Prasanna sajee

MOCK TEST-TERM 1 - CLASS 12

Class 12 - Chemistry
Time Allowed: 1 hour Maximum Marks: 35

Section A
Attempt any 20 questions
1. Which among the following is not an example of amorphous solids? [0.77]

a) Quartz b) Plastic

c) Glass d) Coke
2. Which of the following is not the characteristic of ionic solids? [0.77]

a) Anisotropic nature. b) Very strong forces of interactions.

c) Brittle nature. d) They are electrical conductors in

solid-state.
3. Schottky defect is observed in crystals when: [0.77]

a) some lattice sites are occupied by b) equal number of cations and anions
electrons. are missing from the lattice.

c) some impurity is present in the d) some cations move from their lattice
lattice. site to interstitial sites.
4. The edge lengths of the unit cells in terms of the radius of spheres constituting face [0.77]
centered cubic, body-centered cubic, and simple cubic unit cell are respectively ________.
4r – – 4r
a) 2r, , 2 √2r b) 2r, 2 √2r,
√3 √3

4r – – 4r
c) , 2 √2r, 2r d) 2 √2r, , 2r
√3 √3

5. Nature of binding forces present in carbon dioxide molecules in solid-state are [0.77]

a) Metallic forces b) Electrostatic forces

c) Hydrogen bonding d) London forces

6. KH value for Ar(g), CO2 (g), HCHO (g) and CH4 (g) are 40.39, 1.67, 1.83 × 10-5 and 0.413 [0.77]

respectively.
Arrange these gases in the order of their increasing solubility.

a) Ar < CH4 < CO2 < HCHO b) HCHO < CO2 < CH4 < Ar

c) Ar < CO2 < CH4 < HCHO d) HCHO < CH4 < CO2 < Ar

7. Colligative properties depend on ________. [0.77]

a) the nature of the solute particles b) the nature of solvent particles.

dissolved in solution.

c) the number of solute particles in d) the physical properties of the solute

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 solution. particles dissolved in solution.
8. Which of the following colligative properties is associated with the concentration term [0.77]
molarity?

a) Osmotic pressure b) Lowering of vap. pressure

c) Elevation in b.p. d) Depression in f.p.

9. Which among the following show positive deviation? [0.77]

a) Chloroform and benzene b) Acetone and aniline

c) Hydrochloric acid and water d) Acetone and carbon disulphide

10. On dissolving sugar in water at room temperature solution feels cool to touch. Under which [0.77]
of the following cases dissolution of sugar will be most rapid?

a) Powdered sugar in cold water. b) Sugar crystals in hot water.

c) Sugar crystals in cold water. d) Powdered sugar in hot water.

11. Assertion (A): HOF bond angle in HFO is higher than HOCl bond angle in HClO. [0.77]
Reason (R): Oxygen is more electronegative than all halogens except fluorine.

a) Both A and R are true and R is the b) Both A and R are true but R is not the
correct explanation of A. correct explanation of A.

c) A is true but R is false. d) A is false but R is true.

12. Assertion (A): F - F bond in the F2 molecule is strong. [0.77]

Reason (R): F atom is small in size.

a) Both A and R are true and R is the b) Both A and R are true but R is not the
correct explanation of A. correct explanation of A.

c) A is true but R is false. d) A is false but R is true.

13. Assertion (A): Ethanol gives iodoform test while methanol does not. [0.77]
Reason (R): Ethanol is less reactive than methanol towards nucleophilic addition reactions.

a) Both A and R are true and R is the b) Both A and R are true but R is not the
correct explanation of A. correct explanation of A.

c) A is true but R is false. d) A is false but R is true.

14. Assertion (A): With HI at 373 K, ter-butyl methyl ether gives ter-butyl iodide and [0.77]
methanol.
Reason (R): The reaction occurs by SN2 mechanism.

a) Both A and R are true and R is the b) Both A and R are true but R is not the
correct explanation of A. correct explanation of A.

c) A is true but R is false. d) A is false but R is true.

15. Assertion (A): Ether behaves as bases in the presence of mineral acids. [0.77]
Reason (R): Due to the presence of lone pairs of electrons on oxygen.

a) Both A and R are true and R is the b) Both A and R are true but R is not the
correct explanation of A. correct explanation of A.

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 c) A is true but R is false. d) A is false but R is true.
16. DNA fingerprinting is used [0.77]

a) to determine paternity of an b) in forensic laboratories

individual

c) all of these d) to identify racial groups

17. Peptide linkage is present in: [0.77]

a) Carbohydrates b) Proteins

c) Vitamins d) Rubber
18. IUPAC name of neo-Pentylbromide is: [0.77]

a) 1-Bromo-3-methylbutane b) 1-Bromo-2,2-dimethylpropane.

c) 1-Bromo-1,2-dimethylpropane d) 1-Bromo-2-methylbutane
19. The reaction of toluene with chlorine in the presence of iron and in the absence of light [0.77]
yields ________.

a) b)

Mixture of and

c) d)

20. Anisole reacts with a mixture of concentrated sulphuric and nitric acids gives [0.77]

a) None of these b) ortho-nitro anisole

c) paranitroanisole d) both ortho and paranitroanisole

21. Which reagent will you use for the following reaction? [0.77]
CH3CH2CH2CH3 → CH3CH2CH2CH2Cl + CH3CH2CHClCH3

a) Cl2 gas in the presence of iron in b) NaCl + H2SO4

dark

c) Cl2 gas in dark d) Cl2/UV light

22. In the reaction [0.77]

a) Phenols are acidic in nature. b) They can donate a proton to a

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 stronger base

c) Cleavage of O - H bond d) All of these

23. Arrange the following compounds in increasing order of boiling point: Propan-1-ol, butan- [0.77]
1-ol, butan-2-ol, pentan-1-ol

a) Propan-1-ol, butan-2-ol, butan-1-ol, b) Pentan-1-ol, butan-2-ol, butan-1-ol,

pentan-1-ol propan-1-ol

c) Propan-1-ol, butan-1-ol, butan-2-ol, d) Pentan-1-ol, butan-1-ol, butan-2-ol,

pentan-1-ol propan-1-ol
24. Assertion (A): On adding NaCl to water its vapour pressure decreases. [0.77]
Reason (R): The addition of non-volatile solute increases the vapour pressure.

a) Both A and R are true and R is the b) Both A and R are true but R is not the
correct explanation of A. correct explanation of A.

c) A is true but R is false. d) A is false but R is true.

25. Assertion (A): Water boils at 373 K as the vapour pressure at this temperature becomes [0.77]
equal to atmospheric pressure.
Reason (R): Vapour pressure of water is less than 1.013 bar at 373 K.

a) Both A and R are true and R is the b) Both A and R are true but R is not the
correct explanation of A. correct explanation of A.

c) A is true but R is false. d) A is false but R is true.

Section B
Attempt any 20 questions
26. The number of atoms per unit cell in a body centered cubic structure is [0.77]

a) 1 b) 4

c) 2 d) 6
27. Which of the following is true about the value of refractive index of quartz glass? [0.77]

a) Different in different directions b) Same in all directions

c) Always zero d) Cannot be measured

28. A compound formed by elements A and B crystallizes in the cubic structure where A atoms [0.77]
are at the corners of a cube and B atoms are the face centre. The formula of the compound
is:

a) A2B b) A2B3

c) AB2 d) AB3

29. The lattice site in a pure crystal cannot be occupied by ________. [0.77]

a) ion b) molecule

c) atom d) electron
30. A 500 g of tooth paste has 0.2 g of fluoride concentration. Fluorine concentration in terms [0.77]
of ppm is

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 a) 250 b) 200

c) 1000 d) 400
31. The unit of Ebullioscopic constant is ________. [0.77]

a) K kg mol-1 or K (molality)-1 b) kg mol-1 K-1 or K-1(molality)-1

c) K mol kg-1 or K (molality) d) mol kg K-1 or K-1(molality)

32. In which unit, the concentration of solution remains independent of temperature [0.77]

a) formality b) normaility

c) molality d) molarity
33. Which of the following statements is false ? [0.77]

a) Units of atmospheric pressure and b) The value of molal depression

osmotic pressure are the same. constant depends on the nature of
the solvent.

c) Relative lowering of vapour pressure d) In reverse osmosis, solvent

is a dimensionless quantity. molecules move through a
semipermeable membrane from a
region of lower concentration of
solute to a region of higher
concentration.
34. Which of the following reaction depicts the oxidizing behaviour of H2SO4? [0.77]

a) Ca(OH)2 + H2SO4 → CaSO4 + 2H2O b) 2PCl5 + H2SO4 → 2POCl3 + 2HCl +

SO2Cl2

c) NaCl + H2SO4 → NaHSO4 + HCl d) 2HI + H2SO4 → I2 + SO2 + 2H2O

35. Which of the following hydrides is the most acidic? [0.77]

a) H2S b) H2Se

c) H2Te d) H2O

36. First compound of inert gas was prepared by Bartlett in 1962. The compound is: [0.77]

a) XeOF4 b) XeO3

c) XeF6 d) Xe[PtF6]

37. Which of the following elements does not show allotropy? [0.77]

a) Arsenic b) Antimony

c) Nitrogen d) Bismuth
38. In question arrange the compounds in increasing order of rate of reaction towards [0.77]
nucleophilic substitution.

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 a) (a) < (c) < (b) b) (c) < (b) < (a)

c) (c) < (a) < (b) d) (a) < (b) < (c)
39. When a haloalkane with β – hydrogen atom is heated with alcoholic solution of potassium [0.77]
hydroxide then:

a) All of these b) elimination of halogen atom from α

– carbon

c) elimination of hydrogen atom from d) alkene is formed as a product

β – carbon
40. IUPAC name of (CH3)3CCl is: [0.77]

a) n – butyl chloride b) 3 – chloro butane

c) t – butyl chloride d) 2-chloro, 2-methyl propane

41. Name the following compound as per the IUPAC system [0.77]
CH3

C H3  -  C  -  C  = CH - C H3
| |

CH3 CH3

a) 3, 4, 4 - trimethylpent - 2 - ene b) 2 diethyl, 3 - ethyl pentene

c) None of these d) 2, 2, 3 - trimethylpent - 4 - ene

42. Mark the correct order of decreasing acid strength of the following compounds. [0.77]

a) d > e > c > b > a b) b > d > a > c > e

c) e > d > b > a > c d) e > d > c > b > a

43. One mole of an organic compound 'A' with the formula C3H8O reacts completely with two [0.77]
moles of HI to form X and Y. When 'Y' is boiled with aqueous alkali forms Z. Z answers the
iodoform test. The compound 'A' is ______.

a) methoxyethane b) ethoxyethane

c) Propan – 2 – o1 d) Propan – 1 – o1
44. Alkenes react with water in the presence of acid as catalyst to form alcohols. [0.77]

a) nucleophilic attack of water on b) Protonation of alkene and

carbocation carbocation

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 c) Deprotonation to form alcohol d) All of these
45. The process of converting alkyl halides into alcohols involves _____________. [0.77]

a) substitution reaction b) addition reaction

c) rearrangement reaction d) dehydrohalogenation reaction

46. Structure of a disaccharide formed by glucose and fructose is given below. Identify [0.77]
anomeric carbon atoms in monosaccharide units.

a) ‘a’ carbon of glucose and ‘e’ carbon b) ‘f’ carbon of glucose and ‘f ’ carbon
of fructose. of fructose.

c) ‘a’ carbon of glucose and ‘b’ carbon d) ‘a’ carbon of glucose and ‘a’ carbon
of fructose. of fructose.
47. Proteins are found to have two different types of secondary structures namely α-helix and [0.77]
β -pleated sheet structure, α-helix structure of protein is stabilized by

a) peptide bonds b) van der Waals forces

c) dipole-dipole interactions d) hydrogen bonds

48. ____ are joined together by phosphodiester linkage between 5′ and 3′ carbon atoms of the [0.77]
pentose sugar.

a) Nucleosides b) Nucleic acids

c) Proteins d) Nucleotides
49. The combination of nitrogen – containing heterocyclic base with 1ꞌ position of sugar is [0.77]
known as

a) s – RNA b) nucleotide

c) m – RNA d) nucleoside
Section C
Attempt any 2 questions
50. Assertion (A): Among nitrogen halides NX3, the dipole moment is highest for NI3 and [0.77]
lowest for NF3.
Reason (R): Nitrogen halides NX3, have a trigonal pyramidal structure.

a) Both A and R are true and R is the b) Both A and R are true but R is not the
correct explanation of A. correct explanation of A.

c) A is true but R is false. d) A is false but R is true.

51. Match the items given in column I with that in column II: [0.77]
Column I Column II
(a) Collagen. (i) Globular Protein.

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 (b) Insulin. (ii) Nucleic Acid.
(c) RNA. (iii) Amino Acid.
(d) Glycine. (iv) Fibrous Protein.
52. Read the passage given below and answer the following questions: [38]
The properties of the solutions which depend only on the number of solute particles but not
on the nature of the solute are called colligative properties. Relative lowering in vapour
pressure is also an example of colligative properties.
For an experiment, sugar solution is prepared for which lowering in vapour pressure was
found to be 0.061 mm of Hg. (Vapour pressure of water at 20o C is 17.5 mm of Hg.)
i. Relative lowering of vapour pressure for the given solution is:
a. 0.00348
b. 0.061
c. 0.122
d. 1.75
ii. The vapour pressure (mm of Hg ) of solution will be:
a. 17.5
b. 0.61
c. 17.439
d. 0.00348
iii. Mole fraction of sugar in the solution is:
a. 0.00348
b. 0.9965
c. 0.061
d. 1.75
iv. If the weight of sugar taken is 5 g in 108 g of water then molar mass of sugar will be:
a. 358
b. 120
c. 240
d. 400
v. The vapour pressure (mm of Hg) of water at 293 K when 25 g of glucose is dissolved in 450
g of water is:
a. 17.2
b. 17.4
c. 17.120
d. 17.02

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