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Origin of High-Grade Gold Ore, Source of Ore Fluid Components, and Genesis of the
Meikle and Neighboring Carlin-Type Deposits, Northern Carlin Trend, Nevada
POUL EMSBO,† ALBERT H. HOFSTRA,
U.S. Geological Survey, MS-973, Box 25046, Federal Center, Denver, Colorado 80225
Abstract
The Meikle mine exploits one of the world’s highest grade Carlin-type gold deposits with reserves of ca. 220 t
gold at an average grade of 24.7 g/t. Locally, gold grades exceed 400 g/t. Several geologic events converged at
Meikle to create these spectacular gold grades. Prior to mineralization, a Devonian hydrothermal system al-
tered the Bootstrap limestone to Fe-rich dolomite. Subsequently the rocks were brecciated by faulting and
Late Jurassic intrusive activity. The resulting permeability focused flow of late Eocene Carlin-type ore fluids
and allowed them to react with the Fe-rich dolomite. Fluid inclusion data and mineral assemblages indicate
that these fluids were hot (ca. 220°C),of moderate salinity (<6 wt % NaCl equiv), acidic, and H2S rich. Gold-
rich pyrite formed by dissolution of dolomite and sulfidation of its contained Fe. Where dissolution and re-
placement were complete, ore-stage pyrite and other insoluble minerals were all that remained. Locally, these
minerals accumulated as internal sediments in dissolution cavities to form ore with gold grades >400 g/t.
Petrographic observations, geochemical data, and stable isotope results from the Meikle mine and other de-
posits at the Goldstrike mine place important constraints on genetic models for Meikle and other Carlin-type
gold deposits on the northern Carlin trend. The ore fluids were meteoric water (δD = –135‰, δ18O = –5‰)
that interacted with sedimentary rocks at a water/rock ratio of ca. 1 and temperatures of ca. 220°C. The ab-
sence of significant silicification suggests that there was little cooling of the ore fluids during mineralization.
These two observations strongly suggest that ore fluids were not derived from deep sources but instead flowed
parallel to isotherms. The gold was transported by H2S (δ34S = 9‰), which was derived from Paleozoic sedi-
mentary rocks. The presence of auriferous sedimentary exhalative mineralization in the local stratigraphic se-
quence raises the possibility that preexisting concentrations of gold contributed to the Carlin-type deposits.
Taken together our observations suggest that meteoric water evolved to become an ore fluid by shallow circu-
lation through previously gold- and sulfur-enriched rocks. Carlin-type gold deposits formed where these fluids
encountered permeable, reactive Fe-rich rocks.
FIG. 1. Simplified geologic map of the Goldstrike property on the northern Carlin trend, Nevada, showing the footprint
of Carlin-type deposits projected to surface. Modified from Bettles (2002).
TABLE 1. Sequence of Hydrothermal and Igneous Events on the Northern Carlin Trend
Late Devonian Sedex alteration and Stratiform: from massive barite with sphalerite, Stratiform: synsedimentary debris flows 1, 2, 3
mineralization boulangerite, galena, and tetrahedrite to terminate mineralized beds and contain
“pinstripe pyrite” with minor barite, ore clasts, predates compaction and
sphalerite, tetrahedrite, chalcopyrite, and Au lithification of Devonian host rocks; cut
by early diagenesis and petroleum migration
Discordant: zebra dolomite with sphalerite, Discordant: cut by early diagenesis
barite, boulangerite, pyrite, galena, and petroleum migration
tetrahedrite, chalcopyrite, quartz, and Au
Late Devonian Early diagenesis Barite rosettes and nodules cut and contain Predates compaction and lithification of 3
inclusions of Sedex sulfides, Au, and enclosing rocks and is cut by petroleum
diagenetic pyrite and dolomite migration and bedding-parallel burial
stylolites
Early Mississippian? Petroleum migration Sequence of several crosscutting quartz Minerals and veins are cut by maximum 4
and deep-burial veins, silicification of carbonates, migration burial stylolites, suggesting a lower
diagenesis of petroleum, remobalization of Au, Mississippian age during emplacement
dolomite veins, and stylolites of Roberts Mountains allochthon;
burial stylolites are cut by Jurassic dikes
40
Late Jurassic Igneous intrusion Intrusion of Goldstrike diorite stock and Ar/39Ar dates on hornblende (157.87 ± 4, 5, 6
related monzonite and lamprophyre dikes 0.24 Ma) and phlogopite (158.88 ± 0.26
Ma) from lamprophyre dikes; zircon
U/Pb age (159–158 Ma) on Goldstrike
stock and monzonite dikes
40
Late Jurassic Polymetallic Auriferous polymetallic quartz veins with Ar/39Ar date on sericite (154.6 ± 7
mineralization galena, bournonite, freibergite, pyrite, 1.4 Ma)
sphalerite, chalcopyrite, covellite, minor
bismuthinite, and sericite; widespread
quartz-sericite-pyrite ± arsenopyrite (QSP)
alteration of intrusive rocks
Cretaceous Igneous- Richmond Hill stock 5 km southeast K/Ar age on illite (95 Ma) in Bluestar; 8, 9, 10
40
hydrothermal of Goldstrike, Sericitic alteration at Ar/39Ar on reset sericite at Goldstrike
Bluestar-Genesis and Betze-Post, (117 Ma); K/Ar of K-altered Roberts
Cu mineralization at Mike deposit Mt. Formation (111 ± 2 Ma)
40
Eocene Igneous intrusion Porphyritic dacite to rhyodacite, biotite- Ar/39Ar on biotite and sanidine (38.1– 6, 11
feldspar porphyry dike (BFP), thin dikes 39.21 Ma); U/Pb of zircon (37.8–38.1 Ma)
intruded in along the Betze-Post fault
Miocene? Epithermal Purple Vein Hg prospect just south of Probably related to Miocene regional 4, 12
Meikle mine bimodal magmatism and widespread
epitherrmal mineralization
Pliocene Low-temperature Extensive carbonate dissolution, collapse Cuts Carlin Formation (14.3–15.3 Ma), 4, 13, 14
hydrothermal brecciation, precipitation of calcite and U/Pb on calcite (2 Ma)
barite in the Bootstrap limestone
References: 1 = Emsbo et al., 1997; 2 = Emsbo et al., 1999; 3 = Emsbo et al., 2002; 4 = Emsbo, 1999; 5 = Emsbo et al., 1996; 6 = Mortensen et al., 2000;
7 = Emsbo et al., 2000; 8 = Arehart, 1993b; 9 = Drewes-Armitage et al., 1996; 10 = Teal and Branham, 1997; 11 = Ressel et al., 2000; 12 = Wallace, 2003; 13
= Hofstra et al., 2000; 14 = Emsbo and Hofstra, 2003
This paper draws on detailed petrographic, geochemical, 1995) and studies of breccia distribution and petrography
geochronologic, and isotopic studies originally presented in (Evans, 2000). We present new petrographic, geochemical,
Emsbo (1999) to explain the origin of the high-grade ores at and isotopic data for both Meikle and other Goldstrike de-
Meikle. It also draws on previous work on the geology of the posits and utilize pertinent observations and data from nu-
Meikle deposit and the northern Carlin trend (Leonardson merous previous workers (Arehart et al., 1993a,b; Drewes et
and Rahn, 1996; Volk et al., 1996; Armstrong et al., 1997; al., 1996; Leonardson and Rahn, 1996; Ferdock et al., 1997;
Emsbo et al., 1997; Teal and Jackson, 1997; Griffin, 2000; Williams, 1997; Peters et al., 1998; Ressel et al., 2000) to
Ressel et al., 2000), including fluid inclusion studies (Lamb, make comparisons with other northern Carlin-trend deposits.
We first characterize the effects of hydrothermal activity on for isotopic analyses on the basis of petrographic characteris-
igneous dikes in the Meikle, Betze-Post, and Ren deposits. tics, crosscutting relationships, fluid inclusion characteristics,
The chemical, mineralogic, and isotopic effects on igneous and cathodoluminescence (CL). Ore- and late ore-stage sul-
rocks help to constrain the composition of ore fluids, deposi- fide minerals were selected for isotopic analyses using petro-
tional mechanisms, and age of these deposits. The hydrother- graphic characteristics and mineral geochemistry determined
mal effects on the carbonate rocks at Meikle are then de- by microprobe, SEM, and laser ablation ICP-MS analyses.
scribed using a similar approach. Textures of carbonate rocks Ore-stage clay minerals in mineralized intrusive rocks were
and collapse breccias are described in detail as they directly selected using petrographic, geochemical, whole-rock XRD,
relate to formation of high-grade ore. Our data and observa- and SEM methods and separated by elutriation using the
tions lead to conclusions that are different from those of pre- method in Folger et al. (1996). Clay separates from altered
vious workers, and we propose a new genetic model for and mineralized biotite-feldspar-porphyry dikes at Betze-Post
Meikle and neighboring deposits on the northern Carlin and lamprophyre dikes at Meikle were analyzed for δD and,
trend. A key element of our model is the critical roles played in most cases, δ18O compositions. The δD values of fluid in-
by preore deformation and igneous and hydrothermal events clusion water in late ore-stage orpiment from Betze-Post and
on the subsequent Carlin-type mineralization. late ore-stage stibnite and quartz from Meikle also were ana-
lyzed. Oxygen isotope analyses of silicate minerals were car-
Methods ried out using the bromine pentafluoride technique (Clayton
A combination of field mapping, petrographic observations and Mayeda, 1963). Carbonate minerals were analyzed by re-
(transmitted, reflected, cathodoluminescence), scanning action with 100 percent phosphoric acid at 25°C following
electron microscope (SEM), X-ray diffraction (XRD), geo- McCrea (1950). Acid fractionation factors were taken from
chemical, and microprobe analyses was used to study the ores Friedman and O’Neil (1977). Hydrogen isotope analyses
and to resolve the complicated paragenetic sequence at were performed by thermal decrepitation of clay minerals
Meikle and other Goldstrike deposits. The ages of dikes on and/or crushing of fluid inclusion samples in stainless steel
the northern Carlin trend were used to constrain the timing tubes. The liberated H2O was converted to hydrogen gas
of ore-related hydrothermal and structural events. New using uranium metal (Friedman and Hardcastle, 1970). Sul-
40
Ar/39Ar analyses have been used to supplement published fur isotope analyses were carried out using a continuous flow
geochronology; additional information was obtained from method similar to that described by Giesemann et al. (1994).
crosscutting field relations (Emsbo, 1999). Textural charac- Isotopic compositions of gases were measured using either a
teristics, in conjunction with immobile element geochemistry, Finnigan MAT 252 or a Micromass Optima isotope ratio mass
were used to identify and distinguish the different intrusive spectrometer. Isotopic compositions are reported in δ nota-
rocks and their alteration histories. tion relative to VSMOW for oxygen and hydrogen, PDB for
A combination of hand samples of Meikle ore and core carbon, and CDT for sulfur. All of the stable isotope analyses
samples in and around the Meikle deposit (83 1.5-m-long and were made at the USGS laboratories in Denver.
815 12-m-long composite core samples from 37 drill holes)
were analyzed for 48 major and trace elements by instrumen- Geologic History of the Northern Carlin Trend
tal neutron activation analysis (INAA) and inductively cou- Carlin-type mineralization on the northern Carlin trend is
pled plasma-optical emission spectrometry by Actlabs in An- primarily hosted in the para-autochthonous Silurian-Devon-
caster, Canada. Major, minor, and REE analyses of igneous ian Roberts Mountains and Devonian Popovich Formations.
rocks were analyzed by wavelength dispersive X-ray fluores- The ore at Meikle is mainly hosted in the Bootstrap limestone
cence spectrometry and inductively coupled plasma-mass (Fig. 2). At Meikle, this unit is more than 600 m thick and
spectrometry (ICP-MS) at the U.S. Geological Survey consists of biomicritic wackestones to grainstones containing
(USGS) in Denver. These data reveal consistent elemental as- ooids deposited on a shallow shelf margin that is equivalent in
sociations related to the different chemical compositions of age to the Silurian-Devonian Roberts Mountains and the De-
different sedimentary and igneous rocks and different hy- vonian Popovich Formations (Fig. 3; Griffin, 2000). The
drothermal events (Emsbo et al., 1995; Emsbo, 1999; Tables Roberts Mountains Formation at the Betze-Post deposit, ap-
1 and 2). Microanalyses of sulfide minerals were conducted proximately 1.5 km south, is a thin-bedded to laminated silty
using an electron microprobe and laser ablation ICP-MS (Ri- limestone that represents a deeper water, lower slope-basin
dley and Lichte, 1998) at the USGS laboratories in Denver to depositional environment (Armstrong et al., 1997). The
investigate the siting of Au and the distribution of major and Popovich Formation is 300 m thick and is divided informally
trace elements including Fe, S, As, Sb, Hg, Te, Tl, Bi, Co, Ga, into four members (cf. Bettles, 2002; Fig. 3). The strati-
Ge, In, Mn, Mo, Ni, Pb, Re, Se, U, W, and Zn. Where Au, Ag, graphically lowest Wispy member consists of thick bioclastic
and Sb in sulfide minerals were near or below the detection debris flows interbedded with bioturbated, wispy laminated
limits of the microprobe, laser ablation ICP-MS was used. Fe, calcareous mudstone. The overlying Planar member consists
S, and As concentrations measured by microprobe analysis of laminated calcareous mudstone, interbedded with thin fos-
were used to standardize between methods. The data are de- siliferous debris flows. Overlying the Planar member is the
scribed in detail by Emsbo (1999). Microthermometric data Soft-Sediment Deformation member which consists of lami-
were collected on fluid inclusions in stibnite using a Fluid nated to medium-bedded, gray to black micritic mudstone
Inc. modified USGS-type gas-flow heating/freezing stage and distinguished by convoluted bedding suggestive of syndeposi-
a microscope equipped with an infrared light source. tional slumping. These three members all pinch out against
Ore- and late ore-stage quartz and calcite were separated the Bootstrap limestone just south of Meikle (Griffin, 2000).
Geochemical
Age Event signature1 Pyrite2 Isotopes (‰)3 Fluid inclusions References
Late Devonian Sedex Stratiform: Ba, Zn, Zn, Cu, Pb, Stratiform: δ34S barite n.a. 1, 2, 3
alteration and V, Cd, Sb, Ni, Pb, Mn, Hg, Ni, (26–33), pyrite (–15 to 11);
mineralization Cu, As, Hg, Au, Ag, Se, Ag, Au δ18O barite (13–16)
Tl, Au/Ag = 0.02–5
Discordant: δ34S barite
Discordant: Ba, Zn, (22–31), sphalerite (10–18);
Cd, Pb, Sb, Cu, As, δ18O barite (13–17),
Hg, Ag, Au, Tl, Au/Ag dolomite (11–16), quartz Sphalerite and
= 0.03–0.003 (12–14); δ13C dolomite quartz NaCl = 9–20,
(–1 to –5) Th = 200°–250°C
Late Devonian Early diagenesis Ba and Mg n.a. δ34S barite (37–52); n.a. 4
δ18O barite (22.6–22.9)
Early Mississippian? Petroleum Ca, Mg, C, Zn, Fe, n.a. δ18O quartz (20–23), Th = 150 ± 20°C, 4, 5
migration and Mn, Si, Au δ18O dolomite (19–22), high-density CH4, P
deep-burial δ13C (–2.6 to –0.3) = 0.6–1.4 kbars
diagenesis
Late Jurassic Polymetallic Vein: Pb, Cu, Zn, As, As, Sb, Pb, δ18O vein qtz (14–16); Three-phase CO2- 4, 6
mineralization Ag, Sb, Bi, Te, Au Zn, Cu, Bi, δ34S QSP pyrite (15), H2O, Th = 200°–
Ag vein pyrite (16), 225°C, 10 m % CO2,
sphalerite (11), galena (9) clathrate melting 8.7
(2.5 NaCl), CO2
melting –57.7 (5 mol
% CH4 or N2),
P > 1.8 kbars
Cretaceous Igneous/ Cu, Fe, Zn, Ag, Bi, n.a. n.a. n.a. 7
hydrothermal Mo, Te, Au
Eocene Carlin-type Au As, Au, Sb, Ag, Hg, Au, As, Sb, δ34S avg pyrite (10), Two modes; NaCl = 3
mineralization Tl, W, and Te, Hg, Tl, Te, realgar (6), stibnite (6); 2–6 and 0–1, Th =
Au/Ag = 10 W δD H2O (–135); δ18O 200°–230° and
H2O (–5) 175°–190°C
Pliocene Low- Ca, Mn, Ba n.a. δ18O calcite (3–5), Most inclusions 8
temperature barite (3), δ34S barite necked and single
hydrothermal (15–16); δ13C calcite (0–2). phase Th = <70°C,
one sample Th =
67°–76°C
References: 1 = Emsbo et al, 1999; 2 = Emsbo et al, 2002; 3 = Lamb, 1995; 4 = Emsbo, 1999; 5 = Kuehn, 1989; 6 = Emsbo et al, 2000; 7 = Teal and Bran-
ham, 1997; 8 = Emsbo and Hofstra, 2003
Abbreviations: n.a. = not analyzed, NaCl = wt % NaCl equiv, P = pressure, qtz = quartz, Th = temperature of homogenization (°C)
1
Data from references and Table 3 in decreasing order
2
Pyrite trace-element signature in decreasing order from references and Table 4 and 5
3
Data from Table 6
The Upper Mud member is a laminated, black to dark-gray debris flows, and synsedimentary slumping, is believed to re-
limey mudstone with thin beds of pyrite and lenses of phos- flect foundering of the carbonate platform and synsedimentary
phatic chert that overlies the Soft-Sediment Deformation extensional faulting (Emsbo et al., 1997, 1999; Griffin, 2000).
member and is the only member that continues to the north Devonian para-autochthonous rocks are overlain by al-
where it overlies the Bootstrap limestone. The Popovich For- lochthonous chert, siltstone, mudstone, and minor limestone.
mation is overlain by the Rodeo Creek unit that is composed of This complex assemblage of rocks includes imbricate slices of
argillite interbedded with silty carbonaceous mudstone and the Ordovician Vinini Formation, Silurian Elder sandstone,
chert. The carbonaceous nature of the Popovich Formation and Devonian Slaven Chert that were emplaced along the
and Rodeo Creek unit is evidence that these strata were de- Roberts Mountains thrust during the Late Devonian-Early
posited under anoxic conditions in a restricted basin (Emsbo et Mississippian Antler orogeny (Roberts et al., 1958). These
al., 1997). This Devonian stratigraphic sequence, with its rocks are unconformably overlain by mid-Miocene lacustrine
abrupt lateral and vertical facies changes, thick sequences of and tuffaceous sediments of the Carlin Formation.
Carlin Fm (Tertiary)
Popovich Fm (Devonian)
Bootstrap Limestone
Lower Main Zone
(Silurian-Devonian)
Elder Fm (Silurian and Devonian)
and Vinini Fm (Ordovician)
500 m
No vertical exaggeration
FIG. 2. Simplified geologic cross section A–A' showing the upper and lower Main zones of the Meikle deposit, Nevada.
Geologic interpretations are from drill holes prior to mining. Modified from Bettles (2002).
Volcaniclastic fluvial-lacustrine
siltstone, sandstone at the Goldstrike property includes six temporally, mineralog-
MIOCENE VOLCANIC ROCKS ically, geochemically, and isotopically different hydrothermal
Rhyolite flows
events, four of which deposited gold (Emsbo, 1999; Tables 1
SILURIAN - DEVONIAN and 2). The first event occurred in Late Devonian time when
ELDER FORMATION AND
auriferous brines discharged to the sea floor through synsed-
0-1000 m
ARGILLITE MEMBER - AA ber of lines of evidence suggests that these occurrences are
Limy siltstone, mudstone and chert
sedimentary exhalative in origin: (1) they are stratiform and
30-90 m
Limy mudstone and chert (argillite) δ18O values identical to those of sulfate in Late Devonian sea-
Disconformity water and other sedimentary exhalative barite deposits in
DEVONIAN - POPOVICH FORMATION
UPPER MUD MEMBER - UM Nevada; (3) the abrupt facies changes in the Popovich For-
60 m
Laminated limey to dolomitic mudstone mation are evidence of synsedimentary faulting and founder-
MEIKLE
SOFT SEDIMENT
30-60 m
PLANAR MEMBER - PL
Laminated limey to dolomitic mudstone
primary carbonate minerals in ore-grade material is strong ev-
WISPY MEMBER - WS idence that the gold was not introduced by a Carlin-type
60-90 m
ORDOVICIAN - SILURIAN
100 m +
that is comprised of thin (1–4 mm), concordant laminae of of the pyrite in the veins and quartz-sericite-pyrite is consis-
mainly pyrite with minor sphalerite, tetrahedrite, chalcopy- tently 15 per mil (Emsbo et al., 2000).
rite, and native gold. Rocks characterized by pinstripe pyrite Small mid-Tertiary (ca. 38 Ma) dacite to rhyodacite biotite
also contain barite in beds as much as 4 cm thick and as nod- feldspar porphyry dikes are present on the northern Carlin
ules and rosettes. Pinstripe pyrite together with minor barite trend that were altered and mineralized by the Carlin hy-
has been recognized over an area of 20 km2 on the northern drothermal event, constraining the age of the Carlin-type
Carlin trend (Emsbo et al., 1999, 2002). Small lenses of mas- mineralization to mid-Tertiary time (Emsbo et al., 1996;
sive sulfide with barite as thick as 0.5 m also are present in Emsbo, 1999; Ressel et al., 2000). The Purple Vein Hg
this rock. Grains of native gold, generally <1 µm wide, are prospect just south of Meikle might be a local manifestation
present as inclusions in tetrahedrite, chalcopyrite, pyrite, and of Miocene epithermal systems that occur regionally (John
barite and as free grains in the mudstone; they are overgrown and Wallace, 2000; Wallace, 2003). Finally, a lower tempera-
by diagenetic barite nodules, indicating that native gold ture, gold-deficient Pliocene hydrothermal event caused
formed contemporaneously with the barite and base metal postore dissolution of carbonate minerals, collapse breccia-
sulfide. Gold contents of as much as 500 ppm and 2,200 ppm tion, and precipitation of calcite and barite in resulting cavi-
have also been measured by electron microprobe and laser ties at Meikle (Emsbo and Hofstra, 2003).
ablation ICP-MS in pyrite and Cu sulfide minerals that lacked
microscopically visible inclusions of native gold (Emsbo, Alteration and Mineralization of Igneous Rocks
1999). This pyrite also contains high concentrations of Zn, Pb, in Northern Carlin Trend Deposits
Cu, Ni, Mn, Hg, and Se, with As generally <1 wt percent
(Emsbo et al., 1999). Similar auriferous pyrite, interpreted as Alteration of igneous rocks
early diagenetic, has been reported at the Gold Quarry mine Jurassic lamprophyre dikes, monzonite dikes, and the
on the southern Carlin trend (Sha, 1993). Goldstrike stock, as well as the late Eocene biotite feldspar
At Meikle the underlying Bootstrap limestone is perva- porphyry dikes on the Goldstrike property, were all locally al-
sively dolomitized and locally silicified in and along vertical tered prior to Carlin-type mineralization. Lamprophyre dikes
faults that were loci of major venting, depositing base metals, typically were altered to calcite, dolomite, magnesite, chlo-
barite, and minor gold. The resulting dolostone exhibits rite, quartz, and illite (2M) following their emplacement in
“zebra” texture, which is characterized by alternating bands of Jurassic time. The Jurassic hydrothermal system also locally
white and gray sparry dolomite. The δ13C (–1 to –3‰) and altered the monzonite dikes to quartz, illite (2M), and pyrite
δ18O (12–15‰) values of the dolomite are typical of those of (QSP in Table 1). Similarly, feldspar, the glassy groundmass,
deposits formed by basinal fluids including both sedimentary chlorite, and hornblende in many biotite feldspar porphyry
exhalative and Mississippi Valley-type deposits (Emsbo, dikes were altered to a mixture of illite (2M), quartz, and
1999). Cathodoluminescence microscopy (CL) displays com- minor smectite and kaolinite. Biotite, however, was not al-
plex color zoning ranging from a mottled, dark reddish brown tered by this preore event.
in gray bands to a bright reddish orange to yellowish red in Alteration minerals associated with Carlin-type mineraliza-
the white sparry dolomite. The proportions of high- and low- tion are similar in all four igneous rock types at Meikle, Betze-
luminescence dolomite vary greatly among samples. Electron Post, and Ren (ca. 2 km northeast of Meikle). Except for
microprobe analyses show that the gray, weakly luminescent quartz, pyrite, and some illite, all major primary igneous min-
dolomite contains 5 to 10 wt percent FeO, whereas the highly erals (i.e., hornblende, phlogopite, pyroxene, olivine, biotite,
luminescent, white dolomite contains 0.01 to 1 wt percent and feldspars) and preore alteration minerals are absent in
FeO (Emsbo, 1999). samples altered by the Carlin-type fluids. Strongly mineral-
The Devonian sedimentary exhalative alteration and min- ized dikes contain kaolinite, quartz, and varying proportions
eralization are cut by bitumen veins, quartz and/or calcite of 1M and 2M illite. Increasing kaolinite and 1M illite con-
veins, and stylolites that formed during burial diagenesis in tents with an increase in Au- and As-rich Fe sulfide minerals
early Mississippian time (Table 1). These features are cut by is apparent in mineralized samples, suggesting their forma-
the Late Jurassic Goldstrike stocks and related dikes tion during mineralization (Emsbo, 1999). Mineralized sam-
(160–158 Ma) that account for most igneous activity on the ples of biotite feldspar porphyry dikes also commonly contain
northern Carlin trend (Emsbo, 1999). Minor hydrothermal smectite. Iron-bearing minerals in the different dikes (i.e.,
activity associated with these intrusions deposited base and hornblende, olivine, phlogopite-biotite, magnetite, and il-
precious metals in quartz veins, and the Goldstrike stock and menite) are typically replaced by pyrite, marcasite, or ar-
related monzonite dikes were altered to quartz-sericite-pyrite senopyrite (Fig. 4). Ti-bearing minerals are altered to leucox-
(Emsbo et al., 2000). Pyrite associated with this quartz- ene. Zircon and apatite appear unaffected during even the
sericite-pyrite alteration is texturally, geochemically, and iso- strongest alteration.
topically distinct from pyrite formed during other events Chemical gains and losses during hydrothermal alteration
(Table 2). It occurs as euhedral brassy grains up to 0.5 mm of the dike rocks were evaluated using logarithmic isocon di-
across and is complexly zoned, with some zones containing as agrams (Grant, 1986; Hofstra, 1994). Of the major elements,
much as 9.3 percent As and 0.2 percent Sb and between ca. 5 Al, Ti, P, Si, and Fe were immobile, except for Si which ap-
and 100 ppm Au. In addition to high base metal contents pears slightly depleted in the biotite feldspar porphyry dike.
(2,800 ppm Pb, 1,000 ppm Cu, and 1,000 ppm Zn), the pyrite This depletion is consistent with the hydration of volcanic
contains high Bi (140 ppm), Ag (13 to 33 ppm), and Te (17 glass that is observed in the matrix of fresh samples. There is
ppm) contents and lacks Hg (<1 ppm). The δ34S composition no evidence for introduction of base metals (Cu, Zn, Cd, and
1000000
A
100000
10000
1000
Altered Lamprophyre, ppm
100
10
.1
Location of Samples
.01 Betze/Post
Up to 25% mass decrease Meikle
Constant mass Ren
.001
.001 .1 10 1000 100000
10000
Altered Dikes, ppm
1000
100
10
.1
.01
Constant mass Constant mass Constant mass
.001
.001
.01
.1
10
100
1000
10000
100000
1000000
.001
.01
.1
10
100
1000
10000
100000
1000000
.001
.01
.1
10
100
1000
10000
100000
1000000
although Fe was immobile on a hand sample scale, Fe moved trend deposits. These differences are especially apparent be-
on the microscale to form auriferous pyrite rims on the pre- tween Jurassic lamprophyre and monzonite dikes. The for-
ore pyrite (Stenger et al., 1998). mer commonly have higher gold grades than enclosing sedi-
There are striking differences between gold contents of mentary rocks, whereas monzonite dikes are poor ore hosts.
various intrusive rocks in the ore zones of northern Carlin Lamprophyre dikes in ore zones are typically homogeneously
Au ppm
12
60 8
8
Au ppm
4
40
0
20 s 6000
As ppm
7 A
0 0% 4000
/1
Fe Content w 2000
6 e
rit 0
Monz BFP Di Lamp Py
S (wt %)
50
Hg ppm
5 40
e
rit 30
Py 20
4 BFP 10
0
Di 50
Lamp 40
3 LampM
Tl ppm
ite
LampP pyr 30
eno 20
Monz Ars 10
2 0
200
Sb ppm
160
1 120
80
25% Mass Loss 40
0 0
0 1 2 3 4 5 6 7 8
Fe (wt %) Lamprophyre Monzonite
FIG. 6. A. Plot of wt percent Fe vs. wt percent S in mineralized igneous
rocks from the Goldstrike property (Appendix) illustrating the increase of S
and immobility of Fe. The pyrite, pyrite with 10 wt percent As, and ar-
senopyrite lines indicate the Fe stoichiometry of respective minerals. Tie
lines in gray are between unaltered and mineralized counterparts. Sulfur in-
creases until the stoichiometry of As-rich pyrite or arsenopyrite is reached.
The apparent increase in Fe content does not reflect introduced Fe but 1 cm
rather a loss of other constituents (see discussion in text). Sulfur and Fe were
not normalized to an immobile element to emphasize the resulting increase FIG. 7. Laser ablation ICP-MS chemical analyses across the contact be-
in Fe due to mass loss. Inset box plots of Au contents in mineralized samples tween a monzonite dike and a younger lamprophyre dike at Meikle illustrat-
from each rock type are arranged according to their initial Fe contents. BFP ing the difference in their susceptibility to mineralization. The lamprophyre
= biotite feldspar porphyry dike, Di = Goldstrike diorite, Lamp = hornblende contains inclusions of the monzonite dike and is thus the younger rock. Dots
lamprophyre, LampM = mafic lamprophyre, LampP = phlogopite lampro- indicate the locations and the size of spots analyzed (Table 4).
phyre, Monz = monzonite.
mineralized and form high-grade ore. Monzonite dikes are enter the dike. Decalcification by acidic Carlin-type fluids has
mineralized locally in the most intense parts of the hy- been shown to be an important control on mineralization in
drothermal system but only along their margins and in frac- sedimentary rocks by many workers (Kuehn, 1989; Ilchik,
tures. These relationships are apparent at all scales. Figure 7 1990; Bakken, 1991; Hofstra et al., 1991; Hofstra, 1994). In
shows a contact from an ore zone in the Meikle deposit be- contrast, the monzonite dike at Meikle was composed pri-
tween a monzonite dike that is cut by a younger lamprophyre marily of sericite and quartz, which were both relatively sta-
dike. On a hand sample scale, both dikes have experienced ble during Carlin-type alteration. No significant secondary
the same degree of interaction with the mineralizing fluid, permeability was created during alteration of this rock,
but laser ablation ICP-MS analyses show remarkable differ- thereby inhibiting fluid interaction. In the biotite feldspar
ences in the concentrations of Au and related elements in the porphyry dikes, abundant smectite, which is a swelling clay
two rock types. Gold averages 10 ppm in the lamprophyre that is relatively inert to the Carlin-type hydrothermal fluids,
and drops to <1 ppm within 0.25 cm in the monzonite dike, most likely decreased permeability. In addition the biotite
where it is only detectable near fractures. Like the monzonite feldspar porphyry was intruded only shortly before develop-
dikes, the late Eocene biotite feldspar porphyry dikes are also ment of the Carlin-type hydrothermal system, and therefore,
a poor ore host, being mineralized only on their margins and was not affected by the faulting and fracturing experienced by
along fractures that cut them. Although biotite feldspar por- the Jurassic dikes (Emsbo, 1999; Ressel et al., 2000).
phyry dikes locally contain significant Au, they generally con-
tain less Au than surrounding sedimentary rocks. The Gold- Alteration and Mineralization of
strike diorite stock is chemically intermediate in character; in Sedimentary Rocks at the Meikle Mine
portions of the Betze-Post deposit, it is sufficiently mineral- Most ores at Meikle are hosted in complex breccias in the
ized that it can be mined. Bootstrap limestone that extend from 250 to more than 600
Two factors apparently influence the degree of mineraliza- m below the surface but remain open at depth. The orebody
tion in the dikes: their Fe contents, and the ability of the ore has been subdivided into three ore zones on the basis of
fluid to penetrate the dikes. Lamprophyre dikes initially were geometry and depth. The Upper Main and South Meikle
composed of 10 to 20 percent carbonate minerals, mostly cal- zones are hosted in the Popovich Formation (Fig. 2). Ore is
cite, that were readily dissolved by the acidic Carlin-type ore hosted in breccias and mudstones on the southwest side of
fluids, creating secondary permeability and allowing fluid to the monzonite dikes and beneath lamprophyre dikes that, in
many cases, also host high-grade ore. The Lower Main zone
forms the high-grade core of the Meikle deposit and was the
primary focus of this part of the study (Fig. 8). It averages 60
m thick and has a strike length of 365 m. It trends N 20°–30°
W, is mainly steeply dipping (Volk et al., 1996), and is re-
stricted to the footwall of the monzonite dike in the dolomi-
tized Bootstrap limestone (Fig. 8). Gold mineralization is best
developed in heterolithic breccias in these dolomitized rocks
(Fig. 9), and minor amounts of ore extend into flanking non-
brecciated dolostone along faults and fractures (Fig. 8).
Description and paragenetic relationships of the Meikle ore
Dolomite-hosted ore: Gold grades of the Meikle ore are typ-
ically less than 30 g/t but reach as high as 90 g/t in unbrec-
ciated dolomite. Like the lamprophyre dikes, dolomite be-
comes dark brown to black where mineralized, due to the
presence of fine-grained pyrite. In strongly mineralized
dolomite, primary textures are destroyed, but mineralization
commonly grades into barren dolomite that retains its original
texture (Fig. 10A). Grains of ore-stage pyrite are typically <3
µm wide, anhedral, and have a “spongy,” porous texture (Fig.
10B, C). In highly mineralized samples, ore-stage quartz is
usually a minor constituent (Fig. 10C, D). Where present, it
is subhedral to anhedral and essentially nonluminescent
8m/86.6 g/t
3m/47.6 g/ t
11m/41.6 g/t
25m/24.3 g/t
5m
/19
.9
g/ t
25m
/28
.6 g
/t
55
m
/5
49
3.6
m
/5
g/
6.6
t
Breccia 69 g/
t
m
Dolomite /1
01
.1
Monzonite Dike g/ FIG. 9. Photographs of breccias from the Lower Main ore zone in the
t
Bootstrap Limestone Meikle deposit. A. Ore-stage breccia dominated by clasts of zebra dolomite
near the contact with massive zebra dolomite (see Fig. 8; 15–cm–long
Popovich Fm. Mudstone scratcher for scale). B. Heterogeneous ore-stage breccia near the contact
> 6.2 g/t Au 25 m with a monzonite dike showing clasts of monzonite, ore, and preore barite
that are cemented and silicified by later ore-stage quartz and pyrite. C. Thin
FIG. 8. Cross section (3500NW) showing definition drilling and simplified section of breccia similar to that in B showing different clast types that are
geology of the Lower Main ore zone in the Meikle deposit. cut by late ore-stage quartz. Note clast of cave-fill ore.
FIG. 10. Photographs of dolomite-hosted ore. A. Mineralized dolomite showing sulfidation front ranging from weakly min-
eralized dolomite (upper right) which retains its texture to dominantly ore-stage pyrite with nearly complete dolomite disso-
lution and destruction of zebra textures (lower left). Note replacement of Fe-rich gray zebra dolomite bands over white
coarse dolomite. B. Transmitted light photomicrograph of dolomite partly replaced by ore-stage pyrite. Note absence of
quartz. C. Similar to B, but ore-stage pyrite here is accompanied by uncommon ore-stage quartz. Inset shows preore euhe-
dral quartz overgrown by clear ore-stage quartz containing inclusions of ore-stage pyrite. D. Porous, friable, decalcified zebra
dolomite with relict preore barite and quartz veinlets (white), insoluble residues, and ore-stage pyrite.
under CL except for a slight, dark-blue color. Most quartz ap- Lamb (1995) reported salinities ranging between 2 to 6 and 0
pears to be paragenetically later than the ore-stage pyrite. The to 1 wt percent NaCl equiv, and homogenization temperatures
rare fluid inclusions in ore-stage quartz that we observed are of 200° to 230°C and 175° to 190°C, for these inclusions.
small (<2 µm in size), liquid-rich inclusions with irregular to Many original components of the dolostones were appar-
rounded shapes. At room temperature, they have gas bubbles ently insoluble in the acidic ore fluid and are preserved in the
that typically comprise ca. 20 vol percent of the inclusions. most strongly mineralized and altered samples (Fig. 11A-I).
FIG. 11. Photographs of different preore minerals that constitute insoluble residues in mineralized samples with exam-
ples of crosscutting relations that constrain the age of gold ore formation at Meikle. A. Distinctive preore euhedral quartz
bracketed by related preore discordant sedimentary exhalative mineralization sphalerite and barite. Inset of quartz shows
characteristic oval-shaped, ca. 2-µm, two-phase fluid inclusions (arrow) and a solid carbonate inclusion similar to those de-
scribed by Lamb (1995). Salinities as high as 20 wt percent NaCl equiv and filling temperatures of ca. 230°C for these in-
clusions overlap those measured in sphalerite and barite (data from Lamb, 1995). Quartz associated with sedimentary ex-
halative mineralization has mean δ18O values of 13 per mil (Tables 1 and 5). B. Hand sample of preore sphalerite and related
base metal sulfide minerals, dolomite, and barite, cut by fracture filled with bitumen. C. Preore diagenetic quartz cut by bi-
tumen which are both cut by and included in a Late Jurassic lamprophyre dike. The δ18O values of similar quartz average
22.7 per mil (Tables 1 and 5). D. Clast of sedimentary exhalative preore barite and sphalerite in Late Jurassic lamprophyre
dike. E. Fine-grained gold ore-stage pyrite surrounds euhedral preore pyrite. F. Preore quartz in dolomite that is dissolved
and replaced by opaque ore-stage pyrite. G. Porous, low reflectance bitumen grain surrounded by ore-stage pyrite. H. Grain
of sedimentary exhalative sphalerite overgrown and cut by ore-stage pyrite. I. Tetrahedrite (Tet.) and preore pyrite; tetra-
hedrite is replaced partly by ore-stage pyrite along edge not armored by preore pyrite.
Preore quartz, distinguished by its petrographic and fluid in- “dropped” significantly from their original stratigraphic posi-
clusion characteristics, is locally overgrown by later, ore-stage tions, suggesting extensive dissolution collapse brecciation
quartz (Figs. 7D and 11A, F). Angular to subrounded grains into open-space created during mineralization.
of bitumen also are present in high-grade ore but are typically Fractures and interstices in crackle breccias commonly
more porous and less reflective than those in unmineralized contain ore-stage pyrite and clasts of older material foreign to
samples, indicating some reaction between the bitumen and the enclosing rocks. For example, interstices in crackle brec-
the ore fluid (Fig. 11G). Preore pyrite is commonly over- cias in the monzonite dikes are filled by fine-grained minerals
grown and cut by ore-stage pyrite (Fig. 11E); however, many that predate intrusion of the dikes, including grains of preore
base metal sulfide minerals related to the Devonian sedimen- quartz, bitumen, sulfide minerals, and dolomite (Fig. 12A).
tary exhalative event exhibit dissolution features. Tetrahedrite The presence of these minerals in fractures that cut the dike
is commonly highly corroded, and in some cases replaced, by indicates their physical transport, probably due to settling,
ore-stage pyrite (Fig. 11I); elsewhere, it appears to have been into the fractures.
protected as inclusions in sedimentary exhalative pyrite. Cave-fill ore: The highest Au grades at Meikle (185–400
Sphalerite grains, which are common to abundant in highly g/t) are in rocks that are interpreted to have formed locally as
mineralized samples, are slightly rounded, perhaps again in- internal sediment in dissolution breccia cavities. These ores
dicating slight dissolution (Fig. 11H). Grains of sedimentary contain stratified and graded beds of Au-rich ore-stage pyrite
exhalative barite also are commonly present in strongly min- and quartz with varying proportions of preore insoluble
eralized samples but are rounded, embayed, and locally re- residues consisting of fine grains of dolomite, quartz, sulfide
placed by quartz, indicating that barite was also soluble in the minerals, barite, and bitumen (Fig. 11A-I). Angular to sub-
ore fluid. Barite is less abundant in ore than in unmineralized rounded rock clasts in these sediments are from the Bootstrap
host rocks, consistent with barite having been relatively more limestone, Popovich and Vinini Formations, and Jurassic ig-
soluble than sphalerite during mineralization. neous rocks, as well as earlier formed Meikle ore. Their well-
In the most strongly mineralized samples, nearly all stratified character and the sedimentary structures displayed
dolomite has been removed leaving only ore-stage pyrite, by rocks and hydrothermal minerals of different ages are evi-
quartz, and other insoluble minerals. Where dissolution and dence that these sediments accumulated in open spaces
sulfidation of dolomite was not accompanied by deposition of within cavities created by hydrothermal dissolution.
quartz, the result was a highly porous and friable rock com- Many sedimentary structures in layers of granular, ore-
posed of delicately intergrown ore-stage pyrite and insoluble stage pyrite suggest that it, too, was deposited as clastic sedi-
residue minerals, with Au grades as high as 190 g/t (Fig. 10E). ment and not by selective replacement of preexisting cave fill.
Breccia-hosted ore: Most ore at Meikle is contained in the In some layers, ore-stage pyrite is size graded and is the dom-
extremely complex breccias of the Lower Main zone (Fig. 9). inant mineral present. Beds of auriferous pyrite are locally
Although minor collapse and fault brecciation preceded Car- disrupted by distinctive synsedimentary and soft-sediment
lin-type mineralization, within ore zones these older breccias features, such as dropstones, fluidized structures, slumps,
are overprinted by ore-stage brecciation. The resulting rocks load casts (flame structures), and beds that drape over larger
are heterogeneous, and in most cases, matrix supported with clasts (Fig. 12B-E).
clasts of zebra dolomite, dike rocks, Bootstrap limestone, Compositions and textures of cave-fill ores are highly vari-
Popovich Formation mudstone, argillite, preore sulfide min- able. At one end of the spectrum are internal sediments com-
erals, barite, and quartz. Although the dominant clast type is posed dominantly of corroded and leached grains of dolomite
zebra dolomite (Fig. 9A), clast compositions are highly vari- that are similar to so-called “sanded dolomite” in Mississippi
able and commonly reflect the compositions of the immedi- Valley-type deposits (Heyl et al., 1959). These rocks exhibit
ate surrounding rocks (e.g., along the monzonite footwall alternating light and dark layers of variable thickness. Coarser
most clasts are monzonite; Fig. 9B, C). Carlin-type ore is beds consist of silt- to sand-sized dolomite grains mixed with
commonly present as clasts in breccias that have been ce- granular preore sulfide minerals, bitumen, quartz, barite, and
mented by additional ore-stage quartz and pyrite, which is ev- ore-stage pyrite that are present as free grains and/or as in-
idence of ore-stage brecciation (Figs. 9 and 12). Matrix min- clusions in larger grains and clasts when not disaggregated or
erals are dominated by ore-stage pyrite and quartz, mixed dissolved out of their dolomite host. Commonly, these strata
with grains of preore dolomite, quartz, barite, sulfide miner- grade into dark layers with higher contents of ore-stage
als, bitumen, and minor amounts of clay minerals. The pro- pyrite, preore sulfide minerals, and bitumen and show a cor-
portions of preore minerals vary according to the intensity of responding decrease in the size and abundance of dolomite
mineralization and the source of the clasts. grains (Fig. 12C). An increase in organic carbon content is ap-
Ore-stage breccias in Meikle resemble dissolution and col- parent in the finer beds, and because of its uniformly small
lapse breccias in Mississippi Valley-type deposits, i.e., crackle grain size, ore-stage pyrite is also concentrated within the
breccias dominate upper parts of the breccia bodies and con- finer grained strata. The gold contents of these samples are
sist of close-packed fragments that exhibit little rotation; rub- variable, typically below 15 g/t, and correspond to the amount
ble breccias comprise most of the orebody and are composed of dark-colored material. Where “sanded” dolomite was sub-
of down-dropped, matrix-supported clasts, including both sequently mineralized, the dolomite-rich layers are porous
rock and ore material as matrix; and internal sediments and and replaced by disseminated pyrite (Fig. 12F).
trash zones composed of insoluble residues accumulated in At the other end of the spectrum are rocks composed al-
dissolution cavities at the base of the breccia bodies (Sangster, most entirely of ore-stage pyrite and quartz. They are similar
1988). Many clasts from different stratigraphic units have to rocks in the high sulfide beds described above (Fig. 13D);
FIG. 12. Photographs of ore-stage pyrite deposited as clastic cave-fill sediment. A. Monzonite crackle breccia filled in by
ore-stage pyrite and various preore grains that settled into the fracture. B. Core sample of cave-fill ore with textures close to
that of the sanded dolomite in Mississippi Valley-type deposits (Heyl et al., 1959). C. Graded beds of ore-stage pyrite and
sanded dolomite grains. D. Load casts with flame structures disrupting beds of ore-stage pyrite. E. Argillite dropstone with
preore quartz and bitumen veins in beds of ore-stage pyrite and dolomite. Note associated fluidization features. F. Core sam-
ple of sanded dolomite cave-fill ore as in B that was subsequently dissolved and sulfidized. Note porosity at former locations
of sanded dolomite and dolomite clasts.
they also contain minor amounts of preore sulfide minerals, and formation of “sanded” dolomite were broadly contempo-
bitumen, barite, and rare grains of dolomite. The quartz in raneous with graded, ore-stage pyrite.
these layers consists of variable proportions of preore and The Meikle deposit also contains late Pliocene dissolution
ore-stage quartz; only a few samples contain predominantly collapse breccias with internal sediments that are distinguish-
ore-stage quartz (Fig. 13C). Pyrite contents are generally 20 able from the breccias and internal sediments which formed
to 50 percent and Au contents commonly exceed 300 g/t. The during gold mineralization (Tables 1 and 2). These features
absence of porosity in these ores indicates that they are not a are described in another paper (Emsbo and Hofstra, 2003).
product of dissolution and sulfidation of sanded dolomite. Late ore-stage drusy quartz, stibnite, and pyrite: Drusy
Overprinting and crosscutting relationships indicate that quartz, stibnite, and/or brassy pyrite form overgrowths on
cave-fill sedimentation was synchronous with Carlin-type ore-stage quartz and pyrite. These minerals also fill frac-
mineralization and not the result of postore dissolution and tures that cut ore and cement brecciated ore clasts. Drusy
pyrite concentration. For example, the dolomite-rich layers quartz is far more abundant than ore-stage replacement
are locally leached and sulfidized, a feature that is typical of quartz at Meikle. Stibnite, however, locally forms veins that
rocks altered by Carlin-type fluids (Fig. 12F). Also, clasts of cut cave-fill ore (Fig. 14A). These veins are as much as 1.5
high sulfide cave-fill sediments are present in breccias that m across with crystals 0.3 m in length. Late ore-stage pyrite
have been subsequently silicified and sulfidized by ore-stage is not significant.
pyrite; the breccias are also cut by late ore-stage veins (Figs. Drusy quartz typically exhibits a progression from fine- to
9, 12E, and 14A). These crosscutting relations are com- medium-grained, granular to coarse euhedral crystals. Cathodo-
pelling evidence that dissolution of host rock, brecciation, luminescence reveals prominent zoning, with the initial granular
FIG. 13. Photograph of cave-fill ore from Meikle containing quartz from various sources. A. Photograph shows striking
similarity between cave-fill ore from the Reocin (left) carbonate-hosted Pb-Zn deposit, Spain, consisting of nearly pure spha-
lerite, and high-grade (390 g/t Au) cave-fill ore from Meikle (right), consisting of almost entirely of ore-stage pyrite. B. Thin
section of high-grade Meikle ore in A showing graded pyrite-rich sample with quartz having a δ18O value of 13.4 per mil,
consistent with a sedimentary exhalative origin (Table 1). Inset 1 shows sedimentary exhalative quartz grains with distinctive
fluid and carbonate inclusions (see Fig. 11A) that comprise most of the sample. Inset 2 shows elongate grain of diagenetic
quartz. C. Finely bedded cave-fill ore (311 g/t Au) showing graded beds of quartz, ore-stage pyrite, and minor amounts of
other insoluble minerals. Most quartz is clear ore-stage quartz confirmed by a whole-rock δ18O value of 5.5 per mil; however,
the sample also contains some preore quartz. Inset 1 shows preore quartz overgrown by ore-stage quartz. Inset 2 shows ore-
stage quartz containing ore-stage pyrite similar to that in Figure 10D. D. Graded, sulfide-rich cave fill with “trash” zone of
preore quartz. Inset 1 shows large clast of diagenetic quartz as seen in Figure 10C. E. Sulfide-rich sample (138 g/t Au) that
includes poorly sorted grains of bitumen containing diagenetic quartz (whole rock δ18O = 20.6‰) as in Figure 11C.
quartz exhibiting only a slight greenish-blue luminescence –2.6°C, indicating a salinity of 4.3 wt percent NaCl equiv
which grades into brighter, bluish-green to yellowish-gray lu- (Bodnar et al., 1985). The similarity of these homogenization
minescence in the youngest growth zones (Fig. 14B). Stibnite temperatures and salinities to those found for ore-stage
± pyrite is present as inclusions in, and overgrowths on, the quartz (Lamb, 1995) strongly suggests that stibnite and drusy
younger, more luminescent quartz. The oldest, weakly lumi- quartz were deposited from the same hydrothermal fluid that
nescent cores contain irregular, liquid-rich fluid inclusions formed the ore.
that are 1 to 2 µm wide and exhibit consistent liquid to vapor Late ore-stage drusy quartz and pyrite locally occur with
ratios (ca. 4:1). Fluid inclusions in progressively younger Ag, Hg, Au tellurides and native Au (Fig. 14D, F). This as-
zones are more irregular in shape, necked, and exhibit vari- semblage is rare, cuts across and surrounds earlier formed
able liquid to vapor ratios. Examination of stibnite in infrared ore-stage pyrite, and is present on the margins of quartz vein-
light reveals spectacular fluid inclusions as much as 100 µm in lets that also cut these ore-stage minerals (Fig. 14D, F).
diameter that display consistent liquid to vapor ratios of ca. The quartz, stibnite, and pyrite of the late ore-stage are
4:1 (Fig. 14C). Homogenization temperatures measured in commonly cut by a distinct generation of zoned quartz that
fluid inclusion assemblages from four different samples range luminesces a bright light green to greenish-yellow (Fig. 11B).
from 200° to 220°C. Freezing points cluster tightly around Although it forms overgrowths on the older, late ore-stage
FIG. 14. Examples of late-ore stage minerals at Meikle. A. Photomicrograph showing massive stibnite and quartz cutting
cave-fill ore. B. Cathodoluminescence photomicrograph of latest stage highly luminescent quartz, overgrowing and cement-
ing late ore-stage drusy quartz. Banding in late-stage drusy quartz is shown in inset. Note brecciation of the late-stage drusy
quartz. C. Photomicrograph of fluid inclusions in stibnite from A in infrared light. These inclusions homogenized between
210° and 220°C and have a freezing point depression of –2.6°C, corresponding to 4.3 wt percent NaCl equiv. D. Quartz vein
with native Au and a grain of calaverite cutting high-grade pyrite-rich Meikle ore (reflected light). Ore-stage pyrite is clearly
cut by and occurs as inclusions in native gold. Gold grains average 12 wt percent Ag (reflected light). E. Orpiment and stib-
nite in late-ore stage calcite (transmitted light) and orpiment and fluid inclusions in late ore-stage calcite. F. Grains of HgTe
and AgTe surrounding ore and preore pyrite.
drusy quartz and stibnite, this quartz commonly fills fractures 1000000
TABLE 3. Electron Microprobe Analyses of Meikle Lower Main Zone Ore-Stage and Late Ore-Stage Minerals
Au As Fe S Ag Sb Zn Cu Total
Sample no. Mineral Stage (wt %) (wt %) (wt %) (wt %) (wt %) (wt %) (wt %) (wt %) (wt %)
1300-gp1 Pyrite OS 0.27 4.03 44.13 49.57 b.d. 0.33 0.07 b.d. 98.41
1300-gp2 Pyrite OS 0.21 3.19 43.86 50.38 0.12 0.55 0.05 0.05 98.41
1300-gp3 Pyrite OS 0.23 3.33 43.63 49.21 0.15 0.70 0.01 0.08 97.33
1300-p4 Pyrite OS 0.35 4.34 43.58 49.18 0.19 0.37 b.d. 0.05 98.06
1300-p4 Pyrite OS 0.37 4.35 43.50 49.55 0.01 0.43 b.d. 0.04 98.24
21-1100 Pyrite OS 0.04 1.06 46.97 53.56 0.05 0.01 b.d. b.d. 101.68
21-1100 Pyrite OS 0.23 3.32 44.66 50.57 b.d. b.d. 0.01 0.30 99.09
21-1100 Pyrite OS 0.06 3.30 45.34 51.33 b.d. b.d. 0.04 b.d. 100.07
21-1100 Pyrite OS 0.05 2.35 45.46 52.38 b.d. b.d. 0.04 0.05 100.32
ex92-904 Pyrite OS 0.03 7.51 43.16 47.78 0.12 0.42 0.03 0.08 99.14
ex92-904 Pyrite OS 0.04 0.90 46.35 53.41 0.07 b.d. 0.07 0.08 100.91
ex53-1501 Pyrite OS 0.12 2.54 45.00 51.33 0.08 0.39 b.d. 0.29 99.75
ex53-1501 Pyrite OS 0.25 4.10 44.80 50.36 b.d. 0.38 0.05 0.28 100.22
ex53-1501 Pyrite OS 0.26 4.03 44.32 49.70 0.14 0.74 0.11 0.30 99.60
ex53-1501 Pyrite OS 0.29 3.67 44.35 49.99 0.04 0.34 b.d. 0.28 98.97
ex53-1501 Pyrite OS 0.04 2.11 46.43 53.08 0.04 0.02 0.02 0.07 101.81
ex53-1501 Pyrite OS 0.11 0.57 46.12 53.12 b.d. 0.03 0.03 0.05 100.02
ex53-1501 Pyrite OS 0.09 0.68 45.36 51.87 b.d. 0.04 0.04 0.01 98.09
ex53-1501 Pyrite OS 0.19 3.19 43.59 37.12 0.10 0.09 0.21 0.04 84.53
ex53-1501 Pyrite OS 0.10 1.35 43.52 50.16 0.07 1.43 b.d. 0.06 96.69
ex53-1501 Pyrite OS 0.08 1.33 43.60 49.89 0.03 1.48 0.02 0.03 96.46
92-1009 Pyrite OS 0.09 4.99 44.68 49.96 b.d. 0.02 b.d. 0.03 99.77
92-1009 Pyrite LO b.d. 1.93 45.46 52.36 b.d. 0.21 0.01 0.09 100.05
92-1009 Pyrite LO 0.05 3.16 45.53 51.74 0.04 0.02 0.09 0.07 100.69
1300-p1 Pyrite LO 0.02 0.43 46.77 53.17 0.07 0.15 0.03 0.01 100.64
1300-p2 Pyrite LO b.d. 1.45 46.28 52.62 0.06 0.11 b.d. 0.06 100.57
1300-p3 Pyrite LO b.d. 0.40 45.71 52.48 0.08 0.18 b.d. b.d. 98.85
1300-p4 Pyrite LO b.d. 0.46 44.71 52.79 0.11 1.16 b.d. b.d. 99.23
1300-lp5 Pyrite LO 0.04 1.18 45.40 52.48 b.d. 1.32 b.d. b.d. 100.42
1300-p6 Pyrite LO b.d. 1.36 46.28 52.81 b.d. 0.06 0.06 b.d. 100.56
1300-p7 Pyrite LO 0.04 1.57 45.54 52.08 0.05 0.55 0.02 b.d. 99.85
1300-p8 Pyrite LO b.d. 0.60 45.83 51.57 0.08 0.74 b.d. 0.01 98.82
92-1009 Pyrite LO b.d. 1.42 45.40 52.76 0.08 0.14 0.01 0.04 99.84
92-1009 Pyrite LO b.d. 0.98 46.40 53.57 0.14 0.23 0.03 0.03 101.39
1300-G Gold LO 84.10 b.d. 0.69 0.53 13.84 b.d. b.d. b.d. 99.16
ex53-1501 Gold LO 87.47 b.d. 0.02 0.04 11.38 b.d. b.d. b.d. 98.90
ex53-1501 Gold LO 87.96 b.d. 0.04 0.05 11.59 b.d. b.d. b.d. 99.64
ex53-1501 Gold LO 87.58 b.d. b.d. 0.02 11.96 b.d. b.d. b.d. 99.56
ex53-1501 Gold LO 87.73 b.d. 0.02 0.01 11.89 b.d. b.d. b.d. 99.65
concentrations have been found at the Deep Star deposit 91 ppm (Tables 3 and 4). SIMS analyses of a late ore-stage
(3,700 ppm Au; Fleet and Mumin, 1997). pyrite sample contained between 1.0 and 54.7 ppm Au
Electron microprobe analyses of ore-stage pyrite yield a (Lamb, 1995). Concentrations of As in the late ore-stage
mean As content of 3.4 wt percent and a mean Sb content of pyrite also are lower than those in ore-stage pyrite and aver-
0.3 wt percent (Table 3). The correlation between As + Sb age 1.2 wt percent, whereas Sb is significantly higher, averag-
and S indicates that these elements are present as substitu- ing 0.95 wt percent. Although lower than in ore-stage pyrite,
tions for sulfur in the pyrite (Emsbo, 1999). Similarly, a linear mean contents of the other ore-related elements are still high
correlation of Au and Fe suggests that Au is present as a solid in late-stage pyrite (262 ppm Hg), (26.7 ppm Ag), (125 ppm
solution in the pyrite lattice in agreement with the interpre- Tl), (15.5 ppm Te). Base metals and U are elevated in the lat-
tation of Fleet and Mumin (1997). LA-ICP-MS analyses of est ore-stage, Au-poor pyrite.
ore-stage pyrite yield high average concentrations of Hg (858 Concentrations of As, Ag, Sb, Hg, Tl, W, and Te are all con-
ppm), Ag (179 ppm), Tl (791 ppm), Te (61 ppm), and W (6.8 sistently high in ore-stage pyrite containing >1,000 ppm Au
ppm) (Table 4). The concentrations of these elements also are (Table 4); however, concentrations of these elements de-
proportional to those measured in hand samples and correlate crease linearly with Au from ore-stage to late ore-stage pyrite.
with Au contents. Base metals, Ni, and Co contents are low Ag/Au ratios are generally consistent (ca. 10) through the par-
and show no correlation with Au. Bi was below detection agenetic sequence (Table 4) and also correspond to the ratio
(<0.5 ppm) by LA-ICP-MS. in late ore-stage native Au (Table 3). Interestingly, Te de-
Gold contents of late ore-stage pyrite that precipitated in creases linearly with Au content but increases dramatically in
open space range from < 0.2 ppm to 400 ppm with a mean of late ore-stage pyrite. In samples of ore-stage pyrite that con-
TABLE 4. LA-ICP-MS Analysis of Meikle Lower Main Zone Ore-Stage and Late Ore-Stage Pyrite and Altered Igneous Rocks
Ag As Au Bi Cu Hg Pb Sb Te Tl U W Zn
Sample no. Stage (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm)
Pyrite analyses
1300A OS 210 18,000 2,068 0.1 380 990 51 4,200 39 670 0.1 0.1 100
1300A OS 250 25,000 2,288 0.1 800 800 57 3,100 62 590 0.1 0.1 39
1300A OS 430 25,000 2,508 0.1 790 1,200 100 4,800 98 770 9.9 37.0 10
1300A OS 330 47,000 2,068 0.1 850 1,800 120 5,200 120 670 55.0 26.0 99
1300A OS 200 32,000 1,716 0.1 560 1,500 170 3,800 130 440 45.0 22.0 32
1300C OS 280 21,000 2,244 0.1 550 1,200 65 4,100 100 940 82.0 23.0 37
1300C OS 360 33,000 3,564 0.1 960 1,600 120 6,500 110 920 76.0 23.0 39
1300C OS 310 24,000 2,904 0.1 940 930 82 4,400 84 700 80.0 30.0 30
1300C OS 250 12,000 1,408 0.1 340 660 47 3,300 53 440 42.0 25.0 30
1300C OS 91 22,000 880 0.1 1,000 2,000 190 11,000 17 320 46.0 0.1 30
ex21-1281 OS 120 25,000 1,900 0.1 480 360 480 4,900 64 920 0.7 8.9 20
ex21-1281 OS 120 24,000 1,600 0.1 580 340 66 4,300 70 1,000 0.7 3.7 10
ex21-1281 OS 140 26,000 1,800 0.5 590 400 66 6,500 66 1,000 0.6 3.8 5
ex21-1281 OS 130 24,000 1,500 0.1 340 370 43 4,100 50 830 0.2 0.1 5
ex21-1281 OS 41 20,000 820 0.1 340 560 43 9,400 20 450 1.8 2.6 30
ex21-1281 OS 39 21,000 620 0.4 530 490 140 17,000 23 560 0.8 1.1 84
ex21-1281 OS 74 32,000 2,800 0.1 830 380 110 7,000 42 1,200 1.0 5.2 30
ex21-1281 OS 62 30,000 1,500 0.1 720 560 80 10,000 31 1,100 0.7 7.4 49
ex21-1281 OS 78 32,000 1,500 0.1 600 570 63 11,000 29 1,200 5.4 2.9 10
ex21-1281 OS 65 21,000 1,100 0.1 290 450 24 7,700 14 1,100 1.5 1.1 5
39-1543 LO 0.1 27,000 0.6 0.5 88 270 7.1 10,000 21 71 12.0 3.1 360
39-1543 LO 0.1 32,000 1.4 0.3 130 280 5.2 13,000 18 87 12.0 0.1 500
39-1543 LO 2.2 28,000 1.1 0.4 130 230 6.9 11,000 17 59 19.0 1.7 460
39-1543 LO 0.1 26,000 1.1 0.6 160 330 6.7 12,000 18 83 9.4 0.4 320
39-1543 LO 0.1 26,000 1.1 0.1 110 230 6.2 11,000 31 56 32.0 2.6 360
39-1543 LO 0.1 24,000 1.2 0.5 150 220 4.7 11,000 13 64 19.0 1.2 500
39-1543 LO 0.1 25,000 0.8 0.1 110 270 4.7 12,000 2 73 19.0 0.1 440
39-1543 LO 1.5 24,000 1.2 0.3 160 210 3.7 11,000 20 70 15.0 0.1 470
39-1543 LO 1.8 34,000 0.2 0.1 51 220 12 20,000 18 96 21.0 2.6 94
1300C LO 40 6,200 220 0.1 40 460 20 4,000 1 280 4.0 6.8 30
1300C LO 40 7,100 110 1.0 30 350 63 3,000 1 280 7.7 2.8 30
1300C LO 25 23,000 18 0.1 36 690 1.1 4,500 1 610 0.1 0.1 34
Crush LO 29 24,000 240 0.1 830 100 51 2,600 5 15 41.0 32.0 98
Crush LO 28 30,000 400 0.1 1,700 37 66 16,000 56 6.8 11.0 14.0 250
Crush LO 73 41,000 370 0.1 990 40 33 1,300 12 20 54.0 14.0 69
Abbreviations: L = lamprophyre, LO = late ore stage, M = monzonite, n.a. = not analyzed, OS = ore stage
tain >1,600 ppm Au there is little variation in As/Sb, whereas gests that Fe was introduced by another fluid. This interpre-
pyrite with lower Au concentrations shows a progressive de- tation is supported by the elevated base metal and U contents
crease in As/Sb with decreasing Au into the latest stages (Fig. of the late pyrite. The high U contents (as much as 40 ppm)
15C). The decrease in As/Sb with decreasing Au suggests that in the late ore-stage pyrite suggest that the inferred second
As was progressively depleted from the ore fluids as ore-stage fluid was relatively oxidized, because a reduced fluid can
pyrite precipitated (Emsbo, 1999). The increasing Sb con- carry only low concentrations of U (Hem, 1986).
centration in late ore-stage pyrite is consistent with the pre-
cipitation of stibnite late in the paragenetic sequence (see Isotopic Composition of Ores
also, Theodore et al., 2003). Similarly, the Te spike in late-
stage pyrite correlates with the appearance of telluride min- The δ18O values of ore-stage minerals
erals. The occurrence of minor late ore-stage pyrite in open The δ18O values of ore-stage minerals are distinct from
spaces suggests that, unlike main ore-stage pyrite, this pyrite those of other paragenetic stages (Tables 1, 5, and 6). Ore-
did not form by sulfidation of host-rock Fe. Instead, it sug- stage quartz from Meikle has an average δ18O value of 5.7
TABLE 5. δ18O and δD Analyses of Quartz, Clay, and Fluid Inclusion Water
Sample Deposit Mineral δ18O (‰) δD (‰) δ18OH2O (‰) δ18OH2O1 (‰) δDH2O2 (‰)
Discordant Sedex
EX6C-1250.5 Meikle Quartz 14.0
GB647-1464 Meikle Quartz 12.3
GB39-1342 Meikle Quartz 11.5
EX6C-1250.5 Meikle Quartz 12.2
Early Mississippian diagenesis and petroleum migration
GB539-1338W Meikle Quartz 19.7
GB541-1410 Meikle Quartz 23.4
GB600-958 Meikle Quartz 19.4
GB732-1219 Rodeo Quartz 22.8
GB720-1082 Rodeo Quartz 22.0
Late Jurassic polymetallic mineralization
BASE B-P Quartz 15.9
BASE 2 B-P Quartz 14.2
Ore stage
Ex30-2310 (<0.5) Meikle K, I 3.1 –142.0 –2.2 –126.0
Ex30-2310 (1–0.5) Meikle K, I 4.1 –162.0 –1.4 –142.0
Ex30-2328 (<0.5) Meikle K, I 4.0 –152.0 –1.4 –134.5
Ex30-2328 (1–0.5) Meikle K, I –159.0 –141.5
5040-1 (1–0.5) B-P C, I/S, K –146.0 –130.0
5040-1 (<0.5) B-P C, I/S, K 1.0 –154.0 –4.7 –138.0
5040-2 (1–0.5) B-P I/S, K –143.0 –123.0
5040-2 (<0.5) B-P I/S, K 0.5 –152.0 –5.1 –134.5
1300-3475A Meikle Quartz 5.6 –4.9
1300-3475B Meikle Quartz 5.5 –5.0
EX21-1252 Meikle Quartz 4.0 –6.4
EX92-1685 Meikle Quartz 8.0 –2.5
EX21-1252 Meikle Quartz 5.5 –4.9
EX91B-1041 Meikle Quartz 7.6 –2.8
Mixed paragenesis
EX53-1501 Meikle WQuartz 21.5
EX-21-1100 Meikle WQuartz 13.4
GB783-1349 Meikle WQuartz 17.4
GB720-1040 Meikle WQuartz 21.9
EX53-1501 Meikle WQuartz 20.6
GB783-1363 Meikle WQuartz 15.0
1300-3475B Meikle WQuartz 5.5
Late ore stage
GB-605-921 Meikle Quartz3 –142.0
GB-600-951 Meikle Stibnite3 –142.0 –19.0
Crush Meikle Stibnite3 –146.0 –14.5
GB-600-950.5 Meikle Quartz3 –137.0
GB-605-921.1 Meikle Quartz3 –144.0
POSTORP B-P Orpiment3 –135.4 –15.9
1175-LS1 Meikle Quartz 6.5 –6.5
CRUSH-B Meikle Quartz 5.4 –7.6
GB539-1338(S) Meikle Quartz 5.0 –8.1
CRUSH-CL Meikle Quartz 4.6 –8.4
1300-3475L Meikle Quartz 3.2 –9.8
GB39-1543 Meikle Quartz 3.2 –9.8
1225-LS1 Meikle Quartz 2.3 –10.7
GB-605-909.5 Meikle Quartz 0.1 –12.9
GB39-1543 Meikle Quartz 1.6 –11.4
Abbreviations: B-P = Betze-Post, C = chlorite, I = illite, K = kaolinite, S = smectite, WQuartz = whole-rock quartz
1 Calculated from ore-stage (220°C) and late ore-stage (180°C) quartz using Zheng (1993), ore-stage clay (220°C) using Sheppard and Gilg (1996)
2 Calculated at 220°C, using Sheppard and Gilg (1996)
3 Fluid inclusion water
per mil (range 4.0–8.0‰). Late ore-stage calcite from Gold- calcite, average –4.7 per mil (range –6.4 to –2.5‰; Fig. 16).
strike has an average δ18O value of 5.1 per mil (range 3.4– The δ18O compositions of clay minerals from mineralized in-
6.7‰). Fluid δ18OH2O values calculated using the fractiona- trusive rocks from Meikle and Betze-Post range from 4.1 to
tion factors of O’Neil et al. (1969) and Zheng (1993), assum- 0.5 per mil (Table 5). The clay mineral-water fractionation fac-
ing mineral precipitation at 220°C for quartz and 200°C for tors of Sheppard and Gilg (1996) for 220°C yield fluid δ18OH2O
Number of analyses
16 1164 Meikle B. Lim 24.9 0.3 6
LIMALSO Meikle Pop. Lim 22.7 –0.82
MP1CC Meikle Pop. Lim 23.7 –0.78
MP1 1120 Meikle Pop. Lim 24.4 –0.94 5
GB666 1327 Meikle Pop. Lim 24.6 –0.5
GB732 1227 Rodeo Pop. Lim 22.9 –1.9 4
GB732 1210 Rodeo Pop. Lim 21.2 –1.9
EL5060 B-P Lamp. Dol 20.9 –4.8
Discordant Sedex
3
1075-3575 Meikle ZDol 14.2 –2.2
1075-3575 D A Meikle ZDol 13.8 –2.9 2
1075-3575D B Meikle ZDol 14.3 –2.9
1175 LS-1A Meikle ZDol 13.4 –1.2
1175 LS1 B Meikle ZDol 13.5 –0.6 1
1175 LSL Meikle ZDol 13.6 –1.6
L-1225 LS-1B Meikle ZDol 13.4 –2.2 0
EX21C-1198 A Meikle ZDol 11.1 –1.3
EX21C 1281A Meikle ZDol 12.0 –2.5 -20 -15 -10 -5 0 5 10 15 20 25 30
EX21C-1281 B Meikle ZDol 13.1 –3.2 δ18O (SMOW)
EX21C-1066A Meikle ZDol 14.5 –3.0
EX21C-1066B Meikle ZDol 12.4 –3.0 FIG. 16. Stacked histogram of calculated δ18O values for ore-stage fluids
EX21C-1066C Meikle ZDol 16.0 –1.6 in equilibrium with quartz, clay minerals at 220°C, and late ore-stage calcite
EX21C-1066D Meikle ZDol 14.0 –2.3 at 200°C from Meikle and Betze-Post. Fractionation factors from O’Neil et
EX92 1042.5A Meikle ZDol 17.2 –1.9 al. (1969) and Zheng (1993) for quartz and calcite and Sheppard and Gilg
EX92 1233.7A Meikle ZDol 12.3 –1.3 (1996) for clay minerals. Data from Table 5 and Arehart et al. (1992).
EX92 1233.7B Meikle ZDol 12.1 –3.1
Ex92-1218A Meikle ZDol 12.6 –1.7
EX92 1218B Meikle ZDol 11.4 –1.9
EX92-1218B Meikle ZDol 12.0 –1.7 values of –5.1 to –1.4 per mil. These values are consistent
GB548 1270A Meikle ZDol 13.7 –1.9
GB548 1270B Meikle ZDol 12.6 –1.4 with the values obtained from analyses of clay in mineralized
GB548 1270C Meikle ZDol 13.6 –1.0 Betze-Post samples (Arehart et al., 1993a). Recalculations of
MV-1 1262.5A Meikle ZDol 10.6 –1.5 data from Arehart et al. (1993a), using the same tempera-
ZEB Meikle ZDol 14.0 –1.9 ture and fractionation factors employed here, yield fluid
EX92 1042.5B Meikle ZDol 15.2 –5.2
δ18OH2O values of –5.2 to 1.1 per mil. Thus, the δ18OH2O
Early Mississippian diagenesis and petroleum migration
MP1-1116 Meikle Dol 19.3 –1.2 value of ore-stage fluids calculated from all ore-stage miner-
GA 43-1328 B GA Dol 19.5 –0.3 als on the Goldstrike property is –3.5 ± 2.9 per mil (Fig. 13).
GA43 1328A Meikle Dol 21.5 –0.6 The calculated δ18OH2O values for the ore-stage fluids are
GB1647 Meikle Dol 19.3 –2.6 higher than the measured δ18O values of fluid inclusion
Ore-stage altered host rocks water extracted from late ore-stage orpiment (–15.9‰)
1225 LS-1A Meikle ZDol 10.9 –2.4
1225 LS-1B Meikle ZDol 10.3 –0.4 from Betze-Post and from stibnite (–19 and –14.5‰) from
1225 LS-1C Meikle ZDol 9.0 –0.2 Meikle. Late ore-stage drusy quartz with stibnite and pyrite
1225 LS1D Meikle ZDol 9.6 0.0 generally has lower δ18O values than ore-stage quartz, aver-
L-1225 LS-1A Meikle ZDol 11.5 –2.7 aging 2.0 per mil (range 3.2–0.1‰). It is therefore likely
EX21C 1198B Meikle ZDol 11.6 –0.8
EX21C 1066D Meikle ZDol 9.6 –1.0 that this quartz records the δ18OH2O value decrease from ore
GB598-1333 A Meikle ZDol 7.6 0.4 stage to late ore stage; however, two samples of stibnite-
GB732 1219 Rodeo Pop. Lim 16.8 –1.4 bearing late ore-stage quartz have higher δ18O values (as
G539-1497 Meikle Lamp. Dol 5.8 0.8
DDFINE Meikle B. Lim 3.4 2.6
much as 7‰), similar to those of ore-stage quartz (Table 5).
DCOARSEWHT Meikle B. Lim 4.7 3.2 High-grade cave-fill ore from Meikle and preore jasperoids
Late ore stage cut by Carlin-type mineralization exhibit a range of whole-
BZ-921 960 Meikle Calcite 6.2 –7.5 –3.3 rock oxygen isotope compositions, most likely dominated by
WB-15 1127A Meikle Calcite 4.8 2.1 –4.8 preore quartz with high δ18O values (Table 5 and Fig. 13C-
WB-15 1127B Meikle Calcite 4.8 2.5 –4.8
WB-4C 1776 Meikle Calcite 3.4 2.7 –6.1
D). These data call into question prior interpretations from
GB 760 1232 Meikle Calcite 6.7 2.8 –2.8 previous studies that jasperoids with high δ18O isotope values
MV-1 1262.5VEIN Meikle Calcite 3.9 2.7 –5.7 are ore stage.
GB666 1327 Meikle Calcite 5.0 1.8 –4.5
The δD values of clay minerals and fluid inclusion water
Abbreviations: B = Bootstrap limestone, B-P = Betze-Post, Dol = dolomite, The isotopic compositions of water in equilibrium with clay
GA = Golden April, Lamp = lamprophyre, Lim = limestone, Pop = Popovich
Formation, ZDol = zebra dolomite minerals in mineralized igneous rocks were calculated using
1 Calculated at 200°C, using fractionation factor from O’Neil et al. (1969) fractionation factors in Sheppard and Gilg (1996) at 220°C.
Because clay minerals from the mineralized igneous rocks such low values are compelling evidence that the hydrothermal
contain mixtures of kaolinite, smectite, and illite, estimates of fluids were of meteoric origin (Taylor, 1979). The δ18OH2O val-
their relative proportions were made using XRD. Calculated ues calculated from ore-stage quartz and clay minerals are
fluid δDH2O values for the finest clays (<0.5 µm) are –134 to shifted 10 to 20 per mil from the meteoric water line due to ex-
–139 per mil (Table 5 and Fig. 17). These values are similar change with sedimentary carbonate rocks at ca. 220°C and a
to the measured δD value of –135 per mil for fluid inclusion water to rock ratio (W/R) as high as 1 (Taylor, 1979).
water in late ore-stage orpiment. Fluid δDH2O compositions These calculated ore-stage δ18OH2O and δDH2O values in-
recalculated from data on clay minerals in mineralized sam- clude those from two samples from the deepest mineralized
ples from Betze-Post (Arehart et al., 1993a), using the frac- lamprophyre dike (710 m) known at Meikle (samples EX30-
tionation factor for kaolinite at a temperature of 220°C, yield 2310 and EX30-2328 in Table 5). These samples were analyzed
values ranging from –130 to –138 per mil that are similar to to test for indications of a deeply sourced magmatic or meta-
the results of this study (Fig. 17). The δD values of fluid in- morphic ore fluid that might have been masked by dilution
clusion water in late ore-stage quartz and stibnite from this with meteoric water. No isotopic evidence for a deeply sourced
study range from –139 to –146 per mil and are slightly lower fluid was found (Fig. 17). Considering the huge volume of hy-
than those from other ore-stage minerals. drothermal fluid that would have been required to transport
The δDH2O value calculated for the finest clay fraction and the the amount of Au present in these deposits, it seems unlikely
measured values for fluid inclusion waters in ore-stage minerals that a significant component of magmatic or metamorphic ore
from both Meikle and Betze-Post are indistinguishable, and fluid would have left no isotopic trace. All δ18O and δD data
A B
0 SMOW
Metamorphic Water
-20
e
Lin
ter
Wa
Late Ore-Stage Quartz Fluid Inclusion s
ric
Supergene
-60
teo
Alunite, NV
Me
60 to 170 Ma
e
Lin
ite
-100
25°
C
Tuscarora, NV
-120
Supergene Lone Mnt, NV
-140 Kaolinite
-20 -10 0 10 20 30 10 20 30 40 50 60
Range From Ore-Stage Qtz & Calcite (220° C) Ma
Range From late ore-stage Qtz (180° C)
δ18O (SMOW)
FIG. 17. A. The δ18O and δD values calculated for ore fluids based on data from ore-stage clay minerals in the Meikle
and Betze-Post deposits at 220°C (closed circles) and measured in late ore-stage fluid inclusions (squares) (Table 5). Also
plotted are values for ore-stage fluids calculated from ore-stage clays (open circles) and supergene kaolinite (stars) in Betze-
Post from Arehart et al., (1992). The δD values from late ore-stage fluid inclusions in quartz are plotted left of the y-axis;
the range of δ18O values calculated from ore-stage quartz and calcite at 220°C and late ore-stage quartz at 180°C (Table 5)
are shown below the x–axis. Field for ore-stage fluids (gray) includes δD values from the smallest clay fraction in the most
strongly mineralized samples from Meikle and Betze-Post and all ore-stage quartz and calcite δ18O data. Field for late ore-
stage fluids includes all fluid inclusion and late ore-stage quartz data. Fractionation factors from O’Neil et al. (1969) and
Zheng (1993) for quartz and calcite and from Sheppard and Gilg (1996) for clay minerals. B. The δD age curve with δD
values for two meteoric water-dominated epithermal deposits (Tuscarora and Lone Mountain) dated at 38 and 39 Ma (mod-
ified from Hofstra et al., 1999). The intersection of δD values for the ore-stage and the lower δD values from the late ore-
stage minerals constrains the age of Carlin-type mineralization to the older intercept on the δD age curve between ca. 40
and 35 Ma. See text for discussion.
δ13C ‰ (PD B )
tral Nevada has varied dramatically over the past 170 m.y. due
to climatic changes (Hofstra et al., 1999), with cooler climates
resulting in lower δD values. A distinct meteoric water δD -2
low at 30 Ma coincides with glacial buildups in Antarctica and
a drop in worldwide sea level (Prothero, 1994). Comparison
of the low δD values measured in this study with the δD age
-4
curve supports the mid-Tertiary age of mineralization (Fig.
17). The lower δD values from the late ore-stage minerals
constrain the age to the older intercept on the δD age curve
(40–35 Ma). Supergene alunite as old as 26 to 30 Ma (Arehart -6
et al, 1992; Heitt, 1992) cuts ore at Gold Quarry and also sug-
gests that the mineralization corresponds to the older intercept.
The tightly constrained δD values from this study are also in-
-8
distinguishable from the ca. –135 per mil value that has been 0 5 10 15 20 25
found in fluid inclusions in quartz from 39 Ma epithermal Au- δ18O ‰ (SMOW)
Ag veins at Tuscarora, Nevada, and the –139 per mil value
found in fluid inclusions in quartz from 38 Ma quartz veins from FIG. 18. Plot of δ13C vs. δ18O values for Goldstrike carbonate minerals.
Data are from Table 6 and Emsbo and Hofstra (2003). Fields represent dif-
Lone Mountain, Nevada (Hofstra et al., 1997; Fig. 17B). Alter- ferent paragenetic stages. Large arrows show trends from host-rock values to
ation clay minerals from mineralized biotite feldspar porphyry hydrothermal minerals. Dashed arrows are tie lines between unaltered and
dikes yield δD and δ18O values indistinguishable from those mineralized rocks. Lamp. = lampropyre.
measured in mineralized samples at Goldstrike. These data,
combined with petrographic and geochemical evidence, are
compelling evidence that the 39 Ma biotite feldspar porphyry Late ore-stage calcite is isotopically distinct from preore car-
dike at Betze-Post was mineralized shortly after its emplace- bonate minerals. The δ18O values of the calcite, however, are
ment by the same hydrothermal fluids that formed Meikle. similar to those of ore-stage quartz and alteration clays on the
The δDH2O values inferred from supergene kaolinite and Goldstrike property and δ18O values of carbonate minerals in
alunite isotopic compositions (Arehart et al., 1992) constrain altered host rocks in other Carlin-type deposits in Nevada
the age of supergene weathering to ca. 10 Ma (Fig. 17). (Rye, 1985; Ilchik, 1990; Hofstra, 1994; Arehart, 1996). The
δ13C values of late ore-stage calcite are higher than those of
The δ13C and δ18O values of ore-stage and carbonate minerals in unaltered Bootstrap limestone and sig-
late ore-stage carbonate minerals nificantly higher than those of carbonate minerals in unaltered
No samples of late ore-stage calcite were available for analy- Popovich Formation. In contrast, most decarbonation trends
sis at Meikle; however, veins of late ore-stage calcite in the associated with pluton-related ore deposits progress toward
Popovich Formation from elsewhere on the Goldstrike prop- lower δ18O and δ13C values (Taylor, 1987). The high δ13C val-
erty yield δ18O values of 3.4 to 6.7 per mil, which are consis- ues of late ore-stage calcite veins are surprising given that they
tent with those of other ore-stage minerals (Table 6 and Fig. typically are present at the periphery of decalcified zones in
16). The δ13C values of these veins are 2 to 3 per mil (Table 6 the Popovich Formation and should be buffered by its low
and Fig. 18). One sample has a δ13C value of –7.5 per mil but δ13C values. The anomalous compositions might have resulted
a δ18O value of 6.2 per mil that is consistent with other ore- from (1) contribution of CO2 with a high δ13C value from
stage samples. The δ13C and δ18O values of carbonate miner- unidentified external sources (Arehart, 1996), (2) boiling, (3)
als in altered and mineralized rocks reflect varying degrees of decreasing temperature, or (4) decrease in CO2/CH4. Al-
exchange with the ore fluid. For example, original carbonate though CO2 might have entered the ore fluid from external
δ13C and δ18O values in unaltered lamprophyre dikes and in sources, it is likely that the extensive dissolution of carbonate
Bootstrap limestone are shifted toward those of late ore-stage minerals in the Popovich Formation would have resulted in a
calcite in mineralized samples (Fig. 18). The δ13C and δ18O wide range of δ13C values, as documented in other systems
values of mineralized zebra dolomite also exhibit shifts toward with multiple carbon sources (Lohmann, 1988). No evidence
late ore-stage calcite (Fig. 18), although not all samples show of boiling has been recognized in fluid inclusions, and boiling
significant shifts. Several highly mineralized samples show typically results in a wide range of δ13C values. Declining tem-
only minimal exchange with the Carlin-type fluid. Corroded perature could increase δ13C values, although cooling from
dolomite grains in these samples indicate that reprecipitation 200° to 100°C results in an increase of only ca. 2 per mil
of neoformed ore-stage dolomite was inhibited by the acidic (Ohmoto and Rye, 1979). This might account for the high δ13C
ore fluids, thus explaining the lack of significant shifts. values of late ore-stage calcite if carbon was derived from the
Bootstrap limestone but not if carbon was derived from the pyrites analyzed in that study indicate that they were formed
Popovich Formation, which, as indicated by its extensive de- by the Jurassic hydrothermal system (Emsbo, 1999; Emsbo et
calcification, is a more likely source. al., 2000). Massive veins of late ore-stage stibnite from Meikle
Reduction of CO2 in the ore fluid, either at its source or have δ34S values of ca. 6.5 per mil (Table 7 and Fig. 19), al-
during interaction with organic matter in the Popovich For- though some tiny crystals of stibnite have values as low as –32
mation, would decrease CO2/CH4. This mechanism has been per mil. Late ore-stage pyrite also exhibits a wide range in
invoked to explain the high δ13C values of hydrothermal δ34S values, down to –28.1 per mil, similar to SHRIMP data
dolomite in the Pine Point and Gays River carbonate-hosted on late ore-stage pyrite from Arehart et al. (1993a). Orpiment
Pb-Zn deposits (Ohmoto and Rye, 1979). Similarly, extremely and realgar from Betze-Post, South Meikle, Rodeo, and
high δ13C values are known to result from reaction between Golden April have δ34S values that fall mainly between 5 and
hydrocarbons and meteoric fluids (Longstaffe, 1987). A simi- 7 per mil but range between 4 and 11 per mil (Table 7 and
lar trend toward high δ13C for ore-stage calcite in altered or- Fig. 19). A single sample of realgar from Meikle falls within
ganic-rich Pilot Shale in the Alligator Ridge deposit (Ilchik, this range (5.6‰; Evans, 2000).
1990) supports the interpretation that reaction with organic At 220°C, the equilibrium δ34S value of pyrite should be ap-
matter reduced CO2 in the ore fluid. The samples of late ore- proximately 5 per mil higher than those of coexisting orpiment,
stage calcite with low δ13C values (–7.5‰) may reflect CO2 realgar, and stibnite (Hofstra, 1997), consistent with observa-
formed by oxidation of CH4 or organic carbon. tions from the Goldstrike property. The δ34S values calculated
for H2S from these minerals at Meikle and other Goldstrike de-
The δ34S values of Carlin-type sulfide minerals posits is remarkably consistent at 9 ± 1 per mil. This narrow
The majority of δ34S values of ore-stage pyrite from Meikle range of δ34S values and the absence of ore-stage barite indi-
range from 7 to 13 per mil with a mean of 10 per mil (Table cate that H2S was the dominant sulfur species in the ore fluid.
7 and Fig. 19). Five samples of ore-stage pyrite measured by The calculated δ34S value of 9 per mil for H2S in the ore
Evans (2000) also fall within that range. A single lamprophyre fluid at Goldstrike is much higher than that typically found in
sample, containing disseminated, unzoned, Au- and As-rich porphyry Cu deposits in western North America (0 ± 5‰;
pyrite has a δ34S value of –21.6 per mil that is similar to val- Ohmoto and Rye, 1979; Ohmoto and Goldhaber, 1997).
ues for late ore-stage pyrite. The δ34S values of ore-stage Thus, a magmatic source of sulfur seems unlikely. Several au-
pyrite from Betze-Post range from 8 to 11 per mil (Fig. 19), thors have proposed a sedimentary source for the sulfur con-
similar to the results for “ore-stage” pyrite from Arehart et tained in Carlin-type deposits (Rye, 1985; Arehart, 1996;
al.(1993a). Although their (1993a) SHRIMP data extend to Gammons, 1997; Hofstra, 1997), originally derived from Pa-
higher δ34S values (up to 20‰) than those found in this study, leozoic sea-water sulfate and incorporated into sedimentary
the petrographic and geochemical characteristics of most rocks in the form of sulfate and sulfide minerals and organic
sulfur compounds with a wide range of δ34S values (Fig. 20).
H2S could have been generated from any of these sulfur
Meikle Mean H 2S reservoirs and incorporated into a hydrothermal fluid through
(1) hydration of pyrite, (2) alteration of organic matter, (3)
thermochemical sulfate reduction (TSR), and (4) inorganic
5 sulfate reduction by ferrous minerals. Figure 20 demon-
-21.6
strates that several sources of sulfur, individually or in combi-
nation, may have generated H2S with a δ34S value of 9 per mil
0
Number of analyses
In contrast, cooling was important during the late ore stage. realgar saturation. Undersaturation in orpiment and realgar
The progression from regularly shaped fluid inclusions in may also be due to the precipitation of large amounts of ore-
quartz to highly irregular, necked inclusions containing vari- stage As-rich pyrite, resulting in removal of As and H2S from
able liquid/vapor in late quartz can be interpreted in terms of the fluid. This is supported by the As/Sb of Meikle pyrite
decreasing temperatures of deposition (Bodnar et al., 1985). which decreases through the paragenetic sequence. Stibnite
This is consistent with homogenization temperatures that precipitated because it is stable at lower activities of H2S
range from a mean of 220° to a low of 175°C (Lamb, 1995). (Barton and Skinner, 1979). The more abundant late ore-
The occurrence of crystalline quartz throughout the parage- stage quartz at Meikle may result from the extensive porosity
netic sequence (Fig. 14B) supports temperatures above 150° and permeability developed by dissolution and brecciation
to 200°C, as mainly amorphous silica precipitates at lower during ore-stage mineralization. The increased permeability
temperatures (Rimstidt, 1997). Cooling also is indicated by may have promoted greater influx of meteoric water, result-
precipitation of quartz, stibnite, and rare Au, Hg, Ag telluride ing in more efficient cooling of the system and more extensive
minerals since their solubility decreases substantially during precipitation of quartz.
cooling (Rytuba, 1985; Zhang and Spry, 1994).
Simple cooling, however, cannot account for the deposition Genetic Models for Carlin-Type Mineralization
of native gold in late ore-stage quartz because the decrease in Hypotheses previously proposed for the formation of Car-
its solubility between 175° and 220°C is insufficient (Shen- lin-type deposits fall into three general groups advocating
berger and Barnes, 1989); however, oxidation of the ore fluid magmatic, metamorphic, or deeply circulated meteoric waters
could have caused the deposition of significant gold for their generative hydrothermal fluids. Each of these hy-
(Romberger, 1986), which is consistent with mixing of a sec- potheses is evaluated below by comparing the characteristics
ond, more oxidized fluid that introduced Fe, base metals, and of Au deposits formed in each of these environments with the
U. The very low δ34S values of some late ore-stage sulfide geologic observations, data, and interpretations of this study.
minerals also are consistent with oxidation. Together, the evi-
dence indicates that the ore fluid progressively mixed with a Magmatic origin
cooler, low-salinity, slightly oxidized, unexchanged meteoric Radtke et al. (1980), Alvarez and Noble (1988), Arehart et
fluid during the waning stages of the hydrothermal system. al. (1993b), Sillitoe and Bonham (1990) and Ressel et al.
(2000) have proposed that magmas provided the fluids, ore
Comparison of Meikle with Betze-Post components—including gold, and the thermal energy to drive
The mineralogy and geochemistry of ore in intrusive rocks fluid flow that transported and deposited gold beyond the
from Betze-Post and Meikle are indistinguishable and indi- “source” intrusion.
cate interaction with fluids similar to those that produced There is no evidence for a large synmineralization, late
high-grade ore hosted in sedimentary rocks. The isotopic sig- Eocene intrusive center underlying Goldstrike. Magnetic
natures of the deposits are also indistinguishable, and the anomalies, the regional pattern of apatite fission-track ages,
fluid inclusion homogenization temperatures and salinities and the size and distribution of Eocene dikes all indicate that
reported by Lamb (1995) are very similar, except perhaps for the nearest substantial magmatic center is >12 km southeast
a slightly higher mean temperature at Meikle. The dominant of Goldstrike (Ressel et al., 2000; Bettles, 2002; Chakurian et
ore depositional mechanism in both deposits was sulfidation al., 2003). Despite the extraordinary spatial density of drill
of reactive Fe to form the disseminated, auriferous, As-rich holes to depths of 750 to 1,000 m, there is no evidence of the
pyrite. styles and zoning of mineralization, alteration, and geochem-
Collectively, the data provide strong evidence that the hy- istry observed in intrusion-related hydrothermal systems.
drothermal fluids which formed Betze-Post and Meikle were Moreover, fluid inclusion studies and stable isotope studies
part of the same hydrothermal system. Differing sites of ore have failed to detect variable salinities or evidence of mag-
deposition, host-rock compositions, evolving fluid composi- matic H2O, CO2, or H2S.
tions, and the relative importance of different depositional
processes can explain their differences. Betze-Post is much Metamorphic origin
larger than Meikle and is hosted predominantly in calcareous The second group of hypotheses involves the generation of
rocks of the Popovich Formation, with smaller amounts of ore H2O, CO2, and H2S fluids by deep-seated metamorphic de-
in the Goldstrike stock and adjacent calc-silicate rock and volatilization of sedimentary rocks. These fluids are thought
hornfels. Meikle, on the other hand, is hosted primarily in to be generated by prograde metamorphism, with heat pro-
dolomitic breccias with some ore in lamprophyre and mon- vided by magmatism,and discharge triggered by crustal ex-
zonite dikes. The presence of marcasite in Betze-Post may re- tension. The fluids are thought to have scavenged gold from
flect lower temperatures. Alternatively, the stock and some of metasedimentary rocks and flowed upward to shallower lev-
the more siliciclastic strata at Betze-Post were less efficient els along major extensional faults where gold deposition may
buffers of pH than were the dolomites at Meikle, thus allow- have occurred (Seedorff, 1991; Groves et al., 1998).
ing the ore fluids to remain acidic and thereby favoring pre- Some characteristics of orogenic gold deposits are shared
cipitation of marcasite (Barton and Skinner, 1979). Precipita- by northern Carlin-trend deposits. During mid-Tertiary time
tion of realgar, orpiment, and stibnite are primarily controlled the regional stress regime changed from contraction to exten-
by cooling of the ore fluid. The absence of late ore-stage or- sion, providing favorable conditions for migration of meta-
piment and realgar and the presence of stibnite at Meikle morphic fluids from the lower or middle crust into the upper
may be due to cooling at temperatures above orpiment and crust (Seedorff, 1991; Hofstra, 1994). Many orogenic deposits
lie along transcontinental fault zones (Groves et al., 1998; tures (= 300°C) would cause extensive exchange between the
Goldfarb et al., 2001) similar to the 60-km-long, deep-pene- fluid and sedimentary rocks, resulting in δ18O values signifi-
trating structural zone that occurs along the Carlin trend cantly higher than those obtained.
(Grauch, 1998; Rodriguez, 1998; Wooden et al., 1998). Also, As noted above, deep circulation of meteoric water would
many geochemical characteristics of orogenic gold deposits, also result in high concentrations of SiO2 and widespread pre-
including the low salinity and high H2S contents of the fluids, cipitation of quartz which is not found in the ore-stage Car-
an Au/Ag of ca. 10, and an increase in As, Hg, Te, and low lin-type mineralization. Mass balance calculations on the
base metal contents (Groves et al., 1998), are similar to those basis of solubility estimates for gold and silica in such an ore
of northern Carlin trend deposits. Although carbonate and fluid demonstrate the magnitude of this problem. Using the
sericite alteration in mesothermal deposits differs from the most conservative values modeled by Ilchik and Barton
decalcification and argillic alteration found here, this differ- (1997), namely the highest gold and lowest quartz solubilities,
ence may result from lower temperatures and pressures and the fluid fluxes at the site of ore deposition would have
reaction with carbonate rocks. In addition, the δ34S values required that rocks containing 100 g/t Au be completely
from Carlin-type deposits are the same as those of underlying silicified. This is clearly at odds with the fact that virtually no
Paleozoic sedimentary rocks and are consistent with an oro- silica precipitated during formation of high-grade ore. A low
genic model in which H2S is derived from metasedimentary W/R (ca. 1) is also problematic because the average crust con-
rocks. tains 3 ppb Au, and even assuming 100 percent extraction, at
Many inconsistencies, however, exist between the meta- this W/R the fluid could not have contained more than 3 ppb
morphic hypotheses and the results of this study. For exam- Au. Formation of these spectacular deposits from an ore fluid
ple, δ18O and δD values of metamorphic fluids typically range with such a low gold content is difficult to envision.
between 10 to 20 per mil and 0 to –70 per mil, respectively
(Taylor, 1987), and are clearly higher than the values reported A new genetic model for Carlin-type deposits at Goldstrike
here. Most importantly, the δD values that cluster tightly None of the prior hypotheses for formation of Carlin-type
around –135 per mil preclude deeply sourced metamorphic deposits is completely consistent with the data and observa-
water. Metamorphic hydrothermal systems at shallow crustal tions of this study. The occurrence of both Devonian aurifer-
levels, even in districts with significant mixing with meteoric ous sedimentary exhalative and mid-Tertiary Carlin-type min-
water, typically show higher δD values, characteristic of the eralization in the same rocks is intriguing. It raises the
metamorphic component (Groves et al., 1998). In addition, possibility that the rocks underlying the Carlin trend influ-
δ13C values of carbonate minerals in metamorphic gold de- enced the generative fluids of two unrelated hydrothermal
posits range between –22 to –0.5 per mil and average ca. –3 systems, separated in time by 300 m.y., to conditions favor-
per mil (Ohmoto and Rye, 1979), very different from the pos- able for gold transport (Emsbo et al., 1999).
itive values observed in Carlin-type deposits. The huge vol- We have previously suggested that the sedimentary exhala-
umes of water that would have been required to transport the tive occurrences provided a preenriched source of gold and of
gold in these deposits make it unlikely that isotopic evidence many of the associated trace elements (As, Sb, Ag, Hg, Tl) for
of a metamorphic ore fluid could be completely obscured. Fi- Carlin-type deposits (Emsbo et al., 1999). The presence of an
nally, the lack of quartz in Carlin-type ores is inconsistent with original gold enrichment in these rocks might explain the oc-
derivation of the ore fluid from depth because metamorphic currence of multiple Au-rich hydrothermal events of differ-
fluids have high concentrations of SiO2 and cooling of these ent ages and types in the Carlin trend (Table 1); however, the
fluids would cause widespread precipitation of quartz (Hol- W and Te may have been derived from preexisting poly-
land and Malinin, 1979). metallic mineralization associated with Jurassic intrusions.
Remobilization of gold from sedimentary exhalative accumu-
Deep circulation of meteoric water origin lations during mid-Tertiary time can explain many enigmatic
The third hypothesis invokes deep circulation of meteoric characteristics of Carlin-type deposits. The strata hosting the
water during crustal fracturing and thinning that accompa- gold-rich sedimentary exhalative mineralization are pyritic,
nied mid-Tertiary extension (Hofstra, 1994; Ilchik and Bar- carbonaceous, and baritic, thus capable of generating H2S by
ton, 1997). In this model meteoric waters are thought to have thermochemical sulfate reduction, breakdown of organic sul-
circulated to depths of >10 km where they leached gold and fur compounds, and/or dissolution of pyrite during subse-
other ore components. Carlin-type gold deposition then quent heating, all of which would have resulted in δ34S values
formed in zones of upwelling where fluids reacted with rocks similar to those measured in ore-stage sulfide minerals of
at shallow levels. The meteoric water hypothesis is supported Carlin-type ores (Fig. 20). Interaction of heated meteoric wa-
by isotopic and geochronologic evidence for circulation of ters with these preenriched sedimentary rocks could have
Tertiary meteoric waters to below the brittle-ductile transi- generated an H2S-rich fluid, suppressing the solubility of base
tion in metamorphic core complexes (Wickham et al., 1993). metals and scavenging gold and other trace elements. Upon
This hypothesis is similar in many ways to the metamorphic migration into rocks containing reactive Fe, auriferous pyrite
gold model, the major difference being that ore fluids have would be deposited by sulfidation, thus forming the epige-
low δD values, thus reflecting their meteoric origin. The nar- netic Carlin-type deposits.
row range and low δ18OH2O values from Goldstrike, however, This sequence of events resolves many previously problem-
indicate that the fluid was relatively unexchanged (W/R = ca. atic characteristics of the Carlin-type ore fluid. Relatively
1), which is inconsistent with deep circulation. At the ca. 10- shallow circulation of meteoric water would explain the δ18O
km depths of the brittle-ductile transition, ambient tempera- and δD values that are inconsistent with other hypotheses
and would indicate that the generative hydrothermal fluids Armstrong, A.K., Theodore, T.G., Kotlyar, B.B., Lauha, E.G., Griffin, G.L.,
were moderately evolved meteoric waters. A preenriched Lorge, D.L., and Abbott, E.W., 1997, Preliminary facies analysis of Devon-
ian autochthonous rocks that host gold along the Carlin trend, Nevada: So-
source also would enable these waters to become Au satu- ciety of Economic Geologists Guidebook Series, v. 28, p. 109–118.
rated at much higher W/R ratios, accounting for the low δ18O Bakken, B.M., 1991, Gold mineralization, wall-rock alteration, and the geo-
values exhibited by ore-stage minerals. It also solves the prob- chemical evolution of the hydrothennal system in the main ore body, Car-
lem of the low quartz content, because the Au-enriched lin mine, Nevada, in Raines, G.L., Lisle, R.E., Schafer, R.W., and Wilkin-
son, W.H., eds., Geology and ore deposits of the Great basin: Symposium
source rocks are present at the same stratigraphic level as the proceedings, Reno, Geological Society of Nevada, p. 233–234.
epigenetic Carlin-type ores, facilitating near-isothermal trans- Bakken, B.M., and Einaudi, M.T., 1986, Spatial and temporal relations between
port and deposition of gold. Preenriched rocks also resolve wall rock alteration and gold mineralization, Main pit, Carlin gold mine, Nevada,
other mass balance problems in that they require a smaller U.S.A, in Macdonald, A.J., ed., Gold ’86: Toronto, Ontario, p. 388–403.
volume of source rock to supply the gold required to form a Barton, P.B., and Skinner, B.J., 1979, Sulfide mineral stabilities, in Barnes,
H.L., ed., Geochemistry of hydrothermal ore deposits, Second edition:
Carlin-type deposit. New York, Wiley, p. 278–403.
Although this model explains many characteristics of the Bettles, K.H., 2002, Exploration and geology, 1962 to 2002, at the Goldstrike
deposits, it does not account for the complete dissolution of property, Carlin trend, Nevada: Economic Geology Special Publication 9,
carbonate and pervasive argillic alteration observed in high- p. 275–298.
Bodnar, R.J., Reynolds, T.J., and Kuehn, C.A., 1985, Fluid inclusion system-
grade ores. Sulfidation of host-rock Fe may produce appre- atics in epithermal systems: Reviews in Economic Geology, v. 2, p. 73–96.
ciable acid, but mass balance calculations indicate that it is Chakurian, A.M., Arehart, G.B., Donelick, R.A., Zhang, X., and Reiners,
not sufficient to explain the intensity of alteration in high- P.W., 2003, Timing constraints of gold mineralization along the Carlin trend
grade ores. Further work is needed to investigate this prob- utilizing apatite fission-track, 40Ar/39Ar, and apatite (U-Th)/He: ECONOMIC
lem. Additional work is also needed to determine whether GEOLOGY, v. 98, p. 1159–1171.
Claypool, G.E., Holser, W.T., Kaplan, I.R., Sakai, H., and Zak, I., 1980, The
sufficient gold was introduced by the sedimentary exhalative age curves of sulfur and oxygen isotopes in marine sulfate and their mutual
hydrothermal system to account for that present in Carlin- interpretation: Chemical Geology, v. 28, p. 199–260.
type deposits. Documentation of the spatial distribution of Clayton, R.N., and Mayeda, T.K., 1963, The use of bromine pentafluoride in
sedimentary exhalative enrichments relative to Carlin-type the extraction of oxygen from oxides and silicates for isotopic analysis:
Geochimica et Cosmochimica Acta, v. 27, p. 43–52.
deposits is necessary to assess whether it is hydrologically fea- Drewes, A.S.P., Romberger, S.B., and Whitney, C.G., 1996, Clay alteration
sible to transport gold from the Au-enriched rocks into the and gold deposition in the Genesis and Blue Star deposits, Eureka County,
deposits. Finally, detailed petrographic, geochemical, and iso- Nevada: ECONOMIC GEOLOGY, v. 91, p. 1383–1393.
topic studies of the deposits are needed to determine if gold Emsbo, P., 1999, Origin of the Meikle high grade gold deposit from the su-
was remobilized. This is the direction of our current research perposition of Late Devonian sedex and mid-Tertiary Carlin-type gold min-
eralization: Unpublished Ph.D. thesis, Golden, Colorado, Colorado School
in the district. of Mines, 394 p.
Acknowledgments ——2000, Gold in sedex deposits: Reviews in Economic Geology, v. 13, p.
427–437.
We would like to thank Barrick Goldstrike Mines, Inc., for Emsbo, P., and Hofstra, A.H., 2003, Origin and significance of postore dis-
supporting this research. Many discussions and help from solution collapse breccias cemented with calcite and barite at the Meikle
gold deposit, northern Carlin trend, Nevada: ECONOMIC GEOLOGY, v. 98,
the Barrick staff, including Keith Bettles, Al Lander, Jane p. 1243–1252.
Zimmerman, Jan Lamb, David Park, Terry Collins, and Jeff Emsbo, P., Collins, T., and Winegardner, J., 1995, Results of the North block
Volk, were critical to this study. We would also like to thank down hole geochemical survey: Elko, Nevada, Barrick Goldstrike Mines
Bob Rye and Craig Johnson for their help with isotopic Inc., unpublished internal report, 51 p.
analyses and Fred Lichte and Greg Meeker for their help Emsbo, P., Hofstra, A.H., Park, D., Zimmerman, J.M., and Snee, L., 1996, A
mid-Tertiary age constraint on alteration and mineralization in igneous
with the microanalytical analyses at the USGS; in addition, dikes on the Goldstrike property, Carlin trend, Nevada [abs.]: Geological
a thank you to Freda Hubler for providing the groundwork Society of America Abstracts with Programs, v. 28, no.7, p. A476.
that made this study possible. Craig Johnson, François Emsbo, P., Hutchinson, R.W., Hofstra, A.H., Volk, J.A., Bettles, K.H.,
Robert, and Ted Theodore are thanked for greatly improv- Baschuk, G.J., Collins, T.M., Lauha, E.A., and Borhauer, J.L., 1997, Newly
discovered Devonian sedex-type base and precious-metal mineralization,
ing the manuscript through their thoughtful and thorough northern Carlin trend, Nevada: Society of Economic Geologists Guidebook
reviews. Series, v. 28, p. 109–118.
Emsbo, P., Hofstra, A.H., Volk, J.A., and Lauha, E.A., 1998, Genesis of high-
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Sample MP-1 EL50602 GA32-1746 GB588C-894 GB598-906 GB605-930 GB539-1464 EX90C-951 GA3412303 BR-1C-1374 BRIC-1375 P384-432.5 FBP
Deposit Meikle Betze-Post Golden April Meikle Meikle Meikle Meikle Meikle Golden April Ren Ren Betze-Post Betze-Post
Type LampM LampH LampP LampH LampH LampH LampH LampH LampP LampP LampP LampH LampM
Method 1 1, 2 1, 2 1, 2 1, 2 1, 2 1, 2 1,2 2 1,2 1,2 1,2 1,2 1,2
Major elements (wt %)
SiO2 42.02 50.19 48.20 47.91 53.70 56.60 58.90 n.a. 46.60 56.34 54.70 50.42 39.90
Al2O3 8.01 13.26 12.40 13.08 16.20 16.10 16.20 15.53 10.70 14.10 14.40 13.68 11.40
0361-0128/98/000/000-00 $6.00
Fe2O3 8.54 8.08 7.52 7.32 8.46 10.00 7.31 10.19 6.47 10.34 10.80 7.93 9.42
MgO 12.00 8.72 7.13 6.24 1.76 0.67 0.61 0.15 8.42 0.63 0.73 4.78 5.27
CaO 7.22 6.72 6.30 6.87 2.64 0.82 0.72 0.66 7.05 1.52 1.35 6.69 10.10
Na2O 1.72 2.26 0.70 2.18 0.06 0.03 0.04 0.04 1.35 0.30 0.04 2.35 0.03
K2O 1.14 2.84 2.82 2.93 3.73 4.21 4.33 0.58 4.04 3.63 3.74 3.39 0.31
TiO2 0.80 1.13 1.36 1.05 1.29 1.25 0.99 1.35 1.03 1.75 1.72 1.09 1.06
P2O5 0.36 0.37 0.42 0.35 0.46 0.55 0.48 0.41 0.66 0.88 0.97 0.43 0.55
LOI 16.75 5.35 11.67 10.10 9.77 8.91 8.66 n.a. 10.98 10.44 10.20 7.57 13.80
S 0.55 0.51 0.20 0.22 6.13 7.68 5.78 n.a. 0.18 7.98 8.21 0.06 3.47
Trace elements (ppm) except Au (ppb)
Ag <0.4 <0.4 <0.4 <0.4 <0.4 34.7 5.1 0.8 <0.4 <0.4 0.4 <0.4 <0.4
As 40 61 10 40 590 560 1,100 3,700 4 2,300 2,100 13 18,000
Au 2 <2 7 150 674 5,550 17,900 14,300 18 47,200 58,700 18 <6
Ba 2,000 1,200 1,500 1,600 770 <50 3,000 2,600 4,900 290 340 2,200 2,500
Bi <5 <5 <0.2 <5 <5 <5 <5 <5 -0.2 <5 <5 <5 <5
Cd <0.5 <0.5 n.a. <0.5 1.4 1.9 0.5 <0.5 n.a. <0.5 1.2 <0.5 1.9
Ce 87 170 110 140 170 160 170 140 199.1 210 200 140 140
Co 49 44 32 28 41 32 22 55 31.8 47 41 26 79
1101
Cr 1300 660 590 510 710 290 280 870 680 1,000 990 200 2,100
Cs 2 <1 23 15 39 21 13 <1 5 15 16 12 1
Cu 57 68 79 34 131 94 60 68 49 90 60 74 62
Eu 2.3 3.5 2.5 2.8 3.1 2.4 2.8 2.4 4.2 3.4 3.3 3 3.7
Hf 5 6 8 5 7 7 7 5 11 19 19 6 5
Hg <1 1 <1 <1 <1 21 14 50 <1 56 50 <1 <3
La 46 89 61 78 96 85 95 88 110 94 98 76 67
Lu 0.26 0.39 0.28 0.35 0.39 0.61 0.42 0.43 0.27 0.48 0.63 0.33 0.85
Mn 1,013 886 n.a. 792 357 7 17 25 n.a. 24 5 851 1,384
Mo <1 <1 <5 <1 9 4 3 15 7 <3 <3 <1 <1
Nd 35 65 51 53 72 56 56 55 81 94 83 54 49
MEIKLE AND NEIGHBORING DEPOSITS, CARLIN TREND
Ni 369 239 137 133 295 101 125 266 190 223 314 58 602
Pb 10 5 n.a. 12 <5 9 5 24 16 10 <5 6 5
Rb 47 61 97 120 170 160 170 35 80 170 160 99 <15
Sb 2.2 25 3.1 8.6 25 230 100 280 1.8 87 83 6.8 80
Sc 23 25 28 21 19 13 8.6 24 18 19 23 21 39
Se <3 <3 <3 <3 <3 5 <3 <3 <3 7 <3 <3 <3
Sm 7.2 11 8 9.4 11 9.7 9.2 9 13 14 14 9.6 9.3
Sr 824 911 390 801 78 40 33 58 1,321 46 40 949 277
Te n.a. n.a. n.a. n.a. <0.2 9 <0.2 <0.5 8 n.a. 1 n.a. <0.2
Th 12 14 14 13 16 13 18 19 24 36 33 12 17
Tl n.a. n.a. 1.8 n.a. 1.8 87.6 19.7 35.3 0.7 n.a. 126.1 n.a. 15.7
U 3.2 3.4 4 2.8 7.2 7.1 5.5 10 6.8 <0.9 <0.6 3.7 12
V 119 146 189 128 211 276 167 210 116 211 255 142 188
W <1 <1 <4 <1 60 61 82 260 1.2 230 120 <1 150
Y 17 24 20 20 14 20 16 30 24 20 17 22 25
Yb 1.7 2.4 1.9 1.9 2.2 3.9 2.4 3.1 2.1 2.6 2.7 2.2 3.8
Zn 71 476 43 75 76 56 46 145 38 105 79 77 80
1101
APPENDIX (Cont.)
1102
Sample G18201379 G18201380 R22C-555 P213-1754 R9-884 EX-24C EX 92-896.5 WB4C-1720 BZ-15 EL5040 5040 #1 5040-2H P333C-924
Deposit Betze-Post Betze-Post Betze-Post Betze-Post Ren Meikle Meikle Golden April Betze-Post Betze-Post Betze-Post Betze-Post Betze-Post
Type Di Di Di Di Di Monz Monz Monz BFP BFP BFP BFP BFP
Method 1 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2 1,2
0361-0128/98/000/000-00 $6.00
MgO 4.68 4.25 2.83 3.31 2.46 0.34 0.3 0.89 0.69 1.09 1.17 0.56 2.12
CaO 7.12 7.8 5.46 6.58 4.9 0.3 0.18 2.9 2.15 0.76 0.67 0.69 2.34
Na2O 3.2 3.43 3.1 0.05 2.23 0.34 0.05 0.06 1.93 0.39 0.21 0.05 0.3
K2O 2.4 2.13 2.31 3.47 3.16 3.72 4.05 3.24 3.86 3.69 4.02 2.5 2.08
TiO2 1.4 1.39 1.16 1.18 0.87 0.28 0.27 0.54 0.27 0.49 0.48 0.46 0.49
P2O5 0.37 0.48 0.29 0.42 0.29 0.1 0.11 0.23 0.18 0.26 0.26 0.25 0.27
LOI 1.58 1.46 3.27 7.72 10.9 3.5 2.98 6.78 4.8 6.23 4.73 6.37 8.85
S 0.01 0.56 0.03 3.27 0.15 0.89 1.11 0.12 <0.005 <0.005 0.01 2.52 0.24
1102
Cs <2 <2 4 12 5 6 4 3 n.a. 16 15 11 10
EMSBO ET AL.
Cu 19 9 10 19 6 5 3 <5 1 5 6 5 7
Eu 2.6 2.6 2 2.2 2.4 0.6 0.6 1.9 n.a. 1.5 1.7 1.3 1.8
Hf 6 5 6 5 7 4 4 9 n.a. 7 7 5 7
Hg <1 <1 <1 27 <1 13 5 <1 n.a. <1 <1 7 2
La 53 52 46 57 79 32 27 69 43 47 47 46 54
Lu 0.44 0.44 0.46 0.38 0.52 0.22 0.19 0.44 n.a. 0.37 0.35 0.33 0.42
Mn n.a. n.a. 566 840 702 17 6 n.a. 380 691 243 136 654
Mo <5 <5 <1 <2 <1 12 7 7 3 <1 3 <1 5
Nd 43 49 31 34 49 12 15 43 30 32 30 21 34
Ni 22 27 12 6 5 7 3 3 3 22 16 21 4
Pb n.a. n.a. <5 <5 <5 10 11 n.a. 30 15 22 28 8
Rb 79 54 87 140 120 160 110 100 n.a. 170 180 110 87
Sb 1.5 0.6 1.1 19 0.5 50 25 9.1 n.a. 4.7 2.8 14 10
Sc 22 19 19 17 11 3.5 3.1 5.2 4 4.4 4.4 3.7 5
Se <3 <3 <3 3 <3 <3 4 <3 n.a. <3 <3 <3 <3
Sm 7.3 8.3 6.2 7 8.6 2.6 2.4 5.2 n.a. 5.6 5.2 5.2 6.5
Sr 776 927 706 146 452 15 11 182 490 59 47 42 35
Te 8 <0.5 n.a. <0.2 n.a. n.a. 1 <0.5 n.a. n.a. 0 2 n.a.
Th 13 9.3 9.8 15 18 12 12 16 13 11 12 11 13
Tl 0.4 0.3 n.a. 13.9 n.a. n.a. 9.7 1.4 n.a. n.a. <0.2 6.8 n.a.
U 1.6 3.6 2.2 6.2 3.7 5.4 4.2 3.9 n.a. 3.7 4.5 4.9 4.8
V 165 158 138 179 66 51 21 38 18 38 37 36 36
W <4 <4 <1 20 <1 5 4 <4 n.a. 2 <1 11 4 3
Y 27 30 18 16 20 10 8 21 14 13 11 10 12 10
Yb 2.7 2.7 2.7 2.6 3.4 1.2 1.1 2.9 n.a. 2.2 2.2 2 2.4
Zn 32 22 75 29 73 46 40 72 54 143 121 163 66
APPENDIX (Cont.)
Sample P213 P333 P333-920H P213-1783 EX21-1146 EX21-1085.5 EX21-1290 GB598 1175 LSL 156M-04 GB732-1219 76C 1475 BASE
Deposit Betze-Post Betze-Post Betze-Post Betze-Post Meikle Meikle Meikle Meikle Meikle Rodeo Rodeo Rodeo B/P
Type BFP BFP BFP BFP Zebra Dol D ore D ore Dsedex Dsedex Ssedex Ssedex Ssedex Jvein
Method 1 1,2 1,2 1,2 1,2 3 3 2 2 2 2 2 2 2
0361-0128/98/000/000-00 $6.00
MgO 1.46 0.73 1.75 1.31 18.24 13.93 4.01 12.05 5.67 4.51 2.67 0.07 0.99
CaO 3.87 0.57 0.83 3.26 29.38 22.39 6.34 17.56 9.65 7.89 5.6 2.8 0
Na2O 0.37 0.08 0.05 0.58 <.02 0.27 0.09 0.18 0.01 0.03 0.03 <0.01 0.01
K2O 3.07 2.53 2.21 2.96 <.04 0.1 0.01 0.01 0.04 1.19 1.3 0.19 0.61
TiO2 0.45 0.46 0.46 0.45 <.02 <.02 0.02 0.02 0.02 0.22 0.23 0.06 0
P2O5 0.23 0.25 0.25 0.27 <.02 0.11 0.14 0.03 0.03 0.27 0.18 0.6 0.03
LOI 8.79 6.55 6.1 9.45 n.a. n.a. n.a. n.a. n.a. n.a. n.a. n.a. n.a.
S 0.16 1.8 0.31 0.09 0.23 2.38 n.a. n.a. n.a. n.a. n.a. n.a. n.a.
1103
Cs 11 14 12 12 n.a. n.a. <1 <2 <1 4 <1 <1 <4
Cu 7 3 6 6 20 30 112 901 917 158 142 16 14028
Eu 1.5 1 1.7 1.6 <8 <8 <0.3 <0.3 <0.2 1.8 1.4 0.5 <2
Hf 6 6 7 7 n.a. n.a. <1 <2 <1 4 7 <1 <3
Hg 1 29 <1 <1 0.5 15 82 310 120 73 200 6 <8
La 42 45 48 50 <8 <8 <1 6 4.4 34.3 39 11.7 16
Lu 0.31 0.51 0.39 0.37 n.a. n.a. <0.14 <0.15 <0.05 0.9 0.92 0.08 <0.35
Mn 537 36 251 495 2,400 1,700 553 827 530 95 98 35 586
Mo 4 <3 4 <1 0.99 0.75 8 <3 <2 229 220 41 <1
Nd 32 28 33 31 <20 <20 42 <11 <5 15 33 <5 <15
MEIKLE AND NEIGHBORING DEPOSITS, CARLIN TREND
0361-0128/98/000/000-00 $6.00
MgO 0.13 0.76 0.07 0.36 4.97 10.26 9.72 11.14 0.13 0.17 0.15 0.08 0.17
CaO 2.85 2.74 0.81 0.67 16.78 21.66 19.84 21.56 6.86 4.42 2.43 1.34 3.19
Na2O 0.07 0.13 0.05 0.03 0.01 0.04 0.03 0.04 0.03 0.07 0.03 0.03 0.01
K2O 0.18 0.75 0.11 1.9 0.39 0.37 0.34 0.19 0.18 0.18 0.23 0.23 0.16
TiO2 0.03 0.07 0.02 0.67 0.05 0.05 0.05 0.03 0.03 0.05 0.07 0.03 0.03
P2O5 0.38 0.95 0.36 0.33 1.69 2.03 2.06 0.93 0.3 0.38 0.52 0.54 0.39
LOI n.a. n.a. n.a. n.a. n.a. n.a. n.a. n.a. n.a. n.a. n.a. n.a. n.a.
S n.a. n.a. n.a. n.a. n.a. n.a. n.a. n.a. n.a. n.a. n.a. n.a. n.a.
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Cs <1 <1 2 6 1 1 1 1 1 1 1 1 1
EMSBO ET AL.
0361-0128/98/000/000-00 $6.00
MgO 0.08 0.36 0.1 0.43 0.12 0.1 Lu 0.1 0.28 0.22 0.56 0.1 0.05
CaO 1.48 0.56 1.25 0.29 0.85 0.56 Mn 82 23 39 87 32 30
Na2O 0.03 0.01 0.03 0.03 0.03 0.03 Mo 42 13 480 57 370 160
K20 0.16 2.28 0.16 2.47 0.57 0.33 Nd 5 31 18 14 8 5
TiO2 0.03 0.68 0.03 0.35 0.1 0.07 Ni 26 116 151 93 106 80
P2O5 0.43 0.3 0.78 0.18 0.57 0.37 Pb 16 25 161 45 16 5
LOI n.a. n.a. n.a. n.a. n.a. n.a. Rb 15 77 15 80 15 15
S n.a. n.a. n.a. n.a. n.a. n.a. Sb 540 160 1,260 92 630 500
Sc 0.4 8.1 0.8 5.5 1.5 1.1
Trace elements (ppm) except Au (ppb) Se 0.5 1.4 0.2 2.9 9.5 22
Ag 62.8 1 23.1 3.4 2.6 2 Sm 1.5 4.9 2 2.3 2.1 1.1
As 4,700 1,600 9,700 1,800 4,000 2,300 Sr 11 40 15 17 13 13
Au 85,600 7,830 337,000 10,900 103,000 30,500 Te 0.8 0.2 0.6 0.2 0.2 0.3
Ba 2,600 11,000 25,000 7,300 22,000 25,000 Th 0.2 7.4 0.2 7.5 3.5 0.2
Bi 0.2 0.2 0.2 0.2 0.8 2 Tl 210 17 314 27 126 74
Cd 1.9 8 126.2 5.1 2.8 2.9 U 0.5 9.7 0.5 10 0.5 0.5
Ce 33 81 54 39 28 3 V 22 211 93 307 213 138
Co 3 15 5 9 3 2 W 1 12 27 11 20 18
Cr 490 320 270 240 250 230 Y 13 22 22 23 19 12
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Cs 1 11 1 3 1 1 Yb 0.4 1.6 0.8 1.9 0.4 0.2
Cu 261 46 121 49 45 68 Zn 73 720 9304 378 266 198
Eu 0.2 1.4 0.5 0.6 0.2 0.2
Abbreviations: BFP = biotite feldspar porphyry, Breccia = breccia-hosted ore, Cave = cave-fill ore, Di = Goldstrike diorite, Dol = dolomite, D ore = dolomite-hosted ore, Dsedex = discordant sedex,
Jvein = Jurassic vein, LampH = hornblende lamprophyre, LampM = mafic lamprophyre, LampP = phlogopite lamprophyre, Monz = monzonite, n.a. = no data, Ssedex = stratiform sedex
1 1 = WDXRF, 2 = INAA+ICP-OES, 3 = ICP-OES
2 40Ar/ 39Ar age of hornblende in sample (157.87 ± 0.24 Ma)
3 40Ar/ 39Ar age of phlogopite in sample (158.88 ± 0.26 Ma)
MEIKLE AND NEIGHBORING DEPOSITS, CARLIN TREND
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