Sri Chaitanya IIT Academy., India. AP, TELANGANA, KARNATAKA, TAMILNADU, MAHARASHTRA, DELEL RANCHL ‘right Ghoiee for the Real flapirant ICON CENTRAL OFFICE, MADHAPUR - HYD Sec: Jr. Super60-1 Date: 19-06-17 Time: 07:30 AM to 10:30 AM Max. Marks: 198 Name of the Student: 1D. NO: PAPER-I 19-06-17_Jr.Super60-I_WTA-8_Weekend Syllabus PHYSICS: Projectile motion on inclined planes.relative velocity (Relative velocity 1D,2D Rate of approach and rate of separation,condition for collission of two projectiles,relative motion of one projectile with respect to another projectile,rain problems river boat problems,air craft wind problems etc..) CHEMISTRY: Chemical Equilibrium: Equilibrium involving physical processes: solid - liquid, liquid - gas and solid - gas. General characteristics of equilibrium involving physical process, Equilibrium involving chemical processes, characteristics of equilibrium state, Law of mass action, equilibrium constant, characteristics of equilibrium constant, Kp, Kerelation Lechatlier's principle - factors effecting equilibrium concentration, pressure, temperature and effect of catalyst, principle applied for synthesis of ammonia and sulphur trioxide and other typical reactions, Thermodynamics of equilibrium constant. Significance of AG and AG’ in chemical equilibrium (60%) Enthalpy of reaction - different types of enthalpies, Hess's law, Effect of temperature on enthalpy of reaction - Kirchoff's equation, Hess's law and its applications, Determination of enthalpy of hydration of CuSO4, Resonance energy, Limitations of first law of thermodynamics, Second law of Thermodynamics, Camot cycle, efficiency of thermodynamic system, Entropy - physical significance, expressions in all types of processes .Gibb's free energy - physical significance, spontneity of processes(30%) Cumulative Syllabus(10%) MATHS: Trigonometric Equations (30%), Determinant (60%), Cumulative (10%)Svi Chaitanya IIT Academy 19-06-17_te.Super60-l_ JEE-Adv_(2012_P2)_WTA-8_0'P CHEMISTRY: SECTION -1 (SINGLE CORRECT CHOICE TYPE) This section contains 8 multiple choice questions. Each question has 4 choices (A), (B), (C) and (D) for its answer, cut of which ONLY ONE is correct. Marking scheme +3 for correct answer , 0 if not attempted and -1 21. For the reaction, X,0, (1) 2X0, (g), AU=21 eal, AS all other cases. 20 calK™ at 300K, Hence aG is A) 2.7 kcal B) -27 kcal ©) 9.3 kcal D) -9.3 keal 22. For the reaction - C(s) + H;O(g) + CO(g) + Ha(g) , AH’ = 133 ki/mol and AS* = 133 JKmol at 298 K. The minimum temperature in °C above which this reaction is spontaneous is A) 1000 B) 325 ©) 552 D)727 23. When NaNO,is heated in a closed vessel. Oxygen is liberated and NaNO, is left behind At equilibrium A) Addition of NaNO, favour reverse reaction B) Addition of NaNO, favour forward reaction C) Increasing temperature favour forward reaction D) Increasing pressure favour forward reaction See: Ir. Super60-1 ‘Space for rough work Page 14Sei Chaitanya ITT Academy 19-06-17_te Super60-I_ JEE-Adv_(2012_P2)_WTA-_0'P 24. At 1100K, water vapour decomposes into H,(g) and 0,(¢) only to the extent of 107% when pressure is maintained at 1 atm. The value of Kp for the decomposition of one ( ree mole of H,0 is (HOH, +50,| A) 5x10" B) J5x10% C) V5x10% D) 33x10" 25. 0.5 mole of H,(g) and 1.0 mole of HI(g) (but noJ, ) are added to a 1.0 litre vessel and allowed to reach equilibrium according to the following reaction #, (g)+1, (g) = 2(g) IE x is the equilibrium concentration of I,(g). Then correct expression for equilibrium constant is: 1-2xy' (42x) x(0.5-x) (0.5+x)x Ajeet) _ py Gti eo D ) Ose) tam Oa a 26. Which of the following statements is correct? A) IE Kbe the equilibrium constant for A=*B and K, be the equilibrium constant for C= D then equilibrium constant for the reaction AsD a BsC is & Ky B) IE K,be the equilibrium constant for P=2Q and K, be the equilibrium constant for RS then equilibrium constant for the reaction See: Ir. Super60-1 ‘Space for rough work Page 15Svi Chaitanya ITT Academy 19-06-17_te Super60-l_ JEE-Adv_(2012_P2)_WTA-_0'P & PrRSO+S is : iz C)IE Kjbe the equilibrium constant for 4} B=C4D the equilibrium constant for nA+nB = nC +nDis (K,}"".n can be fraction also D) The equilibrium constant unit for the gaseous reaction CH, +H, 2 C,H, is mol’dm 27. Calculate the percentage dissociation of #,5,, If 0.1 mole of H,S is kept in 0.5 L vessel at 1000K. The value of X, for the reaction 2H Sg) > Hyg) + Sy) 18 1.02107 A)01 B) 0.01 o1 D) 10 28. For the reaction CO,,, +H, =CO,,+H,0,,, K,, is 0.63 at 727°C and 1.26 at 927°C. 03) Then calculate the value of K,, at 1227°C (use log A) 832 B) 2.52 778 D)5.04 See: Ir. Super60-1 ‘Space for rough work Page 16Svi Chaitanya ITT Academy 19-06-17_te Super60-l_ JEE-Adv_(2012_P2)_WTA-8_0'P SECTION (COMPREHENSION TYPE) This section contains 6 mulfiple choice questions relating to two paragraphs with three questions on each paragraph, Each question has 4 choices A), B), C) and D) for its answer, out of which ONLY ONEis correct. Marking scheme +3 for correct answer , 0 if not attempted and -1 in all other cxses. Paragraph for Questions 29 and 30: A flask of 1L having NH,(g) at 2.0atm and 200K is connected with another flask of volume 800 ml having HCi(g) at 8atm and 200K through a narrow tube of negligible volume, The two gases react to form NH,Ci(s) with evolution of 43 KT/mol heat. If heat capacity of HCI(g) at constant volume is 20I/K mol. (neglect heat capacity of flask and NH,Ci solid, volume of solid NH,CI formed and its pressure) (R=0.08 L atm K+ moi) 29. The heat producedis in the reaction is A) 5.375KI B) 4.375KI ©) 68K D) 6.375T 30. The final pressure in the flask is A) 1439atm = ——B) 1.49atm ©) 16.39atm =D) 13.78atmSvi Chaitanya ITT Academy 19-06-17_tr.Super60-l_ JEE-Adv_(2012_P2) WTA-8_a'P Paragraph for Questions 31 and 32: Phosphorous pent chloride when heated in a sealed tube at 700 K, it undergoes decomposition as, PCI, (g) PCI, (g)+Cl,(g), K, =38atm vapour density of the mixture is 74.25 31. Percentage dissociation of PCls may be given as A) 4.04 B) 40.4 44.0 D) 0.404 32. When inert gas is added to the given reversible process then the equilibrium will A) be unaffected B) shift in backward direction C) shift in forward direction D) cannot be predicted Paragraph for Questions 33 and 34: In Haber's process the ammonia is manufactured according to the following reaction, YN, (g) +32 (¢) 2H, (g), AH? =-(22.44) The pressure inside the chamber is maintained at 200 atm and temperature at 500°C. Generally, this reaction is carried out in presence of Fe catalyst See: Ir. Super60-1 ‘Space for rough work Page 18Sri Choitemya IMT Academy 19-06-17 4 Super60L_ JEE-Adv.(2012_P2)_WTA-8_0'P 33. The preparation of ammonia by Haber's process is an exothermic reaction IF the preparation follows the following temperature pressure relationship for its % yield Then for temperature Ty, T2 and Ts, the correct option is 10 Ts bel 1% 3 | 2 a0 n * aol Prassure (atm) —= AQT; >T2>T) B)T,>T)>T3 On=h D) nothing could be predicted 34. 500°C is considered optimum temperature for Haber's process because A) catalyst has maximum activity at this temperature B) energy required is easily obtained at this temperature © yield is maximum at this temperature D) rate is fast enough while the yieldis also appreciable at this temperature See: Ir. Super60-1 ‘Space for rough work Page 19Sri Cheitenye IT Academy 19-06-17 se Super60-l_ JEE-Adv.(2012_P2)_WTA-8_0'P ‘SECTION — Ill (MULTIPLE CORRECT CHOICE TYPE) This section contains 6 mulfiple choice questions. Each question hat 4 choices (A), (8), (C) and (0) for its answer, out of which ONE OR MOREis/ are correct. Marking scheme +4 for correct answer , 0 if not attempted and 0 in all other euses. 35. A certain gas is expanded from (IL, 10atm) to (4L, Satm) against a constant external pressure of latm. If the initial temperature of gas is 300K and heat capacity for the process is 503 °C" (use 1L atm = 100 J), then A) P| =0.3kT B) f= 15 7 C) aU=1470 D)AH =157i 36. The stander enthalpies of formation of CO, gas and HCOOH, are ~ 393.7 kJmol” and- 409.2 kImol" respectively. Which of the following is/are correct ? A) Cy +O) ACOy., SH =-393.7 A mol B) CO.) +Hy,) HCOOH, AH =-15.5 J mol ©) HQ +CO, > HCOOH, — AH = 409.2 I moi* D)¢, AH =-409.2 47 mol yt Fagg) + On) > ACO See: Ir. Super60-1 ‘Space for rough work Page 20Sei Chaitanya: ITT Academy 19-06-17 _tr.Super60-l_ JEE-Adv_(2012_P2)_WTA-8_Q'P 37. 38. ‘Ammonia under a pressure of 20 atm. at 127°C is heated to 327°C in a closed vessel. ‘Under these conditions, ammonia is partially decomposed to N, and H,according to N, (8) +3#,(8) the reaction 2NH,(g): After decomposition at constant volume in the vessel, the pressure increases to 50 atm which of the following statements is/ are correct? A) The degree of dissociation of NH, in 2/3 B) The Kp of the reaction at 327°C is 27x10 atm’ ©) The pressure of M, and NH, gas at equilibrium is 10 atm. each D) The pressure of N, at equilibrium is half that of NH, Which of the following statements is/are wrong A) At equilibrium, concentration of reactants and products becomes constant, because the reaction comes to an halt B) Addition of inert gas at equilibrium for au>0 at constant volume will favour forward reaction. C) Addition of catalyst speeds up the forward reaction more than the backward reaction D) Equilibrium constant of an exothermic reaction increases with increase in temperature See: Ir. Super60-1 ‘Space for rough work Page 21Svi Chaitanya ITT Academy 19-06-17_tr Super60-l_ JEE-Adv_(2012_P2)_WTA-_0'P 39. 40. TEx andy are arbitrary intensive variables, then A) ayis an intensive variable B) xy is an intensive variable ©) (x+y) is an extensive property _D) d/dy is an intensive property Heat of neutralization of oxalic acid (H,C,0,) is — 25.4 kcal/mol with sodium hydroxide solution. Identify the correct option(s) among the following (ionization in the free acid is negligible) A) H,C,O, 2H" +C,0f AH =2 ical B) NaOH +42,C,0, s4nac,o, 4+H,O AH =-137 kcal ©) nH,OH +4H,0,0, + L(V), 0, +0 energy released is less than 12.7 kcal D) Heat of neutralization is determined by using calorimeter. See: Ir. Super60-1 ‘Space for rough work Page 22