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Case study of the use of API 581 on HK and HP material furnace tubes
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CASE STUDY OF THE USE OF API 581 ON HK AND HP MATERIAL FURNACE TUBES
Soudabeh.A.Noori
Professor John Price,
Mechanical Engineering, Monash University, PO Box 197, Caulfield East, Victoria, 3145
john.price@eng.monash.edu.au.
Risk in the formal definition is the product of In this study we are examining some typical reformer
consequence and frequency. The failure of pressure tubes. Reformer tubes are generally made from cast creep
equipment can have several undesirable consequences resistant austenitic steel HK grade (25 Cr, 20 Ni, 0.4 C) or
such as fires, toxic releases, major environmental damage HP grade (26 Cr, 35 Ni, 0.4 C). Although the furnace
and business interruption losses. Given this it should be tubes are usually designed for a normal life of 100,000 h
the intention that not only the frequency of failure but also (11.4 years), their actual service life, however, varies from
the consequence of failures should be reduced by 30,000 to 180,000 h, which is 5 to 20 years depending on
inspection/maintenance activities. the service conditions and the quality of materials.[1]
1
Table 1
Process and Design Data of HK and HP Furnace Tubes
Material HK40 HP
Wall Thickness mm 14 15
Design Pressure MPa 1.73 1.68
Inside Diameter mm 110 110
Design Temperature ºC 925 1015
Actual Tube Metal Temperature ºC 905 905
Allow Strength MPa 13.4*0.8(T44) 9.8*0.8(T64)
Actual Tube Stress MPa 5.49 5.17
P in MPa 1.24 1.24
T in ºC 557 557
2
Table 2
Larson –Miller Parameter and Long-Term Failure Probability
result, by considering the Larson-Miller curve of HK and 530. Here LM delta is calculated by using mean and
HP, it was established that elastic metal temperature limit
minimum Larson-Miller curves in API 530 and also the
could be around 600 ºC. Hence the determination of long-
term creep is necessary because T elas is less than TMT. manufacture’s data sheet. To calculate Mean Larson-
Miller parameter for HP and HK Microsoft Excel ‘Least-
“The elastic limit (proportional limit) is the greatest Square Regression method’ is used. The results for HK
load a material can withstand and still spring back to its and HP were approximately same. Analysis of this data
original shape when the load is removed.”[4] Table J-5 illustrates that HP and HK have TMSF less than one for
API 581 contains the elastic stress limit for creep different stresses.
consideration for specified materials. This table does not
include the tube materials of this case study and the elastic API 581 introduces credits based on inspection
stress limit for HK and HP materials was calculated by effectiveness to adjust TMSF LT . By considering,
reference to data published (in advertising literature) by
inspection category of ‘usually effective’ which is defined
the manufacturers. Elastic stress limit was estimated to be
as “Visual inspection, UT thickness measurements of all
4 to 6 MPa at the design temperature limit. Table 1 shows
tubes” and N (number of inspections) equal to 1, TMSF is
that tube actual stress could be more than elastic stress
adjusted for HP and HK and is about 0.2485. Results of
limit. From this it is evident that long-term creep should
long- term creep analysis are shown on Table 2 as below.
be considered for furnace tubes.
3.1.2 Determination of short -term failure
3.1.1 Determination of Long Term Creep probability
Failure Probability
3
API 581 states that the temperature factor can be up Table 3
to 149ºC more than design tube metal temperature for 10- Short term over heating Failure Factor and TMSF ST
1000 hours and it depends on plant history of over- without considering online monitoring
heating, heavy coking, operation or burner control
problems. Table 2 shows failure factor and TMSF ST for Over- Over- heating FF ST TMSF ST
over-heating at 100, 50 and 10ºC for one day, one week heating
Temperature C
and one month without considering online monitoring. For Period
overheating around 10ºC for one month the TMSF ST is One day 100 17 Very high
50 0.4 0.82
more than 10. By using on-line monitoring method 10 0.019 0.56
consisting of daily visual and burner adjustment by
One week 100 330 Very high
operators, TMSF ST will be reduced to 0.24. 50 7.40 906
10 0.35 0.78
In this study, there was not any organized historical One 100 2923 -
data to provide information on plant over-heating month
problems or unpredicted conditions. It is assumed 50 65 Very high
overheating up to 40ºC for 20-30 hours might be happen 10 3.14 12
by operating condition or human error. Short-term
technical module sub-factor (TMSF ST ), in this range is
less or equal to 1. API 581 states that ‘On-line To calculate release rate, initially it is identified that
release occurs in gas form. Gas flows through an orifice at
Monitoring Factor’ should be used to adjust TMSF ST . sonic or subsonic velocity. Equation (9) is used to find out
Table J-9 in Appendix J is used to calculate ‘On-line the nature of gas flow. The result from equation (9) shows
Monitoring Factor’. If the on-line monitoring method is P trans =0.17 MPa. As process data shows upstream
daily visual and burner adjustment by operation, TMSF ST pressure is equal to 1.24 MPa, which is greater than
is reduced to 0.02. P trans , so gas discharge at sonic velocity.
3.2 Consequence Analysis
k
Having examined likelihood of failure as represented k 1 k 1
by the TMSF and its effects, the other half of risk analysis P trans =P a ( ) (9)
is consequence analysis. Consequence analysis starts with 2
determination of representative fluid and its properties, Release rate is calculated for each hole size by using
calculation of possible release rate, identification release equation (10)
type and phase after release. Finally, release mass is
1
determined for each of the hole sizes to calculate k 1 2
flammable and toxic consequence area. KM g c 2 k 1
W g (sonic) = C d AP
Consequence analysis of furnace tube does not
RT 144 K 1
considered vapour cloud explosion (“VCE”), fireball or
flash fire outcomes because of firebox as a source of
ignition and approval of continuous model for furnaces
API 581 models all releases as an immediate or
release, which decrease the possibility of cloud of vapour continuous form and has established a simplified method
over 10000 lb.
for modeling release by identifying hole size and amount
of release in 3 minutes. In this study amount of release in
At first, it should be noted that, it is difficult to find
3 minuets was calculated to confirm the type of release
out all necessary data of a mixture for RBI analysis.
and it was found to be less than 10,000 lb in 3 minutes.
Reducing gas is not a pure material. So it is recommended This supports Appendix J the release type for furnace
by API 581 to choose one material base on material’s tubes is in continuous form. We have calculated release
properties in mixture. API 581 recommends selecting a
rates and amount of release in 3 minutes for each hole size
representative fluid with a lower normal boiling point
for Hydrogen are shown on Table 5.
(“NBP”) than the fluid being considered. In this case, the
hydrogen has the highest percentage in reducing gas, with
lowest NBP in this mixture, so after elimination of inert
materials as an alternative for modeling. The
representative fluid here is modeled as hydrogen
representative fluid properties are shown on Table 4.
4
Table 4
Reducing Gas Composition and Properties for Radiant and Convection Section
2 3
*C p =A+BT+CT +DT , K=C p /C p -R, R=1.987BTU/(lb mole)( F)
**Property mix = xi * Property i , AIT = auto ignition temperature, NBP =normal boiling point
Finally, to determine release, the inventory category Considering toxic consequences in this case, it was
is found from Table B-3 appendix B API 581. The necessary to consider that Hydrogen Sulphide is very
inventory category is B, so 5,000 lb as an inventory is toxic by inhalation and may cause damaging effects to the
used to calculate consequence area. In addition to nervous system. Reducing gas includes 25 ppmv H2S.
inventory data the analyst should be notice to The exposure limit value for H2S is identified from the
representative fluid auto ignition temperature to calculate Material Safety Data Sheet (“MSDS”) to be 10 ppm.
the consequence area of flammable and toxic From this it is found that Hydrogen Sulphide may cause
consequence. In this case the release is in continuous form toxic effects after release. Release rate and duration was
and auto ignition temperature of Hydrogen is 400ºC. API used to determine consequence area for this toxic gas. The
581 states that auto-ignition is not likely if process results of consequence analysis are shown in Table 7.
temperature is less than auto-ignition temperature plus
27 C . From the process data, it is found that in this case Table 5
auto-ignition is likely. Release Rates for Each Hole Size for Hydrogen
5
Table 6
Total release mass and consequence area for each hole size
2
X= total release rate or mass, A= area ft Hydrogen
Continuous release Auto ignition likely
Area of Equipment A*=1146X a Area of Fatalities A=3072X a
X=0.84 X correct =0.21 A=240.66 A correct =48.13 X=0.84 X correct =0.21 A=645.12 A correct =129.02
X=13.44 A=3850.56 X=15.5 A=10321
X=30.25 X correct =3.36 A=8666.62 A correct =770.11 X=35.25 X correct =3.36 A=23232 A correct =2064.36
X correct =7.56 A correct =1733.3 X correct =7.56 A correct =4646.4
Probabilities of outcome Processed above AIT
Ignition Jet fire Flash fire VCE
0.9 0.9 Negligible Negligible
Table 7
Consequence Analysis for Each hole Size
Table 9
Summary of RBI Results
6
Table 8
Inspection Methods and Intervals for Furnace Tubes based on TMSF
Inspection Intervals
3.2.1.1.1 Inspection 3.2.1.1.2 Nature of inspection
20 Years Highly Effective
10 Years Usually Effective
5 Years Fairly Effective
7
Likelihood
5
MH MH MH H H
4
(I) Flammable Consequence (equipment)
M M MH MH H (II) Flammable Consequence (facilities)
3 (III) Toxic Consequence category
(IV) Qualitative RBI Result
L L M MH H
2 M
L L (IV) M MH
1 M M MH
L L (I) (II) (III)
A B C D E
Consequence Category
8
7 CONCLUSIONS 9 NOTATION
We have applied API 581 to a furnace tube example. 2
A = cross-section area (in )
The furnace tubes considered were not listed in the code AIT = auto ignition temperature
and API 581 was quite difficult to apply. In the case C= Larson-Miller constant
studied, the main result is that TMSF is less than 10 for a
very long period so that the only inspections required were C d =discharge coefficient (for gas C d = 0.85 to l)
“Highly Effective” inspections every 20 years. Since the FF= Failure factor
creep life calculations are generally done for 20 years g c = Conversion factor from lb f to lb m =32.2 lb m -ft/
operation this means that even these moderately high risk 2
tubes may never be inspected. lb f -sec
K = Cp/Cv,= usually 1.4 for air
In practice this inspection schedule seems very optimistic, LMP= Larson-Miller parameter
20 years is a long time not to inspect a furnace operating Lm = Larson Miller Parameter at the current operating
in the creep range. The resulting inspections proposed are conditions
not adequately defined so that we may not be confident
LM delta = Average difference between mean and
that we are conducting “Highly Effective” inspections.
minimum Larson-Miller curves in API 530
LM avg = Mean Larson-Miller parameter
8 REFERENCES
M = MW=molecular weight (lb/lbmol)
1. Ashok Kumar Ray, S.K.S., Yogendra Nath NBP =normal boiling point
Tiwari, Jagannathan Swaminathan, Gautam Das,
P trans = transition pressure (psia)
Satyabrata Chaudhuri, Raghubir Singh, Analysis
of failed reformer tubes. Engineering Failure P = upstream pressure (psia)
Analysis, 2003. 10: p. 351-362. Pa = atmospheric pressure (psia),
2. American Petroleum Institute, Risk-Based R = gas constant (10.73 ft3-psia/lb-molºR)
Inspection, Base Resource Document, API 581, T = upstream temperature (ºR)
API Publishing Services, Washington, May TMT = tube metal temperature
2000. TMSF LT = Long term technical module sub-factor
3. American Petroleum Institute, Calculation of
TMSF ST = Short term technical module sub-factor
Heater-Tube Thickness in Petroleum Refineries.
API 530, S., API Publishing Services, t oh =Time exposure to over-heating
Washington, October 1996.
4. E.Neely., Practical metallurgy and materials of W g (sonic) = gas discharge rate, sonic flow (lbs/sec)
industry. 2003, Prentice Hall. Ohio, p 449.
5. Valbuena, R.R., L.C.Kaley, and M.L. Wechsler,
Inspection Methodology Designed to Optimize
Budgets. Materials Performance, 1998. 37(2): p.
89.
6. Robert C. Reid, J.M. and T.K.S. Prausnitz,
Properties of gases and liquids. Third ed. 1977,
New York: McGraw-Hill. 688.
7. M.Zuo, S.C., Y.Nonaka, Fitting creep-rupture
life distribution using accelerated life testing
data. Transactions of the ASME, 2000. 122: p.
482-487.
8. LeMay, L., Principles of mechanical metallurgy.
1983, New York: Elsevier
9. Farmer F R, Reactor safety and siting: a proposed
risk criterion, Nuclear Safety, 8(6), December
1967, pp 539-548
10. Victorian Work Cover Authority, The
requirements for “demonstration” under the
Occupational Health and Safety (Major Hazard
Facilities) Regulation, Guidance Note 16,
September 2001.