MOCK TEST-II ( 2021-22)

SUBJECT-CHEMISTRY (043)
CLASS-XII
Time allowed: 90 minutes Max. Marks: 35

General Instructions:
1. The Question Paper contains three sections.
2. Section A has 25 questions. Attempt any 20 questions.
3. Section B has 24 questions. Attempt any 20 questions.
4. Section C has 6 questions. Attempt any 5 questions.
5. All questions carry equal marks.
6. There is no negative marking.
SECTION-A
This section consists of 25 multiple choice questions with overall choice to attempt
any 20 questions. In case more than desirable number of questions are attempted,
ONLY first 20 will be considered for evaluation.

1). Helium gas is used for filling balloons for meteorological observations. This is
because:
(a). It is an inflammable gas
(b). It is a non-inflammable gas
(c). It is a light gas
(d). Both (b) and (c)
2). In which pair most efficient packing is present?
(a). hcp and bcc
(b). hcp and ccp
(c). bcc and ccp
(d). bcc and simple cubic cell
3). The number of moles of NaCl in 3 litres of 3 M solution is:
(a). 1
(b). 3
(c). 9
(d). 27
4). The most unsymmetrical and symmetrical systems are respectively:
(a). tetragonal, cubic
(b). triclinic, cubic
(c). rhombohedral, hexagonal
(d). orthorhombic, cubic

5). Which of the following alkyl halides undergoes the fastest SN1 reaction?

(a). Methyl chloride

(b). Ethyl chloride
(c). Isobutyl chloride
(d). tert-Butyl chloride.
6). The sequence of amino acids in each polypeptide chain in a protein is called:
(a). primary structure
(b). secondary structure
(c). tertiary structure
(d). quaternary structure
7). Lucas test can be used to distinguish between:
(a). Phenol and p-cresol
(b). Propanol and ethanol
(c). Butanol and 2-methylpropan-2-ol

(d). Ethanol and glycol

(c). Butanol and 2-methylpropan-2-ol
8). The correct order of acidity is:
a). HClO2< HClO<HClO3< HClO4
b). HClO4 < HClO3 < HClO2 < HClO
c). HClO< HClO2< HClO3 < HClO4
d). HClO4 < HClO2 < HClO3 < HClO
9). The compound that reacts fastest with Lucas reagent at room temperature is:
a). butan-1-ol
b). butan-2-ol
c). 2-methylpropan-1-ol
d). 2-methylpropan-2-ol
10). Which are the correct statements regarding defects in solids?
(i). Frenkel defect is usually favoured by a very small difference in the sizes of cation
and anion.
(ii). Frenkel defect is a dislocation defect.
iii). Trapping of an electron in the lattice leads to the formation of F-centre.
(iv). Schottky defect have no effect on the physical properties of solids. The correct
options are:
a). (i) and (ii)
b). (ii) and (iii)
c). (i) and (iv)
d) (ii) and (iv)
11). The correct sequence of boiling points of the compounds: n-butane,
ethoxyethane, pentanol and pentanal in increasing order is:
a). pentanol< n-butane< pentanal< ethoxyethane
b). n-butane < ethoxyethane < pentanol< pentanal
c). n-butane < pentanal< ethoxyethane < pentanol

d). n-butane < ethoxyethane < pentanal< pentanol

12). The value of Henry’s constant, KH
a). increases with increase in temperature
b). decreases with increase in temperature
c). remains constant
d). first increases, then decreases
13). Among the following the one that gives positive iodoform test upon reaction with
I2 and NaOH is:
(a). C6H5CH2CH2OH
(b). CH3CHCH2OH
CH3
(c). PhCH(OH)CH3
(d). CH3CH2CH(OH)CH2CH3
14). Which of the following compounds has a lone pair of electrons at the central
atom?
(a). H2S2O8
(b). H2S2O7
(c). H2SO3
(d). H2SO4
15). α-D(+) glucose and β-D(+) glucose are:
(a). enantiomers
(b). geometrical isomers
(c). epimers
(d). anomers
16). In SN2 reactions, the correct order of reactivity for the following compounds:
CH3Cl, CH3CH2Cl, (CH3)2CHCl and (CH3)3CCl is
(a). (CH3)2CHCl > CH3CH2Cl > CH3Cl > (CH3)3CCl

(b). CH3Cl > (CH3)2CHCl > CH3CH2Cl > (CH3)3CCl

(c). CH3Cl > CH3CH2Cl > (CH3)2CHCl > (CH3)3CCl
(d). CH3CH2Cl > CH3Cl > (CH3)2CHCl > (CH3)3CCl
17). The compound that does not undergo hydrolysis by SN1 mechanism is:
(a). CH2=CHCH2Cl
(b). C6H5Cl
(c). C6H5 CH2Cl
(d). C6H5CH(C6H5)Cl:
18. Suiphur dioxide acts as a
(a). reducing agent
(b). bleaching agent
(c). oxidising agent
(d). all of these
19). What is the vapour pressure of an aqueous solution containing 5% by mass of
urea (NH2CONH2) at 298K? The vapour pressure of water at 298K is 23.75 mm Hg.
(a). 22.275 mm Hg
(b). 22.375 mm Hg
(c). 23.275 mm Hg
(d). 23.375 mm Hg
[ Molar mass of urea (MB) = 60 gmol-1
Molar mass of water= 18 gmol-1,

wB= 5g, wA= 95 g,

Vapour pressure of water= 23.75g

PAₒ- PA/ PAₒ = wB. MA / wA. MB

Or, 23.75- PA/ 23.75 = 5X18/ 95X 60

Or, PA =23.375 mm ]
20). The decreasing order of boiling points of the following compounds are:
(a). H2O > H2Te > H2Se > H2S
(b). H2O > H2S > H2Se > H2Te
(c). H2Te > H2Se > H2S > H2O
(d). H2S > H2Se > H2Te > H2O
21). The anomeric carbon in D(+) glucose is
(a). C-1
(b). C-2
(c). C-5
(d). C-6
22). What is the mass of concentrated nitric acid that should be used to prepare 250
ml of 2.0 M HNO3 solution? [Given: concentration of HNO3 solution = 70%]
(a).70.0 g conc. HNO3
(b). 54.0 g conc. HNO3
(c). 45.0 g conc. HNO3
(d). 90.0 g conc. HNO3
[ Molarity = WX1000/ MwX Vsoln (ml)
Or, 2= W/63X 1000/250 or, w= 63/2
Mass of acidX 70/100= 63/2
Or, Mass of acid= 45 g ]
23). Which of the following reagents may be used to distinguish between phenol and
benzoic acid?
(a). Neutral FeCl3
(b). Aqueous NaOH
(c). Tollen’s reagent
(d). Molisch’s reagent

24). The basic character of the hydrides of Group 15 elements decreases in the order:
(a). SbH3> PH3> AsH3> NH3
(b). SbH3> AsH3> PH3> NH3
(c). NH3> SbH3> PH3> AsH3
(d). NH3>PH3> AsH3> SbH3

25). For an aqueous solution, freezing point is -0.186ₒC. Elevation of the boiling point
of the same solution is [K =1.86ₒCmol-1kg and K =0.512ₒCmol-1kg]:
f b

(a). 0.186ₒC

(b). 0.0512ₒC

(c). 1.86ₒC

ₒ
(d). 5.12 C

SECTION-B
This section consists of 24 multiple choice questions with overall choice to attempt
any 20 questions. In case more than desirable number of questions are attempted,
ONLY first 20 will be considered for evaluation.

26). The increase in the temperature of the aqueous solution will result in its:
(a). Molarity to increase
(b). Molarity to decrease
(c). Mole fraction to increase
(d). Mass % to increase
27). Chlorobenzene is formed by reaction of chlorine with benzene in the presence of
AlCl3. Which of the following species attacks the benzene ring in this reaction?

(a). Cl–
(b). Cl+
(c). AlCl3
(d). [AlCl4]−
28). The ion that cannot undergo disproportionation is:
(a). ClO4-
(b). ClO3-
(c). ClO2-
(d). ClO-

29). Curdling of milk is an example of:

(a). breaking of peptide linkage
(b). hydrolysis of lactose
(c). breaking of protein into amino acids
(d). denaturation of protein
30). The correct IUPAC name for diethylbromomethane is:
(a). 1-bromo-1,1-diethoxyethane
(b). 3-bromopentane
(c). 1-bromo-1-ethylpropane
(d). 1-bromopentane

31). NCl3 is hydrolysed but NF3 is not because:

(a). of difference in their reactivity due to the difference in dipole moment values
(b). NCl3 is polar while NF3 is not
(c). of the presence of vacant d-orbitals on chlorine which are absent in case of NF3
(d). NCl3 shows dipole-dipole attraction with water
32). AB crystallizes in a bcc lattice with edge length 387pm. The distance between the
two oppositely charged ions in the lattice is:
(a). 150pm
(b). 200pm
(c). 300pm
(d). 335pm

33). In which of the following molecules, carbon atom marked with asterisk (*) is
asymmetric?

(i). H (ii) D (iii). H

C* C* C* CH 3
I Cl I Cl
Br Br OH C2H5

(iv). H

C*
H CH3
C2 H5

(a). (i), (ii), (iii), (iv)

(b). (i), (ii), (iii)
(c). (ii), (iii), (iv)
(d). (i), (iii), (iv)

34). Which of the following interhalogens is not known?

(a). IF7
(b). FCl3
(c). ClF5
(d). BrF3

35) . The concentration of cane sugar solution which is isotonic with 0.86%
solution of urea(60g/mol) is:
(a). 4.9%
(b). 3%
(c). 5.8%
(d). 8.4%
36). Which of the following is not a protein?
(a). wool
(b). nail
(c). hair
(d). gene

37). A brown ring is formed in the ring test for NO3-

ion. It is due to the formation of:
(a) [Fe(H2O)5(NO)]2+
(b) FeSO4.NO2.
(c) [Fe(H2O)4(NO)2]2+
(d) FeSO4.HNO3.

38). Total volume of atoms present in a face-centered cubic unit cell of a metal is (r is
atomic radius):
(a). 24/3 πr3
(b). 12/3 πr3
(c). 16/3 πr3
(d). 20/3 πr3

39). A gas has a characteristic fishy odour and blue colour. It restores the colour of
blackened lead paintings. It also acts as bleaching agent in the absence of moisture.
The gas is:
(a). O2
(b). SO2
(c). Cl2
(d). O3

40. Aspirin is an acetylation product of

(a). p-dihydroxybenzene
(b). o-hydroxybenzoic acid
(c). o-dihydroxybenzoic acid
(d). m-hydroxybenzoic acid

41). Identify Z in the sequence of reactions:

HBr/H2O2 C2H5ONa
CH3CH2CH=CH2 Y Z

(a). CH3-(CH2)3-O-CH2CH3
(b). CH3-(CH2)2-O-CH2CH3
(c). CH3-(CH2)4-O-CH3

(d). CH3-CH2-CH(CH3)-O-CH2CH3

42). Which of the following properties does not correspond to the order:
HI < HBr < HCl < HF
(a). Thermal stability
(b). Reducing power
(c). Ionic character
(d). Dipole moment

43). During the dehydration of alcohols to alkenes by heating with conc. H 2SO4, the
initiating step is:
(a). elimination of water
(b). protonation of alcohol molecule
(c). formation of ester
(d). formation of carbocation

44). Grignard reagent is not prepared in aqueous medium but prepared in ether
medium because:
(a). it is insoluble in water
(b). the reagent is highly reactive in ether
(c). the reagent reacts with water
(d). the reagent becomes inactive in water.

Question No. 45 to 49 consist of two statements – Assertion (A) and Reason (R).
Answer these questions selecting the appropriate option given below.

(a). Both A and R are true and R is the correct explanation of A.

(b). Both A and R are true and R is not the correct explanation of A.
(c). A is true but R is false.
(d). A is false but R is true.

45). Assertion: Noble gases have large negative values of electron gain enthalpy.
Reason: Noble gases have stable electronic configuration.

46). Assertion: KCN reacts with methyl chloride to give methyl isocyanide.
Reason: CN- is an ambident nucleophile.

47). Assertion: Aquatic species are more comfortable in cold water than in warm
water.
Reason: KH values for both N2 and O2 decrease with increase of temperature.

48). Assertion: Fluorine has high reactivity.

Reason: F_F bond has low bond dissociation enthalpy.

49). Assertion: Acetone-chloroform mixture shows negative deviation from Raoult’s

law.
Reason: H-bonding between acetone and chloroform is stronger than that between
acetone-acetone and chloroform-chloroform.

SECTION-C
This section consists of 6 multiple choice questions with an overall choice to attempt
any 5. In case more than desirable number of questions are attempted, ONLY first 5
will be considered for evaluation.
50). Match the following:

COLUMN I COLUMN II
(i). Keratin (A). α amino acid
(ii). Sucrose (B). Fibrous protein
(iii). Glycine (C). 51 amino acids
(iv). Insulin (D). Disaccharide
(v). Fructose

Which of the following is the best matched options?

(a). i-C, ii-B, iii-A, v-D
(b). i-C, ii-A, iii-D, iv-B
(c). i-B, ii-D, iii-A, iv-C
(d). i-A, ii-B, iii-C, iv-D

51). Which of the following analogies are correct?

(a). F: 1s22s22p5 :: Ar : 1s22s22p63s23p6
(b). Bromine: greenish yellow :: Chlorine: red

(c). Noble gases: Negative electron gain enthalpy :: Halogens: positive electron gain
enthalpy
(d). Nitrogen: can form dπ-pπ bond :: Phosphorous: can not form dπ-dπ bond

52). Which of the following analogies are correct?

(a). Finkelstein reaction: Fluoroalkanes :: Swarts reaction: Iodoalkanes
(b). Benzyl carbocation: resonance stabilised :: Phenyl carbocation: not resonance
stabilised.
(c). SN1: inversion of configuration :: SN2: racimisation.
(d). Bromobutane: lower boiling point :: 2-bromo-2-methylpropane: higher boiling
point

CASE1: Read the passage given below and answer the following questions 53-55.

Point defects are the irregularities from ideal arrangement around a point or an atom
in a crystalline substance. In ionic solids, Frenkel defect is shown when the smaller
ion is dislocated from its normal site while Schottky defect is basically a vacancy
defect.
 Fig [ I ]

Fig [ II ]
53). The defects shown by ionic compounds as in Fig [ I ] and Fig [ II ] are called
respectively as:
(a). Schottky, Frenkel
(b). Frenkel, Schottky
(c). Electronic defects, F-centre
(d). None of these.
54). What is the effect of these defects on the density of the solid?
(a). Increases, increases
(b). Decreases, decreases
(c). No change, decreases
(d). Decreases, no change

55). Which ionic compound can show defect as shown in Fig [ II ]?

(a). ZnS
(b). AgCl
(c). NaCl
(d). None of these.