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Introduction
Alkanes, alkenes and alkynes are simple hydrocarbon chains with no functional groups. The simplest organic
compounds are the alkanes. Alkanes have only single bonds between carbon atoms and are called saturated
hydrocarbons. Alkenes have at least one carbon-carbon double bond. Alkynes have one or more carbon-carbon
triple bonds. Alkenes and alkynes are called as unsaturated hydrocarbons. Alkanes have the general formula of
CnH2n+2 where n is the number of carbon atoms. Alkenes have the general formula C nH2n. The general formula
for alkynes is CnH2n-2. Acetylene is the simplest alkyne with the formula as C 2H2.
The International Union of Pure and Applied Chemistry (IUPAC) has established rules to systematize the naming
of hydrocarbon molecules.
1. Straight-chain hydrocarbon molecules that contain only singly-bonded carbons are called alkanes. When
naming these molecules, the final syllable in their name is "ane."
2. Straight-chain hydrocarbon molecules that contain at least one doubly-bonded carbons are called
alkenes. When naming these molecules, the final syllable in their name is "ene."
3. Straight-chain hydrocarbon molecules that contain at least one triply-bonded carbons are called alkynes.
When naming these molecules, the final syllable in their name is "yne."
4. Prefixes are attached to the last syllable to indicate the number of carbons in the hydrocarbon chain.
The IUPAC prefixes for the first twelve carbon chain lengths are:
1 2 3 4 5 6
meth- eth- prop- but- pent- hex-
7 8 9 10 11 12
hept- oct- non- dec- undec- dodec-
5. Alkenes and alkynes with hydrocarbon chain lengths of four or greater require a numbering scheme to
the chain to designate the location of a multiple bond. The rules regarding this numbering scheme are:
a. The numbering system begins at the end of the molecule nearest the location of a multiple bond.
b. The number in the name is assigned relative to the carbon in the chain where a multiple bond begins.
c. A number is included for each multiple bond in the chain. The numbers are separated by commas.
d. A dash connects the number locations to the hydrocarbon name.
STRAIGHT-CHAIN ALKANES Complete the table below.
No. of Molecular Condensed
Name Structural Formula
Carbons Formula Structural Formula
C5H12 pentane
5 CH3(CH2)3CH3
C6H14 hexane
6 CH3(CH2)4CH3
C7H16 heptane
7 CH3(CH2)5CH3
C8H18 octane
8 CH3(CH2)6CH3
C9H20 nonane
9 CH3(CH2)7CH3
C10H22 decane
10 CH3(CH2)8CH3
STRAIGHT-CHAIN ALKENES Complete the table below. *For alkenes with four or more carbon atoms, draw
the double bond between the first and second carbon atoms (see example below).
No. of Molecular Condensed
Name Structural Formula
Carbons Formula Structural Formula
C3H6 propene
3 H2C=CHCH3
C6H12 1-hexene
*6 H2C=CH(CH2)3CH3
C7H14 1-heptene
*7 H2C=CH(CH2)4CH3
C8H16 1-octene
*8 H2C=CH(CH2)5CH3
C9H18 1-nonene
*9 H2C=CH(CH2)6CH3
C10H20 1-decene
*10 H2C=CH(CH2)7CH3
STRAIGHT-CHAIN ALKYNES Complete the table below. *For alkynes with four or more carbon atoms, draw
the triple bond between the first and second carbon atoms (see example below).
No. of Molecular Condensed
Name Structural Formula
Carbons Formula Structural Formula
propyne
3 C3H4 HC≡CCH3
C6H10
*6 1-hexyne HC≡C(CH2)3CH3
C7H12
*7 1-heptyne HC≡C(CH2)4CH3
C8H14
*8 1-octyne HC≡C(CH2)5CH3
C9H16
*9 1-nonyne HC≡C(CH2)6CH3
C10H18
*10 1-decyne HC≡C(CH2)7CH3