Problem Set 3

Titration

1. Describe the preparation of

a. 600 mL of a solution that is 0.0825 M in K+ starting with solid K4Fe(CN)6
b. 9.0L of a solution that is 60.0 ppm in Na+ , starting with solid Na2SO4.
c. 250 m; of 20% aqueous acetone

2. A 0.1752 g sample pf primary-standard-grade AgNO3 was dissolved in 502.3 mL of

distilled water. Calculate the molarity of Ag+ in this solution.

3. A 0.3367 g sample of primary-standard-grade Na2CO3 required 28.66 mL of H2SO4

solution to reach the endpoint in the reaction

CO32- + 2H+ -> H2O + CO2 (g)

What is the molarity of H2SO4?