Mole Concept(Chemistry)

(Assignment – 7)
1. When 100 ml of 1 M NaOH solution and 10 ml of 10 N H2SO4 solution are mixed
together, the resulting solution will be :
(a)alkaline (b)acidic (c)strongly acidic (d)neutral
Ans. (d)
Sol. Number of millimoles of NaOH = 1 × 100 = 100
Number of milliequivalent of NaOH
= millimoles valency factor = 100× 1=100
Number of milliequivalent of H2SO4 = 10× 10 = 100
 Number of milliequivalent of NaOH = Number ofmilliequivalent of H2SO4
The resultant solution will be Neutral.
2. Normality of 0.74 g Ca(OH)2 in 5 mL solution is
(a) 8 N (b) 4 N (c) 0.4 N (d) 2 N
Ans. (b)
0.74
Sol. No. of equivalent   2  0.02
74
0.02 0.02 1000
Normality  3
  4N
5  10 5
3. Normality of a 2 M sulphuric acid is
(a) 2 N (b) 4 N (c) N/2 (d) N/4
Ans. (b)
Sol. Normality = Valency factor × Molarity
Normality = 2× 2 = 4 N
4. 1 L of a normal solution is diluted to 2000 ml. The resulting normality is :
(a) N/2 (b) N/4 (c) N (d) 2 N
Ans. (a)
Sol. On dilution, the resultant normality can be calculated as
N1V1 = N2V2
1× 1 = N2× 2
1
 N2  N
2
5. What volume of 0.232 N solution contains 3.17 milliequivalent of solute ?
(a)137 mL (b)13.7 mL (c)27.3 mL (d)12.7 mL
Ans. (b)
Sol. No. of milli equivalent = Normality ×Vml
3.17 = 0.232×Vml
3.17
V   13.7ml
0.232
6. 1L solution of NaOH contains 4.0 g of it. What shall be the difference between molarity
and the normality ?
(a) 0.10 (b) zero (c) 0.05 (d) 0.20
Ans. (b)
Sol. Normality = Valency factor × Molarity
For NaOH, valency factor = 1
For NaOH, Normality = Molarity
7. 100 ml of 0.3 N HCl is mixed with 200 ml of 0.6 N H2SO4. The final normality of the
resulting solution will be
(a) 0.1 N (b) 0.2 N (c) 0.3 N (d) 0.4 N
Ans. (d)
Sol. M eq. of HCl = 1 × 30 = 30
M eq. of H2SO4 = 0.6× 200 = 120
Total meq = 120 + 30 = 150 and Total volume = 300 ml
The Normality of resultant solution will be,
N = 150/300 = 0.5 N.
8. Normality of a mixture of 30 mL of 1N H2SO4 and 20 mL of 4N H2SO4 is
(a) 1.0 N (b) 1.1 N (c) 2.0 N (d) 2.2 N
Ans. (d)
Sol. Normality of a mixture is given by

9. Normality of solution obtained by mixing 10 mL of 1N HCl, 20 mL of 2N H2SO4 and 30

mL of 3N HNO3 is
(Use the Final volume as sum of all volumes).
(a) 1.11 N (b) 2.22 N (c) 2.33 N (d) 3.33 N
Ans. (c)
Sol. Similarly,
N V  N 2 V2  N 3V3 110  2  20  3  30
N net  1 1 
V1  V2  V3 10  20  30
10  40  90 140
   2.33 N
60 60
10. 25 mL of a solution of Ba(OH)2 on titration with a 0.1 M solution of HCl gave a titre value
of 35 mL. The molarity of barium hydroxide solution was
(a) 0.07 (b) 0.14 (c) 0.28 (d) 0.35
Ans. (a)
Sol. As law of chemical equivalence, [LOCE]
(N ×V)Acid = (N × V)Base
Normality of HCl =Molarity × h'-factor
=0.1Acid 1 = 0.1 N
Normality of Ba(OH)2 =Molarity × 'n'-factor =M × 2
Thus, applying LOCE
(N V) HCl  (N V) Ba (OH)2
 0.1 × 35=M × 2 × 25
Molarity of Ba(OH)2 =0.07M