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Applied Thermal Engineering 171 (2020) 115074

Contents lists available at ScienceDirect

Applied Thermal Engineering


journal homepage: www.elsevier.com/locate/apthermeng

Prediction of dehydration performance of supersonic separator based on a T


multi-fluid model with heterogeneous condensation

Hongbing Dinga, Chunqian Suna, Chao Wanga, , Chuang Wenb, Yuhe Tiana
a
Tianjin Key Laboratory of Process Measurement and Control, School of Electrical and Information Engineering, Tianjin University, Tianjin 300072, China
b
Faculty of Engineering, University of Nottingham, University Park, Nottingham NG7 2RD, UK

H I GH L IG H T S

• Multi-fluid model with heterogenous condensation in supersonic separator was built.


• Interphase slip and droplet behavior of heterogenous condensation were studied.
• Dew point depression and water removal rate of supersonic separator were predicted.
• Both heat transfer coefficient and residence time of droplets must be considered.
• Optimal radius is 0.85 μm and water removal rate is 87.82% when p = 250 kPa. in

A R T I C LE I N FO A B S T R A C T

Keywords: Supersonic separation is a novel technology. A multi-fluid slip model for swirling flow with homogenous/het-
Supersonic separator erogenous condensation and evaporation processes in the supersonic separator was built to estimate the se-
Condensation and evaporation paration efficiency. This model solves the governing equations of compressible turbulent gas phase and dispersed
Multi-fluid model homogenous/heterogenous liquid phase considering droplet coalescence and interphase force. Its prediction
Natural gas dehydration
accuracy for condensation and swirling flows was validated. Then, the flow field, slip velocity and droplet
Separation efficiency
trajectory inside the separators with different swirl strengths were investigated. The maximum values of radial
slip velocity are 29.2 and 8.26 m/s for inlet foreign droplet radius of 1.0 and 0.4 µm. It means the larger foreign
droplet has a better condensation rate. However, the residence time of larger foreign droplet in core flow is
shorten. Thus, the inlet radius of foreign droplet has to be moderate for best separation efficiency. Finally, the
dehydration performances of separator were evaluated. The optimal radius of inlet foreign droplet to maximize
the dehumidification and efficiency was found. For the separator with swirl strength of 22%, the optimal radius
is 0.85 µm at inlet pressure of 250 kPa, where the maximum dew point depression is 42.41 °C and the water
removal rate is 87.82%.

1. Introduction natural gas processing, including adsorption, absorption, cryogenic


separation, turbine expansion, and Membranes [6]. However, these
Natural gas as a popular and cleaner alternative to coal and other technologies have some disadvantages, such as complex structure, large
fossil fuel, plays a crucial role in the next decades and reduces the equipment, huge investment and possibility of environmental pollution.
carbon and other emissions leading to the long-term benefits for public The supersonic separator operated without rotating parts and che-
health and the environment [1]. However, the presence of water vapor, micals is a revolutionary technique for removing water vapor and heavy
heavy hydrocarbons and carbon dioxide (CO2) [2] in raw natural gas hydrocarbons from natural gas [7]. It also potentially uses for CO2 re-
causes several problems, such as reduction of heating value [3], cor- moval in CCS (carbon capture and storage). As a simple, reliable and
rosion of water combined with the sour gases including CO2 and H2S, environmentally friendly separator [8], the condensable vapor is con-
formation of hydrate, the blockage of equipment and pipelines, and CO2 densed instantaneously during the gas expansion, and then separated
emission [4]. Therefore, separation technology is crucial for natural gas from the natural gas because of the strong centrifugal force [9]. It can
processing [5]. Several separation techniques can be utilized for the prevent the hydrate problem without any inhibitor and regeneration


Corresponding author.
E-mail address: wangchao@tju.edu.cn (C. Wang).

https://doi.org/10.1016/j.applthermaleng.2020.115074
Received 12 August 2019; Received in revised form 9 February 2020; Accepted 11 February 2020
Available online 11 February 2020
1359-4311/ © 2020 Elsevier Ltd. All rights reserved.
H. Ding, et al. Applied Thermal Engineering 171 (2020) 115074

Nomenclature Greek

A area, m2 α volume fraction, –


ak heat transfer coefficient, W m−2 K−1 β gas-liquid mass ratio, –
Cc Cunningham slip correction factor, – Γ specific heat ratio, –
c sound speed, m s−1 γ pressure loss ratio, –
cp specific heat capacity, J kg−1 K−1 ΔT dew point depression, °C
cs species mass fraction, – δij Kronecker delta, –
Ds Mass diffusion coefficient, m2 s−1 η water removal rate, %
DT subcooling, °C λ thermal conductivity, W m−1 K−1
Dω cross-diffusion term, kg m−3 s−2 μ dynamic viscosity of fluid, Pa s
d throat diameter of nozzle, mm ρ density of fluid, kg m−3
E total energy, J kg−1 σ surface tension, N m−1
FD drag force, kg m−2 s−2 σk , σ ω turbulent Prandtl numbers, –
f collision frequency, Hz τij deviatoric stress tensor, Pa
Gk, Gω the generations of k and ω υ single water molecule volume, m3
hlg latent heat of water vapor, J kg−1 Φ relative humidity, pv/ps(Tg) × 100%
J homogeneous nucleation rate, m−3 s−1 χ mole fraction of water vapor, –
K bulk elastic modulus, Pa ψ recovery of dry gas at the outlet
Kn Knudsen number, – Ω magnitude of strain rate, s−1
k turbulence kinetic energy, J kg−1 ω specific dissipation rate, s−1
kB Boltzmann’s constant. 1.38 × 10−23 J K−1
M dimensionless mass flow rate, – Subscripts
Ma Mach number, –
mm mass of water molecule, 2.99 × 10−26 kg * stagnation condition
m liquid mass changing rate, kg m−3 s−1 a, r, t axial, radial, tangential
n droplet number concentration, m−3 c critical
Pr Prandtl number, – d dew point
p pressure, Pa eff effective
Q mass flow-rate, kg s−1 g gas
Rep Reynolds number het heterogeneous
Rg gas constant of air, J kg−1 K−1 hom homogeneous
Rv specific gas constant of water vapor, J kg−1 K−1 i, j, k tensor notation
r droplet radius, m k species
S swirl strength, – l liquid
Ss supersaturation of water vapor, – rel relative
Si,j mean strain rate, s−1 s saturation
T fluid temperature, °C tu turbulent
TR reduced temperature, – v water vapor
Tr droplet surface temperature, °C
t time, s Superscripts
u velocity of fluid, m s−1
Vs interphase slip velocity, m s−1 in, out Inlet, outlet
xj Cartesian coordinates (tensors), m nt nozzle throat
xa, xr axial and radial coordinates, m dry, wet dry and wet gas outlets
Yk , Yω the dissipations of k and ω

system because of the low temperature and short residence time inside water dew point. Wen et al. [13] compared the temperature and pres-
the supersonic separator [10]. Although many works have been done sure profiles obtained by FLUENT with phase envelope diagrams by
for optimizing the structure and performance of supersonic separator, HYSYS and found the supersonic separators is suitable for liquefied
the actual dehydration performance is still far from being satisfactory, natural gas. Hammer et al. [14] investigated CO2 removal of supersonic
as the flow inside supersonic separator is quite complex which includes separator from dry 2.98% CO2 exhausts by using Aspen HYSYS. Ni-
condensation, evaporation, vorticity, turbulence, shockwave and in- knam et al. [15] used Aspen HYSYS to predict the 3S unit performance
terphase slip. by conventional unit operations, then analyzed the performance of
The goal of supersonic separator is to remove condensable vapors nozzle and proposed an efficiency model for supersonic separation by
from the gas flow and achieve a lower dew point or strip the gas of integrating COMSOL, HYSYS and MATLAB software [16]. Arinelli et al.
heavy hydrocarbons. The dew point depression and water removal rate [17] developed two steady state Unit Operation Extensions (UOE) and
of the supersonic separator are really desired. Currently, there are two the vapor-liquid equilibrium (VLE) envelopes for HYSYS 8.8 to simulate
approaches for predicting its separation performance, the computa- supersonic separator and membrane permeation for treating humid
tional fluid dynamics using Fluent software [4] and the process simu- natural gas with 44%mol CO2. Bian et al. [18] proposed a novel gas
lation conducted in Aspen HYSYS [11]. liquefaction process and the liquefaction efficiency under different
For process simulation, Karimi and Abdi [12] investigated the flow condition were calculated by using MATLAB and HYSYS. Rezakazemi
field of single-phase gas in a Laval nozzle without swirl by using Aspen et al. [19] carry out a series of process simulation by Aspen HYSYS to
HYSYS, and found the gas could potentially be dehydrated to very low compare recovery of ethane from typical JT Valve, Turbo-Expander and

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H. Ding, et al. Applied Thermal Engineering 171 (2020) 115074

Twister Technology. Brigagão et al. [20] developed a new CCS unit by laboratory tests, and leads to the heterogeneous condensation. This
using a supersonic separator based on HYSYS 8.8. CO2 emissions can be process can effectively reduce the free energy barrier and promotes the
reduced by 43% with economic performance. de Medeiros et al. [21,22] condensation appearance. Ma et al. [40] experimentally investigated
proposed UOE module for estimating sound speed of two-phase systems the effect of foreign droplets on vapor condensation by using droplet
in supersonic reactors for multiphase multi-reactive equilibrium system enlargement according to heterogeneous condensation theory. Ding
via HYSYS. However, it is recognized that their results were not vali- et al. [41] carried out a two-dimensional multi-phase turbulence model
dated against experimental data. for homogeneous/heterogeneous condensation to investigate the effect
For CFD simulation, Malyshkina [23] numerically investigated the of condensation on mass flow rate of Laval nozzle without swirl. Ni-
single-phase swirling flow inside a supersonic separator and analyzed knam et al. [42] experimentally obtained dehydration of low-pressure
effects of Mach number and temperature on recovery of pressure. Wen gas in supersonic separator with heterogeneous condensation of water
et al. [24,25] studied the flow characteristics and mass flux inside a droplets containing small foreign droplet and built a two-phase Euler-
supersonic separator with and without swirls. Wang and Hu [26] in- Euler model in 2D asymmetric domain for analyzing the dehydration
vestigate the effects of swirling generator and drainage structure where efficiency. However, they did not consider homogenous nucleation
the RNG k-ε turbulence model was utilized. Liu [27] established a process and the drag model was not provided. Shooshtari and Shahsa-
three-dimensional single-phase numerical model considering the com- vand [43] built a heterogeneous condensation model without inter-
pressible and strong swirling effect to study the flow field and to opti- phase slip for optimizing geometry of the Laval nozzle which was va-
mize separation performance. Alnoush and Castier [28] proposed a lidated by Dykas’s predictions [44]. Bian et al. [45] built a physical
shortcut one-dimensional single-phase numerical modeling for the model for homogenous and heterogeneous condensations in a Laval
conceptual preliminary design of supersonic separator. nozzle. However, the interphase slip velocity was ignored which is not
On this basis, two-phase models based on the discrete particle suitable for the swirling flow in a supersonic separator.
method (DPM) were built. Wen et al. [29] and Yang et al. [30] studied As mentioned above, there is a lack of CFD model for accurate
natural gas flow characteristics and particle separation behavior by prediction of liquid droplets trajectories inside supersonic separator
using DPM model with particle diameter constant of 1.4 µm. Liu et al. with combination of swirling, nucleation, growth, evaporation, slip,
[31] also predicted the particle behavior inside a supersonic separator collision and coalescence in respect of the operation optimization of the
employing the DPM model, where the particle diameter range is from supersonic separator. This paper proposed a novel multi-fluid (slip)
10 to 50 µm, However, the typical particle size in the supersonic se- model for the swirling flow with the homogenous/heterogenous con-
parator is 0.1–2 µm [32] from Twister BV. Jiang [33] studied the gas densation and evaporation processes in supersonic separator. The
flow field and CO2 droplet trajectory inside a supersonic separator mathematical modeling and performance assessment of present multi-
employing DPM model. The size of CO2 droplet is set to be a constant of fluid model have been conducted. It provides an effective method to
1.25 µm. However, these researches do not consider the complex nu- analyze the effects of homogeneous/heterogeneous condensation with
cleation-condensation process of condensable vapor and the evapora- enhanced heat transfer coefficient due to strong swirl on the dehydra-
tion process of droplet inside the supersonic separator. tion efficiency of supersonic separator.
Take into account the condensation process in the supersonic flow,
Ma et al. [34] built an Eulerian two-fluid model to investigate homo- 2. Supersonic separator
genous condensing flow in a Laval nozzle. Shooshtari and Shahsavand
[35] provided a new theoretical approach based on mass transfer rate to In this paper, the supersonic separator is composed of a central body
predict liquid droplet growth of homogenous condensation of binary and some vanes were designed, as shown in Fig. 1. The annular channel
mixtures in a Laval nozzle. Ding et al. [36] proposed an analytical so- between the central inner body and the shell wall forms a supersonic
lution to predict Wilson point of homogeneous nucleation inside the nozzle section, a cyclonic separation section and a diffuser with the dry
nozzle. Castier [37] conducted several numerical simulations for the and wet gas outlets [24]. The swirling flow is generated by several
natural gas partial condensation inside a Laval nozzle without swirl. static vanes with specific turning angle at the subsonic section which
Dykas [38,39] built an in-house CFD code with 3-D RANS equations for can control the flow swirl strength.
single-fluid no-slip model to predict the wet steam and moist air con- Several parameters related to the separation efficiency and hydra-
densation process within a Laval nozzle. Wen et al. [4] developed a tion performance were defined. The pressure loss ratio γ is expressed as
numerical model of homogenous nucleation to predict CO2 condensa-
tion because of condensation inside supersonic flows. The condensation pin − pout
γ=
model predicted 18.6% of condensed liquid fraction. pin (1)
Actually, raw natural gas usually contains foreign droplets before
where p is the pressure of the fluid. The superscripts in and out re-
entering into the supersonic separator in practical operation and
present inlet and outlet conditions.

Fig. 1. Structural diagram of supersonic separator with a swirling generator.

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H. Ding, et al. Applied Thermal Engineering 171 (2020) 115074

The recovery of dry gas at the outlet is defined as where the total energy is E and hlg is the latent heat, J kg−1. The ef-
cpg μ
fective turbulent thermal conductivity is λ eff = λ g + Pr tu . The devia-
Q dry Q in − Qwet tu
ψ= × 100\% = × 100\% toric stress tensor (τij )eff is defined by
Q in Q in (2)
where Q in , Q dry and Qwet represent the mass flow rates at inlet, dry and ∂u¯ gj ∂u¯ gi ⎞ 2 ∂u¯ gk
(τij )eff = μ ⎛⎜ + ⎟ − μeff δij
wet gas outlets. ⎝ ∂x i ∂x j ⎠ 3 ∂xk (8)
The dew point depression ΔTd is defined as [40],
where the effective turbulent viscosity is μeff = μ + μtu and the turbu-
ΔTd = Tdin − Tdout (3) lent viscosity μtu is described by

where T is gas temperature and the subscript d represents dew point. In ρg k 1


μtu =
fact, even if no separation occurs, the partial pressure of water vapor ω max ⎡ 1 , ΩF2

and dew point at dry gas outlet will also decrease due to the gas ex- ⎣ a∗ a1 ω ⎦ (9)
pansion. Thus, the dew point depression ΔTd at dry gas outlet should be where k and ω are turbulence kinetic energy, J·kg and specific dis- −1

divided into two parts, ΔTd1 due to expansion (without phase change) sipation rate, s−1, respectively. The strain rate magnitude is
and ΔTd2 due to separation (with phase change), namely Ω = 2Si,j Si,j and the component of mean strain rate Si,j is computed by
ΔTd = ΔTd1 + ΔTd2. The effective dew point depression is ΔTd2 due to
the condensation and separation. Si,j =
1
2 ( ∂u¯j
∂x i
+
∂u¯i
∂x j ). The coefficient a* is a low-Reynolds number cor-
The water removal rate ηv at dry gas outlet is calculated by rection. a1 is a constant 0.31. F2 is the blending function.
The species transport equation for gas phase is expressed by
χvin − χvdry
ηv = × 100\%
χvin (4) ∂ ∂ ∂ ⎛ ∂cs ⎞
(αg ρg cs) + (αg ρg u j cs) = ⎜Ds α g ρg ⎟ + Scs
∂t ∂x j ∂x j ⎝ ∂x j ⎠ (10)
where, χ is the mole fraction of water vapor and the subscript v re-
presents the water vapor. where cs is the species mass fraction and Ds is mass diffusion coefficient.
Scs is source term in species transport equation. If the species is water
3. Mathematical model vapor, Scs = −(mhom + mhet).
The turbulence kinetic energy and specific dissipation rate for gas
3.1. Multi-fluid model for condensation-evaporation swirling flow phase are expressed as:

The multi-fluid model for condensation-evaporation swirling flow in



∂t
(ρg k ) +

(ρ kugj)
∂x j g
=

∂x j

(μ + ) ⎤⎦ + G − Y

μtu
σk
∂k
∂x j k k

supersonic separator was built according to the following assumptions: ∂ρg ω


⎡ (μ + ) ⎤⎦ + G − Y + D
∂ ∂ μtu ∂ω
(i) The droplet is spherical; (ii) The released latent heat is completely ∂t
+ (ρ ωugj)
∂x j g
= ∂x j σω ∂x j ω ω ω
⎣ (11)
absorbed by the gas phase due to the comparatively small heat capacity
of droplet; (iii) both homogeneous and heterogenous condensations are where Gk and Gω are the generation of k and ω. Yk and Yω are the
considered; (iv) For the heterogenous condensation, the concentration dissipations of k and ω. Dω is cross-diffusion term. σk and σω are the
nhetin and radius rhetin of the inlet foreign droplets (mainly contains turbulent Prandtl number.
water) are specified at the inlet; (v) The velocity slip between the gas The dispersed homogeneous and heterogeneous (foreign) droplet
and dispersed liquid phase is taken into account. number concentrations nhom and nhet (m−3) are calculated by
The mass conservation equation of the gas phase (humid gas) is ∂nhom ∂
expressed as + (nhom u j,hom ) = J − nhet f
∂t ∂x j (12)
∂αg ρg ∂
+ (αg ρg ugj) = −(mhom + mhet ) ∂nhet ∂
∂t ∂x j (5) + (nhet u j,het ) = 0
∂t ∂x j (13)
where the subscript g represent gas phase. αg, ρg and ugj are the volume
where the subscripts hom and het represent homogenous and hetero-
fraction, density and mean velocity component of gas phase.
genous. f is the mean collision frequency of one heterogenous droplet
αg = 1 − αhom − αhet . The source items mhom and mhet are liquid mass
with others homogenous droplets. J is nucleation rate, m−3 s−1. The
changing rates from homogenous and heterogenous condensations,
homogeneous and heterogeneous volume fraction αhom and αhet are
respectively, kg m−3 s−1. The momentum conservation equation of the
computed as follows,
gas phase is computed by
∂αhom ρl 3
∂ 4πrhom
∂αg ρg ugi ∂ + (αhom ρl u j,hom ) = mhom − nhet fρl
+ (αg ρg ugi ugj) ∂t ∂x j 3 (14)
∂t ∂x j
∂αhet ρl 3
∂p ∂ ⎡ ∂ugj ∂ugi 2 ∂ugk ⎞ ⎤ ∂ ∂ 4πrhom
= − αg + αg μg ⎜⎛ + − δij + (αhet ρl u j,het ) = mhet + nhet fρl
⎟⎥ + ∂t ∂x j 3
∂x i ∂x j ⎢ ⎝ ∂x i ∂x j 3 ∂x k ⎠⎦ ∂xj (15)

¯
(−αg ρg u′gi u′gj ) − (mhom + mhet ) ugi − FDi where ρl is density of water droplet. Thus, the effective densities of
(6)
homogenous and heterogenous droplet are
where μg is the dynamic viscosity of gas phase, i, j and k are tensor ρ hom = αhom ρl , ρ het = αhet ρl (16)
notations. ugi′ is the fluctuating component of the fluid velocity. FDi is
the component of drag force. δij is the component of Kronecker delta. The velocity components uj,hom and uj,het for the homogenous and
The energy conservation equation of the gas phase is described by heterogenous droplets in liquid phases are calculated by

∂αg ρg E ∂ ∂αhom ρl u i,hom ∂


+ [αg (ρg E + p) ugj] + (αhom ρl u i,hom u j,hom ) = mhom ugi + FDi,hom
∂t ∂x j ∂t ∂x j (17)

∂ ⎡ ∂Tg ∂αhet ρl u i,het ∂


= αg (λ eff ) + αg ugi (τij )eff ⎤ (m m )h
⎥ + hom + het lg + (αhet ρl u i, het u j,het ) = mhet ugi + FDi,het
∂x j ⎢
⎣ ∂x j ⎦ (7) ∂t ∂x j (18)

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H. Ding, et al. Applied Thermal Engineering 171 (2020) 115074

where FDi,hom and FDi,het are the components of drag force between the where TR = Tg/Tc is the reduced temperature and Tc is critical tem-
continuous and the dispersed phases. perature (647.3 K). The dew point temperature Td is deduced by [48]

⎧ 2663.5 (12.537 − lg pv ), Td⩽213.65 K


3.2. Nucleation rate and droplet growth model
⎪ − 60.45 + 7.0322 ln p + 0.37(ln p )2 + 273.15, 213.15 K ⩽ T ⩽
v v d
Td =
In this study, classical nucleation rate J (m−3 s−1) is calculated by ⎨ 273.15 K
[46] ⎪ 2
⎩− 35.957 − 1.8726 ln pv + 1.1689(ln pv ) + 273.15, Td >273.15 K
υρg2 2σ 16π υ2σ 3 (29)
J= exp ⎜⎛− ⎞

Ss πmm5 ⎝ 3 (kB Tg )3 (lnSs)2 ⎠ (19) The latent heat of vapor at the arbitrary temperature is computed by
[49]
where υ, σ, mm and kB represent the volume of single water molecule
(m3), liquid surface tension (N m−1), the mass of single water molecule 1 − Tg 647.3 ⎞0.38
hlg = hlg0 ⎛
(2.99 × 10−26 kg), and Boltzmann’s constant (1.38 × 10−23 J K−1)
⎜ ⎟

⎝ 1 − 0.5767 ⎠ (30)
respectively. The supersaturation of vapor is Ss = pv/ps(Tg), where ps
(Tg) is the water vapor saturation pressure at temperature Tg. where the latent heat of water hlg at the normal boiling point hlg0 is
The critical nucleation radius rc of the droplet is described by 2262.2 kJ·kg−1.


rc = 3.3. Droplet coalescence and drag model
ρl Rv Tv ln(Ss ) (20)
where, Rv represent specific gas constant of water vapor. The mean The mean collision frequency f of one heterogeneous foreign droplet
radii rhom and rhet are expressed as (collector) with surrounding smaller homogeneous droplets is described
1 1
by (O’Rourke [50])
3α 3 3α 3
r hom = ⎛ hom ⎞ , r het = ⎛ het ⎞
⎜ ⎟ ⎜ ⎟ f = nhom π (r het + r hom )2urel (31)
⎝ 4πn hom ⎠ ⎝ 4πnhet ⎠ (21)
where urel = |uj,het − uj,hom| is relative velocity between homogeneous
Thus, the liquid mass changing rates mhom and mhet are calculated
and heterogeneous droplets. After the collisions, these smaller homo-
by
geneous droplets are collected by heterogeneous droplet, and the het-
4πrc3 2 dr hom 2 dr het
erogeneous droplet radius increases up gradually. It is necessary to
mhom = Jρl + nhom ρl 4πrhom , mhet = nhet ρl 4πrhet
3 dt dt (22) consider the effect of drag force in two-phase momentum equations for
the swirling flow with strong centrifugal force. For smaller Reynolds
The growth rate of droplet (both condensation and evaporation) is
numbers, the molecular viscous force dominates [51]. Thus, according
expressed as
to the Stokes’ law, the drag force FD is given by [52]
3
∑ ak ⎯→
⎯ 9μg ⎯→
⎯ 9μg
dr FD,hom = αhom (→
ug − →
uhom ), FD,het = αhet (→
ug − →
uhet )
= k= 1 (Tr − Tv ) 2
2rhom Cc 2
2rhet Cc
dt ρl hlg (23)
(32)
where ak is heat transfer coefficient. The subscript k represents different where Cc is the empirical Cunningham slip correction factor which is
species in gas phase. The droplet surface temperature Tr is calculated by calculated by
rc
Tr = Td (pv ) − D T Cc = 1 + 2Kng (1.257 + 0.4e−1.1 (2Kng) )
(33)
r (24)
where DT is subcooling, =Td(pv) − Tg. Td(pv) is the dew point tem-
perature at local water vapor pressure. 4. Experimental validation
The flow inside the supersonic separator is strongly rotational and
turbulent. The centrifugal acceleration can achieve 106–107 m s−2 [24]. 4.1. Numerical implementation
The velocity slip between the gas and liquid phase has to be taken into
account, for purpose of calculating the heat transfer coefficient accu- All the cases were simulated by ANSYS FLUENT, while the gov-
rately. The heat transfer coefficients ak between the water droplet and erning equations and the source terms were performed with C code by
each gas species are calculated by the User-Defined-Scalar (UDS) and User-Defined-Function (UDF) in-
terfaces. The density-based solver with implicit formulation and the
λk 1
ak = (2 + 0.6Re0.5
p Prg
0.33)
Roe-FDS for flux type were utilized for calculating governing equations
2r 1 + 2 8π Γk
1.5 Pr k
× 1 + Γk
Knk (25) of multi-fluid flows including the gas and liquid phases. The second-
order upwind scheme was employed for discretization. The gradients of
where Rep, Г, λ and Kn are Reynolds number, specific heat ratio,
flow variables for spatial discretization were calculated by the least
thermal conductivity and Knudsen number, respectively. For the water
squares cell based gradient evaluation. For turbulence model, the SST k-
vapor, Kn is expressed as
ω model was selected as the viscous model of gas phase. The structured
3μ v Rv Tg quad-map meshes were utilized for better convergence. For inlet
Knv = boundary conditions, the total temperature and pressure of fluid were
4pv r (26)
given. The static pressure was set at the outlet. The concentration nhetin
The relative Reynolds number Rep, het is described as of inlet foreign droplet with a given radius rhetin were specified at the
inlet. The constant-temperature condition which is equal to inlet gas
Re p, het = 2ρg r het |→
uhet − →
ug| μg = 2ρg r het |Vs| μg (27) temperature was enforced at walls. The solutions of density ρg, velocity
where Vs is the slip velocity, =uhet-ug. Besides, the liquid surface ten- ugj, energy E, turbulence kinetic energy k, specific dissipation rate ω of
sion σ is calculated by [47] the gas phase, the droplet concentration nhom and nhet, the liquid phase
effective density ρhom and ρhet, the liquid velocity uj,hom and uj,het were
σ = (85.27 + 75.612TR − 256.889TR2 + 95.928TR3 ) × 10−3 (28) converged to normalized residual mean square of 10−5.

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H. Ding, et al. Applied Thermal Engineering 171 (2020) 115074

4.2. Experimental apparatus Table 1


The experiments for model validation.
This study mainly focuses on simulation analysis. The experiments Model validation Device Working fluid
are necessary to verify the accuracy of multi-fluid (slip) mathematical
model. Thus, an experimental apparatus including a pure air generator, Homogenous condensation in transonic 2D nozzle [54] moist nitrogen
flow 3D nozzle moist air
humidifier and acquisition controller [53] was built, as shown in Fig. 2.
Particle behavior in swirling flow Cyclone separator air
The pure air (dry gas) generator is composed of a compressor, a puri- [55]
fier, a gasholder, a self-operated pressure regulating valve and a mo- Mass flow rate in swirling flow Supersonic separator air
torized valve with feedback adjustment for controlling the pipeline
pressure (0.1–0.6 bar, 0.2%) and flowrate (0.5–100 m3/h, 0.5%). The
gas temperature (30–50 °C) is controlled by a tubular pipe heater with a the present CFD model was validated by some experiments in the Laval
silicon-controlled rectifier regulator. For controlling the relative hu- nozzle. The first validation was derived from Wyslouzil test [54] with a
midity (0–100%) of the moist gas, the micron droplets are generated by 2D nozzle where the working fluid is moist nitrogen. The length, inlet
a high-pressure micro-fog generator, and then evaporate within the diameter and throat diameter of 2D nozzle are 133 mm, 40 mm and
evaporator to form the moist air at the upstream of the Laval nozzle and 12.7 mm with diffuser angle of 1.8° and the ratio of the outlet area to
supersonic separator. A Vaisala HUMICAP humidity and temperature the throat area Aout/Ant is 1.58. The inlet stagnation pressure
probe HMP110 is used to measure relative humidity and temperature. p*in = 60.0 kPa and temperature T*in = 287 K with water vapor partial
The light extinction method and image method are used to confirm that pressure pvin = 1.00, 0.50 and 0.26 kPa respectively.
there is no any water droplet at the inlet. Then, the experimental data of A number of mesh tests were performed to guarantee a grid-in-
3D supersonic nozzle and supersonic separator can be used to validate dependent solution. First, the effect of node numbers (N1 × N2) was
the prediction accuracy of homogenous condensation in transonic flow studied. The first procedure (N1 fixed and N2 varies) revealed that the
and mass flow rate in swirling flow, respectively. For 3D supersonic mass flow rates with grid nodes 60 × 280, 60 × 300 and 60 × 320 are
nozzle, the time-averaged pressure signals along the axis of nozzle and 1.781, 1.768 and 1.767 kg s−1 m−1 where the relative errors of two
the pressure fluctuation signals at a specific point near nozzle wall are adjacent cases are −0.73% and −0.056%, and the mass-weighted
measured by 12 pressure probes. For supersonic separator, its mass flow average velocities at outlet are 465.379, 461.247 and 460.826 m/s
rate at different swirl strength are calibrated by a flow standard facility. where the relative errors of two adjacent cases are −0.98% and
−0.091%, respectively. The second procedure (N2 fixed and N1 varies)
4.3. Model validation revealed that the mass flow rates with grid nodes 50 × 300, 60 × 300
and 70 × 300 are 1.782, 1.768 and 1.765 kg s−1 m−1 where the re-
Because the size of nozzle of supersonic separator is small and the lative errors are −0.79% and −0.17%, and the mass-weighted average
swirling speed is fast, it is very difficult hard to measure condensation velocities at outlet are 465.213, 461.247 and 460.740 m/s where the
and swirling flow inside supersonic separator experimentally. relative errors of two adjacent cases are −0.85% and −0.11%, re-
Therefore, the validation of homogenous condensation and swirling spectively. Therefore, a grid size of 60 × 300 ensured a grid in-
flow are also performed by using supersonic nozzle and cyclone se- dependent solution. The meshes near the throat and boundary layer
parator. Model validation can be divided into three steps. The first step were refined for better capturing the condensation and shock phe-
is validation of homogenous condensation in a 2D nozzle and a 3D nomena in the transonic flow, as show in Fig. 3(a). It is observed that
nozzle. The second step is validation of particle behavior in cyclone the numerical results of condensation-induced pressure jumps are in
separator. The third step is validation of mass flow rate of gas through well agreement with the experimental data, as show in Fig. 3(b). The
the supersonic separator. The experiments for model validation are present CFD model can predict 2D nonequilibrium condensation pro-
shown in Table 1. cess in the transonic flow accurately.
The second validation was performed in a 3D toroidal-throat su-
4.3.1. Condensation flow in Laval nozzle personic nozzle with a throat diameter d of 10 mm and a curvature
The prediction accuracy of homogenous condensation process via radius of 870 mm in our own experiment, as shown in Fig. 4. The grid of

Fig. 2. The experimental apparatus for the nozzle and supersonic separator.

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H. Ding, et al. Applied Thermal Engineering 171 (2020) 115074

(a) The configuration and mesh of Laval nozzle

(b) The profiles of pressure ratio at the nozzle center downstream of nozzle throat
Fig. 3. Comparisons of CFD results with experimental data reported by Wyslouzil.

Fig. 6. A series of grid independence analysis revealed that the grid


numbers of 53,468 ensured a grid independent solution. The working
fluid is dry air where Φ*in = 0%. The pressure at the top of vortex
finder near the exit tube is 1 atm. The inlet velocity is 20 m s−1. The
solid particle material was a typical cement raw material with a con-
centration of 1%. The solid particle is equivalent to the inlet hetero-
geneous droplet of multi-fluid model without condensation. A com-
parison of the tangential velocity of gas flow field between the
simulation and experiment is plotted in Fig. 7. A comparison of col-
lection efficiency of particles between the simulation and experiment is
plotted in Fig. 8. The simulation values agree well with the experi-
mental data which indicates that the present model can predict beha-
Fig. 4. The configuration of 3D toroidal-throat supersonic nozzle. vior of particles in swirling flow very well.

3D nozzle is axisymmetric, thus, a series of grid independence analysis


4.3.3. Mass flow rate in supersonic separator
revealed that a grid size of 50 × 260 ensured a grid independent so-
The effects of swirl strength on the mass flow rate within a super-
lution. The working fluid is moist air. In all cases, the inlet total pres-
sonic separator were also validated. The experimental data was derived
sure is 300 kPa and the static pressure at the outlet is 1 atm. The outlet
from our experiment. The separator is 528 mm long, and has 70 mm/
static temperature is equal to the inlet value. The pressure profiles near
80 mm and 40 mm wall diameters at inlet and outlet. The diameters of
the nozzle wall with different inlet relative humidity Φin and tem-
the central body and the shell wall at the throat are 14 mm and 20 mm,
perature T*in are shown in Fig. 5(a) and (b), respectively. It also in-
respectively. The drainage gap size is about 2.0 mm. The only differ-
dicates that CFD data are well consistent with experimental results. The
ence between supersonic separator A and B is the inlet diameter, se-
pressure jump due to released latent heat inside the 3D supersonic
parator A is 80 mm and separator B is 70 mm.
nozzle was captured accurately.
The configuration and structured mesh of the supersonic separator
A whose nominal swirl strength is 20% and the recovery of dry gas
4.3.2. Particle behavior in the cyclone separators outlet is 0.72, are plotted in Fig. 9. A series of grid independence
To evaluate the simulation results of swirling flow by the present analysis revealed that the numbers of hexahedral meshes 576,300 en-
model, an experiment of a cyclone separator reported by Wang [55] sured a grid independent solution. Besides, nominal swirl strength of
was utilized. The configuration of the cyclone separator is shown in supersonic separator B is 50%. The comparison of mass flow rates

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H. Ding, et al. Applied Thermal Engineering 171 (2020) 115074

(a) Pressure profiles near the nozzle


wall with different inlet relative humidity

Fig. 6. Configuration of the cyclone separator (Unit: mm).

(b) Pressure profiles near the nozzle


wall with different inlet temperature
Fig. 5. Comparisons of CFD results with our own experiments.

between simulation and experiment is shown in Fig. 10. The swirl


strength S is defined as the ratio of the tangential velocity ut to the axial
velocity ua (~318 m/s) at the throat. The dimensionless mass flow rate
M is normalized by the mass flow rate with no swirling flow. It is found
that the maximum error is about 2.7% at the swirl strength of 93.4%. It
indicates that the proposed model predicts the strongly swirling su-
personic flow accurately. Fig. 7. Tangential velocity in a cyclone separator.

5.1. Flow field, interphase slip and droplet behavior


5. Results and discussion
Four cases were utilized to analyze the gas flow field, interphase slip
Firstly, the detailed predictions for the gas and liquid (droplet) and droplet behavior. The common conditions are T*in = 30 °C,
phases behaviors, especially for interphase velocity slip and liquid Φ*in = 100% (pvin = 4246 Pa), pout = 100 kPa, ρhetin = 0.01 kg m−3
phase distribution are illustrated. Then, the results of dehydration (volume fraction αhetin ≈ 1 × 10−5). The differences among these
performance (dew point depression ΔTd and water removal rate ηv) of cases are as follows, Case 1-Case 3: p*in = 167, 200 and 250 kPa
the supersonic separator at various conditions, i.e., total pressure, ra- (γ = 0.4–0.6) with the same rhetin = 1.0 μm and nhetin = 2.39 × 1012
dius and concentration of inlet foreign droplet, and swirl strength were m−3. Case 4: rhetin = 0.4 μm with p*in = 250 kPa (γ = 0.6), and
obtained. nhetin = 3.74 × 1013 m−3. If not specified, the supersonic separator A
with nominal swirl strength S = 20% is assigned by default.

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H. Ding, et al. Applied Thermal Engineering 171 (2020) 115074

However, it should be noticed that two-phase sound speed cgl is sensi-


tive to pressure. For case of p*in = 167 kPa, the minimum pressure
inside supersonic separator is 56.098 kPa with Tg = 290.67 K. if
αl = 6.5 × 10−5, it shows cg = 341.78 m s−1 and cgl = 326.72 m s−1
where the error between them is 4.4%. Thus, two-phase Mach number
should be utilized to calculate Mach number, i.e. Ma = u/cgl.
The Mach number contours for Case 1 and Case 3 inside the su-
personic separator A are plotted in Fig. 11. It illustrates the complexity
of shock wave, especially near the drainage channel. For Case 1 with
smaller pressure loss (γ = 0.4) as shown in Fig. 11(a), the maximum
Mach number upstream of the shock is 1.239 at axial position
xa = 91 mm, where the maximum subcooling DT is 25.84 °C.
On the other hand, when the inlet pressure increases up to 250 kPa,
the shock wave will move downstream and reach the gas-liquid se-
paration point with the maximum Mach number of 1.765 and sub-
cooling DT of 48.76 °C, as plotted in Fig. 11(b). The fluid inside the
drainage channel instantaneously reduces to subsonic speed, while the
central fluid keeps supersonic and then a secondary shock occurs at the
dry gas outlet channel. This complex shock is called lambda shock-
system accompanying irreversible entropy production and loss of ex-
Fig. 8. Comparisons of collection efficiency between CFD results with experi-
ment. ergy [58].
The tangential velocity and swirl strength dominate the slip velocity
and separation efficiency. However, the strong swirl strength decreases
5.1.1. Shock wave and swirl strength Mach number and increases the static temperature inside the Laval
The sound speed in air-water two-phase mixture fluid can be cal- nozzle, damaging the expansion characteristics of the nozzle [24].
culated by (Wood’ law [56]) Fig. 12(a) and (b) show the tangential velocities and streamlines of the
1 gas phase for Case 3 in supersonic separators A and B. Fig. 12(a) il-
cgl = lustrates that the maximum tangential velocity in the separator A is
(αg K g −1 + αl Kl−1)(ρg αg + ρl αl ) (34)
ut = 67.7 m s−1 and the maximum centrifugal acceleration is
where αg is volume fraction of gas, and αl = 1 − αg is volume fraction of 8.70 × 105 m s−2 with swirl strength of 22%. In Fig. 12(b), the max-
liquid, K is bulk elastic modulus. For liquid water, Kl = 2.19 × 104 Pa. imum tangential velocity in the separator B reaches 136.1 m s−1 and
For ideal air gas, Kg = 1.4 pg. the corresponding centrifugal acceleration is 3.5 × 106 m s−2 where
Another model proposed by Kieffer [57] is as follows the swirl strength achieves 45%. Then, the water vapor will be con-
densed and separated from the non-condensable gas due to the low
cgl temperature and the strong centrifugal force.
⎛ Gg, ref ⎞1 Γ
pref − p ⎞
= ⎜βρl, ref ⎛⎜ ⎟ + exp ⎛

⎞ ⎟

⎝ p ⎠ ⎝ Kl ⎠ ⎟ 5.1.2. Condensation and evaporation zones


⎝ ⎠
1 2 −1
As we know, the water vapor will condense in the supersaturated
1 Γ
⎧ ⎡ βρl, ref Gg, ref 1 pref − p ⎤ ⎫ region and the droplets will evaporate in the unsaturated region. As
[(1 + β ) ρl, ref ]1 2 ⎢ + exp ⎛



⎨ Γp(1 + Γ) Γ Kl ⎝ Kl ⎠ ⎦ ⎬ previously mentioned, both dry gas outlet and wet gas outlet are
⎩ ⎣ ⎭ (35)
100 kPa for Case 1 and Case 3. The heterogenous condensation is
where β is gas-liquid mass ratio. Gg,ref = Tref Rg/ρrefΓ−1.
ρl,ref and pref are dominant and the homogenous condensation can be ignored in these
chosen as 1000 kg/m3 and 1 bar. two cases.
It is found that the results of Eqs. (34) and (35) are almost same. The contour of the liquid mass changing rate mhet for Case 1 when

Fig. 9. The configuration and structured meshes of the supersonic separator A.

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H. Ding, et al. Applied Thermal Engineering 171 (2020) 115074

mass changing rate mhet is from −936.7 to 958.3 kg m−3 s−1 (max-
imum latent heat release rate is 2.51 × 109 J m−3 s−1). The liquid mass
changing rate at the near wall cells are shown in Fig. 13(b). It is found
that the evaporation process occurs in two parts, the near-wall heating
zone and pressure recovery zone.
For the purpose of demonstrating the condensation and evaporation
processes, the distributions of the droplet radius and the vapor mass
fraction along the axial direction are plotted in Figs. 14 and 15. The
radial positions xr of Line 1-Line 3 are 7 mm, 8 mm and 9 mm, re-
spectively. Fig. 14 shows radius distributions of heterogenous
droplet along Line 2 at different total pressures when inlet foreign
droplets rhetin = 1.0 μm, and ρhetin = 0.01 kg m−3.
It indicates that the heterogenous droplet size starts growing rapidly
at the throat. Along with the increasing of heterogenous droplet size, its
changing rate becomes smaller. The heterogenous droplet size will
reach a maximum at the location of shock wave, and then begin to
decrease due to the evaporation. The heterogenous droplet size grows
to 1.44, 1.83 and 2.26 μm at xa = 91.35, 174.50 and 227.40 mm for
Fig. 10. The swirl strength effect on mass flow rate in the supersonic separator.
p*in = 167, 200 and 250 kPa.
The mass fraction of the water vapor in the gas phase also can re-
p*in = 167 kPa is plotted as Fig. 13(a). It reveals that both condensation flect the changes of condensation and evaporation. Fig. 15 shows the
and evaporation processes occur inside the separator. The global range results of mass fraction of water vapor for Case 3 with rhetin = 1.0 μm
of the liquid mass changing rate mhet is from −402.3 to 712.1 kg m−3 and Case 4 with rhetin = 0.4 μm. It is found that the mass fraction of
s−1. According to Fig. 11(a), the shock occurs at axial position water vapor at entrance of drainage will increase with the decrease of
xa = 91 mm which coincides with the evaporation onset. This is be- the inlet foreign droplet size, which means the smaller inlet foreign
cause the fluid velocity begins to slow down and the static temperature droplet radius rhetin is, the worse dehydration performance is. The dif-
recovers to high value downstream of shock wave, and then droplets ferences of performance are attributed to the interphase velocity slip
evaporate into the gas phase gradually. and the uneven distribution of liquid phase.
When the inlet pressure increases to 250 kPa, the rates of both
condensation and evaporation are bigger. The global range of liquid

(a) Case 1: p*in = 167 kPa ( = 0.4)

(b) Case 3: p*in = 250 kPa ( = 0.6)


Fig. 11. The Mach number contours of the gas phase inside the supersonic separator.

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H. Ding, et al. Applied Thermal Engineering 171 (2020) 115074

(a) Separator A: maximum tangential velocity is ut = 67.7 m s-1.

(b) Separator B: maximum tangential velocity is ut =136.1 m s-1.


Fig. 12. Tangential velocities and streamlines of the gas phase for Case 3 in separators A and B.

(a) at the core region for Case 1: p*in = 167 kPa ( = 0.4)

(b) at the near wall cells for Case 3: p*in = 250 kPa ( = 0.6)
Fig. 13. The contours of the liquid mass changing rate mhet in the condensation and evaporation zones.

5.1.3. Slip velocity and liquid phase distribution of the drag force. Besides, the axial slip velocity along the radial di-
The slip velocity and drag force play a critical role in controlling the rection is from zero (central inner body) to a negative minimum to zero
trajectory of droplet which can determine the separation performance again and then to positive maximum at the shell wall. Comparing
in the cyclone section. As the main factor, the effect of inlet foreign Fig. 16(a) and (c), it indicates that the bigger inlet droplet diameter is,
droplet radius on the slip velocity distribution is discussed firstly. the bigger droplet inertia is, and the larger slip speed will be. Fig. 16(b)
The axial and radial components of slip velocity at different loca- and (d) show the radial component of slip velocity at different loca-
tions of Case 3 and Case 4 are shown in Fig. 16. As shown in Fig. 16(a), tions. As we know, the radial slip speed causes the droplets to separate
the magnitude of axial component of slip velocity decreases gradually from primary gas fluid. It is obvious that the axial velocity of centrifugal
along the flow direction where the maximum velocity lag of the droplet droplet is larger than local velocity of gas phase. The maximum radial
for xa = 90, 140, and 190 mm is 48.2, 33.9 and 24.3 m s−1 as the result slip speed is 29.2 m s−1 for Case 3 and 8.26 m s−1 for Case 4.

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H. Ding, et al. Applied Thermal Engineering 171 (2020) 115074

condition is assumed, thus the streamline of liquid phase goes around a


circle at the cyclone as shown in Fig. 17(a) and the effective density of
heterogeneous droplet is almost uniform. Due to no slip in single-fluid
model, the value of heat transfer coefficient of Eq. (25) is smaller than
that of multi-fluid model. The droplet number of heterogenous droplet
(nhetin = 2.39 × 1012 m−3 in this case) is not usually enough to prevent
the homogenous nucleation in single-fluid model. The percentages of
heterogenous and homogenous condensations are 8% and 90%. When
switching to the multi-fluid slip model, the streamline at the cyclone
section is centrifugal motion as shown in Fig. 17(b). The heat transfer
coefficient around the heterogenous droplet sharply increases as a re-
sult of the interphase slip velocity. In this situation, the homogeneous
condensation almost disappears. The effective density of heterogeneous
droplet near the shell wall increase sharply due to the centrifugal force
leading to the achievement of the separation performance.
Besides, the effective density contour of heterogeneous droplet for
Case 4 with rhetin = 0.4 μm by using multi-fluid model is plotted in
Fig. 18. Compared with the contour of Case 3 with rhetin = 1.0 μm in
Fig. 17(b), it reveals that the large droplet trajectory deflects faster than
Fig. 14. The axial distributions of the droplet radius at Line 2 for Case 1, Case 2 the small droplet as the result of the centrifugal force. However, if the
and Case 3. droplet size is quite large, the residence time of heterogenous droplet in
core flow will be too short which causes the insufficient heterogenous
condensation and the failure of the separation. Thus, the inlet hetero-
genous droplet size should be moderate.

5.2. Dehydration performance

The results of the dehydration performance of supersonic separator


at different inlet conditions, when T*in = 30 °C, Φ*in = 100%
(pvin = 4246 Pa) and pout = 100 kPa, are shown in Tables 2–4. The
variable pvdry is water vapor partial pressure at the dry gas outlet where
the droplets evaporate again. Tddry and ΔTddry represent the dew point
and the dew point depression at the dry gas outlet.
Fig. 19 shows the curves of the dew point depression ΔTddry versus
inlet foreign droplet size rhetin when p*in = 167 and 250 kPa, where
ΔTd1dry due to expansion at dry gas outlet are 8.77 and 15.22 °C, re-
spectively. It is observed that there is an optimal radius of inlet foreign
droplets to maximize the dehumidification and efficiency of the device.
For p*in = 250 kPa, the maximum of ΔTddry is 42.41 °C (ηv = 87.82%)
at the optimal radius rhetin of 0.85 µm, while for p*in = 167 kPa, the
maximum of ΔTddry is 17.52 °C (ηv = 42.50%) at the optimal radius
Fig. 15. The axial distributions of the mass fraction of water vapor for Case 3 rhetin of 1.25 µm. The residence time of droplet is the main factor
and Case 4. leading to above result which was explained clearly in Figs. 17(b) and
18.
The distribution of liquid phase in the centrifugal field was ana- In addition, as shown in Tables 2 and 3 and Fig. 19, when the inlet
lyzed. At first, the solution accuracy of the two-phase mass transfer was foreign droplet size is less than a critical size, the dew point depression
checked. Taking the results of Case 3 as example, the flow rate of inlet ΔTddry will be smaller than ΔTd1dry where the water removal rate ηv is
foreign droplets is Qhetin = 2.75 × 10−4 kg s−1. For the single-fluid negative, the separator would be ineffective. The critical sizes of rhetin
model, inlet total mass flow rate of gas phase is Qgin = 7.83 × 10−2 kg are 0.26 µm and 0.45 µm for p*in = 250 and 167 kPa, respectively.
s−1, thus inlet mass flow rate of water vapor is Qvin = 8.32 × 10−4 kg When the inlet foreign droplet size continues to decrease, it will begin
s−1 because inlet mass fraction of water vapor is cs,vin = 1.063 × 10−2. to evaporate into the gas phase instead of condensing, thus the water
The outlet flow rate of water contains three parts, Qhetout of hetero- vapor partial pressure at the dry gas outlet increases and the removal
geneous droplets, Qhomout of homogeneous droplets and Qvout of vapor, rate ηv is negative, resulting in the failure of separation.
where Qhetout = 3.40 × 10−4 kg s−1, Qhomout = 7.51 × 10−4 kg s−1 The values of dew point depression ΔTddry at different inlet effective
and Qvout = 2.4 × 10−5 kg s−1 at the gas-liquid separation section densities ρhetin are shown in Fig. 20. It is found that the curve is
(xa = 240 mm). The calculation error of total mass of water between monotonically increasing with the ρhetin for p*in = 250 kPa, where the
the inlet and outlet is 0.72%. On the other hand, For the multi-fluid shock wave is near the entrance of drainage as shown in Fig. 11(b) and
model, Qgin = 7.45 × 10−2 kg s−1 and Qvin = 7.92 × 10−4 kg s−1 at the evaporation is weak. On the other hand, the curve has a maximum
the inlet. The flow rates Qhetout = 9.75 × 10−4 kg s−1, ΔTddry at the optimal effective density of 0.008 kg m−3 for
Qhomout = 3.70 × 10−8 kg s−1 and Qvout = 1.01 × 10−4 kg s−1 at the p*in = 167 kPa. In this situation, the evaporation zone is quite long at
outlet. The calculation error is 0.99%. The results show a favorable the downstream of the shock shown in Figs. 11(a) and 13(a). Although
prediction accuracy for two-phase mass transfer. the water vapor is condensed completely at the condensation zone, it
The streamline and effective density of heterogeneous droplets for re-evaporates again after the shock. When ρhetin is larger than the op-
Case 3 with rhetin = 1.0 μm by using both single-fluid and multi-fluid timal value, the amount of condensation remains the same but the
models are shown in Fig. 17. In single-fluid model, no-slip fluid velocity evaporation increases gradually with the increase of ρhetin, resulting in
the reduction of the dehydration performance.

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H. Ding, et al. Applied Thermal Engineering 171 (2020) 115074

(a) Axial component of slip velocity for Case 3 (b) Radial component of slip velocity for Case 3

(c) Axial component of slip velocity for Case 4 (d) Radial component of slip velocity for Case 4
Fig. 16. The axial and radial components of the slip velocity at different locations.

Figs. 19 and 20 also illustrate the supersonic separator will provide helpful for designing the separator structure and optimizing the se-
better dehydration performance if the pressure loss ratio increases. The paration performance.
dew point depression ΔTd versus the pressure loss ratio γ is plotted in
Fig. 21. The original data of Fig. 21 is also listed in Table 4. It reveals 6. Conclusion
that the dew point depression ΔTddry increases from 6.91 °C
(ηv = 16.23%) to 52.04 °C (ηv = 93.42%) when the pressure loss ratio A novel multi-fluid model with the droplet coalescence and the in-
increases up to 0.7. The larger the pressure loss ratio inputs, the higher terphase force for the homogenous/heterogenous condensation and
the separation efficiency will be. However, high pressure loss ratio evaporation processes in supersonic separator was built to evaluate the
means high energy consumption. dehydration performance. The flow field, slip velocity profile, droplet
Besides, the effect of swirl strength on the separation efficiency was trajectory and liquid phase distribution with different pressure loss
also investigated. The dehydration performance of supersonic separator ratios, the radii and concentrations of inlet foreign droplets were ana-
B with 45% swirl strength is shown in Table 5. The optimal size of inlet lyzed. The dehydration performances were also investigated further.
foreign droplets for heterogenous condensation is 0.28 µm. Compared The conclusions are as follows:
with the results of separator A with 22% swirl strength in Table 2, it is
found that the optimal radius of inlet foreign droplets will be smaller (1) The complex lambda shock-system with maximum Mach number of
when the separator has a stronger swirl strength. These results are 1.765 and subcooling of 48.76 °C was observed in the cyclone

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H. Ding, et al. Applied Thermal Engineering 171 (2020) 115074

(a) Single-fluid (no-slip) model (8% heterogenous +90% homogeneous condensations at xa = 240 mm)

(b) Multi-fluid (slip) model (91% heterogenous + 0% homogeneous condensation at xa = 240 mm)
Fig. 17. Comparisons of streamline and effective density of heterogeneous droplets between single-fluid model and multi-fluid model for Case 3.

Fig. 18. Liquid phase effective density of heterogeneous condensation for Case 4.

Table 2 Table 3
Dehydration performance of supersonic separator A with different rhetin and Dehydration performance of supersonic separator A with different rhetin and
ρhetin of inlet foreign droplets when p*in = 250 kPa (γ = 0.6). ρhetin of inlet foreign droplets when p*in = 167 kPa (γ = 0.4).
rhetin ρhetin nhetin [m−3] pvdry [Pa] Tddry [°C] ΔTddry [°C] ηv rhetin ρhetin nhetin [m−3] pvdry [Pa] Tddry [°C] ΔTddry [°C] ηv [%]
[μm] [kg [μm] [kg
m−3] m−3]

1.0 0.04 9.57 × 1012 86.65 −21.71 51.71 94.90% 1.0 0.04 9.57 × 1012 2059.43 17.80 12.19 19.05%
0.02 4.78 × 1012 130.62 −17.40 47.40 92.31% 0.02 4.78 × 1012 1571.55 13.58 16.42 38.20%
0.01 2.39 × 1012 225.68 −11.48 41.48 86.71% 0.01 2.39 × 1012 1446.73 12.32 17.68 43.11%
0.005 1.20 × 1012 348.99 −6.59 36.59 79.45% 0.005 1.20 × 1012 1483.44 12.69 17.31 41.66%
0.002 4.78 × 1011 736.66 2.63 27.37 56.63% 0.002 4.78 × 1011 1694.78 14.74 15.26 33.35%
0.001 2.39 × 1011 1197.13 9.49 20.51 29.53% 0.001 2.39 × 1011 2113.84 18.22 11.78 16.87%
0.0005 1.20 × 1011 1532.67 13.19 16.81 9.77% 0.0005 1.20 × 1011 2387.42 20.19 9.80 6.13%

2.0 0.01 2.99 × 1011 1319.60 10.93 19.07 22.32% 2.0 0.01 2.99 × 1011 2027.67 17.56 12.44 20.26%
0.5 1.91 × 1013 331.90 −7.16 37.16 80.46% 1.5 7.09 × 1011 1539.66 13.26 16.74 39.45%
0.4 3.74 × 1013 726.40 2.44 27.56 57.24% 0.75 5.67 × 1012 1831.56 15.95 14.05 27.97%
0.3 8.86 × 1013 1418.75 12.02 17.98 16.48% 0.5 1.91 × 1013 2241.32 19.17 10.83 11.86%
0.25 1.53 × 1014 1750.03 15.24 14.76 −3.02% 0.3 8.86 × 1013 2984.91 23.89 6.10 −17.43%
0.2 2.99 × 1014 1999.98 17.34 12.66 −17.74% 0.2 2.99 × 1014 3368.58 25.95 4.05 −32.47%

section, where the maximum tangential velocity was 136.1 m s−1 958.3 kg m−3 s−1 with latent heat release rate of 2.51 × 109 J m−3
and the corresponding centrifugal acceleration was 3.5 × 106 m s−1. When rhetin = 1.0 μm, and ρhetin = 0.01 kg m−3, the hetero-
s−2. genous droplet size grows to 1.44, 1.83 and 2.26 µm for p*in = 167,
(2) The condensation begins to occur at the throat, while the eva- 200 and 250 kPa.
poration appears at the near-wall heating and pressure recovery (3) The magnitude of axial component of slip velocity decreases gra-
zones. The liquid mass changing rate mhet ranges from −936.7 to dually along the flow direction where maximum velocity lag of the

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H. Ding, et al. Applied Thermal Engineering 171 (2020) 115074

Table 4
Dehydration performance of supersonic separator A with different pressure loss
ratio γ when rhetin = 1.0 μm and ρhetin = 0.01 kg m−3 (nhetin = 2.39 × 1012
m−3).
γ [–] p*in [kPa] pvdry [Pa] Tddry [°C] ΔTddry [°C] ΔTd1dry [°C] ηv [%]

0.7 333 83.85 −22.04 52.04 19.58 93.42%


0.6 250 225.64 −11.48 41.48 15.22 86.71%
0.5 200 538.01 −1.60 31.60 11.70 74.66%
0.4 167 1449.39 12.32 17.68 8.77 43.11%
0.3 133 2285.62 19.48 10.52 6.19 23.10%
0.2 125 2845.51 23.09 6.91 3.91 16.23%

Fig. 21. The dew point depression ΔTd versus the pressure loss ratio γ when
inlet heterogenous conditions are ρhetin = 0.01 kg m−3 and rhetin = 1.0 μm.

Table 5
Dehydration performance of supersonic separator B with different rhetin of inlet
foreign droplets when ρhetin = 0.01 kg m−3 and p*in = 250 kPa (γ = 0.6).
rhetin [μm] nhetin [m−3] pvdry [Pa] Tddry [°C] ΔTddry [°C] ηv

1.0 2.39 × 1012 1619.10 14.03 15.97 4.68%


0.75 5.67 × 1012 1075.83 7.93 22.07 36.67%
0.5 1.91 × 1013 542.49 −1.57 31.57 68.06%
0.4 3.74 × 1013 275.71 −9.25 39.25 83.77%
0.3 8.86 × 1013 103.48 −19.86 49.86 93.91%
0.25 1.53 × 1014 116.45 −18.65 48.65 93.14%
Fig. 19. The dew point depression ΔTd versus inlet foreign droplet size rhetin 0.2 2.99 × 1014 370.46 −5.91 35.91 78.19%
when p*in = 167 and 250 kPa. 0.15 7.01 × 1014 1045.34 7.52 22.48 38.46%
0.1 2.39E × 1015 1685.87 14.66 15.34 0.75%

droplet radius should be moderate for the best performance.


(5) There is an optimal size of inlet foreign droplet to maximize de-
humidification and efficiency. When p*in = 250 kPa and
ρhetin = 0.01 kg m−3, the optimal radii of inlet foreign droplet are
0.85 and 0.28 µm in two different separators, in which the max-
imum dew point depression ΔTddry is 42.41 °C and water removal
rate ηv is 87.82% in separator A while maximum ΔTddry = 48.65 °C
and ηv = 93.91% are valid for separator B.

This study provides an insight into dehydration performance of the


supersonic separator considering the condensation, evaporation and
interphase force. For future work, it is important to optimize the
structure of supersonic separator by using present model and in-
vestigate experimentally the water separation efficiency of supersonic
separator via heterogeneous condensation.

Declaration of Competing Interest


Fig. 20. The dew point depression ΔTd versus effective density ρhetin of inlet
The authors declare that they have no known competing financial
foreign droplets when p*in = 167 and 250 kPa.
interests or personal relationships that could have appeared to influ-
ence the work reported in this paper.
droplet is 48.2 m s−1 for rhetin = 1.0 μm. The maximum values of
radial slip velocity are 29.2 m s−1 for rhetin = 1.0 μm and
8.26 m s−1 for rhetin = 0.4 μm, respectively. It is indicated that the Acknowledgement
larger foreign droplet will grow faster due to the enhanced heat
transfer coefficient. This research is supported by National Natural Science Foundation
(4) However, large droplet will deflect faster resulting in a shorter re- of China under Grant 51876143, 61873184, and 61627803, European
sidence time and failure of separation. Thus, the inlet foreign Union’s Horizon 2020 research and innovation programme under the
Marie Sklodowska-Curie grant agreement No 792876.

15
H. Ding, et al. Applied Thermal Engineering 171 (2020) 115074

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