispielsweise die Beiträge von Gunnvor Lindström, sondern geweitet für die Möglichkeiten und Diversität
Rachel Nouet und Jean-Marie Welter ohne weiteres jeder der Objekte in Raum und Zeit, vor allem aber für die sich
der Kategorien zuordnen. Damit erklärt sich jedoch auch aus der Kombination unterschiedlicher Analyseansätze
der Überhang bei den Themenkomplexen Reconstruction ergebenden Mehr-Erkenntnis in unserer Deutung von
(15) und Role (12), wohingegen Resource (5) und bereits Vergangenem.
Representation (8) gewissermaßen Juniorpartner zu sein
scheinen. Ich bin einer Vielzahl von Menschen zu Dank verpflichtet,
die einen wichtigen Anteil an dem Erfolg der Konferenz
Anders als die bisherigen Kongresse war es die Intention und der Genese des Bandes hatten. Zuvorderst dem
in Tübingen, das Material der Bronze an sich in den Fokus „Standing Commitee“ des „Congress on Ancient
zu stellen, um einen weiteren Blick, auch abseits des Bronzes“, das mir in der Vorbereitung der Veranstaltung
Figürlich-ornamentalen, zu ermöglichen. Da gerade in der und besonders bei der Redaktion des Bandes mit Rat und
deutschsprachigen Forschung im Bereich der Klassischen Tat zur Seite stand: Sophie Descamps, Eckhard Deschler-
Archäologie in den letzten Jahrzehnten ein Trend zurück Erb, Norbert Franken, Alessandra Giumlia-Mair, Nadezda
zur reinen Kunstgeschichte zu beobachten ist, wollten wir Gulyaeva, Despina Ignatiadou, Anne-Marie Kaufmann
auch modernen, technologischen Ansätzen eine Plattform Heinimann und Susan Stock.
anbieten. Ziel war ein Nebeneinander traditioneller und
innovativer Ansätze, die so auch in dem vorliegenden Band Carol Mattusch hat als Chair einen unglaublichen
vertreten sind. So geht es nicht nur um das Endprodukt Enthusiasmus bewiesen, als sie sich bereit erklärte,
aus Bronze, sondern ebenso um materialwissenschaftliche sämtliche Beiträge nach dem Review noch einmal
und metallurgische Aspekte sowie die Produktion von Korrektur zu lesen und auch die Formalia zu überprüfen.
Bronzeobjekten, seien es Werkzeuge, Münzen, Statuetten Der Herausgeberin der „British Archaeological Reports“
etc. Der klassischen Erschließung aus einem Materialcorpus und „BAR Publishing“, Birgit Thaller, danke ich für die
heraus stehen technische Analysen zur Seite. Aus unserer Aufnahme in die Reihe „BAR International Series“. Die
Sicht erfüllte die Konferenz, und damit dieser Band, den Betreuung durch Lisa Eaton, Ruth Fisher und Jacqueline
stets formulierten, oftmals nicht umgesetzten Anspruch Senior von Seiten des Verlages war hervorragend und
der Inter- und Multidisziplinarität. Expertinnen und äußerst professionell.
Experten sowohl aus den Bereichen Restaurierung,
Materialwissenschaft, Grabungsarchäologie sowie Dann danke ich den Kolleginnen und Kollegen des
Numismatik als auch kunsthistorisch arbeitende Instituts für Klassische Archäologie der Eberhard Karls
ix
Philipp Baas
x
210mm WIDTH 25.6mm 210mm WIDTH
BAR S2958 2019 BAAS (Ed) Proceedings of the XXth International Congress on Ancient Bronzes
‘This volume contains the very latest news on classical bronzes.
Since 1970, International Bronze Congresses have been the major
forum for disclosing current research on the bronzes of the ancient
world. The Proceedings of the 20th Congress (Tübingen, 2018)
contain 40 papers about recent discoveries, new approaches, and
developing ideas, presented by international scholars with varied
approaches to archaeology, art history, technology, and conservation.
Topics range from belt-buckles to statues, from inscriptions to
helmets, from ancient repairs to recycled metals, from iconography
to tomography, from Greece to Luristan, and from the Bronze Age
to the Late Roman period.’
Carol C. Mattusch, George Mason University emerita
297mm HIGH
The proceedings of the XXth International Congress on Ancient Bronzes address
these key topics, bringing together experts from different backgrounds to
investigate further the developing studies in the field of ancient bronzes. on Ancient Bronzes
Philipp Baas studied Classical Archaeology and History in Bochum, Rome and
Göttingen. He finished his PhD on rural Roman Sicily in 2013. Since then he has
worked at museums and universities in Göttingen, Kassel and Tübingen. His research Resource, reconstruction,
focuses on Roman settlement patterns, Hellenistic and Roman art, and the reception
of classical art. representation, role
Contributors: Stefania Agnoletti, Cristina-Georgeta Alexandrescu, Emilia Banou,
Nova Barrero Martín, Giulia Bison, Maryse Blet-Lemarquand, Margherita Bolla,
Annalena Brini, Nicola Bruni, Andrea Cagnini, Marina Castoldi, Paul Craddock, EDITED BY
Kosmas A. Dafas, Sophie Decamps-Lequime, Fabiano Fiorello Di Bella, Daphni
Doepner, Fabio Fazzini, Norbert Franken, Nicoletta Frapiccini, Stamatis A. Fritzilas, PHILIPP BAAS
Johanna Fuchs, Monica Galeotti, Alessandra Giumlia-Mair, Nadezda Gulyaeva,
Nino Kalandadze, Philip Kiernan, Gunvor Lindström, Rossella Luciano, Jeffrey
Maish, Cristina Isabel Mena Méndez, Benoît Mille, Manuela Mirschenz, Francesca
Morandini, Giulia Morpurgo, José María Murciano Calles, Trinidad Nogales Basarrate, B A R I N T E R NAT I O NA L S E R I E S 2 9 5 8 2019
Rachel Nouet, Vana Orfanou, Omid Oudbashi, Ilyas Özşen, Silvia Pacifico, Aikaterini
Panagopoulou, András Patay-Horváth, Anna Patera, John Pollini, Simone Porcinai,
Nancy Psalti, Eva Riediker-Liechti, Rafael Sabio González, David Saunders, Roland
Schwab, Beat Schweizer, Zetta Theodoropoulou Polychroniadis, Mikhail T reister,
Antonia Tzortzatou, Maciej Wacławik, Marc Walton, Joachim Weidig, Jean-Marie
Welter, Frank Willer, Gerhard Zimmer
Printed in England
210 x 297mm_BAR Baas CPI 25.6mm ARTWORK.indd All Pages 29/11/19 5:24 PM
4
Abstract: The statue is one of the few Roman bronzes known from northern Italy. Since its
discovery a number of hypotheses about its origin and date have been advanced, with reference
to its iconography, resemblance to similar pieces and technique of manufacture. Collaboration
between the Brescia Council, Brescia Museums Foundation and the Florence Opificio delle Pietre
Dure has enabled the formulation of a project for studying, conserving and restoring the statue.
This paper presents the results of scientific investigation and preliminary tests regarding the
treatment of surfaces to determine the most appropriate conservation operations.
The statue’s history (by Morandini) the Capitolium itself – and was then concealed, along with
other works, in an inter-wall cavity in the late Imperial
The bronze statue represents a winged female figure which building, for reasons that are not entirely clear. Perhaps
would originally have displayed to viewers a shield on they were hidden to keep them safe, or maybe this was a
which she had just finished writing, using a stylus held in hoard of metal items waiting to be melted down and given
the fingers of her right hand. Her left foot was placed on new forms and functions.
some object, probably a helmet, and the shield would have
been held between her left arm and bent left leg; neither Hidden in the same place together with the Victory were
shield, stylus nor helmet has survived (Fig. 4.1). found numerous other bronze sculptures and architectural
temple furnishings, including six Imperial epoch portrait
The statue, almost two metres high, was made by lost wax heads, a figured sword belt from an equestrian statue and
casting; some areas have been finished with a chisel and another without relief decoration, a gilt appliqué showing
the band around the hair is damascened (most recently: a prisoner, a statue’s arm, moulded and damascened
Formigli – Salcuni 2011, 5–24). frames, three bands with cylindrical ends, several smooth
frames, and numerous smaller pieces of bronze (Formigli
It was discovered in July 1826 during archaeological – Salcuni 2011, 35–52; for details about cult statue throne
excavations conducted by the Brescia Ateneo di Scienze, frames, see Franken 2002).
Lettere e Art at the Capitolium temple of Roman Brixia;
the statue was found between two walls bordering the The exact year is unknown, but probably the first restoration
temple’s western chamber, together with numerous other of the Victory was attempted in about 1834: a metal frame
bronzes. was built inside the statue in order to connect the wings
and arms, which were found detached and placed near the
These important finds led to the establishment in 1830 – body. This ingenious structure consists of a rectangular-
inside the temple unearthed during this most successful in-section iron bar that extends from the nape to the lower
excavation campaign – of the Museo Patrio (Fig. 4.2), limit of the chiton, with some mechanically connected and
which was visited by the most illustrious scholars of the interlocking side-pieces to which the arms and wings are
epoch (Panazza 2004). joined. To attach the vertical bar to the bronze, the inside
of the statue was filled with an admixture of various rather
The Winged Victory would have once been displayed in compact materials, some of organic origin (Miazzo 1994–
one of ancient Brixia’s principal public buildings, perhaps 1999).
35
F. Morandini, S. Agnoletti, A. Brini, A. Cagnini, M. Galeotti, A. Patera, S. Porcinai
Figure 4.1. Brescia, Museo di Santa Giulia. Bronze statue of Figure 4.2. The Winged Victory in the Museo Patrio,
Winged Victory (1st cent. AD) (Archivio Fotografico Musei Brescia: the missing shield and helmet have been
Civici Brescia). reconstructed, probably using wood and plaster
(photograph c. 1915, Archivio Fotografico Musei Civici
Brescia).
Numerous studies have been made of the bronze, and
interpretative hypotheses been proposed for the bronze,
which came to be identified with the Roman goddess Diagnostic studies, partial maintenance operations and
Victoria (summary in Morandini 2011). examinations of different types have been conducted over
time to ensure the statue’s good state of preservation and
News of Brescia’s Winged Victory spread quickly to better understand its history, in particular its origin,
throughout Europe, to the extent that days before the date, and physical and technical characteristics.
battle of Solferino in June 1859, Napoleon III came to
visit the Museo Patrio – and (as recorded in contemporary During World War II the Victory was removed from the
chronicles) was so struck by the statue and its allegorical Capitolium and hidden in the grounds of a villa south
significance that following his triumph in the battle he of Brescia; checks on its state of preservation at the end
asked for a copy of it. Brescia did its utmost to satisfy of the war involved thorough-going examinations and
this request, making the first plaster cast by direct contact, conservation treatment, conducted in 1948 in Rome at the
from which a bronze copy was then produced – and which Istituto Centrale del Restauro (now Istituto Superiore per
today is on display in the Louvre (Morandini 2009; Le la Conservazione ed il Restauro), with further analyses of
Breton 2019; Panazza 2009 and 2011). the alloy composition (Borrelli 1950, 30; see below) .
The first analyses of the bronze of which the Victory is Research on the statue was taken up again 50 years later
made, conducted by Gian Giacomo Arnaudon, director of when in 1998 the new Museo della Città was opened in the
the Royal Arsenal of Turin chemical laboratories, also date monumental complex of Santa Giulia. The Winged Victory
to this period. The diagnostic operations carried out in 1861 was dismantled and moved to a new display location (not
were among the first archaeometric studies ever conducted far from the previous one).
on an archaeological bronze. These analyses revealed the
composition of the alloy (Arnaudon 1861; Taddia 2010, The temporary removal of wings and arms, that were
122. 124–125; Morandini 2011, 10–11; see below). still attached to the 19th century frame, allowed partial
checks on the sculpture’s interior. These have resulted
Gabriele D’Annunzio wanted a copy of the Victory – but in interesting observations concerning its history,
without wings – for his residence, the Vittoriale degli archaeology and technical features, together with
Italiani, and Giosuè Carducci praised the statue in “Alla antiquarian considerations, opening a fruitful new season
Vittoria” after seeing it in the Museo Patrio. of studies on the statue (Miazzo 1994–1999; Moreno
36
The Brescia Winged Victory: Ongoing Diagnostic Work, Conservation Treatment and Restoration
2002; Ferretti, Miazzo 2011; Morandini 2009; Morandini On that occasion, the eye sockets were filled with coloured
2011; Panazza 2009; Panazza 2011; Salcuni 2011. sheet metal that is still present on the statue; it is likely
that other operations were also carried out on the surfaces:
According to an earlier hypothesis the statue was made some areas were abraded (damascening) and waxy
in Hellenistic times as Aphrodite (therefore without wings substances were applied.
and with a partially different posture), brought to Rome as
war booty, turned into a Victory by the addition of wings, In the following decades, this restoration of the statue
and finally donated to Brescia as an imperial ex voto for was questioned by some scholars, not only due to
the temple (Moreno 2002 with previous bibliography). disagreement with the reconstruction proposed by Labus,
but also because of reportedly incorrect positioning of the
A subsequent study of Roman bronzes in north Italy wings on the back and poor joining of the left arm to the
dates the Winged Victory to the Roman era, specifically shoulder, not properly fitting the edges of the fracture and
to Julio-Claudian times, and for the first time furnishes thus lowering the position of the arm (Rizzini 1910, 275;
hard evidence that the statue’s body was originally made Nicodemi 1926, 47– 48).
together with the wings and arms (Formigli – Salcuni
2011, 5–24). Subsequent 19th-century interventions on the statue can be
traced back to the above-mentioned plaster cast made for
The diagnostic studies carried out in the same period Napoleon III, other probable operations of the same type,
involved the use of strain gauges and acoustic emission left evident traces on the bronze surface which were still
measurements, which highlighted the statue’s generally partly visible when the Victory was transported to Rome
poor condition, due to improper functioning of the to repair the damage suffered during its transfer from the
internal support for wings and arms, and deterioration museum during World War II (also mentioned above). At
of the organic components present in the material that the ICR the various types of deterioration were recorded
anchors this frame. The existence of these problems (Fig. 4.3 and 4.4), and the results of the conservation
was reconfirmed in 2018, underlining the urgent need treatment given were later published (Borrelli 1950).
for taking corrective action with regard to the Winged
Victory’s mechanical state and the condition of its The recently initiated programme of studies on the
surfaces, accompanied by an overall study of its history Winged Victory (see above) has provided the basis for the
and interpretation. conservation project currently being drawn up, which is
the result of collaboration between the Brescia Council,
Conservation Project (by Patera, Brini, Agnoletti) owner of the statue, the Brescia Museums Foundation,
which manages the city museum heritage, and the Ministry
When found, the Winged Victory statue was in a good for Cultural Heritage and Activities, represented by the
state of preservation, with the exception of some lacunae Archaeology, Fine Art and Landscape Superintendency of
in the wing-tips and fingers. The eyes were also missing, as the Provinces of Brescia and Bergamo, and the Florence
were the deity’s specific attributes, which would certainly Opificio delle Pietre Dure (a specialized cultural heritage
have been present originally. The detached arms had been conservation institute). The conservation work and other
positioned “at the sides of the statue” while the wings, also activities currently underway are funded by private firms,
removed, were found “one above the other” at the head. the Brescia Council, and the Brescia Museums Foundation.
These brief notes on the statue’s condition at the time of
discovery may be found in various accounts published in The first conservation objective is the removal of the
the Commentari dell’Ateneo di Brescia (extracts given in 19th century internal metal support that no longer seems
Nicodemi 1926 passim and Bonardi 1937 passim) and in sufficient to safely fulfil the function of attaching the
the Museo di Brescia catalogue (Labus 1838, 136–141, wings and arms for which it was designed (Fig. 4.5).
figs. XXXVIII. XXXIX. XL), which also contains the first
illustrations of it. Various inspections carried out recently through the gaps
left by the removal of the arms indicate that at least in
After the sensational discovery, the interest of scholars the upper part, the material that attached the frame seems
and the academic world focused mainly on the stylistic to have lost the cohesion necessary to fix it solidly to the
examination and identification of the subject sculpted in bronze statue.
bronze; for this reason, the 19th century descriptions known
to us mainly focus on formal aspects, without providing Moreover, non-invasive investigations carried out through
detailed information useful for studying its conservation acoustic emission measurements have highlighted stresses
history and technological characteristics. within the statue, due to the weight of the wings on the
back and the postural asymmetry this causes, also due to
The discoverers, and in particular Giovanni Labus who the no-longer-perfect functioning of the anchoring system.
first studied the statue, were principally concerned with In 1950, during the conservation work conducted in Rome,
reassembling the figure’s various parts (wings, arms and plans were made to eliminate this weighty structure, but
body) and identifying the missing attributes (helmet, were abandoned because of the complexity of the problem
shield and stylus) that are typical of a Winged Victory. (Borrelli 1950, 33). The controlled removal of the support
37
F. Morandini, S. Agnoletti, A. Brini, A. Cagnini, M. Galeotti, A. Patera, S. Porcinai
Figure 4.3 and 4.4. The statue without wings probably in about 1948, just before it was moved to Rome for conservation
treatment in the Istituto Centrale per il Restauro (now ISCR) (Archivio Fotografico Musei Civici Brescia).
Figure 4.5. Detail of the statue’s back showing the two holes The conservation project also involves cleaning the
for attachment of the wings (Archivio Fotografico Musei external surface, which is largely covered by earthy
Civici Brescia). encrustations and deposits of various kinds, including
waxy residues, colouring materials and resins left from
(now possible due to technical improvements) will allow previous interventions.
the design of a new structure for attaching the arms and
wings that will permit the display of the sculpture in The scientific analyses discussed below were conducted in
conformity with conservation requirements. order to identify the origin of these materials, partly so as
to select the most suitable products for their removal. Also
38
The Brescia Winged Victory: Ongoing Diagnostic Work, Conservation Treatment and Restoration
in this case conservation work provides an opportunity tin, 80.70% copper, 7.68% lead, 1.91 % zinc with traces
to acquire new information about the statue, such as for of iron. Later analysis on two samples from the body of
example the possible presence of gilding on the surfaces, the Victory gives slightly different results, reported in
which at present may only be detected in small areas on Table 4.1 (Formigli 2011, 19; Ferro 2011, 19). More spots
the arms. were tested with portable XRF in order to find out possible
differences between the body and the wings (Ferretti 2011,
Scientific investigations (by Cagnini, Galeotti, 18). In the latter case, the thick layer of encrustation plays
Porcinai) a significant role in the elements’ ratio. Inconsistencies
of results due to different analytical techniques, effect of
Before starting any conservation operations, an extensive encrustation thickness and of uneven lead distribution in
investigation of the alloy and of the surface composition the alloy, and poor quality of samples point to the need for
was conducted with the aim of making informed decisions reliable quantitative analyses: these are planned for when
regarding treatment and getting to know more about the the surface will be cleaned up. In fact, removal of soil and
statue’s manufacturing technique and conservation history. thinning of the corrosion layer will make it possible to use
Although priority was given to non-invasive analytical non-invasive means (portable XRF) more confidently for a
techniques (portable X-Ray Fluorescence – XRF-and semi-quantitative survey. Further on, a few metal samples
Reflection Fourier Transform Infrared Spectroscopy – will be taken from selected areas.
FTIR), it proved necessary to sample some fragments of
the encrustation layer and of the patina. Very small flakes While the analysis of the alloy will be presented in an
were investigated by transmission micro-FTIR, and in upcoming publication, preliminary results on the surface
some cases, they were embedded in polyester resin and composition and the patina layer are reported here. They
ground to prepare polished cross-sections. These were indicate the widespread presence of lead in the outer part
studied with optical microscope and Scanning Electron of the surface, confirming the outcomes of past XRF
Microscope (SEM), equipped with energy dispersive investigations (Ferretti 2011, 18). Lead was detected in
X-ray analysis (EDX) probe. quite thin layers on protruding areas and also in thicker
deposits in flatter areas. FTIR spectra, obtained from both
XRF measurements were performed using an XGLab surface reflectance and μ-transmission on samples, show
Elio portable spectrometer (incidence angle 90°; spot that lead is in the form of carbonate and hydroxycarbonate.
size 2.5 mm) equipped with a Si-Drift detector (active Figure 4.6 shows a cross-section of a sample (images with
depth=500 μm, Take-off angle=63.5°, Sample-detector optical and electron microscope). The dense greenish
distance=14mm) and a Rh anode. For reflection FTIR, matrix has a complex composition that includes many
we used an ALPHA Bruker spectrometer. Spectra (200 carbonates (calcium, lead, copper), phosphates (lead,
scans) were collected with a spectral range of 400– calcium, and mixed Ca-Pb phosphates), and silicates. In
7000 cm-1, 4 cm-1 resolution, background on gold plate, the SEM image elongated crystals of lead carbonates,
collecting areas of 4 mm diameter and processed using formed by the recrystallization process, are clearly visible.
OPUS software. (Fig 4.6).
The analyses on samples were performed using a In particular, SEM-EDX analysis of individual particles
Continuum Infrared Microscope linked to a Nicolet Nexus included in the green encrustation identifies phases
FTIR spectrometer, with a spectral resolution of 4 cm-1 containing either silicon and copper, or copper plus
(128 scans) in transmittance mode. calcium and silicon (Fig. 4.7). These phases can be
interpreted as copper silicates and calcium copper
An EVO® MA 25 Zeiss scanning electron microscope silicates, and are widespread in the light green matrix.
equipped with an Oxford EDS X-MAX 80 mm2 microprobe Thick green encrustation also includes dihydrated calcium
and AZTEC® system with a 20 keV voltage was used sulphate and quartz particles. Malachite is widespread
for SEM-EDX. Samples were coated with a carbon film on the surface, partly in the matrix containing copper
prior the analysis. Optical microscopic observations silicates, and partly as a separate phase, as may be seen in
were performed with a Zeiss Axioplan microscope. Figure 4.8, where an agglomeration of malachite overlies
Interestingly, the alloy of the Victory has been investigated a white layer of calcium carbonate. Calcium carbonate is
many times: early analytical data by the Italian chemist also present as little ‘stones’, several millimetres across,
Gian Giacomo Arnaudon date back to 1860 (Arnaudon spread all around the surface. Copper (and lead) chlorides
1861, 177–178). He reported a composition with 9.44% and hydroxychlorides were also detected; for example,
Table 4.1. Quantitative composition of the alloy of the Winged Victory (ND, not detected), (after Formigli 2018, 18 and Ferro
2011, 19)
Method Cu% Fe% Zn% Pb% Ag% Sn% Sb% Au%
ICP-MS 88.38 0,38 0,02 8,41 0,28 ND 0,06 0,17
SEM-EDX 84 ND ND 7 ND 9 ND ND
39
F. Morandini, S. Agnoletti, A. Brini, A. Cagnini, M. Galeotti, A. Patera, S. Porcinai
Figure 4.6. Optical microscope image of cross-section of the encrustation layer. The area in the red square is shown in the
SEM-BSE image.
Figure 4.7. Optical microscope image of cross-section of the light green matrix of the encrustation with SEM-EDX spectra of
individual green particles.
FTIR spectra identify the presence of atacamite (Fig. 4.7 stratigraphy of buried bronze, as described in the literature
and 4.8). (Robbiola – Porter 2006). Indeed, in this preliminary
phase of the work, only limited sampling was performed,
In spite of the presence of tin in the alloy (roughly around and no samples including the entire thickness of the patina
9%), no tin was found in the superficial layer investigated down to the alloy were taken. After this general survey,
so far. This might be due to the fact that the sampled further investigations will be focused on particular areas
volume does not include the complete characteristic and a few samples with complete stratigraphy down to
40
The Brescia Winged Victory: Ongoing Diagnostic Work, Conservation Treatment and Restoration
Figure 4.8. Optical microscope image of cross-section showing an agglomeration of malachite overlying a white layer of
calcium carbonate.
the alloy will be taken from hidden parts of the statue. It nearby objects made of lead or high-lead bronze, or from
is expected that these samples will enable us to acquire a building components such as piping. This hypothesis
deeper knowledge of the composition of the patina. Apart is also compatible with the results of previous XRF
from the extensive presence of soil-derived elements, investigation, which revealed an uneven distribution of
other compounds, coming from past conservation this element on both sides of the Victory, with higher
actions, indicate that our examination is limited to the content on the back. Calcium carbonate and/or lead
outer layer of the patina/encrustation and that the layered carbonate could be responsible for the white efflorescence
system indicated by Robbiola is to be found underneath. covering the surface of the Victory described by the
In fact, FTIR spectra reveal the presence of protective conservators before the treatment carried out at the ICR
and/or finishing compounds, such as animal wax and in 1948 (Borrelli 1950, 32).
poly-methyl-methacrylate. Other compounds – copper
carboxylates and oxalates – are related to the interaction While the copper silicates and calcium copper silicates
of lipids with alloy corrosion compounds. may be explained by reactions between copper corrosion
compounds and soil, questions and doubts arise with
In some spots on the surface, featuring very dark colour regard to the origin of malachite. On one hand, malachite
and smooth appearance, SEM-EDX analysis shows the is one of the typical compounds found in buried bronzes
presence of copper and sulphur, with no oxygen. These (Robbiola – Hurtel 1997), yet we must consider the
data indicate that a sulphide-based artificial black patina possibility of its artificial application to colour the
is present. sculpture (Risser – Saunders 2013, 41–55). In fact, the
1948 ICR report mentions an impressive list of treatments
In general, the interpretation of the analytical data is not and compounds that might have considerably affected
straightforward, because the sculpture has undergone the surface composition and appearance. The authors
various conservation treatments since its discovery, and of this report describe a first quick rinsing with distilled
was reburied during World War II. No documentation water to remove a whitish crystalline deposit, then they
exists on the sculpture’s state of preservation after it was applied a very dilute solution of caustic soda. According
first unearthed, and there are no records concerning the to the ICR conservators, this treatment uncovered the old
19th-century treatments. The existence of plaster replicas patina, with a dark green colour. Then a treatment aimed
of the Victory provides a possible explanation for the at stabilizing the patina (“fissazione della patina”) was
remains of dihydrated calcium sulphate, a material used performed with sulphuric acid, while a subsequent patina
for casting. With regard to the high amount of lead and consolidation (“consolidamento”) was done with copper
its needle-like crystal form, this element could come acetate and copper hydrogencarbonate. The use of these
from the corrosion of the sculpture, with its high-lead two compounds, in combination with acidic and basic
alloy (roughly in the 7%–8% range, Ferro 2011, 19; solutions, may have left on the surface various forms of
Formigli 2011, 18), but it might also have come from copper carbonates and acetates, not easy to differentiate
the burial environment. In fact, no detailed information from naturally formed ones, like, for example, malachite.
is recorded on the sculpture’s discovery context and it is The 1948 records refer to treatment with sodium sulphide
possible that the lead could have migrated either from to make particularly light-coloured areas less evident. The
41
F. Morandini, S. Agnoletti, A. Brini, A. Cagnini, M. Galeotti, A. Patera, S. Porcinai
outcome of this patina treatment may be clearly seen in the Formigli, E. – Salcuni, A., eds., 2011. Grandi bronzi romani
dark areas featuring copper and sulphur alone. dall’Italia settentrionale, Frankfurter Archäologische
Schriften, Bonn.
Notwithstanding the invasiveness of the past operations
Franken N. 2002, Nuove osservazioni sui troni
described above and the doubts about the origin of some
monumentali di divinità nel Capitolium di Brescia, In:
copper-containing compounds, analyses show evidence
F. Rossi, ed. 2002. Nuove ricerche sul Capitolium di
of materials applied in the plaster-casting process, and of
Brescia. Scavi, studi e restauri. Milano, 191–195.
compounds from the soil and from the interaction of soil and
alloy corrosion products. The presence of these substances Labus, G., 1838. Osservazioni archeologiche intorno ai
indicates that the cleaning of the Victory’s surface was monumenti figurati esposti nel Museo. In: G. Nicolini –
not as harsh as one might expect from the account of the R. Vantini – G. Labus 1938. Museo Bresciano Illustrato,
1948 conservation operations. Organic materials and their I. Brescia, 121– 219.
transformation products, on the other hand, have a clear
Le Breton, E., 2009. La Vittoria alata nelle raccolte del
origin in protection/finishing treatments. Besides the wax
Louvre. In: Lucchesi Ragni – Mondini – Morandini
applied in 1948, Paraloid was used in subsequent surface
2009, 67–75.
treatment in 1998, after dusting the surface and removing
old organic coatings. In the current project, preliminary Le Breton, E. 2019, La Victorie ailée de Brescia dans
cleaning trials were carried out on the surface of the statue la gypsothèque du musée du Louvre: d’une statue en
with the aim of finding an effective way to remove natural plâtre à une fonte en bronze, Monuments et mémoires
and synthetic organic materials. The tests were monitored de la Fondation Eugène Piot, (97), pp. 69-93.
with portable digital microscope and reflectance FTIR,
Lucchesi Ragni, E. – Mondini, M. – Morandini, F. eds.
to check, respectively, the effects on the surface and the
2009. Napoleone III a Brescia e a Solferino. La Vittoria
efficacy of the cleaning methods.
celebrata 1859–2009. Milano.
After this preliminary inquiry, many questions remain Miazzo, L., 1994–1999. Considerazioni di restauro in
open about the surface characterization, in particular the occasione dello spostamento della Vittoria alata di
investigation of inner alteration layers, next to the alloy, Brescia, Sibrium, (23), 471–478.
containing cuprite and other oxides. Comparison with
Morandini, F., 2009. Dalla scoperta di una statua antica
fragments taken from inside the sculpture will help to
alla nascita di un simbolo. La Vittoria alata di Brescia.
differentiate between naturally formed compounds and
In: Lucchesi Ragni – Mondini – Morandini 2009, 53–
those added artificially. The possible presence of pigments
57.
and binders used on discoloured areas will be explored
carefully; this investigation will also be extended to the Morandini, F., 2011. Integrazioni e restauri sulla Vittoria
wings and arms. alata di Brescia. In: Formigli – Salcuni 2011, 7–12.
Moreno, P., 2002. Iconografia e stile della Vittoria
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