Answer Tutorial 7

1.
(a) Ĥ =  cp dT
55

 123  10
3
=  18.6  10 5 dT
15

T2
= 123  10 3 T  18.6  10 5
2
 55 2  15 2 
= 123  10 3 (55  15)  18.6  10 5  
 2 
= 4.92  0.2604

= 5.18 kJ/mol

(b) Ĥ =  cp dT
80

 216.3  10
3
= dT
25

= 216.3  10 3 (80  25)

=11.9 kJ/mol

(c) Ĥ =  cp dT
0

=  137.44  10  40.85  10  23.92  10  57.66  10 dT

3 5 8 12

500

T2 T3 T4
=  137.44  10 T  40.85  10
3 5
 23.92  10 8  57.66  10 12
2 3 4
=
0 2  500 2 0 3  5003 0 4  500 4
137.44  10 3 (0  500)  40.85  10 5 ( )  23.92  10 8 ( )  57.66  10 12 ( )
2 3 4
= -68.72-51.06+9.97-0.90

= - 110.7 kJ/mol

2.
(a) The efficiency to convert water at 20oC to saturated steam at 20 bar is 65%.

Q = 0.65 (813 kJ/s) = 528.45 kW (kJ/s)

1
 From steam table: H1 (water at 20oC) = 83.9 kJ/kg
H2 (saturated steam, 20 bar,212.4oC) = 2797.2 kJ/kg
 H = H2 - H1 = (2797.2 - 83.9) kJ/kg = 2713.3 kJ/kg

Since, Q = m H
mQ  528.45kJ / s 2713.3kJ / kg  0.19 kg/s
H

(b) The steam is produced at 212.4 oC and 20 bar,

Thus, Vˆ  0.09950 m3/kg (saturated steam)
0.19kg 0.09950m 3
 the volumetric flowrate =
3
  0.0189 m
s kg s

3.

4.
Substances . ^ . ^
n in (mol/s) H in n out mol/s H out
(KJ/mol) (KJ/mol)
NH3 100 0 - -
O2 200 0 75 ^
H1
NO - - 100 ^
H2
H2O - - 150 ^
H3

Calculate Unknown Enthalpies :

2
  O2 (g, 300 ˚C) :From table B.8, = 8.470 kJ/mol;
300

 29.50
^ 3
 NO (g, 300 ˚C) H 2 =  0.8188 5  ( 0.2925 8 )  0.3652 12 =8.453
25

kJ/mol
^
 H2O (g, 300 ˚C) :From table B.8, H 3 = 9.570 kJ/mol;

. .
Calculate  and  H

.
. n NH 3 100mol / s  25 mol / s
= =
4
vNH 3

. ^ . ^
n H   n in H in
. . . 
H =  Hr +
out out
25mol/s)(-904.7 kj/mol)+ [(75)(8.470)+(100)(8.453)+(150)(9.570)-(100)(0)-(200)(0)]

=- 19700 kJ/s

Energy balance for open system:

. . . . .
Q  Ws   H   E k   E p

Work = 0
Potential = 0
Kinetic = 0

. .
So Q   H = -19700 kJ/s = -19700 kW

5. i) Integration of heat capacity.  Cp (dt )

H=  Cp (dt )
o
200 C

 28.94  10
3
=  (0.4147  10 5 )T  (0.3191 10 8 )T 2  (1.965  10 12 )T 3 dT
500 o C

T2 T3 T4 200
 28.94  10 T  (0.4147  10 )
3 5
=  (0.3191 10 8 )  (1.965  10 12 )
2 3 4 500

3
 (2002  5002 ) 8 (2003  5003)
28.94 103 (200 500)  ( .0 4147105 )  ( .0 319110 )
2 3
 ( 2004  5004)
 ( .1 965 1012)
4

= - 8.682  0.435435  0.124449  0.029917

= -9.212 kJ/mol

Q  nH
20kmol kJ 1000mol
=  (9.212 )x  184  10 3 kJ
h mol 1kmol h

ii) Using specific enthalpies tables provided.

H2(200oC) = 5.15 kJ/mol

H1(500oC) = 14.37 kJ/mol

kmol kJ 1000mol
Q  n( H 2  H 1 )  20  (5.15  14.37)   184  10 3 kJ
h mol 1kmol h

6).

a) Calculate the rate (kg/h) at which steam is produced.

b) Use the steam tables to estimate the volumetric flowrate of the steam produced.