Q1: In the following which bond will be responsible for maximum value of hydrogen

bond
(A) O–H

(B) N–H

(C) S–H

(D) F–H
Q1: In the following which bond will be responsible for maximum value of hydrogen
bond
(A) O–H

(B) N–H

(C) S–H

(D) F–H

Solution:

Hydrogen bonding will be maximum in F–H bond due to greater electronegativity di erence.
Q2: The reason for exceptionally high boiling point of water is
(A) Its high speci c heat

(B) Its high dielectric constant

(C) Low ionization of water molecules

(D) Hydrogen bonding in the molecules of water

Q2: The reason for exceptionally high boiling point of water is
(A) Its high speci c heat

(B) Its high dielectric constant

(C) Low ionization of water molecules

(D) Hydrogen bonding in the molecules of water

Solution:

Hydrogen bonding increases the boiling point of compound.

Q3: Which concept best explains that o-nitrophenol is more volatile than p-nitrophenol
(A) Resonance

(B) Hyperconjugation

(C) Hydrogen bonding

(D) Steric hindrence

Q3: Which concept best explains that o-nitrophenol is more volatile than p-nitrophenol
(A) Resonance

(B) Hyperconjugation

(C) Hydrogen bonding

(D) Steric hindrence

Solution:

o-Nitrophenol has intramolecular hydrogen bonding but p-Nitrophenol has intermolecular hydrogen bonding so boiling
point of p-Nitrophenol is more than o-Nitrophenol.
Q4: In which of the following hydrogen bond is present
(A) H2

(B) Ice

(C) Sulphur

(D) Hydrocarbon
Q4: In which of the following hydrogen bond is present
(A) H2

(B) Ice

(C) Sulphur

(D) Hydrocarbon

Solution:

Ice has hydrogen bonding.

Q5: In the following which has highest boiling point
(A) HI

(B) HF

(C) HBr

(D) HCl
Q5: In the following which has highest boiling point
(A) HI

(B) HF

(C) HBr

(D) HCl

Solution:

HF has highest boiling point because it has hydrogen bonding.

Q6: In a double bond connecting two atoms, there is a sharing of
(A) 2 electrons

(B) 1 electron

(C) 4 electrons

(D) All electrons

Q6: In a double bond connecting two atoms, there is a sharing of
(A) 2 electrons

(B) 1 electron

(C) 4 electrons

(D) All electrons

Solution:

In a double bond connecting two atom sharing of 4 electrons take place as in H2C = CH2
Q7: Which type of overlapping results the formation of a π bond
(A) Axial overlapping of s – s orbitals

(B) Lateral overlapping of p – p orbitals

(C) Axial overlapping of p – p orbitals

(D) Axial overlapping of s – p orbitals

Q7: Which type of overlapping results the formation of a π bond
(A) Axial overlapping of s – s orbitals

(B) Lateral overlapping of p – p orbitals

(C) Axial overlapping of p – p orbitals

(D) Axial overlapping of s – p orbitals

Solution:

p-bond is formed by lateral overlapping of unhybridised p – p orbitals.

Q8: In the following which species does not contain sp3 hybridization
(A)

(B) CH4

(C) H2O

(D) CO2
Q8: In the following which species does not contain sp3 hybridization
(A)

(B) CH4

(C) H2O

(D) CO2

Solution:

CO2 is sp-hybridised.
Q9: As a result of sp hybridization, we get
(A) Two mutual perpendicular orbitals

(B) Two orbitals at 180°

(C) Four orbitals in tetrahedral directions

(D) Three orbitals in the same plane

Q9: As a result of sp hybridization, we get
(A) Two mutual perpendicular orbitals

(B) Two orbitals at 180°

(C) Four orbitals in tetrahedral directions

(D) Three orbitals in the same plane

Solution:

sp-hybridization gives two orbitals at 180° with linear structure.

Q10: Which contains strongest H – bond
(A) O – H ….. S

(B) S – H ….. O

(C) F – H ….. F

(D) S – H ….. F
Q10: Which contains strongest H – bond
(A) O – H ….. S

(B) S – H ….. O

(C) F – H ….. F

(D) S – H ….. F

Solution:

The strongest hydrogen bond is in hydrogen uoride because the power of hydrogen bond μ electronegativity of atom
and electronegativity . So uorine has maximum electronegativity and minimum atomic size.
Q11: Which of the following compound can form hydrogen bonds
(A) CH4

(B) NaCl

(C) CHCl3

(D) H2O
Q11: Which of the following compound can form hydrogen bonds
(A) CH4

(B) NaCl

(C) CHCl3

(D) H2O

Solution:

H2O can form hydrogen bonds rest CH4 and CHCl3 are organic compound having no oxygen while NaCl has itself
intraionic attraction in the molecule.
Q12: Of the following hydrides which has the lowest boiling point
(A) NH3

(B) PH3

(C) SbH3

(D) AsH3
Q12: Of the following hydrides which has the lowest boiling point
(A) NH3

(B) PH3

(C) SbH3

(D) AsH3

Solution:

PH3 has the lowest boiling point because it does not form Hydrogen bond.
Q13: The pairs of bases in DNA are held together by
(A) Hydrogen bonds

(B) Ionic bonds

(C) Phosphate groups

(D) Deoxyribose groups

Q13: The pairs of bases in DNA are held together by
(A) Hydrogen bonds

(B) Ionic bonds

(C) Phosphate groups

(D) Deoxyribose groups

Solution:

conceptual
Q14: Triple bond in ethyne is formed from
(A) Three sigma bonds

(B) Three pi bonds

(C) One sigma and two pi bonds

(D) Two sigma and one pi bond

Q14: Triple bond in ethyne is formed from
(A) Three sigma bonds

(B) Three pi bonds

(C) One sigma and two pi bonds

(D) Two sigma and one pi bond

Solution:
Q15: The bond in the formation of uorine molecule will be
(A) Due to PCl5 overlapping

(B) Due to s – p overlapping

(C) Due to H2O2 > O3 > O2 overlapping

(D) Due to hybridization

Q15: The bond in the formation of uorine molecule will be
(A) Due to PCl5 overlapping

(B) Due to s – p overlapping

(C) Due to H2O2 > O3 > O2 overlapping

(D) Due to hybridization

Solution:

In uorine molecule formation p – p orbitals take part in bond formation.

Q16: The number and type of bonds between two carbon atoms in calcium carbide are
(A) One sigma, one pi

(B) One sigma, two pi

(C) Two sigma, one pi

(D) Two sigma, two pi

Q16: The number and type of bonds between two carbon atoms in calcium carbide are
(A) One sigma, one pi

(B) One sigma, two pi

(C) Two sigma, one pi

(D) Two sigma, two pi

Solution: