CHM 4220 O S ,C P P ,D .L S.

S
C 8 O S

EE
p

#
!y÷q
, sure - s

18-E R ( EAN, E A N ,R )
.
E amples of Transi ion Me als Used in S n hesis

Cr Fe Co(I) Ni
→ Ti
Me al Sc V Mo Mn R Rh(I) Pd C (I) Zn(II)
Zr
W Os Ir(I) P
“d
→ 3 4 5 6 7 8 8 10 10 10
elec ron
elec ron
needed
15 14 13 12 11 10
!0 8 8 8

( ¥÷÷J::i
Rhd )
"
%:
"
: : .

O
coordinately
unsaturated

+
( ]
-
o

+3
. r÷÷÷¥;ru÷ :
O %÷
.

(NHzx4)= 18
-

Could dbt 8 e- e
4e-CUx2)t
coordinating saturated
 E /

P M M

m⑤ Icu, into
Mto :B
to gf carted
A
allyl of
" "

mm: " ¥4 !
'
:
:c -=o '
@
m
no =
.

carbon
monoxide m④
8.1 A T M C
Cha ge e a ? E ec c ea?I c d a e a a ed ( .e. 18 e ec )?

TptohrdD
pass o : : ÷! %?
n
"
:D
Codd
.
-
at
in
• Ru or
Ct . I

:
G bb ca a

¥
a:O
"÷÷÷÷¥÷÷÷÷
*

(
ng
H,
"

+6
- 4 → +2

& .
.
.

-
N -
Cll)

⑥ read Te
"
 8.2 O R M
number
L E
CHIEN
:

f.
some
qwgcinds)
"

O ( solvent
O . .

printer
O A +2
-
Z

→
00
d. addition
Pda) -
pdldqox.no .
oxidation

✓
red - eliminator
R E -2
G- A

⑥ .

RWMgoy.ro refutation
!
bonds
.

←
new
0 A 00 I
 HO
M I { g
-
T

m O
-

O
B E

M
A b
k
k

dimwit alhinerdivatnt

migratory
insertion
De c be each e , de e e Rh da ae h gh :
 CO
T

Ta
I
eaa ed c -c g eac

T M -M S T

8.3 C D

④
ah d f
- -
a eac
O i

O a
← O
*c e a deh de a a e (RCHO RH),
* ac d ch de a ha de (RCOC RC )

④
Lagaan 0*7
a

:*
fondant
¥0
•

( m)
If

origin's •

c, •
cm

w
migration
2
migratory
insertion
8.4 T H R

's
halim alkene
•
gnewcebond
•

gp

⑦
-

Feme
th

E a e: ④ we

oxiaddn
'

eliminator 0

ringworm

:
8.5 P -C C -C R

o
S R rin
.
.

•
•

oxaddn
'

E a e: refineries
0
OI
a
0
transmutation
 S -M R

H
B
b
d

"
b BB

RBI
U eaS -M a a C g Reac ach e e he f g a f a :

" B A
g
. .
i
.
Z
z

ABB " b
Ipp ,
/ppy Boy ,
pdCMhd4

NaOH

O O

he
8.6 O M R
q
9 )
alkene O
⑥ ⑥ payloads
C -M
#1
R2

CH2
R1 R1

retro L M CH2 [ 2+2]

[ 2+2]
'

c cloaddition

9
L M CH2 L M CH2

o R1 R2 R1
CH2

retro
[ 2+2] ML [ 2+2]
c cloaddition

R1 CH2
H2C CH2
R2

#2

U eaC -Me a he Reac ach e e he f g a f a :

KHZ CHECK
HO HO

boo ! CO Me =p
④
•
2
MeO MeO
come
e ge 'm
Ian

←
|¥ ←

HECK
R -C M (RCM)
catal tic c cle continues

H2C M

• • M
• •
CH2 CH2 CH2 CH2 M
H2C CH2

origins creutz

I am
}
•

O O
o o
P

O
O
✓

O O O O
O
ph
on
Wed btw ←
bond

• *
*