06-04-17 - SR - IPLCO - Jee Adv - Ph-III - GTA-1 - New Model-1 (P1) - Q'Paper

GT A-1
Sri Chaitanya Narayana IIT Academy

(SRI SARVANI EDUCATIONAL SOCIETY)
COMMON CENTRAL OFFICE-MADHAPUR-HYDERABAD
Sec: Sr.IPLCO Date: 06-04-17
Time: 09:00 AM to 12:00 Noon Max.Marks: 330
PAPER-I
06-04-17_Sr.IPLCO_GTA-1_Weekend Syllabus
Mathematics : Total Syllabus
Physics : Total Syllabus
Chemistry : Total Syllabus

Sri Chaitanya Narayana IIT Academy 06-04-17_Sr.IPLCO_JEE-ADV_(New Model-1_P1)_Ph-III_GTA-1_Q’P
IIT-JEE-NEW Model-1_P1
Time:9:00 AM to 12:00 Noon IMPORTANT INSTRUCTIONS Max Marks: 330
MATHEMATICS:
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Sec – I(Q.N : 1 – 5) Questions with Multiple Option Correct 5 -2 5 25
Matrix Matching
Sec – II(Q.N : 6 – 10) +12 -4 5 60
(+3/-1 for every match)
Sec – III(Q.N : 11 – 15) Questions with Integer Answer Type 5 -3 5 25
Total 15 110
PHYSICS:
Sec – I(Q.N : 16 – 20) Questions with Multiple Option Correct 5 -2 5 25
Matrix Matching
Sec – II(Q.N : 21 – 25) +12 -4 5 60
Sec – III(Q.N : 26 – 30) Questions with Integer Answer Type 5 -3 5 25
Total 15 110
CHEMISTRY:
Sec – I(Q.N : (31 – 35) Questions with Multiple Option Correct 5 -2 5 25
Matrix Matching
Sec – II(Q.N : (36 – 40) +12 -4 5 60
Sec – III(Q.N : (41 – 45) Questions with Integer Answer Type 5 -3 5 25
Total 15 110
Sr. IPLCO_P1_Advanced Space for rough work Page 2

MATHEMATICS: Max. Marks : 110
SECTION – I
(MULTIPLE CORRECT ANSWER TYPE)
This section contains 5 multiple choice questions. Each question has 4 options (A), (B), (C) and (D) for its answer,
out of which ONE OR MORE than ONE option can be correct.
Marking scheme: +5 for correct answer, 0 if not attempted and -2 in all other cases.
 x   x 
1. f , g :  \ 1   such that f  2x  1  2 g  2x  1  2x and f  g   x, then
 x 1   x 1 
x 2  4x  1 x 2  3x  1
A) f  x   B) g  x  
x 1 x 1
C) f  5   3 2 D) g  2   1
2. Let A, B  M n    are square matrices of same order such that AB  BA  A . Then
A) A 5 B  BA 5  5A 5 B) trace  A   0
C) A must be an Idempotent Matrix D) A must be Nilpotent Matrix
3. Let f : 0,1   be a continuous function such that for all non-negative integer n,
1
 x f  x  dx  0 . Then
n
A) f  0   0 B) f  x  must be identically zero
C) f 1  1 D)  x1 , x 2  [0,1] such that f (x1 )f (x 2 )  0

4. Which of the following is/are true.
A) f , g :    , g  x   0, f  x  is twice differentiable and f   x   f  x    x g  x  f   x 
 f  x  is a bounded function
B) f :    1,1 , twice differentiable such that  f  0     f   0    4, then  x 0  R such

2 2
that f  x 0   f   x 0   0
C) Number of solutions of an equation 2 x  1  x 2 is two.
D) None of these
5. Let two circles of radius r1 and r2  where r1  r2  intersect each other at points P and Q.
Consider the direct common tangent of the two circles, nearer to point P, touching
them at points A and B respectively then
A) Circum radius of  PAB  r1 r2
B) Circum radius of  QAB  r1 r2

r1  r2
C) Circum radius of  QAB 
2
D) Circum radius of  PAB  Circum radius of  QAB

SECTION - II
(MATRIX MATCHING ANSWER TYPE)
This section contains 5 questions. Each question has four statements (A, B, C and D) given in Column I and four statements (P, Q, R
and S) in Column II. Any given statement in Column I can have correct matching with ONE or MORE statement(s) given in Column II.
For example, if for a given question, statement B matches with the statements given in Q and R, then for the particular question
darken the bubbles corresponding to Q and R in the OMR sheet. For each correct matching will be awarded +3 marks ONLY and
0 if not attempted and -1 in all other cases.
6.
Column-I Column-II
a) tan 400  tan100 0  tan1600 P 6
The value of is
tan 200 tan 40 0 tan 800
b) If ,  are roots of ax 2  bx  c  0, a  0 and Q 5

 
, are roots of x 2  3x  1  0, then the value
 
b2
of is
ac
c) If P is the product of solutions of the equation R 3
x nx  e2 x, then P is less than
d) If the expression kx 2  5xy  2y 2  3x  3y  1 can S 2

be split into two linear factors, then the value
of k is greater than or equal to

7.
Column-I Column-II
a) The set of points z satisfying z  i z  z  i z , is P) An ellipse with
4
contained in or equal to eccentricity
5
b) The set of points z satisfying z  4  z  4  10 , is Q) The set of points z
contained in or equal to satisfying Im z  0
c) If   2, then the set of points z   

1
is R) The set of points z

satisfying Im z  1
contained in or equal to
d) 1
If   1, then the set of points z    is contained S) The set of points z

satisfying Re z  2
in or equal to

8. Match the following for system of linear equations:-
2x  3y  5z  12 , 3x  y  z   , x  7y  8z  17
Column-I Column-II
a) Unique solution P)   2,   7
b) Infinite solutions Q)   2,   7
c) No solution R)   2,   7
d) Consistent system of equation S)   2,   7

9. Let â, bˆ and ĉ are three unit vectors mutually inclined to each other at an angle  .
ˆ ˆ  d.b
Also d̂ is an unit vector such that d.a ˆ ˆ  d.c
ˆ ˆ  cos  .
Match the entries for  given in Column-I with their corresponding values for  given
in Column-II.
Column-I    Column-II   
a)  P) 
2 4
b)  Q)  1 
cos 1  
3  3
c) 1 R) 2
cos 1   cos 1
4 3
d) 5 S) 
cos 1  
8 6

10.
Column-I Column-II
a) Number of ways in which 3 squares of unit length P) 441
can be chosen on a 8  8 chessboard, so that all
squares are in same diagonal line, is
b) Number of three letter words that can be formed Q) 361
using the letters of the word “LIVELIHOOD”, is
c) Number of five element subset that can be chosen R) 392
from the set of the first 11 natural numbers so that
atleast two of the five elements are consecutive, is
d) Number of ways in which the letters of the word S) 264
‘ABBCABBC’ can be arranged such that the
sequence of the letters ABBC does not appear in
any word, is

SECTION – III
(INTEGER ANSWER TYPE )
This section contains 5 questions. The answer is a single digit integer ranging from 0 to 9 (both inclusive).
Marking scheme +5 for correct answer , 0 if not attempted and -3 in all other cases.
11. If a function f  x  satisfies f  x  1  4f  x  1  f  x   and number of possible choices for
f 1 such that f  2017   0, is K. Then sum of all digits of log 2 K  is_____
12. If the largest possible side of an equilateral triangle with vertices within a unit square
(the vertices of the triangle can be inside the square or on its boundary) is
a  b; a, b   . Then a  b is….
 1
 a
 
1
b
13. If Lim   n  1 ! n 1   n! n
  b , then  a  is…..
n 
 
14. Let f :   , be twice continuously differentiable function such that
 f  2  f  7  
2f  x  1  f  x   f  2x  , then   is_______
 f  9  
15. f :    be a continuous function such that f  f  x    f  x   x  0 x   then number
of such functions is……

PHYSICS: Max. Marks : 110
SECTION – I
16. A very long uniformly rough horizontal conveyor belt is moved with constant velocity
6 m/s. A small coin is projected on belt from origin of a co-ordinate system as shown
in figure. Which is fixed to the ground so that initially it starts moving with speed
v = 8m/s on the belt along y-axis. The coefficient of friction between coin and surface
of belt is   0.6 , the width of belt d = 5m, take g  10 m / s 2 .
y
6 m/s
d
v
A) Coin moves with constant acceleration on the belt

B) Coin moves with non uniform acceleration on the belt
C) Coin leaves the belt with speed 5m/s
D) Finally coin comes to rest on the belt

17. A satellite of mass m orbits around the Earth in an elliptical path of semi-major and
semi-minor axis 2a and a respectively such that the Earth is located at one of the foci
of the elliptical path. At an instant when the satellite is located at a distance of r , its
velocity is u at an angle of 600 with respect to the position vector of the satellite from
the centre of the Earth. Consider only the gravitational force between the satellite and
the Earth and assume that the Earth is a perfect sphere.
(Assume that mass of the satellite is negligible as compared to mass of the Earth)
A) Orbital angular momentum of the satellite with respect to centre of the Earth is
3
mur
2
B) Areal velocity of position vector of the satellite with respect to centre of the Earth
3
is ur
4
8 a 2
C) Time period of orbital motion of the satellite around the Earth is
3 ur
D) Time period of satellite’s orbital motion is independent of mass of the Earth

18. Max Planck noted in 1899 the existence of a system of units based on the three
fundamental constants G, c, and h. These constants are dimensionally independent in
the sense that no combination is dimensionless and a length, a time, and a mass may
be constructed from them.
G
A) The length can be represented by formula
c3
c
B) The length can be represented by formula
G
C) The dimensional formula for acceleration is 3/2c 5/2G 1/2
D) The dimensional formula for acceleration is  1/2c 7/2G 1/2
19. A stationary sound source emits a wave that is received by a stationary observer as
p  p 0 sin kx  wt  .
A) If source moves towards the observer, he will perceive higher k as well as higher 
B) If source moves towards the observer, he will perceive lower k but higher 
C) If observer moves towards the source, he will perceive same k but higher 
D) If observer moves towards the source, he will perceive higher k as well as higher 

20. A parallel plate air capacitor is connected to a battery. If plates of the capacitor are
pulled further apart, then which of the following statements are correct?
A) Strength of electric field inside the capacitor remain unchanged, if battery is
disconnected before pulling the plate
B) During the process, positive work is done by an external force applied to pull the
plates whether battery is disconnected or it remain connected
C) Potential energy in the capacitor decreases if the battery remains connected during
pulling the plates apart
D) Potential energy in the capacitor decreases if the battery is disconnected before
pulling the plates apart
SECTION - II
21. An ideal monatomic gas undergoes different types of processes which are described in
Column – I match the corresponding effects in column – II. The letters have their
usual meaning.

Column – I Column – II
a) PV-2 = constant P) If volume increases then temperature
will also increase
b) PV2 = constant Q) For expansion, heat will have to be
supplied to the gas
c) C = Cv + 2R R) If temperature increases then work
done by gas is positive
d) C = Cv – 2R S) If pressure increases the work done
by gas is negative
22. A square loop is placed near a long straight current carrying wire as shown.


Match the following

a) If current is increased P) Induced current in loop is clockwise
b) If current is decreased Q) Induced current in loop is
anticlockwise
c) If loop is moved away R) wire will attract the loop
from the wire
d) If loop is moved toward S) wire will repel the loop
the wire
23.
Column I Column II
a)   rays P) Continuous energy distribution
with dark lines in between
b)   rays Q) Continuous energy distribution
with sharp peaks in between
c) Absorption spectrum of R) Continuous energy distribution
Hydrogen
d) X-rays S) Discrete energy distribution

24.
Column I Column II
a) Uniform positively charged Sphere having P) Field at C1 is from C2 to C1
a spherical cavity. The electric
C1
C2
( C1 & C 2 represents the center

of sphere and spherical cavity
respectively)
b) Spherical cavity in a uniform spherical Q) Field at C1 is from C1 to C2
Planet. The gravitational
C1
C2
( C1 & C 2 represents the center
of sphere and spherical cavity
respectively)
c) Cylindrical cavity in a wire carrying R) Field at C2 is from C2 to C1
uniform current density. The magnetic
C1 C2
( C1 & C 2 are the points on the

axis of cylinder and cylindrical cavity
respectively)
d) Two uniformly charged non conducting S) Field at C2 is perpendicular to
shells outer shell is positively charged C1C2
inner shell is negatively charged. The
electric
C2
C1
( C1 & C 2 represents the

center of spherical shells)

25. A satellite is in a circular equatorial orbit of radius 7000 km around the Earth. If it is
transferred to a circular orbit of double the radius,
Column I Column II
a) Angular momentum P) Increases
b) Area of Earth covered by Q) Decreases
satellite signal
c) Potential energy R) Magnitude becomes double
d) Kinetic energy S) Magnitude becomes half
SECTION – III
26. The main scale of a vernier calipers reads in millimeter and its vernier is divided into
ten divisions, which coincide with seven divisions of main scale. Furthermore when a
cylinder is tightly placed along its length between two jaws, it is observed that the zero
of vernier scale lies just right to 33rd divisions of main scale and fourth division of
vernier scale coincide with the one of the main scale division. Then the measured
value is 0.83 K cm. Find the value of K.
27. A solid conducting sphere of radius ‘a’ having charge q is surrounded by a concentric
conducting spherical shell of inner radius 2a and outer radius 3a as shown in figure.
The net charge on spherical shell is -2q. If the amount of heat produced when switch is
 q2 
closed is x   . Fill the value of x.
 96 0a 
a 2a
3a
S
28. A long plank P is placed on a horizontal frictionless surface and connected to two
springs of spring constant k and 2k respectively. A cylinder of mass m is placed on the
plank. The plank is displaced towards right (positive direction) and released at t = 0
and it oscillates with amplitude A. The cylinder does not slip on the plank during the
oscillation. The maximum friction force acting on the cylinder during the oscillation is
PkA
. Fill the value of P in OMR sheet.
7

m
2k k
2m
29. On a planet which has the same density as that of earth, they construct a frictionless
inclined plane of inclination 53 with the horizontal. When a block is released on the
inclined plane, it is seen to accelerate at 1 m / s 2 . What is the radius of planet (in
105 m ). Gravitational acceleration at surface of earth is 10 m / s 2 , Radius of earth 6400
km.
30. Three balls are kept on a straight line on a smooth surface. The first ball is projected
towards middle ball as shown. It collides with middle ball of mass m2 which then
collides with m3 . We want m3 to move with maximum possible velocity after one
collision. What should be mass m 2 (in kg)? All collisions are head on and elastic.
m1  4kg m2 m3  9kg
v0

CHEMISTRY: Max. Marks : 110
SECTION – I
31. K a 1 and K a are the 1st and 2nd ionization constants of maleic acid whereas
2
K a 1 ' and K a ' are those of fumaric acid, then choose the correct options among the
2
following .
A) P K a > P K a '
1 1
B) P K a >P K a
2 2
' C) P K a < P K a '
1 1
D) P K a < P K a
2 2
'
32. In a body centred cubic unit cell of A2 type (R is the radius of one particle at a lattice
point)
A) the edge length is equal to 4 R / 3
B) In this arrangement face centre is a regular octahedral void
2d
C) the edge length is equal to where ‘d’ is the shortest distance between two
3
lattice points
D) the square of the edge length is equal to 16R 2

33. A disconnection of 1, 4-diphenylbut -2- yne is given below followed by possible
corresponding synthetic reactions. Which of (A) – (D) is/are include as suitable first
reagent ?
Synthetic steps for the disconnect shown
A) BuLi, THF B) EtMgBr, Et2O

C) NaOEt, EtOH D) NaNH2 , NH3
34. Which of the following statement(s) is/are true about the reaction given below?
A) It involves a carbocation intermediate

B) Rearrangement is due to SN1 reaction mechanism
C) It proceeds via a concerted SN2 pathway
D) It involves neighbouring group participation
35. The potential energy of a diatomic molecule, as a function of the inter nuclear
A B
separation r, is approximated as U  r   
r a rb
Where A & B are positive constants and a > b
As shown in the above figure r0 is the equilibrium bond length. What is the energy
necessary to break the bond from its equilibrium position
A B B A Aa 
A)  B)  C)   1 D) Invalid Data
r0a r0b r0b r0a r0a  b 

SECTION - II
36. Match column I with correct thermodynamic parameters in Column – II (symbols
carry the usual meaning, assume gases to be ideal).
a) One mole of nitrogen gas contained in a cylinder at P) w0
300 K is allowed to expand isothermally against an
external pressure of 5 atm.
b) 3 moles of helium gas at 1 atm are compressed Q) U  0
reversibly and isothermally at 400K to 5 atm pressure
c) An ideal gas is compressed reversibly and R) H  0
adiabatically from a volume of 1dm3 to a volume of
0.25 dm 3
d) One mole of liquid benzene is converted reversibly S) H  U
into vapour at its boiling point by heating it.

37. Column – I has unbalanced reaction, Column – II has the relation between equivalent
mass (E) and molecular mass (M) of the underlined species in column – I.
Unbalanced Reaction
(a) P2 H 4 
 PH 3  P4 H 2 (P) E 
3M
4
(b) I 2 +HNO3 
 HIO3 +NO2 +H2 O (Q) E=
M
3
(c) CuO+NH3 
 N2 +Cu+H2O (R) E=
5M
6
(d) H 2 SO3  H 2 S  S  H 2O (S) stoichiometric coefficient of one of the
reactant species is 1
38. Match the compound in Column –I with their characteristic tests(s)/reaction(s) given
in Column –II
 
a) H 2 N  N H3 C l
P) Sodium fusion extract of the
compound gives Prussian blue
colour with FeSO4

b) Q) gives positive FeCl3, test
c) R) gives white precipitate with

AgNO 3
d) S) reacts with aldehydes to form

the corresponding
hydrazone derivative
39.
Column - I Column – II
a) [Co(NH3)4 (H2O)2] P) Geometrical isomers
Cl2
b) [Pt (NH 3)2 Cl2] Q) Paramagnetic
c) [Co(H 2O)5 Cl] Cl R) Diamagnetic
d) [Ni(H 2O)6] Cl2 S) On reaction with AgNO3 forms 2
equivalents of AgCl

40. Match the following:
Column I Column II
(a) XeF2 (P) Undergoes hydrolysis with water
(b) XeF4 (Q) Act as oxidizing agent

(c) XeF6 (R) Undergoes addition reaction
(d) XeO3 (S) Gives disproportionation reaction with
water or hydroxide ion.
SECTION – III
41. At 25o C , the degree of dissociation of pure water is 1.9  10 9 . If the specific
conductance of water at this temperature is x 106 Sm 1 . Calculate the value of x.
Given ionic molar conductances at infinite dilution for H  and OH  ions are 350  10 4
and 200  104 Sm2 mole 1 respectively

42. Identify the value of ( X – Y )
43. Total no of products ( including stereoisomers ) are formed when (R) – 3 – methyl -1-
pentene is treated with following
CH 3
CH 3  CH 2  CH  CH  CH 2
*
 R
I ) Hg  OAc 2 , H 2O followed by NaBH 4 II) H 2 / Pt
III) BH3 followed by H 2O2 in NaOH IV) Br2/CCl4

44. Number of reactions that lead to the formation of “pyro” form of acid

A) H 3 PO4 
510 K

B) PCl3  H 3 PO3 


C) Phosphorous acid + Br2 
Sealed
tube
 A 
Excess
H O 2
 B  C


D) P4O10  PCl3 
 D   E  F
H 2O
excess
 3RCOCl   w
E) 3RCOOH  PCl3 
 w 
H SO
 Yg   X  H 2O
2 4
 x 

Z
45. Number of reactions that result formation of precipitate [except white ],finally.
A) Pb ( NO3 ) 2   A   B  C

NaOH NaOH H2S
O2  Na2 CO3
B) FeCr2O4   solution    
reaction AgNO3 Ammonia
solution
C) Fe  K 3  Fe  CN 6  
3
 D 
H 2O2
E
D) Zn  K 4  Fe  CN 6  
2
 F 
dilute
acid

E) Pb  NO3 2   G   

NaCl 2 H S

F) Ag  aq  
NH 4OH
H  
NH 3
 OH   I 
 I  
H S
2


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GT A-1

Sri Chaitanya Narayana IIT Academy

Mathematics : Total Syllabus

Physics : Total Syllabus

Chemistry : Total Syllabus

Sr. IPLCO_P1_Advanced Space for rough work Page 2

2. Let A, B  M n    are square matrices of same order such that AB  BA  A . Then

A) f  0   0 B) f  x  must be identically zero

C) f 1  1 D)  x1 , x 2  [0,1] such that f (x1 )f (x 2 )  0

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B) f :    1,1 , twice differentiable such that  f  0     f   0    4, then  x 0  R such

B) Circum radius of  QAB  r1 r2

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b) If ,  are roots of ax 2  bx  c  0, a  0 and Q 5

d) If the expression kx 2  5xy  2y 2  3x  3y  1 can S 2

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b) The set of points z satisfying z  4  z  4  10 , is Q) The set of points z

contained in or equal to satisfying Im z  0

c) If   2, then the set of points z   

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d) Consistent system of equation S)   2,   7

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15. f :    be a continuous function such that f  f  x    f  x   x  0 x   then number

of such functions is……

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A) Coin moves with constant acceleration on the belt

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D) Time period of satellite’s orbital motion is independent of mass of the Earth

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( C1 & C 2 represents the center

( C1 & C 2 are the points on the

( C1 & C 2 represents the

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Synthetic steps for the disconnect shown

A) BuLi, THF B) EtMgBr, Et2O

A) It involves a carbocation intermediate

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c) R) gives white precipitate with

d) S) reacts with aldehydes to form

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(b) XeF4 (Q) Act as oxidizing agent

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III) BH3 followed by H 2O2 in NaOH IV) Br2/CCl4

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A) Pb ( NO3 ) 2   A   B  C

E) Pb  NO3 2   G   

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