1.

The vapor pressure of benzene is found to obey the empirical equation:

2
3229.86 K 118345 K
ln ( P/torr )=16.725− −
T T2
From 298.2 K to its normal boiling point 353.24K. Given that the molar enthalpy of vaporization at
353.24K is 30.8 KJ mol-1, and that the molar volume of liquid benzene 353.24K at is 96.0 cm 3.mol-
1
, use the above equation to determine the molar volume of the vapor at its equilibrium pressure at
353.24K and compare this value with the ideal-gas value.
2. Use the following data to estimate the normal (standard) boiling point and the molar enthalpy of
vaporization of lead.
T/K 1500 1600 1700 1800 1900
P/torr 19.72 48.48 107.2 217.7 408.2

T/K P/torr 1/T LnP

1500 19.72 0.00066667 2.98163335
1600 48.48 0.000625 3.88115134
1700 107.2 0.00058824 4.67469625
1800 217.7 0.00055556 5.38311797
1900 408.2 0.00052632 6.01175725

6
f(x) = − 21597.9333873696 x + 17.3801798574755
5

4
Ln (P)

0
0.00052 0.00054 0.00056 0.00058 0.0006 0.00062 0.00064 0.00066 0.00068
1/T
3. The vapor pressure of solid iodine is given by
−8090.0 K
ln ( P/atm ) = −2.013 ln ( T / K ) +32.908
T
Use this equation to calculate the normal sublimation temperature and the molar enthalpy of
sublimation of I2 at 25°C. The experimental value ∆subH°m of is 62.23 kJ.mol-1.

4. Consider the phase change

C ( graphite ) ⇌ C(diamond)
Given that
ΔrG∘ / J mol−1 = 1895 + 3.363T

Calculate ΔrH∘ and ΔrS∘. Calcula the pressure at which diamond and graphite are in equilibrium
with each other at 25∘C. Take the density of diamond and graphite to be 3.51 g ⋅ cm−3 and 2.25 g ⋅
cm−3, respectively. Assume that both diamond and graphite are imcompressible.