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Construction and Building Materials 156 (2017) 661–674

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Construction and Building Materials


journal homepage: www.elsevier.com/locate/conbuildmat

Review

Waste foundry sand in concrete: A review


Bavita Bhardwaj ⇑, Pardeep Kumar
National Institute of Technology, Hamirpur, India

h i g h l i g h t s g r a p h i c a l a b s t r a c t

 Need of use of waste foundry sand


(WFS) in concrete.
 Material properties of WFS.
 WFS shows enhanced mechanical
performance of concrete.
 Durability of concrete enhanced with
incorporation of WFS up to an
optimum level.

a r t i c l e i n f o a b s t r a c t

Article history: Concrete is the most extensively used construction material in the world, second to water. Increasing rate
Received 7 May 2017 of urbanization and industrialization has lead to over exploitation of natural resources such as river sand
Received in revised form 28 August 2017 and gravels, which is giving rise to sustainability issues. It has now become imperative to look for alter-
Accepted 1 September 2017
natives of constituent materials of concrete. Waste foundry sand, a by-product of ferrous and non ferrous
metal casting industries is one such promising material which can be used as an alternative to natural
sand in concrete. In last few decades, several studies have been conducted to investigate the effect of
Keywords:
addition of waste foundry sand as partial and complete replacement of regular sand in concrete. It has
Waste foundry sand
Concrete
been found suitable to be used as partial replacement of sand in structural grade concrete. A number
Geopolymer concrete of properties have been reviewed in the current paper, the results observed from the various studies
Strength depict that replacement of foundry sand to a certain extent enhance the durability as well as strength
Permeability properties of the concrete but simultaneously decreases the slump value with the increase of replace-
ment level of waste foundry sand.
Ó 2017 Elsevier Ltd. All rights reserved.

Contents

1. Introduction . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 662
2. Foundry sand . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 662
3. Physical properties . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 663
4. Chemical composition . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 663
5. Mechanical properties . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 663
6. Applications of waste foundry sand . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 664
7. Environmental concerns and management options . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 664
8. Waste foundry sand in concrete . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 665

⇑ Corresponding author at: National Institute of Technology, Hamirpur, Hamirpur 177005, India.
E-mail address: bavita.bhardwaj@gmail.com (B. Bhardwaj).

http://dx.doi.org/10.1016/j.conbuildmat.2017.09.010
0950-0618/Ó 2017 Elsevier Ltd. All rights reserved.
662 B. Bhardwaj, P. Kumar / Construction and Building Materials 156 (2017) 661–674

9. Properties of fresh concrete. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 665


10. Compressive strength. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 665
11. Drying shrinkage and modulus of elasticity . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 667
12. Splitting tensile strength . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 668
13. Flexural strength . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 669
14. Abrasion resistance . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 669
15. Water absorption . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 669
16. Water permeability . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 669
17. Carbonation depth . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 669
18. Sulphate resistance . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 670
19. Chloride ion penetration . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 670
20. Ultrasonic pulse velocity . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 671
21. Salt scaling resistance . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 671
22. Freezing and thawing resistance . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 671
23. Microstructure analysis . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 671
24. Conclusions. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 672
Future scope . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 673
Acknowledgements . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 673
References . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 673

1. Introduction ing is also becoming a problem. United States has about 3000 foun-
dries which annually utilizes 100 million tons of sand for its
Concrete, being the most extensively used construction mate- production and about 6–10 million metric tons of waste foundry
rial in the world, is the backbone of all the construction and devel- sand is discarded per year, which goes into landfills [2,3]. With high
opment activities around the world. Each of the primary national average tipping fee of foundry by-products landfilling has
constituent of concrete has an environmental impact, to a different also not remained a feasible option. Indian foundry industry is the
extent. Being used in enormous quantity around the world, it gives third largest casting manufacturer in the world after China and
rise to different sustainability issues. USA. With approximately 5000 foundries and installed capacity of
There is rising concern about over-exploitation of natural sand 15 Million metric tons/annum the annual production of nearly
and gravels, constituents of concrete. The massive use of concrete 9.3 Million Metric tons is reported for 2012–13. The installed capac-
due to boom in urbanization and industrialization has resulted in ity and output could be actually higher than estimate since the sec-
the over-extraction of river sand from the river bed. This has called tor is majorly (around 85%) unorganized that does not reports in
for several harmful consequences, including increased river bed public [4]. Waste produced (WFS) from these foundries is approxi-
depth, lowering of the water table, exposure of bridge substruc- mately 1,710,000 tons (1.71 MT) per annum [5].
tures, major impact on rivers, deltas and coastal and marine In an effort to use the waste foundry sand in large volume,
ecosystems, loss of land through river or coastal erosion and research is being carried out for its possible substantial utilization
decrease in the amount of sediment supply. Furthermore, the sub- as partial replacement of fine aggregate in concrete. Also, foundries
sistence of construction industry has been severely affected due to use high quality size-specific silica sands for use in their moulding
the restrictions in the extraction of sand from the river resulting in and casting operations. Usually raw sand is of a higher quality than
rise of the price of sand [1]. Thus, it has become imperative to look the typical bank run or natural sands used in fill construction sites
for alternative to natural river sand. [6]. Therefore, this can be a very competent material for sand
Increasing population and advancements in technology have led replacement.
to increase in waste production. Thus, many researchers and scien-
tists all over the world are finding new ways to reduce these wastes 2. Foundry sand
or as a better alternative to use them as resources with added val-
ues. Since past several decades, various industrial wastes are being Foundry sand is high quality silica sand that is a by-product
studied extensively as a substitute/replacement material for fine from the production of both ferrous and non-ferrous metal casting
aggregate. Substitution of alternative materials in concrete has been
found to improve both the mechanical and durability properties,
100
and this practice can lead to the sustainable concrete development.
Waste foundry sand (WFS) is one such promising material 90
which needs to be studied extensively as substitute of fine aggre- 80
gates in concrete. It is a by-product from the ferrous and non fer- 70
Percent Finer

rous metal casting industries with ferrous foundries producing 60 Khatib et al., 2010
the most sand. It is characteristically sub-angular to round in shape 50 Prabhu et al., 2014
and has high thermal conductivity which makes it suitable for 40 Naik et al., 2012
moulding, casting operations. Moulding sands are recycled and
30 ASTM C33 LL
reused multiple times during casting process. In due course, the
20 ASTM C33 UL
recycled sand degrades to the state that it can no longer be reused
in the casting process. Then, the old sand is dismissed as by- 10
product, and new sand is introduced into the cycle. 0
0.01 0.1 1 10
Metal alloy casting industries only produce several million tons
of by-product in the world and waste foundry sand (WFS) is the Particle Diameter
major by-product. It has been successfully used as a land filling
Fig. 1. Sieve analysis results of WFS with respect to ASTM C33 limits for fine
material since many years, but due to rising disposal costs, land fill- aggregate.
B. Bhardwaj, P. Kumar / Construction and Building Materials 156 (2017) 661–674 663

industries. It is used for the centuries as a moulding casting mate- Reported values of absorption of WFS were found to vary
rial because of its high thermal conductivity. For various foundry widely, generally on higher side of normal sand, which can be
operations, raw sand is used and several binders and additives attributed to the presence of binders and additives. The specific
are added into it to enhance its properties. Based on binder system gravity of foundry sand has been found to vary from 2.39 to 2.55
used, foundry sand is classified into two categories i.e. clay-bonded [18]. This variability has been attributed to the variability in fines
(green) sand and chemically bonded sand. As evident from the and additive contents in different samples [13]. Several foundries
names, clay-bonded or green sand consists of clay as binder still use binders such as clay, sawdust and wood flour for mould-
whereas in chemically bonded sand chemicals are used as binders. ing. The presence of these particles reduces the specific density
Green foundry sand is generally composed of 85–95% silica sand, of the material, and also decreases the density of the concrete by
4–10% of bentonite clay as binder then 2–10% of carbonaceous creating air voids in the concrete. Table 1 shows some physical
additive, to improve finishing of casting surface. It also contains properties of WFSs used by different authors [11,14,19–22] for
traces of oxides such as MgO, K2O, TiO2. Whereas, chemically their research studies.
bonded sand or chemical foundry sand, consists of 93–99% silica
sand and about 1–3% chemical binder [5]. The silica sand and
chemicals are thoroughly mixed and then a catalyst initiates the 4. Chemical composition
reaction that cures and hardens the mould mass. Most commonly
used chemical binder are- epoxy resins, sodium silicates, furyl Depending upon type of metal, type of binder and combustible
alcohol, phenolic urethanes etc. Presence of carbonaceous addi- used, the chemical composition of waste foundry sand may vary
tives imparts black colour to green foundry sand whereas chemical and it further influences its performance. Sands obtained from a
foundry sand is light in colour. Green foundry sand is preferred for single foundry, however, may not likely show significant variation
moulding operations whereas chemical foundry sand is used for over time; besides, blended sands produced by consortia of foun-
both mould making and core making operations, which require dries often produce sands with consistently same composition.
higher strengths to withstand the heat of molten metal. Waste foundry sand is rich in silica content and is coated with thin
film of burnt carbon, dust and residual binder such as bentonite,
sea coal or chemicals or resins. Due to presence of silica content
3. Physical properties it is hydrophilic owing to which it attracts water to its surface
[13]. Generally, silica content of WFS is lower than regular sand
Foundry sand is sub-angular to round in shape [7]. Alike regular because of the presence of additives [23]. Chemical composition
sand, WFS also mainly consists of silica but its silica content has of WFS as reported by various researchers [16,23–28] is given in
been found lower than regular sand. Depending upon the industry Table 2.
sector from which it originates, type of casting process, type of Waste foundry sands from different foundry processing stages
additives used for moulding, number of times the sand is recycled exhibit different physical and chemical properties [29]. XRD anal-
and type and amount of binder used, its physical and chemical ysis on WFS finer than 75 mm confirmed the presence of quartz
characteristics may vary [8]. About 85–90% of its particles are and carbonates (calcite and dolomite) as well as montmorillonite.
smaller than 100 mm. It is principally made up of sand which is evi- Differential thermal analysis performed on two green WFS, col-
dent from the particle size (0.05–2 mm) of WFS, obtained from 39 lected from same Italian foundry, depicted different amounts of
foundries, ranging from 76.6% to 100%, with a median of 90.3% [9]. carbonaceous additive, about 2.8% in WFS from mould disposal
Since it is basically fine aggregate so it can be expected to be used and 5.1% in WFS from aspiration process during mould crush.
in many applications as substitute of natural sand [10]. The waste foundry sand having more carbon content showed more
However, WFS is too fine to be used as complete replacement of water absorption (5.4%) than the other having lesser carbon con-
regular sand. Fineness modulus of WFS has been found in the range tent (3.3%).
of 0.9–1.6 compared to 2.3–3.1 for normal sand. As per the particle
size distribution of the foundry sand, the size corresponding to 50%
of passing (d50) was around 33 mm and average diameter of foun- 5. Mechanical properties
dry sand particle was observed to be 28.8 mm [11,12]. The grain size
distribution of WFS is very uniform, with approximately 85–95 per- Tests conducted on WFS to check its strength and durability
cent of the material between 0.6 mm and 0.15 mm sieve sizes. such as low Micro-Deval abrasion [30] and magnesium sulphate
While 5–12 percent of foundry sand can be expected to be smaller soundness loss (ASTM C88-05)[31] have shown good results, indi-
than 0.075 mm [13]. The particle shape is typically sub angular to cating good durability. Abrasion loss was found below 2% whereas;
round and it does not meet the gradation requirements for fine Magnesium sulphate soundness loss was within 5–15% [32]. Javed
aggregates as per ASTM C33 [14]. Hence, only partial replacement and Lovell [18] reported relatively high soundness loss, which may
with coarser sand is recommended to meet the standard specifica- be due to the samples of bound sand loss and not a breakdown of
tions of fine aggregate [13]. Fig. 1 shows sieve analysis results of individual sand particles [33]. The angle of shearing resistance or
WFS as reported by various authors [14–16] with respect to ASTM internal friction angle of WFS has been found comparable to shear-
C33 [17] upper and lower limits (UL and LL) for fine aggregate. ing resistance of normal sands i.e. between 33° and 40° [18].

Table 1
Properties of Waste Foundry Sand as reported by different authors.

Authors Naik et al. [19] Guney et al. [20] Siddique et al. [11] Naik et al. [14] Singh and Siddique [21] Prabhu et al. [22]
Specific gravity 2.79 2.45 2.61 1.97 2.18 2.24
Density (kg/m3) 1784 – 1638 1538 1576
Fineness modulus 2.32 – 1.78 1.32 1.89 –
Water absorption (%) 5 – 1.3 3.20 0.42 1.13
Particles below 75 mm (%) 1.08 24 18 54.90 8 8
Moisture content (%) – 3.25 – – 0.11 –
Clay lumps and friable particles 0.40 – 0.90 – 0.80 –

‘–’ Test not performed for the specific property.


664 B. Bhardwaj, P. Kumar / Construction and Building Materials 156 (2017) 661–674

Table 2
Chemical Composition of Waste Foundry Sand as reported by different authors.

Constituents American Foudrymen’s society Etxeberria et al. Sahmaran et al. Basar et al. Singh and Siddique Prabhu et al. Thaarrini et al.
[24] [25] [26] [23] [27] [16] [28]
SiO2 87.91 84.90 76.0 81.85 83.8 87.48 83.93
Al2O3 4.70 5.21 4.45 10.41 0.81 4.93 0.021
Fe2O3 0.94 3.32 5.06 1.82 5.39 1.31 0.950
CaO 0.14 0.58 3.56 1.21 1.42 0.22 1.03
MgO 0.30 0.67 1.98 1.97 0.86 0.18 1.77
SO3 0.09 0.29 – 0.84 0.21 0.07 0.057
MnO – 0.08 0.46 – 0.047 – –
TiO2 0.15 0.19 0.17 – 0.22 – –
K2O 0.25 0.97 1.20 0.494 1.14 – –
P2O5 – 0.05 0.04 – – – –
Na2O 0.19 0.50 0.38 0.764 0.87 – –
LOI 5.15 2.87 5.85 6.93 – 5.81 2.19

6. Applications of waste foundry sand with fungal treated WFS depicted reduction in metal concentration
as compared to the untreated concrete. Furthermore, fungal treat-
The practice of disposing off WFS in landfills is getting unfavor- ment refined the pores of concrete by forming calcium rich bio-
able because of increasing cost of disposal. Furthermore, rising mineral [7].
environmental concerns have made Government to make strict After recycling foundry sand several times in various foundry
regulations to keep check on waste disposal from industries and operations when it is discarded it contains residues of the additives
make them accountable to remediation of wastes. All these issues with dust particles into the waste foundry sand which limits its
can be tackled by reusing and recycling the waste produced. Poten- further reuse. Some foundries use screening systems and magnetic
tial applications of WFS in Civil Engineering works can be – high- separators to segregate particles of different size and separates
way embankment filling [33–37]; flowable fills; in road reusable sand from waste. The discarded waste foundry sand can
construction; in soil stabilization and reinforcement [38]; hydrau- be made free from excess of hazardous contaminants if foundries
lic barrier or liner [36,39] in cement manufacturing; mortar mak- carefully monitors their foundry processes and waste sand [45].
ing [40]; pavement blocks, brick blocks [3,10,11,20,25,41–44]; Most of the foundry sand is produced by the ferrous foundries
asphalt concrete [44]. Beneficial reuse of WFS span a variety of (ductile iron, grey iron, steel) and rest by non ferrous foundries
applications related to infrastructure engineering and rehabilita- such as aluminum, brass, copper and bronze. The sands from cop-
tion works, e.g., highway embankment construction, ground per, brass and bronze foundries are normally not reused. Waste
improvement etc. The use of WFS in such various applications as foundry sand is used as feed to kiln in Portland cement manufac-
alternative to traditional materials can help multiple ways in con- turing and as substitute to fine aggregate in construction purposes.
serving the conventional materials, reducing cost and reducing Most of the WFS from green sand castings is land-filled and some-
burden on environment, hence benefitting country and times is used as supplemental cover [18].
environment. Fiore and Zanetti [43] studied reuse and recycling of foundry
sands. After investigating foundry sands of varying sizes they cat-
egorized the residues into 3 categories according to particle size i.e.
7. Environmental concerns and management options
below 0.1 mm, between 0.1 and 0.6 mm and above 0.6 mm [43].
They suggested that particles above 0.6 mm which constituted
Various additives (organic and inorganic) added into foundry
mainly metallic iron can be reused in the furnaces. Particles
sand, to improve its properties during casting and moulding oper-
between 0.1 and 0.6 mm after regeneration treatment may be
ations, are the main source of organic contaminants. However,
reused in production of cores. Particles below 0.1 mm up to
from testing it has been reported that these reactive organic com-
0.025 mm were proposed to be recycled as raw material for con-
pounds are not present in significant amount in WFS [45]. Depend-
crete industry, and particles below 0.025 mm could be reused in
ing upon type of metal cast and binder used the pH range of WFS
green sand moulding processes. It is observed that proposed reuse
lies in the range between 4 and 8, which is similar to pH range of
and recycling solution is more economical [43].
rainwater in the environment which is within 4–9 [46]. Thus, some
foundry sands have been found corrosive to metals [47]. Besides,
presence of phenols in foundry sand raises concerns regarding its
discharge into surface or ground water supplies by leaching 250
through its stockpiles [13]. However, leachability characteristics
of the entire concrete specimens at different pH conditions repre- 200
senting variant natural cases indicated that the concrete mixtures
Slump ( mm)

containing WFS can be used in the production of concrete with no 150


adverse environmental effects [23].
Guney et al. 2010
The majority of waste moulding sands are categorized as non- 100 Khatib et al. 2010
hazardous waste (that is not corrosive, ignitable, reactive or toxic)
Prabhu et al., 2015
[6]. The washing water of WFS from two different foundry pro-
50
cesses was separated by centrifugation and filtration and then
tested. The Na+concentration was almost double in the washing
0
water of WFS from aspiration process (WFSb) as compared to 0 20 40 60 80 100
WFS from moulding process (WFSa). Whereas, the heavy metals WFS Replacement Level (%)
content was higher (up to 16 times for Al and Zn) in WFSa washing
water than in WFSb [29]. Leachate analysis of concrete prepared Fig. 2. Slump value of concrete mixes at different WFS replacement levels.
B. Bhardwaj, P. Kumar / Construction and Building Materials 156 (2017) 661–674 665

8. Waste foundry sand in concrete Naik et al. [54] studied the effect of partial replacement of fine
aggregate in concrete with clean/new foundry sand and used foun-
Several studies have been conducted on the use of WFS as par- dry sand (WFS) in two proportions i.e. 25% and 35% [54]. Compres-
tial and full replacement of fine aggregate in concrete. Although sive strength value of concrete mixes with WFS were found about
the sand used in foundries have very high percentage of silica 23% and 35% lower than control concrete at 28 days of curing,
but due to finer and unimodal particle size, the increase in WFS whereas, strength of concrete mix with new/clean foundry sand
content in concrete beyond a certain level leads to negative effects was found almost same as control concrete. Similar results were
on concrete. The presence of additives as impurities also causes reported when a wide spread of mixes with three different types
negative effects on the properties in fresh state as well as hardened of sand i.e. foundry sand, fine white sand, blended sand and WFS
state of concrete. were investigated. The compressive strength reduced linearly with
increase in WFS replacement levels. Furthermore, blended sand
mixes also decreased the strength as their content increased [10].
9. Properties of fresh concrete
Etxeberria et al. [25] studied concrete containing green foundry
sand (GFS) and chemical foundry sand (CFS) and reported that with
Generally, it is observed that inclusion of WFS increases the
both concretes more adequate strength than control concrete was
water demand of fresh concrete when added as regular sand
obtained at high water-cement ratio [25]. Even after exposure to
replacement (for the same slump values). Prabhu et al. [22]
high temperatures, higher residual strength was obtained in case
reported no significant loss in workability up to 10% substitution
of concrete mixes with CFS and GFS as compared to control
but beyond this substitution level it started affecting the workabil-
concrete.
ity [22]. This decrease in workability is probably due to the pres-
Naik et al. [55] evaluated the performance of foundry sand as a
ence of water absorbing finer particles i.e. clay-type fine
partial replacement (up to 35%) of the fine aggregate for masonry
materials, ashes and impurities etc. in WFS, which are responsible
blocks and paving stones [55]. Masonry blocks made with WFS
for decreasing the fluidity of the fresh concrete and increasing the
passed ASTM requirements for compressive strength, absorption,
water demand. Increase in water demand further increases the
and bulk density. Bakis [44] explored the possibility of the reuse
demand of superplasticizer [20,22,23,48,49].
of WFS in asphalt concrete production by partially replacing fine
Khatib et al. [15] replaced fine aggregates in normal concrete by
aggregate with it [44]. The particle size distribution of the mixture
WFS in variable proportions (0%, 20%, 40%, 60%, 80% and 100%),
with 10% WFS possibly gives sufficient adherence than the other
observing a systematic loss in slump value from 200mm to zero
mixtures with WFS [20].
[15]. The slump value at 20%, 40%, 60% was 80%, 50% and 20% of
Singh and Siddique [21] observed enhancement in strength of
slump value of control mix (Fig. 2). Aggarwal and Siddique [12]
concrete with increase in WFS content replacing natural sand by
reported increase in water demand of concrete when WFS and bot-
different proportions (5%, 10%, 15% and 20% by mass) [21]. Com-
tom ash (BA) were added to concrete as partial replacement to reg-
pressive strength of concrete at 28-day increased by 8.25–17%.
ular sand, in equal proportions [12]. Upto 60% replacement was
Beyond 15% WFS there wasn’t significant increase in strength
studied and increase in water content by 4%, 6%, 10%, 16%, 22%
which is attributable to increase in surface area of fine particles
and 36% of the initial value was required to maintain the slump
which may have led to reduction of water cement gel in matrix
level of all the mixes constant at 30 mm. Considerable loss in
hence led to inadequate binding [21,27,56]. The factors responsible
slump was observed with elapsed time as compared to the control
for strength reduction are the poor workability of the matrix and
concrete attributable to the generation of higher surface of hydra-
the existence of binder (i.e., very fine powder of carbon and clay)
tion products due to higher fineness of WFA [22].
in WFS [6,41,57] which stick to sand particles and prevents
A delay in initial and final setting times was observed, because
strengthening bond between the cement paste and the aggregate.
very fine carbon particles existed in WFS and/or there was a loss of
Siddique and Kadri [58] reported improvement in strength by the
the link between aggregate and cement paste, causing a delay on
addition of mineral admixture i.e. Metakaolin (MK) of concrete
cement hydration [48]. Similar trends were shown in case of air
containing WFS [58].
entrained concrete, demand for superplasticizer and air entraining
Siddique and Sandhu [52] concluded that alike conventional
admixture increased with increase in WFS content [14].
concrete, the compressive strength of SCC also increased with up
Sahmaran et al. [26] explored the possibility of producing SCC
to 15% replacement level of WFS with sand [52]. The results also
with fly ash and WFS by replacing Portland cement with fly ash
indicated higher early age strength gain i.e. at 7 and 28 days, when
at different replacement levels [26]. The replacement of fine aggre-
compared to the control mix at 15% replacement level of WFS as
gates with WFS was up to 100% by volume, wherein, they con-
fine aggregate.
cluded that the SCC mix meets the EFNARC [50] limits and no
Kaur et al. [59] added fungal (Aspergillus spp.) (fungal culture at
visible segregation or bleeding was observed in the SCC mix but
about 5% (w/v)) treated 20% WFS as sand replacement and
beyond 50% replacement level of WFS the superplasticizer require-
reported 15.6% increase in 28 day compressive strength of concrete
ments were increased to achieve required slump flow etc. [26].
[59]. Incorporation of fungal treated WFS showed improvement in
Similar results are shown elsewhere [51,52]. Joy and Mathew
strength due to plugging of pores within concrete by deposition of
[53] studied effect of WFS on the workability of geopolymer con-
fungal spores or biomineral in pores of cement sand matrix. The
crete made with the addition of GGBS and silica ash and found a
fungal culture (Aspergillus spp.) increased the ability of cement
similar trend of decreasing slump value of concrete [53].
to react properly with foundry sand and hence increased the for-
mation of C–S–H gel. Kaur et al. [7] showed similar results sup-
10. Compressive strength ported by XRD analysis exhibiting some extra peaks of calcium
aluminum silicate (gismondine) in the concrete containing fungal
Among several tests to check the performance of concrete, com- treated WFS (20%) [7]. This confirmed the formation of new phases
pressive strength is of utmost importance. This single test gives an of silicates within the matrix of this mortar material, which caused
idea about several characteristics of concrete. Many properties of an improvement in the strength of the material.
concrete are directly correlated to its compressive strength. Know- Monosi et al. [29] studied two different types of green WFS in
ing its compressive strength, one can easily judge the quality of unwashed as well as in washed state [29]. Regardless of different
concrete. types and dosages of WFS, its addition decreased the strength at
666 B. Bhardwaj, P. Kumar / Construction and Building Materials 156 (2017) 661–674

60

55

Compressive Strength, MPa


50

45
28D
40
90D
35 365D

30

25
0 10 20 30 40 50 60
Replacement Level, %

Fig. 3. Compressive strengths of concrete mixes at different curing ages [11].

50
28Day Compressive Strength, MPa

45
Siddique et al.,
40 2011

35 Aggarwal and
Siddique, 2014
30 Prabhu et al.,
2014
25
Khatib et al.,
20 2010
15

10
0 20 40 60 80 100
Replacement Level, %

Fig. 4. 28-Day Compressive strengths of concrete mixes at different WFS replacement levels.

all percentages (0–30%). As commonly observed that low water of 28 days, 90 days and 365 days (Fig. 3) [11]. The rate of strength
cement ratio helps in gaining higher strengths in concrete, but gain for normal concrete (with slump near 75 mm) between 7 and
unlike WFS addition in concrete achieved negligible advantage at 90 days is found as 72% which is characteristic of normal concrete
water cement ratio below 0.50. Moreover, low water cement ratio [63]. The rate of strength gain for all WFS concrete mixes was clo-
ascribes negative influences on mortar, confirming the results ser to control mix at 90 days, whereas, it was found higher at
reported elsewhere [25]. 365 days [11]. The effect of increase in WFS replacement on
Salokhe et al. [60] concluded that concrete with WFS from fer- 28 day strength of concretes as reported by various researchers-
rous foundries performed better than concrete with non-ferrous Siddique et al. [11]; Aggarwal and Siddique [12]; Prabhu et al.
WFS in case of strength gain [60]. Inclusion of both sands gave [22]; Khatib et al. [15] is shown in Fig. 4.
dense concretes at 20% replacement. Basar and Aksoy [23] investi- In another study, the effect of WFS and bottom ash (BA) in equal
gated the potential reuse of WFS in ready mix concrete production quantities as partial replacement of fine aggregates, in various per-
by studying five different replacement percentages (0, 10, 20, 30 centages (0–60%), on concrete properties was investigated. Con-
and 40%) of regular sand by WFS [23]. The concrete having 20% crete mix with replacement ratio of 30% (15% waste foundry
WFS exhibited almost similar results with the control one along sand and 15% bottom ash) performed best among all the other con-
with similar micro-structural properties and morphological char- crete mixes of given replacement levels (0–60%) [12]. With
acterization. The concretes produced with WFS were lighter than increase in replacement ratio there was improvement in C-S-H
the conventional concrete due to lower density of WFS but still gel formation till 50% replacement signifying comparative densifi-
its density was within the range 2000–2600 kg/m3, valid for nor- cation of mixes. However, gel formation was lower in WFS and BA
mal concrete class. mixes as compared to control mix but there was reduction in num-
Siddique et al. [3,61] reported consistent increase in strength of ber of pores, which was evident from SEM micrographs. The inclu-
concrete with WFS, when added up to 30% as sand replacement, sion of WFS and BA did not affect the strength negatively as the
attributing to densification of concrete matrix due to finer WFS strength of the mixes was within limits and the concretes pos-
particles and also presence of silica content which would have sessed comparable mechanical properties and greater resistance
helped in the formation of C-S-H gel [3,61]. Similar results of con- to aggressive agents (chemical, physical and environmental).
sistent increase in strength at even higher replacement levels i.e. Prabhu et al. [22] used WFS prior washed four times to remove
up to 60% of WFS have been summarized by Pathariya et al. [62] ash and clay particles and thereafter sun dried for two days. They
with maximum strength shown by mix with 60% WFS. Similarly, concluded a comparable compressive strength to that of control
Siddique et al. [11] reported strengths of mixes with 30%, 40% concrete by replacing 20% WFS as fine aggregate replacement.
and 50% of WFS higher than control concrete at the curing ages However, a slight decrease was observed at 30% replacement level
B. Bhardwaj, P. Kumar / Construction and Building Materials 156 (2017) 661–674 667

and beyond that the strength decreased drastically i.e. at 50% due to the loss of capillary water, analogous to hydration of
replacement the decrease in strength was up to 23.95% to that of cement, hence considered important. This is common phenomena
control concrete [22]. Concrete with adequate strength was achiev- in all Portland cement concretes as they age hence it is very impor-
able even when fine aggregates were fully replaced by WFS with tant factor which can’t be overlooked as it affects durability, ser-
strength nearly 50% of the strength of control concrete [15,64]. viceability, long-term reliability, and even structural integrity of
Besides decline in compressive strength with increasing WFS concrete. Ingredients of concrete profoundly influence the shrink-
level it was possible to produce SCC with compressive strength age of concrete.
around 40 MPa at 28 days and 50 MPa at 90 days curing age con- Khatib and Ellis [10] investigated a wider spread of mixes with
taining both WFS and fly ash. Authors predicted the possibility of different types of foundry sand; white fine sand, blended sand and
producing concrete with even higher strength than 40 MPa even spent sand and observed increase in shrinkage of concretes as com-
at 100% WFS replacement [26]. pared to conventional concrete as the level of sand replacement
Few studies are also available on use of WFS as partial replace- with foundry sands increased [10]. Khatib et al. [15] replaced fine
ment of fine aggregate in GPC. Joy and Mathew [53] studied effect aggregates partially and fully with WFS and observed systematic
of replacement of sand with WFS up to 25% on geopolymer con- increase in shrinkage with increase in WFS content (Fig. 5) [15].
crete prepared with silica ash and ground granulated blast furnace At 100% replacement level of regular sand by WFS, shrinkage at
slag (GGBS) [53]. A decrease in strength (7 day and 28 day) beyond 56 days of curing was found to be twice as much as control mix.
15% WFS replacement level was observed, however at all replace- The elastic modulus of concrete is a very important mechanical
ment levels strength was found superior to control mix (0% WFS) parameter reflecting the ability of the concrete to deform elasti-
[53]. Thaarrini et al. [28] studied feasibility of manufacturing cally. Basar and Aksoy [23] investigated the potential reuse of
geopolymer concrete using WFS (50%) with Ground Granulated WFS in ready mix concrete production by studying five different
Blast Furnace Slag (GGBFS) and Bottom ash (BA) as source materi- replacement percentages (0, 10, 20, 30 and 40%) of regular sand
als [28]. Addition of foundry sand, at constant replacement level of by WFS [23]. Prabhu et al. [22] reported reduction in the modulus
50%, did not affect the strength of geopolymer concrete. Geopoly- of elasticity of concrete mixtures with the presence of WFS as par-
mer concretes paver blocks with strength more than target tial replacement of natural sand, consistent with the compressive
strength were successfully produced [28]. strength results [22]. Concrete made with new foundry sand at
It has been observed that the addition of WFS generally 25% & 35% replacement levels showed similar or higher values of
decreases the density of concrete hence its strength. The negative modulus of elasticity at 28 days curing age [54]. Singh and Sid-
effects of WFS addition were more evident in concrete with low dique [27] reported enhancement in modulus of elasticity by
water cement ratio. Upto 20% replacement by WFS generally pro- 1.7–6.4% at 28 days of curing age, depending upon the WFS content
duced concrete with properties similar to control concrete. Some (5, 10, 15 and 20% replacement of natural sand by weight) and fur-
investigations have even reported 30% WFS as optimum replace- ther there was continuous improvement with the increase in cur-
ment level. Concrete with adequate strength was obtained even ing age [27]. Irrespective of the curing time, concrete mix with 15%
at full replacement of normal sand by WFS. The addition of fungal WFS showed maximum value of modulus of elasticity at all ages.
treated sand enhanced the strength gain of concrete by formation Similar results were obtained by Siddique et al. [56] on two mixes
of bio-mineral which led to plugging of pores of cement sand (M20 and M30) with different percentage replacement of WFS.
matrix. The rate of strength gain of WFS concrete was found higher However, concrete with M20 grade gave higher elastic modulus
than conventional concrete at later ages (90–365 days). Special value than M30 concrete at all percentage replacements of WFS
concretes such as SCC and GPC have also been successfully pro- [56].
duced with WFS meeting standards of strength and workability. Concrete exhibited similar elastic modulus as that of control
Hence, good quality structural grade concrete can be produced concrete mix at 10% replacement of natural sand with WFS [20].
with WFS as fine aggregate. Prewashed WFS showed comparable values of dynamic elastic
modulus of concrete mixes up to 20% replacement level whereas,
11. Drying shrinkage and modulus of elasticity a reduction of 12.75% in elastic modulus was observed at 50%
replacement level [22]. Siddique et al. [3] observed secant modulus
Total shrinkage is sum total of plastic, chemical, drying shrink- for 33% of the maximum value of stress, found it to increase with
age, autogenous, thermal and carbonation shrinkage. However, increase in WFS replacement level (10%, 20% and 30%) [3]. Modulus
drying shrinkage is the contracting of a hardened concrete mixture of elasticity of the mixes was found to increase with age and the

-150
28 Day Shrinkage in Microstrain

-200

-250

-300

-350

-400 Khatib et al.,


2010
-450

-500
0 20 40 60 80 100
Replacement level, %

Fig. 5. 28-Day shrinkage value of concrete mixes at different WFS replacement levels [15].
668 B. Bhardwaj, P. Kumar / Construction and Building Materials 156 (2017) 661–674

40,000

28 Days Modulus of Elasticity, kN/mm2


Prabhu et al.,
2014
35,000
Basar and Aksoy,
2012
30,000 Siddique et al.,
2015 (M30)
Siddique et al.,
25,000
2015 (M20)
Singh and
20,000 Siddique, 2012
Naik et al., 1994
15,000
0 5 10 15 20 25 30 35 40 45 50
Replacement level, %

Fig. 6. Modulus of elasticity of concrete with increase in WFS replacement.

increase varied between 5.2% and 12% depending upon age of test- strength of the asphalt concrete mixtures was observed, yielding
ing and replacement level of WFS. values from 1.39 MPa with 0% WFS to 0.94 MPa with 20% WFS.
Shrinkage of WFS mixes was found higher than conventional Siddique et al. [61] investigated the use of WFS as partial
concrete. Modulus of elasticity of concretes with WFS was found replacement of fine aggregate in concrete by 10, 20 and 30% and
similar to strength results. Literature reported the improvement observed consistent increase in split tensile strength than control
in modulus of elasticity of concrete up to a replacement level of concrete by up to 12, 14 and 20% at respective replacement ratio.
30% by WFS Concretes with lower grade showed better effects of Similar observations were made elsewhere [3]. Marginal increase
WFS addition than higher grade concrete. The modulus of elasticity of 3.6–9% in splitting tensile strength was reported with increase
of the concretes with WFS as reported by Naik et al. [49], Singh and in WFS content at 28 days curing age, depending upon level of
Siddique [27], Prabhu et al. [22], Basar and Aksoy [23] and Siddique replacement (10%, 20% and 30%). Guney et al. [20] reported
et al. [56] is shown in Fig. 6. increase in strength up to 10% replacement by WFS then it
decreased further at 15% substitution [20]. Similar results were
reported elsewhere [27,56] which show enhancement in splitting
tensile strength by 3.6–10.4% for concrete replacing natural sand
12. Splitting tensile strength with WFS by different proportions (5%, 10%, 15% and 20% by mass).
Concretes with WFS of M20 grade showed higher values of split-
Another mechanical property to check the quality of the con- ting tensile strength than M30 grade at all WFS percentage levels
crete made with WFS as replacement of sand is the split tensile and at all curing ages [56]. Correspondingly, SCC concrete with
strength. A similar pattern of variation of split tensile strength is 15% WFS content showed higher values of splitting tensile strength
observed as that of compressive strength. Concrete being weak in when studied for replacement level up to 20% [52]. Ferrous WFS
tension and due to its brittle nature, develop cracks when sub- concrete performed slightly better than non-ferrous WFS concrete
jected to tensile forces. with 20% addition gave maximum strength value [60].
The effect of partial replacement of fine aggregate in concrete Prabhu et al. [22] found results of concrete mix up to 20%
with clean/new foundry sand and WFS in two proportions i.e. replacement level of WFS (prewashed four then sun dried) compa-
25% and 35% [54] resulted in decrease of splitting tensile strength rable to control mix, however, beyond 20% slight decrease in
with increase in foundry sand content. Similar and consistent strength was observed up to 30% replacement and it further
decrease in split tensile strength of concrete with increase in decreased at higher replacement levels of WFS. A decrease of
WFS replacement level is reported by other authors [23,62]. Bakis 19.32% in tensile strength was observed as compared to control
et al. [44] investigated the possible use of WFS in asphalt concrete mix at 50% replacement level of WFS [22].
[44]. Indirect tensile strength tests were conducted as per AASHTO Siddique et al. [11] observed that mixes with 30%, 40% and 50%
(1989). With increase in percentage of WFS, linear decrease in WFS showed higher strength at 28 days, 90 days, and 365-days.
28 Day Split Tensile Strength, MPa

3 5
28 Day Flexural Strength, MPa

2.8
2.6 4.5
2.4
Prabhu et al., 2014 4
2.2 Prabhu et al., 2014
2 Siddique et al., 2011
1.8 3.5 Aggarwal and
1.6 Aggarwal and Siddique, Siddique, 2014
2014 3
1.4
1.2
1 2.5
0 10 20 30 40 50 60 0 10 20 30 40 50 60
Replacement level, % Replacement level, %

Fig. 7. 28-day split tensile strength of concrete mixes at different WFS replacement Fig. 8. 28-day flexural strength of concrete mixes at different WFS replacement
levels [11,12,22]. levels [12,22].
B. Bhardwaj, P. Kumar / Construction and Building Materials 156 (2017) 661–674 669

Whereas mixes with 10%, 20% and 60% WFS showed 11.5%, 4.8% increase in curing time [27]. This enhancement in abrasion resis-
and 17.30% decrease in strength respectively, in comparison with tance is attributable to dense matrix due to addition of fine WFS.
the strength of the control mix [11]. An increase in split-tensile
strength values by 24.03%, 19.23%, and 14.42% was observed for 15. Water absorption
30%, 40% and 50% replacement levels respectively at 28-day curing
age. Aggarwal and Siddique [12] investigated the effect of waste Salokhe et al. [60] observed no appreciable effect of WFS on
foundry sand and bottom ash in equal quantities as partial replace- water absorption of concretes [60]. In another study, addition of
ment of fine aggregates in various percentages (0–60%), on con- WFS to concrete mixtures led to increase in water absorption ratio.
crete properties [12]. Splitting tensile vary from 0.062 to 0.080; However, the concrete including up to 20% WFS has a water
0.062 to 0.078; 0.061 to 0.076 and 0.052 to 0.075 times the com- absorption lower than 6%, which indicates that concrete specimen
pressive strength, at ages of 7, 28, 90 and 365 days, respectively. having 20% proportion of replaced regular sand (fine aggregate)
Olutoge et al. [13] concluded that the split tensile strength with WFS could be considered acceptable [23]. Generally, the
increases as the percentages of sand replaced with foundry sand water absorption increases as the WFS in the concrete increases.
increases [13]. The split tensile strength increased by 11.91%, An increase in water absorption is associated with a decrease in
17.44%, 20%, 20.85%, and 25.53% for 20%, 40%, 60%, 80%, and compressive strength and UPV [15]. Increase in water absorption
100% sand replacement with foundry sand respectively when com- with increasing amounts of WFS indicates rise in volume of pores
pared to a conventional concrete mix with natural sand as fine [64]. This may be attributable to the unimodal grain size distribu-
aggregate. Fig. 7 shows 28-day split tensile strength of concrete tion of WFS which may have led to less optimal compacting and
mixes with different WFS replacement levels as reported by vari- hence larger volume of pores [64]. Alternatively, decrease in water
ous researchers. absorption (68.8%) and porosity (45.9%) of concrete with the addi-
On inclusion of WFS split tensile strength yield similar trends of tion of fungal treated 20% WFS in comparison to the concrete con-
results as that of compressive strength. The split tensile strength taining untreated WFS was reported by Kaur et al. [59]. Similar
values goes on decreasing as the percentage replacement of WFS results were shown by Kaur et al. [7]. Fine particles of WFS filled
is increasing beyond a specific range of 15–20% except one or the pores of concrete, besides, fungal treatment further compacted
two studies which shows hike in the split tensile strength values the cement sand matrix by formation of bio-mineral which
up to 50% replacement level. Whereas diminutive literature is increased the C-S-H gel formation, hence reduced the porosity [7].
available that favors the decrement of split tensile strength values Geopolymer concrete produced by using GGBFS and BA as
of concrete mix at smaller replacement levels. source materials and 50% replacement of natural sand by WFS
showed lower absorption values [28]. The water absorption values
of geopolymer concrete mixes at different strength levels (M30,
13. Flexural strength M35, M40, M50, and M55) were found lower than the limit speci-
fied for good concrete i.e. 3%. All the geopolymer mixes showed
Flexural strength is one of the measures of tensile strength of lower rates of absorption and it was also found to decrease with
concrete. It is a measure of an unreinforced concrete beam or slab increase in concrete grade.
to resist failure in bending. Prabhu et al. [22] studied the effect of
addition of WFS from aluminum casting industry on flexural
strength of concretes and obtained the same trend as that of com- 16. Water permeability
pressive strength with comparable results up to 20% replacement
of fine aggregates with WFS [22]. The rate of strength gain at later Permeability of concrete differs from absorption. Permeability
ages was also found lower at substitution level higher than 20% relates to the size of the pores, their distribution and most impor-
[22]. An effect of waste foundry sand and bottom ash in equal tantly their continuity. As a result, permeability is not necessarily
quantities as partial replacement of fine aggregate in various per- directly related to absorption. It has been related to water cement
centages (0–60%), on various concrete properties was investigated (w/c) ratio of concrete. An increase in permeability with increase in
elsewhere [12]. Alike compressive strength result, flexural strength percentage level of WFS was observed with significant increase
of mix with 30% WFS (4.34 MPa) was found comparable to control beyond 30% replacement level with WFS [22]. The value of perme-
mix (4.44 MPa). Fig. 8 shows 28-day flexural strength of concretes ability coefficient at 180 days of curing age, for mix with 30%
with WFS as reported by some authors. replacement by WFS, was found much lower than the maximum
Very limited studies are available on flexural behavior of con- permeability coefficient value recommended by ACI 301–89. Sid-
crete with WFS as partial replacement to regular sand. However, dique R. and Kadri El-Hadj [65] studied the effect of replacement
the results of flexural strength have been found in good correlation of natural sand with WFS by 20%, in concrete containing up to
with compressive strength results. 15% cement replacement with metakaolin [65]. Addition of WFS
led to decrease in initial surface absorption (ISA) of concrete. Kha-
tib et al. [64] investigated the systematic increase in water absorp-
14. Abrasion resistance tion due to capillary action in concrete containing WFS (0%, 30%.
60% and 100%) at all ages of curing i.e. 1, 7, 28 and 90 days [64].
Abrasion resistance is closely related to the compressive The concrete mixes with 60% and 100% replacement levels of
strength of concrete. The type of aggregate and surface finish or WFS depicted higher water ingress (about 3 times of 0% WFS) com-
treatment used has a strong influence on abrasion resistance. Pav- pared with concrete mixes having 0% and 30% replacement levels
ing stones with 35% WFS passed the ASTM abrasion requirements of WFS. The water absorption coefficient or rate of initial water
[55]. Naik et al. [14] reported excellent abrasion resistance by con- absorption was generally observed to decrease with rise in WFS
crete mixes, containing fly ash, with regular sand replaced by WFS, content at all ages.
up to 47% by weight [14]. Resistance to abrasion improved with
curing age. The results were found similar in case of air- 17. Carbonation depth
entrained and non-air-entrained concretes. Singh and Siddique
[27] observed decrease in depth of wear with increase in WFS con- Carbonation of concrete is one of the critical parameters associ-
tent as natural sand replacement which further decreased with ated with the corrosion of steel reinforcements. Generally, there
670 B. Bhardwaj, P. Kumar / Construction and Building Materials 156 (2017) 661–674

exists an increase in carbon ingress with the increase in replace- 1400


ment level of WFS. Increase in carbonation depth was found signif-

Charge passed (Coulombs)


1200
icant beyond WFS 30% [16]. The carbonation depth of 2.70 mm and
5.0 mm was observed in concrete mix at 60% replacement level of 1000
90 Days (Aggarwal
WFS at 90 days and 365 days of curing age respectively, which is and Siddiqui, 2014)
800
far less than the cover of reinforcing steel bars to cause corrosion 365 Days (Aggarwal
[11]. The typical values for coefficient C never exceeded 6 (Table 3) 600 and Siddiqui, 2014)
so the concrete as per table can be adjudged as good concrete [66] 180 Days (Prabhu et
400
The increase in carbonation depth with increase in WFS level was al. 2015)
attributed to poor workability of concrete which resulted in con- 200 365 Days (Prabhu et
tinuous porous system due to poor compactness. Carbonation al. 2015)
0
depth values for concretes with 40% and 50% replacement levels, 0 20 40 60
at 365 days curing age, was found 5.45 mm and 8.41 respectively Replacement Level, %
i.e. closer to cover to reinforcement, which may cause corrosion
[16]. Fig. 9. Variation of charge passed with varying WFS content in concrete mixes with
increasing WFS replacement levels [12,16].

18. Sulphate resistance


In general, there exists decrease in chloride ingress with the
Limited studies which were carried out on sulphate resistance increase in replacement ratio of WFS. Singh and Siddique [27] con-
of concrete containing WFS show mixed type of variations in cluded that inclusion of WFS decreased the chloride ion penetra-
results about sulphate attack. The SCC prepared with WFS as tion in concrete, which indicates that concrete has become
replacement (10–20%) to the natural sand show hike in the denser and impermeable [27]. At 28 days, charges passed were
strength and greater resistance to sulphate attack after keeping it 1368, 1250, 1150, 1060 and 1190 C at 0%, 5%, 10%, 15% and 20%
in magnesium sulphate solution of 50 g/l for 28 days [52]. of WFS. Coulomb value decreased with the increase in WFS content
Whereas, Prabhu observed a decrease in sulphate resistance of up to 15% WFS, which indicate that concrete became more dense.
concrete with the increase in replacement ratio of WFS. A substan- Coulombs charges passed at 91 days are less than those of 28 days,
tial affect on strength properties was observed on concrete mixes which indicate that concrete microstructure become denser. All
containing more than 30% replacement of WFS. Decrease in sul- concrete mixtures had ‘low’ permeability (coulombs between
phate resistance with increase in WFS content was attributed to 1000 and 2000) as per ASTM C1202 (Table 4) [67]. Coulomb value
presence of traces of sulphur (SO3) in the WFS [16]. Thaarrini decreased in mix containing 15% replacement of WFS, which indi-
et al. [28] formed geopolymer concrete paver blocks of different cate a denser concrete production. Finer particles of WFS act as a
grades with fine aggregates substituted by WFS by 50% by weight good filler material to make a stronger internal structure of con-
[28]. Addition of foundry sand had no negative effect on the resis- crete matrix [52]. Rapid Chloride Permeability test values
tance of geopolymer concrete against sulphate attack. decreased with the increase in WFS replacement up to 20% irre-
spective of grade (M20 and M30) of the concrete prepared using
WFS. Both M20 and M30 mixes with WFS came under ‘low’ chlo-
19. Chloride ion penetration ride ion permeability (1000–2000 C) at 28 days and under ‘very
low’ chloride ion permeability (100–1000 C) at 365 days curing
A durable concrete is the one that performs satisfactorily under age [56].
anticipated exposure condition during its service life span. One of The concrete prepared with the addition of WFS in the presence
the main characteristics influencing the durability of concrete is of fly ash resulted in better resistance to chloride ions ingress. All
its permeability to the ingress of chloride. The chloride ion present the mixtures showed comparable or better results than the control
in the concrete can have harmful affect on concrete as well as on concrete mix, with better resistance shown by mixes with up to
the reinforcement. Swelling of concrete due to chloride ion pene- 20% replacement by WFS [14]. The improved performances of
tration is 2–2.5 times larger than that observed with water mixes with WFS and fly ash were attributed to better microstruc-
penetration. ture resulting from additional pozzolanic reactions. In other stud-
ies, up to 30% replacement by WFS showed better resistance to
Table 3
Typical values of C for quality of concrete [66].
4100
C (mm/yr0.5) Concrete
>9 Poor 4000
9 > C>6 Average
<6 Good
3900
0% WFS
UPV (m/s)

3800
20% WFS
3700
Table 4 40% WFS
Chloride-Ion Penetrability Based on Charge Passed as per ASTM C1202 3600
60% WFS
[67].
3500 80%WFS
ASTM C1202
3400 100%WFS
Charge Passed (coulombs) Chloride Permeability
>4000 High 3300
0 10 20 30 40 50 60
2000–4000 Moderate
1000–2000 Low
Curing Time (Days)
100–1000 Very Low
<100 Negligible Fig. 10. Variation in USPV velocity of concretes with different values of WFS at
different curing ages [15].
B. Bhardwaj, P. Kumar / Construction and Building Materials 156 (2017) 661–674 671

chloride penetration than control concrete [11,16]. Cement type, 22. Freezing and thawing resistance
water to cement ratio, curing condition, and testing age have effect
on chloride permeability of concrete [11]. Aggarwal and Siddique Naik et al. [14] conducted study to check freeze and thaw resis-
[12] reported very low RCPT values in all mixes with WFS and tance of concrete with WFS in different proportions (up to 47% by
BA as partial replacement [12]. Values as low as 750 C at 90 days weight) with fly ash content, varying in proportions to WFS con-
and 500 C at 365 days were observed in the replaced mixes. Varia- tent [14]. The test was conducted as per ASTM C666 (Procedure
tion of charge passed with variation in WFS level and curing age, as B) [71]. Upto 20% replacement showed comparable results to con-
reported by different authors, is shown in Fig. 9. trol mix while highest resistance was shown by mix with highest
percentage of WFS and fly ash attributable to enhanced
20. Ultrasonic pulse velocity microstructure due to additional pozzolanic contributions of fly
ash. Similarly, in another study [12], all mixes with WFS and bot-
Ultrasonic pulse velocity (UPV) test is used to check the quality tom ash in equal proportions, as sand replacement (0–60%),
of concrete also defects within concrete by passing electronic showed better resistance than reference mix at 90 days curing
waves through the concrete. In general, UPV value increases with age. Mass loss due to scaled-off material was observed between
the increase in WFS content in concrete mixes as well as with 0.31% and 0.66% at 90 days and between 0.92% and 1.87% at
age. Singh and Siddique [27] reported the electronic wave velocity 365 days for all replaced mixes. Furthermore, the visual rating for
value for WFS mixes varying between 4231 m/s and 4284 m/s with mixes, as per ASTM C 672 [70], never exceeded 2 and for most of
maximum velocity observed for mix with 15% WFS [27]. Moreover, the mixes it lied between 0 and 1.
UPV values for all the mixes fall under the range of good quality
concrete as per BIS 13311 (part 1): 1992 [68] and ASTM C597- 23. Microstructure analysis
2016 [69]. This increase in UPV value signifies better density,
homogeneity and lack of defects within concrete. Whereas beyond Scanning Electron Microscopy (SEM) technique was used by
20% replacement level of WFS, there existed a gradual decrease in some researchers for carrying out micro analysis of WFS and con-
the UPV values, however with the increase in curing age the USPV crete incorporating it. The SEM micrograph of WFS particles
values got increased (Fig. 10) [15]. Similarly, UPV values between revealed its sub-angular to round shape (Fig. 11) [26,48].
3500 and 4500 m/s were observed for the concrete mixes of two Calcium-silica-hydrate (C-S-H) gel is the major phase present in
different grade (M20 & M30) prepared with 0–20% WFS. Concretes the conventional concrete, which is primarily influenced by the
of M20 grades with WFS showed better improvement in UPV than grain size, type of particles, composition of dispersed phases/
M30 grade of concrete with WFS [56]. Prabhu et al. [22] reported stages, pore structure etc. [12]. Aggarwal and Siddique [12] studied
UPV values of mixes up to 50%WFS greater than 3500 m/s, indicat- the SEM micrographs of concrete containing WFS and BA as a par-
ing good concrete [22]. Similar results were catered with a replace- tial replacement of fine aggregates up to a replacement level of 60%
ment level of WFS up to 100% having UPV values ranging between on a magnification of 1.5KX [12]. The clear and proper C-S-H gel
3500 and 4800 m/s at all ages of curing. An increase in WFS leads spreads all around the reference mix. Inclusion of WFS and BA by
to a decrease in UPV and there is sharp increase in UPV between 10% (WFS + BA) remarkably decreased the voids in concrete but
the ages of 1 day and 7 days of curing for all mixtures [64]. It is C-S-H gel was not spread extensively as in case of reference mix,
clearly visible that with increase in curing time the density of con- owing to lesser quantity of WFS and BA. Enhancement in the
crete is increasing and with increase in replacement levels the strength up to a replacement level of 50% (WFA + BA) was evident
value decreases. from the SEM micrographs showing formation of needle like struc-
tures around WFS and BA and comparative even spread of C-S-H
21. Salt scaling resistance gel thereby obtaining a dense structure. The SEM graphs of mix
with 60% replacement showed disintegrated concrete due to com-
Naik et al. [14] investigated the effects of replacement of regular ing out of WFS and BA particles out of the structure, furthermore
concrete sand by WFS in different proportions (up to 47% by lesser and uneven formation of C-S-H gel lead to lower strength
weight) in air-entrained and non-air-entrained concretes contain- of the concrete mix. Fig. 12 shows the SEM Micrographs of control
ing different proportions of fly ash [14]. Salt scaling resistance of mix, 10% replacement level and 60% replacement level respectively
concrete was measured as per ASTM C672 [70]. The salt-scaling [12].
resistance of concrete mixes containing up to 20% WFS was found The scanning electron microscopy images of fungal treated con-
comparable to reference mix. However, it decreased dramatically crete with up to 20% WFS as sand replacement depicted the gener-
for concrete mixes with WFS levels of 43% and beyond represent- ation of calcified filaments and bio-mineral by the fungal activity
ing very low resistance to salt-scaling. [72]. The development of bio-mineral clogged up the voids of the

Fig. 11. SEM Micrographs of (a) Rounded WFS (b) Angular WFS [26].
672 B. Bhardwaj, P. Kumar / Construction and Building Materials 156 (2017) 661–674

Fig. 12. SEM micrograph of (a) Control Mix (b) 10% Replacement of WFS and BA (c) 60% Replacement of WFS and BA [12].

Fig. 13. (a) Untreated WFS Concrete (b) Fungal Treated WFS Concrete [72].

treated concrete, thus, it acted as filler material, thereby enhancing mance of WFS is still within standard specifications of some British
the water absorption and porosity of the concrete mix. Similar SEM and American codes, it can be a trusted material for making struc-
results were yielded by the researcher in their another study tural members. Because of the varied source of generation of the
wherein they developed concrete by replacing 10% and 15% fungal foundry sand (ferrous and non-ferrous) there still remains possibil-
treated WFS with fine aggregates [7]. The SEM images of untreated ity of conducting more tests to make the conclusions more viable
and fungal treated WFS concrete are given in Fig. 13. to the researchers and the construction industry and developing
a more sustainable concrete. This paper contains review of various
publications on use of WFS as substitute to natural sand in con-
24. Conclusions crete. The conclusions made are as follows:-

Consideration of sustainability in construction practices and 1. Presence of impurities such as clay, saw dust etc. particles
construction materials has become imperative for the survival of reduces the specific density of the material, and also
construction industry. Alternatives to conventional construction decreases the density of the concrete by creating air voids
materials are being studied worldwide since past few decades. in the concrete. Increase in substitution of WFS leads to
Waste foundry sand is one such alternative to regular sand, con- decrease in unit weight of concrete.
stituent of concrete. However, waste foundry sand is a lower qual- 2. Majority of waste foundry sands are categorized as non-
ity material and has some adverse effects on concrete properties hazardous waste (that is non-corrosive, ignitable, reactive
when used in high or complete replacement to sand, the majority or toxic) and have shown good durability.
of research studies showed that, yet it can be used to make struc- 3. In general, increase in substitution leads to decrease in
tural concrete as well. A number of studies have been carried out workability of concrete attributed to presence of finer parti-
on utilization of WFS in concrete, wherein, optimum replacement cles of sand and additives. The trend was same in case of
level is obtained as 30% for most of the properties. Since the perfor- special concretes like SCC and GPC. Beyond 50% replacement
B. Bhardwaj, P. Kumar / Construction and Building Materials 156 (2017) 661–674 673

there was drastic increase in water demand of concrete. Self References


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